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  • تصحيح البكالوريا 2016sm PDF

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    الغزيزال الحسن EL GHZIZAL Hassane
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    115 views2 pages

    تصحيح البكالوريا 2016sm PDF

    Uploaded by

    الغزيزال الحسن EL GHZIZAL Hassane

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 2

    2016

    :
    ) (2 pH = 10,4 :
    (122 :
    ( pKa1= 9,2 (1
    ( : 1-1 S1 . C1 = 10-2 mol.L-1
    pH1 = 10,6
    100 :
    ( 111 :
    A AB
    )NH3(aq) + H2O(l HO(aq) +

    )NH4+(aq) (0,25
    xf NH 4+ (1-1-2
    = 2 =
    xmax C2
    NH 4+
    = NH 4+ + [ HN 3 ]2 = C2 2 2
    2 NH 4+ + [ HN 3 ]2
    2

    ) 2 = ( NH 4+
    2

    pH2 = 10,4

    xf HO .V1 HO
    f f
    = 1 = =
    xmax C1.V1 C1
    Ke
    = K e = HO . H 3O + HO
    f f f H 3O +
    f
    2 = 0, 06 = 6 0 0
    Ke 1 K e .10+ pH1
    (123 1 2 = 1 . 1 =
    H 3O + C1 C1
    f
    2 1 S2 S1
    10 .1010,6
    14
    = A.N : 1 4.102 = 4 0 0
    (2 . 102 (113
    (21 :
    ) NH 3( aq ) + CH 3 NH + 3( aq ) NH 4(+ aq ) + CH 3 NH 2( aq

    (22
    2
    NH +
    CH 3 NH 2( aq ) [ HO(aq ) ]e .[ NH 4+ ( aq ) ]e [ HO(aq ) ]e 2 ) ( C1.1
    ) 4( aq
    e e =K = =
    ='K [ NH 3( aq ) ]e C1 [ HO(aq ) ]e C1 C1. 1
    NH 3( aq ) CH 3 NH + 3( aq )
    e e 2 2 2
    C1. )10 (0.04
    CH 3 NH 2( aq ) H 3O + ( aq ) NH 4(+ aq ) =K 1
    = 1, 67.105
    = e e
    . e 1 1 1 0.04
    CH 3 NH + 3( aq ) NH 3( aq ) . H 3O + ( aq )
    e e e (12 S2 pH2 = 10,4
    K A2 10 10.4
    (112 :
    = = 3,16.102
    K A1 1, 67.105
    (23 ...... = NH 4(+ aq ) = CH 3 NH 2( aq )
    e e
    2016

    nt ( H 3O(+aq ) ) = V . H 3O(+aq ) + 4 x = V . H 3O(+aq ) 2 H 2O( l ) O2( g ) + 4 H (+aq ) + 4e


    0 t
    6 H 2O( l ) O2( g ) + 4 H 3O(+aq ) + 4e
    4 x = V . H 3O(+aq ) V . H 3O(+aq ) = V .(10 pHt 10 pH0 )
    t 0

    V CV xe C xe C
    NH 3( aq ) = CH 3 NH + 3( aq ) = = = NH 4(+ aq )
    x = .(10 pHt 10 pH0 ) e e 2V 2 2V 2 e
    4 2
    NH 4(+ aq ) CH 3 NH 2( aq ) NH 4(+ aq )
    pH1 =1,5 t1 ( 3 K'= e e
    = e

    NH 3( aq ) CH 3 NH 3( aq )
    +
    CH 3 NH + 3( aq )
    2

    6 H 2O(l ) O2( g ) + 4 H 3O(+aq ) + 4e (1 e e e


    2
    NH 4(+ aq ) C
    I .(t1 t0 ) I .t1 K'= K '( NH 4(+ aq ) ) = NH 4(+ aq )
    e
    n1 (e ) = 4 x1 = = = 4 x1 = V .(10 pHt 10 pH 0 ) C
    ( NH 4( aq ) )
    + 2 2 e e

    F F 2 e

    V .F C
    K '. = NH 4(+ aq ) (1 + K ') NH 4(+ aq ) =
    C K'
    t1 = .(10 pH t 10 pH 0 ) 2 e e 2 (1 + K ')
    I
    0, 4 96500 1,5
    t1 = (10 103 ) = 4, 44.103 s ( 24
    0, 266
    [ HN3 ]e
    pH e = pK A1 + log( )
    NH 4+
    e
    F I CV xe C xe C
    NH 3 = = = NH 4+
    pH e 2V 2 2V 2 e

    (mol.L-1 ) C C K' C (1 + K ') C K '


    NH 3 = =
    e 2 2 (1 + K ') 2(1 + K ')
    elghzizal@live.fr . C 1
    NH 3 =
    e 2 1+ K '
    (2016/06/14) . C 1
    2 1
    pH = pK A1 + log( 1 + K ' ) = pK A1 + log( )
    C K' K'
    2 (1 + K ')
    1
    pH = 9, 2 + log( ) = 9, 2 + 0, 75 9, 95
    3,16.102

    :
    .
    O2(g)/H2O(l) : ( 1
    2 H 2O(l ) O2( g ) + 4 H (+aq ) + 4e
    6 H 2O(l ) O2( g ) + 4 H 3O(+aq ) + 4e
    : ( 2

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