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Ion Exchange Membranes

High-performance fumasep ion exchange membranes for Electro Membrane Processes


High-performance fumasep ion exchange membranes for Electro Membrane Processes

Physical and chemical properties

Type Reinforcement Thicknessa) IEC Selectivityb) Specific Stability


arearesistancec)
m meq/g % cm pH

Standard Grade Membranes


FAS anion none 30-50 1.0 >97 <1 1-14
FKS cation none 30-50 1.4 >98 <1 1-14
FAS anion PET 90-100 1.0 >95 <3 1-9
FKS cation PET 90-100 1.4 >98 <4 1-9
FAM anion PET/GF 90-100 1.6 >92 <3 1-9
FKM cation PP 90-100 1.9 >95 <1.7 1-9

Membranes for Electrodialysis with Bipolare Membranes


FAB anion PEEK 100-120 - >96 <5 1-14
FKB cation PEEK 100-120 1.3 >98 <5 1-14
FBM bipolare PEEK 180-200 - - - 1-14

Special Grade Membranes


FAD anion PET 80-100 1.5 >93 <0.8 1-9
FKD cation PEEK 80-100 1.3 >95 <1.8 1-14
FAP anion PEEK/PTFE 140-160 - >95 <6.5 1-6
FAA anion PEEK 100-120 1.5 >95 <1.5 1-14
FKL cation PEEK 100-120 1.0 >98 <5 1-14
FKE cation none 50 1.3 >98 <1.5 1-14

Fluorinated Membranes for Electrolysis


F-10180 cation PTFE 180-200 1.0 - <0.5 1-14

Ultrex Membranes
AMI-7001 anion PP 500 1.3 >96 25-30 1-10
CMI-7000 cation PP 450 1.6 >97 25-30 1-10

a) reference membrane dried over P2O5 in vacuo.


b) determined from membrane potential measurement in a concentration cell 0,1/0,5 M KCl @ 25 C
c) in Na+-/Clform at T=25 C in H2O
PET = polyester
PP = polypropylene
GF = glassfiber
PEEK = polyetheretherketone
PTFE = polytetrafluoroethylene
High-performance fumasep ion exchange membranes for Electro Membrane Processes

Ion Exchange Membranes

FuMA-Tech the company for functional membranes and Membranes for Electrodialysis with Bipolare Membranes
plant technology is one of the leading manufacturer of ion Our products fumasep FAB, FKB and FBM are designed and
exchange membranes for different electrochemical operations. optimized for electrodialysis with bipolare membranes.
The EDBM is the combination of conventional electrodialysis
Our modern coating plant produces porous, non-porous and for salt separation with electrochemical water splitting for the
functional membranes with excellent resistance to acids, conversion of a salt into its corresponding acid and base.
bases, solvents and oxidation. fumasep FAB is an anion exchange membrane which is deve-
loped for very low proton crossover to receive a high concent-
ration of acid. fumasep FKB is a cation exchange membrane
Standard Grade Membranes optimised for high cation transport in combination with high
The fumasep FAS and fumasep FKS are standard anion/ OH- retention. fumasep FBM is a bipolare membrane, which
cation exchange membranes for electrodialysis and reversed induce the splitting of water into protons and hydroxide ions.
electrodialysis. They are cost saving membrane types with re-
inforcement as well as non reinforced films. Those membrane
types are optimised in view of thickness, conductivity, perm- 3-Compartment-Cell ED-Bipolar
selectivity and area resistance, depending on the application.
The recommended applications are for example desalisation
processes, concentration of salts, acids and bases, nitrogen
removal from drinking water.

The microheterogenous membrane types fumasep FAM and


FKM are based on strong base anionic and strong acid ca-
tionic ion exchange resin. The membranes are reinforced for
highest mechanical stability. Special fields of application are
processes like desalination, demineralization and electrodeio-
nization to produce ultrapure water.

Figure 1: Electrodialysis with bipolare membranes in a 3-compartment cell


The bipolar membrane fumasep FBM combines high selec- Special Grade Membranes
tivity and efficiency as well as high chemical stability within The fumasep FAD anion exchange membrane is a membrane
a broad pH range, excellent mechanical stability and low type with excellent properties regarding proton and anion
electrical resistance. It is ideally suited for the production of transport as well as high efficiencey in view of the metal ions
acid and base from the corresponding salts, as well as for rejection. This characteristic is predestinated for the operation
innovative concepts such as biological fuel cells. in diffusions dialysis processes for the recovery of free acids
from spent treatment bath solutions for example in surface
The patented multilayer membrane consists of a selective finishing and textile processes.
anion and cation exchange film. The dissosiation of the water
into protons and hydroxy ions takes place in the special inter-
face layer. The water is transferred into this layer by osmotic
effects.

Figure 3: Diffusion dialysis in a 2-compartment cell

For base recovery by diffusion dialysis, the fumasep FKD


Figure 2: Current/voltage plot of fumasep FBM bipolare membrane
cation exchange membrane is used likewise.
Depending on the process design, up to 95 % of the free acid fumasep membranes are produced according to FuMA-Tech`s
and up to 80 % of the base can be recovered in this way proprietary solution casting technology. They are supplied
and returned to the production process, thus saving chemicals in standard sheet sizes of 200 x 300 mm, 520 x 520, 520
needed for the finishing baths or wastewater treatment. x 1050 mm and on rolls of 500 mm maximum width with
thicknesses ranging from 0.02 mm to 0.25 mm.
fumasep FAP is a chlorine resistant anion-exchange membra-
ne which also allows the transport of protons. This membrane
is used for applications that require highly permselective Ultrex Membranes
membranes with excellent oxidative stability, low area FuMA-Tech is the exclusive distributor of Membranes Internati-
resistance and high mechanical stability. Typical applications onal for Ultrex membranes in Europe.
are electrolysis and battery systems such as vanadium redox
batteries (VRB). AMI-7001 and CMI-7000 membranes are strong base an-
ionic and strong acid cationic heterogeneous ion exchange
fumasep FAA is an alkaline stable anion-exchange membranes for the electrocoat and water treatment industries.
membrane for electrodialysis applications. The membranes are approved for use in electrocoat paint
systems. Furthermore the membranes are used in electrode
fumasep FKL is a cation-exchange membrane for concent- ionization systems for the production of ultra pure water.
ration of bases by electrodialysis. The cationic CMI-7000 and anionic AMI-7001 ion exchange
membranes offer superior performance and physical stability
fumasep FKE is a thin cation-exchange membrane and while being extremely cost effective.
proton conductor for electrolysis with high selectivity.

Fluorinated Membranes for Electrolysis


The fumasep F-10180 PTFE is a cation exchange membrane
based on perfluorinated sulfonic acid/PTFE copolymers with
excellent chemical stability and superior ionic conductance
intended for use in electrolysis. The membrane is reinforced
with woven PTFE for highest mechanical and chemical stabili-
ty. Further application is the production of sodium hypochlori-
te and hypochlorous acid for water disinfection.
Druck: 120612WF
BWT The Company
The Best Water Technology Group was formed in 1990 and guarantee our customers maximum security, hygiene and
today is Europes leading water technology company. More health in the daily use of water, the precious elixir of life. These
than 2,700 employees in over 70 subsidiaries and associates innovations, among others, include SEPTRON, the worldwide
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water partner network. Employees in Research & Development manganese removal, the bipolar technology AQA total for
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methods to target the development of ecological and at the same regeneration salt for softening systems, which at
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of energy consumption of products and well as the new, revolutionary Mg2+-
the consequent minimisation of CO2 technology for better taste of
emissions is a key issue. filtered water, coffee and tea.
With unique high efficiency
When it comes to water, almost membranes for fuel cells and
everywhere, whether at the batteries, BWT is bringing about a
entrance of the water pipe into cleaner and sustainable energy
a building the Point of Entry supply in the 21st century.
- or at the tapping point the
Point of Use, the trend-setting BWT For You and Planet Blue
products by BWT are in use is our mission to take ecological,
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millions of times. For the treatment bility, to provide our customers
of drinking water, mineral water and and partners with the best
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ceutical industry as well as in services in all areas of water treat-
swimming pools, heating and process ment and simultaneously contribute
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For further information:

FuMA-Tech Gesellschaft fr FuMA-Tech Gesellschaft fr BWT Aktiengesellschaft


funktionelle Membranen und funktionelle Membranen und Walter-Simmer-Strae 4
Anlagentechnologie mbH Anlagentechnologie mbH A-5310 Mondsee
Am Grubenstollen 11 Steinbeisstrae 41 43 Tel.: +43/6232/5011-0
D-66386 St. Ingbert D-71665 Vaihingen Enz Fax: +43/6232/4058
Tel.: +49/6894/9265-0 Tel.: +49/7042/97024-0 E-Mail: office@bwt-group.com
Fax: +49/6894/926599 Fax: +49/7042/9702499 www.bwt-group.com
E-Mail: office@fumatech.de E-Mail: office@fumatech.de

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