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O fato de que tais funes estatais existem d origem a uma das estratgias mais
importantes para a anlise termodinmica dos processos complicados que so
susceptveis de serem encontrados no mundo real da cincia e da tecnologia.
Teorema da equipartio
da energia:
Teorema: Molculas em equilbrio trmico tem a
mesma energia mdia associada com cada grau de
liberdade independente
In an ideal gas, the molecules or atoms do not interact. Hence, the internal
energy, U, can only be a function of temperature, T.
When the gas expands into the other compartments : no heat is exchanged
with
the environments and no work is done on the system or surrounding. Thus,
the
internal energy is unchanged, U= 0 and the initial and final temperature of
the gas are the same, Ti=Tf.
So the final states of the gas after expansion into all three compartments
are the same for both processes. Since the entropy is a state function, the
entropy change is path independent and given by the entropy difference
between the initial and final state. The entropy change is the same for both
processes