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Lets us first review the properties of wave. Up until you study wave, you
had studied the basis of Newtonian Mechanics (F = ma and whatnot), which
tells you how objects move under various forces. In more technical language, we
say Newtonian mechanics deals with the motion of particle, because in applying
F = ma we typically ignore the actual shape and structure of the object but
treat it as if it is just a point mass with no size. Think of your trajectory motion;
even though a baseball has a finite volume, when solving problem we only talk
about THE y-coordinate of the ball (the coordinate of what? The center? The
top? The bottom?).
Of course, in the real world everything has size, so apart from displacements,
they can also undergo other type of motion. In particular, if the object is de-
formable (can change shape), then each individual part of the object can be in
independent motion (oscillation especially) while keeping the object as a whole
stationary (So the object is not displaced). We call this a wave motion.
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In particular, in the case of electromagnetic waves, or in other words, light,
the energy is related to the amplitude (or intensity) of the wave only but
nothing else, in the classical wave picture.
1. Particles are localized (the apple is on the tree), whereas waves are ex-
tended and distributed (Wheres the wave? It is everywhere!)
3. Waves can diffract around obstacles, while particles will only be reflected
if blocked.
4. Particles are discrete, you can count and labeled them as 1, 2, 3...; waves
have infinitely many modes, and you can have a continuum of waves at
arbitrary amplitudes (you can turn on your light as bright or as dim as
you like)
5. Waves can overlap hence interfere with each other (superposition), whereas
particles can only collide
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1.4 Light as a Wave
The question of what exactly is light had been one of the biggest questions
in classical physics. Newton and his followers thought light are particles while
Hooke (the one who wrote F = kx for springs) and many others thought
light is some kind of wave. The controversy was not ended until finally in
1801 Thomas Young had performed his famous double-slit experiment (this
experiment is so important that DSE forces you to study it even though it is
already 217 years since its first came out).
In 1887, Hertz (what you called Hz = s1 ) found that when a metal surface is
shinned with light, electrons can be emitted from the surface. This is what we
now called the photoelectric effect.
Not all electrons emitted with the same energy K, because each electron in-
teract and bounded with the metal atoms in a very complicated way, depending
on how strongly it is bounded, more energy is needed to kick it out from the
metal hence less energy is available to be its kinetic energy. But Kmax = eVs is
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the maximum that can be achieved, and it corresponds to the least bounded
electron. We hence define:
The work function is the minimal energy required to remove the least
bounded electron from the metal.
The classical physicists thought that they knew light well enough, thus following
their classical knowledge of light, they made the following theory and predictions
for the photoelectric effect:
A standard laser pointer your teacher uses for class have a power of about
P = 1mW on a area of about A0 1cm2 . Suppose you point that to a metal
atom, who typcially has a radius of r 0.1 109 m and a work function of
about 1eV , then classically you would expect the first electron to be fired
with a time delay t of
Energy N eeded
t =
P ower received by atom
= P 2
A0 r
10( 19)
= 1103
(110 2) (1 109 )2
= 1 sec
So these are the classical prediction. What you have to understand is that,
people in that time thought that physics was completed and they knew every-
thing about physics, about waves and about light. So people in that time is
seriously expecting that their wave theory of the photoelectric effect is correct
there is no reason for it to be wrong.
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2.3 The Experimental Results
But of course, you know how the story goes everything they thought they
knew is completely wrong and not even close.
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Moral of story: Photoelectric effect is something that classical physics com-
pletely failed to explain. There is something more about light that we did not
know, and we need to figure that out.
3 Photon
The resolution eventually came from the famous genius Albert Einstein in
1905 (His Nobel prize was in fact awarded for his work on photoelectric effect).
Stay tuned, not everyone has the luck to learn about the great thoughts from
Einstein.
The problem is that light is a wave, which is impossible to have the photo-
electric effect. To solve this problem, Einstein postulate the following
Einstein:
1. Light is not a just wave, but also a beam of localized particles called
photon.
2. Each photon has energy E = hf ; if there are n photon then the total
E = nhf
3. The intensity of a beam of light is related to the number of photon in
there but not the energy of the individual photon
4. In the photoelectric effect, a photon somehow collide with the electron, and
during the interaction, the photon transfer all its energy to the electron
hence kicking it out from the metal.
Now light is not a wave, problem solved. In particular, the photoelectric effect
can be explained in a simple particle collision picture, which you know well
enough to analyze.
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K = hf (1)
And the reason why there is a cutoff frequency f0 is because the incoming
photon must have enough energy to overcome the attraction from the work
function, so the cutoff occurs when after absorbing the photon, the electron has
exactly zero energy (meaning the electron is completely free from attraction but
has no motion)
0 = hf0 (2)
f0 = (3)
h
hc
= (4)
Finally, this particle picture of light also explain why the photocurrent still
proportion to light intensity and why the first emission of electron occurs almost
immediately. Since the intensity of light tells you how many photon is there
in your light beam, so more intense light has more photon and causes more
electron to be kicked out. Being a measurement of how many electron is flowing
(I = q
t ), I is naturally proportional to the intensity of the current. Also, since
photoelectric effect is interpreted as some sort of collision between photons and
electrons, it is natural that the electron is immediately kicked out when it got
shined by a light.
4 Conclusion
Ok. So in the beginning I said light is wave because only wave, but not particle,
can interfere. But now I said light is particle because only if it is something like
a particle, but not wave, then can it exhibit the photoelectric effect. So whats
the deal?
The answer took quite a great effort for the 20th century physicists to figure
out, and the final answer is No and No.
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and this is what we called nowaday Quantum Mechanics. In the language of
quantum mechanics, light is not a wave nor a particle, it is a quantum called
the photon. It is localized like particles but can interfere with each others
like a wave. And while it has definite momentum and energy like a particle,
you cannot know where exactly is it at any moment; it is spreaded out like
a wave. Strange things like this happen all the time in quantum mechanics,
and to understand how photon interact exactly with electrons would require
something called QED (quantum electrodynamics), which is one step (or several
steps) further from quantum mechanics.
5 Exercise
2. What would the minimum work function for a metal have to be for visible light
(380750 nm) to eject photoelectrons?
Ans: 1.77eV
Ans: 2.14eV
4. The photoelectric work function of potassium is 2.3 eV. If light having a wave-
length of 250 nm falls on potassium, find (a) the stopping potential in volts; (b) the
kinetic energy in electron volts of the most energetic electrons ejected; (c) the speed
of these electrons. (Electron has mass me = 9.11 1031 kg)
Ans: 0.964 V