ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE: 2016 CRASH COURSE DATE:

TOPIC: CHEMICAL KINETIC , SOLID STATE & NUCLEAR CHEMISTRY

SOLUTION

1. (D)
m n m n
Rate 1 k A B ; Rate 2 k 2 A B / 2
rate 2 m 1 n m-n
Hence, 2 2
rate 1 2

2. (B)
2
Rate k FeCl3 SnCl2 [reaction being elementary]
2FeCl3 SnCl2 2FeCl 2 SnCl4
t 0 1.2 M 0.8 M 0 0
time t 0.8 M 0.6 M 0.4 M 0.2 M
2
Rate 2 k 0.8 0.6 1
2

Rate 1 k 1.2 0.8 3

3. (D)

Rate SN2 5.0 105 102 R X
5.0 10 7 R X

Rate SN1 0.20 105 R X

4. (B)
Ea f E a b H 15k cal
Ea f 15 20 5k cal
E a E a catalyst 5 3 103
k catalyst
e RT
e 2 400
e 2.5
k

8. (B)
At radioactive equilibrium, B N B max A N A
2ln 2
A 2
A tmax A
A N0 e A N0 e A N 0 eln 2
A N0 N
N B max A 0
4 4 B

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1

9. (D)
12
Number of t1/ 2 A 6;
2
12
Number of t1/ 2 B 3
4
6 3
1 1 1 1
nA left ; nB left
2 64 2 8
1 1
n A : nB : 1: 8
64 8

10. (A)
Radioactive decay is a first order process. Hence the total number of radioactive nuclei will decrease
exponentially with time.

11. (BC)

12. (BCD)

13. (AC)
In acid catalysed reaction, the rate constant is directly proportional to the extent of ionization of the
acid and hence the strength of the acid.
Relative strength of (I) HX and (II) HY
I kI 3 10 3
0.6
II k II 5 103

14. (ABC)
(A) For zero order reaction rate remains constant, independent of concentration.
t1
Time for 75% reaction 2 75 1.5t 1 2
50
(B) For first order reaction time for any fractional change is independent of initial concentration.
1 1 1
(C) For 2nd order reaction, t
k C C0
1 1 1 1
t 12
k C0 / 2 C0 kC 0
1 1 1 1
t 14 3
k 4 C 0 / 2 C 0 3kC 0

15. BCD

16. (AD)
Half-life of a reaction will decrease only when rate constant increases. Rate constants of all reactions
(endothermic or exothermic) increases on increasing temperature (except the reaction
2NO O 2 2NO 2 )

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17. (D)
All other statements are incorrect.

18. (ACD)
19. (BC)
Isoelectronic ions have the same scattering power of X-rays. Hence, K+ and Cl ; Rb+ and Br

20. (ACD)

21. (BC)

22. (BC)

23. (CD)

24. (BCD)

25. (ABCD)

37. (5)
The magic numbers are 2, 8, 20, 50, 126.

38. (8)
E m 931MeV
0.00859 931
8 MeV

39. (5)
Initial amount of this isotope N 0 100
Final amount of the isotope N 25
n
1
We know that N N 0
2
n
1
So 25 100
2
n
25 1
Or
100 2
n
1 1
Or
4 2
2 n
1 1
Or
2 2
Or n 2
Time taken T n t1/ 2 2 2.5 10 5 5 105 year
Alternatively
CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3
 t1/2 0.3
We can use
t x % log a
ax
t1/2 0.3

t 25% log 100
25
2.5 105 0.3

t 25% log 4
Or t 25% or time required to reduced amount to 25%
2.5 105
log 4
0.3
2.5 105
0.602
0.3
5.0 105 years

40. (5)
a0
log
t15/16 a0 x

t3/4 a0
log
a0 x1
a0
log
a0 / 16 log16 4

a0 log 4 2
log
a0 / 14
t15/16 t3/4 2
2.5 2 5

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4