Professional Documents
Culture Documents
Redox
Redox (short for reductionoxidation reaction) is a chemical reaction in which the
oxidation states of atoms are changed. Any such reaction involves both a reduction process and a
complementary oxidation process, two key concepts involved with electron transfer processes.[1]
Redox reactions include all chemical reactions in which atoms have their oxidation state
changed; in general, redox reactions involve the transfer of electrons between chemical species.
The chemical species from which the electron is stripped is said to have been oxidized, while the
chemical species to which the electron is added is said to have been reduced. It can be explained
in simple terms:
Oxidation is the loss of electrons or an increase in oxidation state by a
molecule/atom/ion.
Reduction is the gain of electrons or a decrease in oxidation state by a molecule/atom/ion.
A good example is the reaction between hydrogen and fluorine in which hydrogen is being
oxidized and fluorine is being reduced: H2 + F2 2HF
We can write this overall reaction as two half-reactions:
the oxidation reaction: H2 2H+ + 2e-
and the reduction reaction: F2 + 2e- 2F-
Example: It exists a wide range of gas sensor products which use the oxidation effect for
the detection of various gases, from explosive gases such as propane, toxic gases such as carbon
monoxide, to air quality sensors for volatile organic compounds (VOCs) that are responsible for
sick-house syndrome.
STEP1:In clean air, donor electrons in tin dioxide are attracted toward oxygen which is
adsorbed on the surface of the sensing material, preventing electric current flow.
STEP2: In the presence of reducing gases, the surface density of adsorbed oxygen
decreases as it reacts with the reducing gases. Electrons are then released into the tin dioxide,
allowing current to flow freely through the sensor.
References: http://www.figaro.co.jp/en/technicalinfo/principle/mos-type.html
http://nano-bio.ehu.es/files/chemical_sensors1.doc_definitivo.pdf
https://en.wikipedia.org/wiki/Redox
https://www.nap.edu/read/4782/chapter/chemicalsensors