Themodynamic Model Selection

Hexamers
WILS-HF
Yes NRTL, UNIQUAC
and their variances
DP?
Yes
LL? Yes WILS-NTH, WILS-HOC,
Dimers NRTL-NTH, NRTL-HOC,
No WILSON, NRTL,
UNIQ-NTH, UNIQ-HOC,
UNIQUAC and their
UNIF-HOC
variances
P < 10 bar
*WILSON,
ij? NRTL VAP?
Yes
* UNIF-LL
UNIQUAC,
UNIFAC
No
LL?
WILSON, WILS-RK, WILS-LR,
No No WILS-GLR, NRTL, NRTL-RK,
UNIFAC, UNIF-
NRTL-2, UNIQUAC, UNIQ-RK,
LBY, UNIF-DMD
UNIQ-2, UNIFAC, UNIF-LL,
Non-Electrolyte Yes SR-POLAR, PRWS, UNIF-LBY, UNIF-DMD
P? RKSWS, PRMHV2,
RKSHMV2
P > 10 bar
ij?
Polar No
E? PSRK, RKSMHV2

Electrolyte
ELECTNRTL

? Nomenclature
? Polarity ij? Interaction
Real PENG-ROB, RK-SOAVE,
LK-PLOCK, PR-BM, RKS- parameters available
BM

R? E? Electrolyte LL? Liquid-Liquid

No-Polar 1 atm CHAO-SEA,
GRAYSON, BK10
Pseudo
& Real Vapor phase
R? P? Pressure VAP?
association
Vacuum BK-10,
IDEAL
Degrees of
R? Real or DP?
polymerization
Pseudocomponents

Taken from Aspen Documentation Manual.