610

35.7768354 1.0104 0.43709836

zi PC TC w
C3 0.61 667.8 343.37 0.0104
C4 0.28 550.7 765.66 0.201
C5 0.11 488.6 845.7 0.2539

nv
a/a-b
0.9928306
Ki = contate de equilibrio

Radfor -rise
A B f(n)=(zi*(ki-1))/(nv*(Ki-1))
Ki zi(Ki-1) Zi(Ki-1)/Ki
35.7768354 21.2138696 0.59294986 0.59711113
0.5310604 -0.13130309 -0.247247 -0.24569158
0.1811316 -0.09007552 -0.49729325 -0.48168112
20.992491 -0.15159039 -0.13026157
a b
 Equilibrio del sistema
1.Un sistema de hidrocarburos tiene la siguiente composicin:
Componente Zi M Tc Pc w
C1 0.3 16.043 343.37 667.8 0.0104
C2 0.1 30.07 550.09 707.8 0.0086
C3 0.05 44.097 666.01 616.3 0.1524
iC4 0.03 58.124 734.93 529.1 0.1848
C4 0.03 58.124 765.66 550.7 0.2010
iC5 0.02 72.151 829.10 490.4 0.2223
C5 0.02 72.151 845.70 488.6 0.2539
C6 0.05 86.178 913.70 436.0 0.3007
C7+ 0.4 140 1146.05667 378.318106 0.45909258
Calcular la relacin de equilibrio del sistema, considerando comportamiento real e id

Psistema= 2100 psia

Tsistema= 150 F 190 R
C7+ = 0.8
Ma C7+= 140 lb/lbmol

Calculando:
Propiedades criticas de la fraccion plus (C7+)
*correlacion de Keesler - Lee
PcC7+ = 378.318106 psia 2.6659465 0.4443057 0.1352738
TcC7+ = 1146.05667 R 420.00974 -264.45307
Tb = 810.329024

Correlacion de Edmister factor acentrico de C7+

w= 0.45909258

ideal
Metodo de Wilson
 Tb
201.27
332.60
416.25
470.78
491.08
542.12
556.92
615.72
810.329024
omportamiento real e ideal.

*Correlacion Mathews - Roland

PcC7+ = 1188 - 431log(M
TcC7+ = 608 + 364 LOG (M
*correlacion de Keesler - Lee
Pcc7+ = exp( 8.3634 - (0.0566/7+) -((
TcC7+ = 341,7 + (811 C7+) + (0,4244 + (
Tb = ((4,5579)*(MC7+^0,15178)*(c7+^0,

ti/xi =Pvi/P =i

Correlacion de Edmister
w=((3*(LOG(Pc/14,7)))/(7*((Tc/Tb)-1)))-1

ideal
ki = Pvi/p =yi/xi
xi= zi/(nL + nki)
yi = xi*ki
nv = nv -(f(nv)/f(nv))

Metodo de Wilson
ki = (pci /1000) exp (5,37(1+wi)(1-(Tci/610)))
Metodo de Standing
ki = (1/) *10^(a+cFi)
Fi = bi((1/Tbi)-(1/T))
bi = (log(Pci/14,7))/((1/Tbi)-(1/Tci))
a = 1,2 + (0,00045p)+((15*10^-8 )*(p^2))
Correcion de C7+
b=
athews - Roland
431log(Mc7+ - 61.1) + (2319 - 852 log(MC7+ 53.71) (C7+ - 0.8)
64 LOG (Mc7+ - 71.2) + (2450LOG( MC7+ 3800) LOGC7+
Keesler - Lee
.3634 - (0.0566/7+) -(( 0.24244 + (2.2898/C7+) + (0.11857/(C7+^2)))*(103)*Tb)+(1,46
(811 C7+) + (0,4244 + (0,1174 C7+))* Tb + (0,4669 - 3,2623 C7+)*((10^5)/Tb)
MC7+^0,15178)*(c7+^0,15427))^3

7)))/(7*((Tc/Tb)-1)))-1

p (5,37(1+wi)(1-(Tci/610)))

/((1/Tbi)-(1/Tci))
p)+((15*10^-8 )*(p^2))
7+^2)))*(103)*Tb)+(1,4685+(3,648/C7+)+(0,47227/(C7+^2))*(10^-7)*(Tb^2))-((0,4201
*((10^5)/Tb)
(10^-7)*(Tb^2))-((0,42019+(1,6977/C7+))*Tb^3*10^-10))
 Composicion del sistema Zi
1.Un pozo produce aceite y gas con la siguiente composicin y una relacin
gas-aceite de 500 scf/STB
Componente Xi Yi M
C1 0.35 0.6 16.043
C2 0.08 0.1 30.070
C3 0.07 0.1 44.097
C4 0.06 0.07 58.124
C5 0.05 0.05 72.151
C6 0.05 0.05 86.178
C7+ 0.34 0.03 160
Calcular la composicin total del sistema, es decir zi

Pyac = 300 psia

Pb = 2800 psia
Tyac = 120 F 580 R
Ma C7+= 160 lb/lbmol
C7+ = 0.823
Rp = 500 scf/STB ft^3 /bbl

Calculando

Moles de gas
ng= 1.31787032

Componente X*M o L (X * M)/o L

C1 5.61505 18.7013 0.30024918
C2 2.4056 22.1573 0.10856918
C3 3.08679 31.5902 0.09771353
C4 3.48744 36.3927 0.09582801
C5 3.60755 35.0537 0.10291496
C6 4.3089 39.2802 0.10969649
C7+ 54.4 38.8912 1.39877402
76.91133

Densidad del liquido mediante Standing-Katz

i=3 Xi*Mi = 68.89068
i=3 (X*Mi)/o = 1.804927

3p = 38.1681253

W1 y W2
i=2 Xi*Mi = 71.29628
W2 = 3.37408908

W1 = 7.30067989

2p = (3p)(1-(0.01386 * W2 )- (0,000082*W2^2))+(0,0379*W2)+(0,0042*W2)^2
LCN = (2p)(1-(0,012*W1 )- (0,000158*W1^2))+(0,0133*W1)+(0,00058*W1)^2
A = -0,0425 * LCN
B = -0,0603 * LCN
p = (1*10^-3)(0,167 + (16,181*10^A))*P - (1*10^-8)*(0,299+(263*10^B))*P^2
T = (0,0133 + 152,4*(LCN+p)^-2,45)(T - 60) - ((8,1*10^-6)-(0,0622*10^(-0,764*(LC
Ls = LCN + p + T

2p = 36.4756456
LCN = 33.0700228
A= -1.40547597
B= -1.99412238
p = 0.2382634
T = 21.6640624
Ls = 54.9723486

Numero de moles del liquido

nL = 0.71474968

Produccion en unidades molares

Rs = 0.0153315

composicion

Componente Y*ng X*nL z

C1 0.79072219 0.25016239 0.51209
C2 0.13178703 0.05717997 0.09297
C3 0.13178703 0.05003248 0.08945
C4 0.09225092 0.04288498 0.06648
C5 0.06589352 0.03573748 0.05000
C6 0.06589352 0.03573748 0.05000
C7+ 0.03953611 0.24301489 0.13901
 Pyac Presion del yacimiento

Pb Presion de burbuja
Tyac Temperatura del yacimiento
Ma C7+ Peso molecular del C7+
C7+ Gravedad especfica del C7+

ng= Rp/379,4
ML= Xsp * M

3p = (i=3 Xi*Mi)/(i=3 (X*Mi)/o)

W2 =((X2* M2)*100)/(i=2 Xi*Mi)

 W1 =((X1* M1)*100)/(i=1 Xi*Mi)

)+(0,0042*W2)^2
0,00058*W1)^2

10^B))*P^2
622*10^(-0,764*(LCN+p))*(T - 60)^2)

nL = Ls / ML

Rs= (Rp * ML)/(379,4 * 5,641 * Ls)

Z=( (Y*ng)+(X*nL))/(ng + nL)

3.La mezcla de hidrocarburos con la siguiente composicin existe en un yacimiento a 23
Componente Zi M Tc Pc
C1 0.3805 16.043 343.37 667.8
C2 0.0933 30.070 550.09 707.8
C3 0.0885 44.097 666.01 616.3
C4 0.0600 58.124 765.66 550.7
C5 0.0378 72.151 845.70 488.6
C6 0.0356 86.178 913.7 436
C7+ 0.3043 200 1296.3015536 276.31893
1

Tyac = 234 F 694 R

Pyac = 3500 Psig 3514.7 Psia
Ma C7+= 200 lb/lbmol
C7+ = 0.8366

Calculando:
Propiedades criticas de la fraccion plus (C7+)
*correlacion de Keesler - Lee
PcC7+ = 276.318931444 psia 3.064376309 0.6159384
TcC7+ = 1296.30155365 R 508.59169773 -232.47274
Tb = 973.16362352

Correlacion de Edmister factor acentrico de C7+

w= 0.6444564505
a)La presin de saturacion (Pb)
Constante de equilibrio, utilizando el metodo de presion de convergencia

Pk = 7800
A= 0.4285807269

Comp. ki Zi*Ki Zi/Ki (Pci)EXP(5,37(

C1 10.3557052994 3.9403458664 0.0367430309 10355.7053
C2 0.6191352532 0.0577653191 0.1506940519 2176.07467
C3 0.2250597925 0.0199177916 0.3932288349 791.017653
C4 0.0805031853 0.0048301911 0.7453121241 282.944545
C5 0.0319043016 0.0012059826 1.1847932145 112.134049
C6 0.013592507 0.0004838932 2.619090058 47.7735844
C7+ 3.6908176E-005 1.1231158E-005 8244.78564288 0.12972117
4.0245602753 8249.9155042
1 40.3
Pd = 0.4260238344

b)La composicin de las fases si la mezcla se separa a 500 psia y 150F.

P fases = 500 psia
T fases = 150 F 610 R
Pk = 7800
A= 0.428580727

Comp. Ki f(n) yi xi
C1
C2
C3
C4
C5
C6
C7+

c)La densidad de las fases.

d)La composicin de las fases si el lquido del primer separador se separa a 14.7 psia y 6
e)El factor de volumen de formacin en el punto de burbuja.
f)La solubilidad original del gas.
g)La viscosidad del aceite en el punto de burbuja.
iste en un yacimiento a 234F y 3500 psig.
wi
0.0104
0.0086
0.1524
0.2010
0.2539
0.3007
0.6444565

0.2257515

zi/((Pci)EXP(5,37(1+wi)(1-(Tci/T))))
3.6743E-005
4.2875E-005
0.00011188
0.00021206
0.0003371
0.00074518
2.34580068
2.34728651
a y 150F.

prte de algo
f(nv)* yi xi yi*Mi xi*Mi xi*Mi/pi

or se separa a 14.7 psia y 60F.

*Correlacion Mathews - Roland
PcC7+ = 1188 - 431log(Mc7+ - 61.1) + (2319 - 852 log(MC7+ 53.71) (C7+ - 0.8)
TcC7+ = 608 + 364 LOG (Mc7+ - 71.2) + (2450LOG( MC7+ 3800) LOG

*correlacion de Keesler - Lee

Pcc7+ = exp( 8.3634 - (0.0566/7+) -(1)+(2)-(3)
1= ( 0.24244 + (2.2898/C7+) + (0.11857/(C7+^2)))*(103)*Tb
2= 1,4685+(3,648/C7+)+(0,47227/(C7+^2))*(10^-7)*(Tb^2)
3= (0,42019+(1,6977/C7+))*Tb^3*10^-10)

TcC7+ = 341,7 + (811 C7+) + (0,4244 + (0,1174 C7+))* Tb + (0,4669 - 3,2623 C7+)*((
Tb = ((4,5579)*(MC7+^0,15178)*(c7+^0,15427))^3

Correlacion de Edmister
w=((3*(LOG(Pc/14,7)))/(7*((Tc/Tb)-1)))-1

Correlacion de Wilson (Ki)

ziKi = 1
Ki = (Pci/P)exp(5,37(1+wi)(1-(Tci/T))

Correlacion de Whitson-Torp (presion de convergencia)

A = 1 -((P-14,7)/(P-14,7))^0,7
Pk = 60MC7 -4200
Ki = ((Pci/pK)^(A-1))*(Pci/p)*EXP(5,37A(1-w)*(1-(Tci/T)))

Presion de rocio (Pd)

Zi/Ki =1,0
Ki = (pci/p)EXP(5,37(1+wi)(1-(Tci/T))
Pd = 1/(zi/(Pci)EXP(5,37(1+wi)(1-(Tci/T))) =1/((/( (5,37(1+)
(1/)))) )
yi yi
 53.71) (C7+ - 0.8)
3800) LOGC7+

^2)))*(103)*Tb
10^-7)*(Tb^2)

(0,4669 - 3,2623 C7+)*((10^5)/Tb)

(5,37(1+)
4.Un aceite crudo existe en el yacimiento en su punto de burbuja de 2520 psia y temper
El yacimiento contiene inicialmente 122 MMbb de aceite. Las instalaciones en superficie c
serie. La primera etapa opera a 500 psig y 100F y la segunda etapa a condiciones estnda
Componente Zi M Tc Pc w
CO2 0.0044 44.01 547.90 1071 0.225
N2 0.0045 28.013 227.60 493.0 0.0400
C1 0.3505 16.043 343.37 667.8 0.0104
C2 0.0464 30.070 550.09 707.8 0.0086
C3 0.0246 44.097 666.01 616.3 0.1524
iC4 0.0683 58.124 734.93 529.1 0.1848
C4 0.0083 58.124 765.66 550.7 0.2010
iC5 0.0080 72.151 829.10 490.4 0.2223
C5 0.0546 72.151 845.70 488.6 0.2539
C6 0.4224 86.178 913.70 436.0 0.3007
C7+ 0.008 225 1336.2556 240.48789 0.7250687
1
Pb= 2520 psia
Tb = 180 F 640 R
Ma C7+= 225 lb/lbmol
C7+ = 0.8364
Yac o = 122 MMbb
1etapa P = 500 psig 514.7 psia
1etapa T = 100 F 560 R

a)Caracterizar la fraccin C7+ en trminos de sus propiedades crticas, punto de ebullici

Calculando:
Propiedades criticas de la fraccion plus (C7+)
*correlacion de Keesler - Lee
PcC7+ = 240.487889 psia 3.2336072 0.6856712 0.2651233
TcC7+ = 1336.25557 R 536.52935 -220.29419
Tb = 1026.66699

Correlacion de Edmister factor acentrico de C7+

w= 0.7250687

b)Calcule el aceite inicial en sitio en STB

c)Calcule los pies cbicos estndar de gas inicialmente en solucin.
d)Calcula la composicin del gas libre y la composicin del aceite residual a 2495 psig, su
a de 2520 psia y temperatura de 180F. El aceite tiene la siguiente composicin:
alaciones en superficie consiste de dos etapas de separacin en
pa a condiciones estndar.
Tb

1026.667

rticas, punto de ebullicin y factor acntrico.

e residual a 2495 psig, suponiendo que la composicin total del sistema permanece constante.
posicin:

*Correlacion Mathews - Roland

PcC7+ = 1188 - 431log(Mc7+ - 61.1) + (2319 - 852 log(MC
TcC7+ = 608 + 364 LOG (Mc7+ - 71.2) + (2450LOG( MC7+ 3800) LOG
*correlacion de Keesler - Lee
Pcc7+ = exp( 8.3634 - (0.0566/7+) -(( 0.24244 + (2.2898/C7+) + (0.11
TcC7+ = 341,7 + (811 C7+) + (0,4244 + (0,1174 C7+))* Tb + (0,4669 - 3,26
Tb = ((4,5579)*(MC7+^0,15178)*(c7+^0,15427))^3

Correlacion de Edmister
w=((3*(LOG(Pc/14,7)))/(7*((Tc/Tb)-1)))-1
permanece constante.
2 log(MC7+ 53.71) (C7+ - 0.8)
OG( MC7+ 3800) LOGC7+

4 + (2.2898/C7+) + (0.11857/(C7+^2)))*(103)*Tb)+(1,4685+(3,648/C7+)+(0,47227/(
C7+))* Tb + (0,4669 - 3,2623 C7+)*((10^5)/Tb)
3,648/C7+)+(0,47227/(C7+^2))*(10^-7)*(Tb^2))-((0,42019+(1,6977/C7+))*Tb^3*10^-1
6977/C7+))*Tb^3*10^-10))
5.Un sistema de aceite crudo con la siguiente composicin existe en su punto de burbuja
Si el peso molecular y gravedad especfica de la fraccin plus es de 225 y 0.823, calcule la
Componente Zi M Tc Pc w
C1 0.42 16.043 343.37 667.8 0.0104
C2 0.08 30.07 550.09 707.8 0.0086
C3 0.06 44.097 666.01 616.3 0.1524
C4 0.02 58.124 765.66 550.7 0.201
C5 0.01 72.151 845.7 488.6 0.2539
C6 0.04 86.178 913.7 436 0.3007
C7+ 0.37 225 1322.4267 234.2617 0.7307199
531.663 5406.9567 3701.4617 1.6577199

P b = 3250 psia
T b = 155 F 615 R
Ma C7+= 225 lb/lbmol
C7+ = 0.823
a)La correlacin de Standing.
b)La correlacin de Alani-Kennedy.
c)La correlacin de van der Waals.

Propiedades criticas de la fraccion plus (C7+)

*correlacion de Keesler - Lee
PcC7+ = 234.26169599 psia 3.2606195 0.6851725 0.2627413
TcC7+ = 1322.4266884 R 530.93081 -217.65712
Tb = 1019.0215377

Correlacion de Edmister factor acentrico de C7+

w= 0.7307199448

Propiedades reducidas
Tr= 0.1137423574
Pr= 0.8780315094

Calculo de presion vapor

A= -44.87070572
B= -93.38364112

Pv= 1.85652E-017

Calcular parametros a y b
a= 0.421875
b= 0.125
R= 10.732 psi ft cu/mol R

a= 383775.84814
b= 1.9596129835

Calcular coeficientes A y B
A= #REF!
B= #REF!

Calculo de Z de liquido
Zl= 0.76817185

Calculo de densidad del aceite en su punto de burbua

Densidad= #REF!
e en su punto de burbuja a 3250 psia y 155F.
e 225 y 0.823, calcule la densidad del crudo usando:
Pv
8.2369E-018
1.0328E-017
1.3242E-023
1.2649E-025
8.0294E-028 d)La ecuacin de estado de redlich-Kwong
9.0614E-030 e)La correlacin de Soave-Redlich-Kwong.
1.7682E-047
1.8565E-017

Pv = Pc*Exp(A+w*B)

*correlacion de Keesler - Lee

Pcc7+ = exp( 8.3634 - (0.0566/7+) -(1)+(2)-(3)
1= ( 0.24244 + (2.2898/C7+) + (0.118
2= 1,4685+(3,648/C7+)+(0,47227/(C
3= (0,42019+(1,6977/C7+))*Tb^3*10
TcC7+ = 341,7 + (811 C7+) + (0,4244 + (0,1174 C
Tb = ((4,5579)*(MC7+^0,15178)*(c7+^0,15427))^3

Correlacion de Edmister
w=((3*(LOG(Pc/14,7)))/(7*((Tc/Tb)-1)))-1

Propiedades reducidas
Tr = T/Tc
Pr = P/Pc

Calculo de presion vapor

A = 5,92714-(6,09648/Tr)-1,2886*LN(Tr)+0,1693*Tr^6
B = 15,2518-(15,6875/Tr)-13,4721*LN(Tr)+0,4357*Tr^6

Calcular parametros a y b
a =(a*(R^2)*(Tc^2))/Pc
b = (b *R*Tc)/Pc
.0566/7+) -(1)+(2)-(3)
+ (2.2898/C7+) + (0.11857/(C7+^2)))*(103)*Tb
3,648/C7+)+(0,47227/(C7+^2))*(10^-7)*(Tb^2)
+(1,6977/C7+))*Tb^3*10^-10)
+ (0,4244 + (0,1174 C7+))* Tb + (0,4669 - 3,2623 C7+)*((10^5)/Tb)
5178)*(c7+^0,15427))^3

Tb)-1)))-1

86*LN(Tr)+0,1693*Tr^6
721*LN(Tr)+0,4357*Tr^6
Comp Zi Tc Pc w Pv
C1 0.42 343.37 667.8 0.0104 2.62883E-016
C2 0.08 550.09 707.8 0.0086 5.96998E-035
C3 0.06 666.01 616.3 0.1524 616.3
C4 0.02 765.66 550.7 0.201 550.7
C5 0.01 845.7 488.6 0.2539 488.6
C6 0.04 913.7 436 0.3007 494.971436
C7+ 0.37 972.8 396.8 0.3498 632.09037062
5057.33 3864 1.2768 2782.6618066
Pb= 3250 psia
Tb= 615 R

Tr= 0.12160567
Pr= 0.84109731

Calculo de presion vapor

A= -41.4910047
B= -85.3658968

Pv= 2782.66181

Calcular parametros a y b
a= 0.421875
b= 0.125
R= 10.732 psi ft cu/mol R

a= 321625.583
b= 1.75579922

Calcular coeficientes A y B
A= 20.5446835
B= 0.74025185

Calculo de Z de liquido
Zl= 0.76817185

Calculo de densidad del aceite en su punto de burbua

Densidad= 291.79826

e
M Comp Zi Tc
16.043 C1 0.42 343.37
30.07 C2 0.08 550.09
44.097 C3 0.06 666.01
58.124 C4 0.02 765.66
72.151 C5 0.01 845.7
86.178 C6 0.04 913.7
225 C7+ 0.37 972.8
531.663 5057.33
Pb= 3250 psia
Tb= 615 R
R= 10.732 psi ft cu/mol R

Obtener a y b para cada componente de la mezcla

a= 0.42747
b= 0.08664

Comp a b
C1 161074.364 0.47809592
C2 493674.603 0.7226405
C3 914485.19 1.00481866
C4 1450246.38 1.2927662
C5 2095821.7 1.60939251
C6 2849637.01 1.94857104
C7+ 3662302.48 2.27955989

Calcular los parametros de mezclado am y bm

am= 1201895.33
bm= 1.2822299

Calcular los coeficientes A y B

A= 3.61577079
B= 0.63138387

Calculo de Z de liquido
Zl= 0.91136647

Calculo de la densidad del aceite en su punto de burbuja

Densidad= 287.257233
 Pc M
667.8 16.043
707.8 30.07
616.3 44.097
550.7 58.124
488.6 72.151
436 86.178
396.8 225
3864 531.663

ft cu/mol R

onente de la mezcla

am bm
168.563097 0.20080029
56.2095851 0.05781124
57.3772314 0.06028912
24.0852352 0.02585532
14.4769531 0.01609393
67.5234716 0.07794284
708.074296 0.84343716
1096.30987 1.2822299

zclado am y bm

ite en su punto de burbuja