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Inorganic
Chemistry
Group 2
2
Thermal decomposition Observation & Equations
Why does the nitrates, carbonates, hydroxides and sulphates decompose to oxides
upon heating?
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2.3 Solubility of sulphates of Group 2 elements
Step 1: The ions are separated to form free gaseous ions. This involves the
breaking of the ionic bonds.
MSO4 (s) M2+(g) + SO42 (g)
Step 2: The free gaseous ions are hydrated by water to form hydrated ions.
M2+(g) + SO42 (g) M2+(aq) + SO42 (aq)
is negative/ exothermic The compound is soluble.
is positive/ endothermic The compound is insoluble.
The more negative the value of , the more soluble the
salt.
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Solubility of Group 2 sulphates when going down the group:
Solubility of Group 2 hydroxides, M(OH)2 and oxides (MO) when going down the group:
SrO/
Soluble You would have to refer to p5 in Module 1 if you do
Sr(OH)2 not remember the acid-base properties of oxides.
The above reason only let you have 1 mark. If more
BaO/
Soluble marks is allocated, you might want to explain this
Ba(OH)2 phenomenone with: Lattice Energy, H hydration and
H solution
5
2.4 Anomalous behaviour of Beryllium (Be)
Beryllium tends to form covalent compounds (e.g.: BeCl2), or ionic compounds with
significant amount of covalent character.
Reason 2:
Beryllium has high effective nuclear charge (Zeff2) The two valence electrons are
tightly held.
As a result, beryllium has high 1st IE & 2nd IE Not readily ionized to form Be2+.
Reason 3:
Be2+ ion is very small Very high charge density Strong polarising power Be2+ ion
can distort the electron cloud of neighbouring anions Gives rise to covalent
character to beryllium salts.
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BeO & Be(OH)2 are AMPHOTERIC
(not basic like other Group 2 oxides & hydroxides).
BeO(s) + 2H+(aq) Be2+(aq) + H2O(l)
BeO(s) + 2OH(aq) + H2O(l) [Be(OH)42](aq)
BeCl2 is covalent.
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Form complexes:
e.g. BeCl2.2NH3
[Be(OH)4]2
BeF42
Because:
Be2+ has high charge density
Be2+ is electron deficient
Be2+ could form coordinate bonds with ligands
Hybridisation
sp3 hybridization
It is when certain pairs of diagonally adjacent elements in Period 2 & Period 3 exhibit
the same chemical properties.
8
Both Beryllium & Aluminium:
Form oxides & hydroxides that are amphoteric
Compound Uses
MgSO4 As laxative