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0 INTRODUCTION
The first competing reaction forms acetic acid, which is a marketable commodity. The second
competing reaction simply forms completely useless products.
The first process involves direct catalytic oxidation of propylene to acrylic acid in a single
stage operation which comprises passing a starting reactant gas mixture containing propylene,
compressed air (compressor) and steam (mixer) through in a single reactor (Plug flow
reactor). The reactor effluent is sent to a separation unit (separator) in which all light gases
are separated as vapor in top stream. Bottom stream that contains mixture of liquid mainly
water, acetic acid and acrylic acid are distilled to produce purified acrylic acid (distillation
column).
Another process involves producing acrylic acid from propylene through acrolein as an
intermediate by catalytic vapor phase oxidation, which comprises passing a starting reactant
gas mixture containing propylene, compressed air (compressor) and steam (mixer) through a
first-stage reactor packed with a molybdenum-containing multi-component catalyst (plug
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flow reactor), passing the resulting acrolein containing gas through a second-stage reactor
packed with a multi-component catalyst containing vanadium and molybdenum (plug flow
reactor). The resulting acrylic acid-containing gas is separated (separator), and absorbed in
water (absorber). A part of the exhaust gas is incorporated in the starting reactant gas mixture
(recycle).
5.0 RESULTS
6.0 ANALYSIS
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When perform economic analysis, a number of economic criteria should be used. It is the
equivalent annual operating cost (EAOC). A negative EAOC means there is a profit. It is
desirable to minimize the EAOC; i.e., a large negative EAOC is very desirable.
7.0 DISCUSSION
This process produces 53,460 metric tons per year of 99.9 mole % of acrylic acid
(AA) product. The number of operating hours should be taken as 8000/yr, about 330 days
which allows the plant for periodic shut down and maintenance. The reactor in the process
shown uses a proprietary catalyst that eliminates the production of the intermediate, acrolein.
Therefore, this process requires only a single reactor.
After reaction, it is essential to cool the products (reactor effluent) quickly to avoid
further homogeneous oxidation reactions. The homogeneous combustion reactions will not
take place so long as the reactor effluent is cooled to below 100 oC immediately after the
reactor. Additional recovery of AA and acetic acid (a by-product) from the gas leaving the
phase separator is achieved in the distillation column.
The kinetics used for the 3 reactions involved are valid in the temperature range, 250
330oC (Refer to Appendix C). Above 330oC the catalyst starts to coke, and below 250 oC the
rate of reaction drops off rapidly. It is recommended that the steam-to-propylene ratio at the
reactor inlet never be set less than 4:1 on a mole basis. This steam is used to inhibit the
formation of coke on the catalyst below temperatures of 330oC.
8.0 CONCLUSION
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As a conclusion, oxidation of propylene produces acrylic acid as main product with
99.99% purity after purification in distillation column. Two other competing reactions which
produced acetic acid as useful by-product and carbon dioxide as non-added value by product
are also considered in the designing of the process. Acrylic acid is produced at a rate of
6682.5kg/h, which is equal to 53,460 metric tons per annum.
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9.0 APPENDIX
9.1 APPENDIX A: PSD AND RESULTS
(b) Simulation with further purification of acetic acid (predicted using shortcut distillation):
Compressed air:
5
Propylene:
Steam:
6
A.4: By-product (Vent gas and acetic acid)
Vent gas:
7
Analysis results for lowering the temperature of incoming feed:
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9.3 APPENDIX C: ECONOMIC OR ENVIRONMENTAL ANALYSIS
Refrigeration $60/GJ
Equipment: <http://www.matche.com/equipcost/Reactor.html>
Compressor (Air, Centrifugal, 125psi)
Heater
Separator (57.6cm diameter)
Plug flow reactor - $20 to $50 per square foot of surface area
(D=3.6m, L=10m; A=133.45m2<437.8ft>)
Distillation column (4ft diameter, 19ft high)
Equipment cost factors:
Pressure (absolute) < 10atm, 0.0
10-20atm, 0.6
20-40atm, 3.0
40-50atm, 5.0
50-100atm, 10
Carbon steel 0.0
Stainless steel 4.0
Total installed cost = Purchased cost (4 + material factor + pressure factor)
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Cost Current Process ($)
Propylene Feed
49,470,400
Reboiler Electricity
90,912,000
Condenser Electricity
90,144,000
Air Compressor Electricity
1,277 ,760
Heater Electricity
621,120
Reactor Electricity
22,396,800
Steam from Boiler
519,325
Total
255,341,405
Economic analysis:
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EAOC = - (product value - feed cost - other operating costs - capital cost annuity)
i(i+1)n
Capital cost annuity = FCI (i+ 1)n1
where FCI is the installed cost of all equipment; i is the interest rate, i = 0.15; and n is the
plant life for accounting purposes, n = 10.
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9.4 APPENDIX D: REACTION KINETICS
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10.0 REFERENCES
Acrylic Acid Prices and Pricing Information. (2011, August). Retrieved 3 rd April 2016 from
http://www.icis.com/resources/news/2007/11/01/9074869/acrylic-acid-prices-and
-pricing-information/
Acrylic Acid Production and Manufacturing Process. (2007, November 01). Retrieved 2 nd
April 2016 from http://www.icis.com/resources/news/2007/11/01/9074872/acrylic-
acid-production-and-manufacturing-process/
Acrylic Acid Uses and Market Data. (2007, November 01). Retrieved 3 rd April 2016 from
http://www.icis.com/resources/news/2007/11/01/9074870/acrylic-acid-uses-and-
market-data/
Anonymous. (2014). Design of Acrylic Acid Production. Retrieved 3 rd April 2016 from
http://www.chemeng.kmutt.ac.th/cheps/Project-4_Acrylic-Acid.pdf
Campbell, W. E., McDaniel, E. L., Reece, W. H., Williams, J. E., Young, H.S. (1970).
Oxidation of Propylene to Acrylic Acid over a Catalyst Containing Oxides of Arsenic,
Niobium, and Molybdenum. Retrieved 1st April 2016 from
http://pubs.acs.org/doi/abs/10.1021/i360035a012?journalCode=iepra6.1
Han, S. (2013). Method for preparing acrylic acid from propane and propylene. Retrieved 2 nd
April 2016 from http://www.google.com/patents/WO2013058888A1?cl=en
Lakowski, C., Hayenga, M., Castillo, M. (1998). Acrylic Acid Production via the Catalytic
Partial Oxidation of Propylene. Retrieved 3 rd April 2016 from
http://www.owlnet.rice.edu/~ceng403/gr1498/AcrylicAcid.htm
Process for producing acrylic acid from propylene. (1979). Retrieved 2 nd April from
http://www.google.com/patents/US4147885
Sood, S. (1995). One Step Oxidation of Propylene to Acrylic Acid. Retrieved 3 rd April 2016
from http://www.collectionscanada.gc.ca/obj/s4/f2/dsk3/ftp05/mq22044.pdf
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