Vaporizier

kj kj
C p i propylalcohol =145 . k =2.413 . k
kmol kg

KJ
C P WATER=4.179 .K
KG

For water:

.. T C =508.3 K

.. T b=394.399 K

.. H f =39838 Kj/kmol

0.38

H vap ,H O = H f
2
[[ T c T
T c T B ]]
0.38

H vap ,H O =39838
2
[[ 508.3 K 382.5 K
508.3 K 394.399 K ]]

kj kj
H vap ,H O =41370.970 =2296.473
2
kmol kg

For IPA

.. T C =647.3 k K

.. T b=375 K

.. H f =40683 Kj /kmol
 0.38

H vap ,IPA =40683

[[
647.3382.5
647.3375 ]]
kj kj
H vap ,IPA =40253.505 =669.82
kmol kg

Q=m i propyl alcohol C p ipropyl alcohol T + mwater C P , water

T +mwater H vapor , water +mIPA H vap , IPA

Q=15120.154 2.413 ( 109.532.83 ) +2232.293 2296.473

+15120.155 669.82

Q=9.652 10 6

Molten salt: T =20

Q=m C p ,molten salt T

kj
9.652 106 kj=1.56 m 20
kg

m=309.358 tons

Pre heater

kj kj
T ref =109.5 C p i propyl alcohol =2.468 . k .. C pwater =2.019 . k
kg kg
 Q=m C P , molten salt T

kj
1.845 106 kj=1.56 m 150
kg

m=7.885 ton

Reactor
325
H ,IPA =272.29+ (32.427+1.886 101 T + 6.405 105 T 29.261 108 T 3) T
25

H ,IPA =272.29+20.104=252.186 kj /kg

325
H out , IPA =272.29+ (32.427+1.886 101 T +6.405 105 T 29.261 108 T 3 ) T
25

H out , IPA =249.691 kj/kg

325
H out , IPA =272.29+ (32.427+1.886 101 T +6.405 105 T 29.261 108 T 3 ) T
25

325
H out , acetone =216.685+ (71.96+20.2 102 T +12.78 105 T 2+ 34.76 108 T 3 )T
25

H out , acetone ==182.745 kj/kmol

325
H out , H = (28.84 103 +0.00765 105 T + 0.3288 108 T 20.8698 1012 T 3 ) T
2
25
 H out , H =9.466 kj/kmol
2

kj 272.29 kj
(
H 0r = 216.685
kmol
)( kmol )

55.605 kj
H 0r =
kmol

226.44 kmol 55.605 kj/kmol

Hr= =12591.196 kj
1

Q= ni H i ni H i + H r
out

25.16 (249.691 ) +226.44 (182.745 ) +226.44 ( 9.466 )

Q=

[251.6 (252.186 ) ] +12591.196=30521.67 kj

Molten salt :

C p ( molten salt between 360 410 )=1.56 kj/kg

Q=m C p ,molten salt T

kj
30521.67 kj=1.56 m 50=391.300 kg /hr
kg

Cooler
T ref =94.7

kj
C P , H =12.608 .k
2
kg
 kj
C P , water=2.035 .k
kg

kj
C P , IPA=2.536 .k
kg

kj
C P , acetone=1.896 .k
kg

Q=[ ( mH C p . H ) + ( mwater C p . water ) + ( mIPA C p . IPA ) + ( macetone C p .acetone ) ]

2 2

( 455.144 12.608 ) + ( 2232.293 2.035 ) + ( 1512.015 2.536 )

Q=

6
+(13151.635 1.896)(94.7350) =10.123 10 kj

Water:
T For the water ( 3525 )=20
kj
C p , water =4.179
kg

Q=m C p ,water T

kj
10.123 106 kj=4.179 m20
kg

m=121.117 ton/hr
condenser

B
log p =A p mm Hg
C+T dp ;

Assumption PT =1.5 1125 mmHg
 y acetone P T y water PT y IPA PT y H PT
+ + + 2
=1
Pacetone T dp Pwater T dp P IPA T dp PH T dp
2

For acetone A=7.02447

B=1161
C=224

For water A=7.02447

B=1161
C=224
For IPA : A=8.37895
B=1788.02
C=227.438
P= X A P A ( Tbp )+ X B PBA ( Tbp )+

m C P T + m H f =Q tot

For acetone
At 94.7 1.5
kj
c p ,acetone =1.297 .k
kg

Qacetone=mC P T

Qacetone=13151.635 kg ( 1.297
kg
kj
.k)
 3
[ ( 81+273.15 ) (94.7 +273.15) ] =223.960 10

0.38

H vap ,H O = H f
2
[[ T c T
T c T B ]]
H acetone =29140 kj/kmol

T c =508.1k

T B=341.5 K

0.38
H vap =29140 [
508.1k 354 k
508.1 k341.5 k ] =28289.029
kj
kg
=487.07
kj
kg

For IPA

At 94.7 1.5

1.761 kj
C IPA= .k
kg

kj
QIPA =1512.015 kg 1.761 ( kg )
. k ( 354.15367.85 ) =36.468 103 kj

0.38

H vap = H f
[[ T c T
T c T B ]]
kj
H f , IPA=39858
kmol
 T c =508.3 K

T b=366.6 k

0.38
H vap =39858 [ 508.3 k354 k
508.3 k366.6 k ] =41169.35
kj
kg
=685.128
kj
kg

For water

At 94.7 1.5
kj
C p , water =1.898 .k
kg

Qwater =2232.293 kg ( 1.898

kg
kj
. k ) ( 354.15367.85 )=58.045 10 kj 3

0.38

H vap = H f
[[ T c T
T c T B ]]
kj
H f ,water =40683
kg

T c =647.3 k

T b=385.186 k

0.38
H vap =40683 [
647.3 k 354 k
647.3 k 385.186 k ] =4 2442.056
kj
kg
=2356.845
kj
kg
For hydrogen

At 94.7 1.5

13.225 kj
Cp, H = .k
2
kg

kj
QH =455.144 kg 13.225
2 ( kg )
. k ( 354.15367.85 )=82.464 103 kj

mi C p , i T + mi H vap ,i =12.3 106 kj

i i

Water:
T for the water =( 3515 ) =20

C p , water =4.182 kj/kg

Q=m C P , water T

kj
682691.799 kj=4.182 m 20
kg

m=147.058 ton/hr

scrubber
Q =Q

T ref =25

455.144 14.419 ( 8125 )+3528.708 1.259 ( 8125 ) +169.107

4.193 ( 8125 )+117.307 1.716 (8125)

42228.319=18777.661+(T =25) 7551.14 9

T =28.1