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T
he long-term growth of numerous industries will depend on the ability
to secure stable and diverse sources of rare earths. Recent years have
seen unprecedented volatility in this sector, with the rare earths being quantities within commercially
processed LREE-rich minerals such
increasingly considered as strategic and critical to a wide range of technolo-
as monazite and bastnsite. HREE-
gies. During the next few years, demand for some of the rare earths is enriched minerals and deposits that
expected to exceed supply. Chinese export-quota policies have had a severe have been processed commercially
impact on the market. Worldwide exploration efforts are now leading to the include xenotime-(Y), ion-adsorp-
tion clays, and synchysite-(Y). New
deployment of a rare earth supply chain based outside China. potential sources of HREEs outside
KEYWORDS : rare earths, rare earth oxide, neodymium, dysprosium, critical metals China tend to be contained in
minerals such as eudialyte, which
have not been processed commer-
cially before.
INTRODUCTION
The rare earth elements (REEs) are a unique group of chem- END USES OF RARE EARTHS
ical elements that exhibit a range of special electronic, REEs have a variety of end uses (FIG. 1). Applications for
magnetic, optical, and catalytic properties. These elements REEs can be divided into two broad categories: process
are enablers: their use in components manufactured from enablers and technology building blocks.
a wide range of alloys and compounds can have a profound
effect on the performance of complex engineered systems. Rare Earths as Process Enablers
The REEs are usually defined as the 15 lanthanoid elements In a number of applications, REEs are used in the lifecycle
(lanthanum to lutetium), plus scandium and yttrium of other materials and components but do not stay with
(Connelly et al. 2005). Promethium is radioactive and has the processed material. In general, simple REE compounds
no stable isotopes; it is thus present in the Earths crust in are utilized, such as rare earth oxides (REOs). Examples
vanishingly small quantities. Scandium exhibits a number include:
of properties that are similar to those of other REEs, but is
Fluid-cracking catalysts (FCCs). These are materials used
seldom found in the same minerals as the other REEs; it
in the petroleum-refi ning industry. La and Ce are added
does not selectively combine with the common ore-forming
to the catalytic compounds (up to 8 wt%) to provide
anions (Hedrick 2000). It should be noted that the other
zeolite stability during the cracking process, which in
REEs are chemically very similar to each other and tend
turn yields high catalytic activity and process selectivity.
to occur together within minerals in varying quantities.
This interaction aids in the transformation of crude oil
Their chemical similarities make them difficult to separate
into gasoline and other useful and valuable petroleum
from each other, once liberated from the minerals in which
products.
they are found.
Automotive catalytic converters. Modern vehicles use cata-
Flow-sheet designers and process engineers divide the REEs
lytic converters to reduce the emission of pollutants that
into three subgroups on the basis of initial segmentation
result from the internal combustion process. CeO2 is the
during the separation process. Lanthanum (La), cerium
primary rare earth compound in such converters and is
(Ce), and neodymium (Nd) are the light REEs (LREEs);
used in a wash coat in conjunction with zirconium (Zr)
samarium (Sm), europium (Eu), and gadolinium (Gd) are
and platinum-group metals. The wash coat can contain
the medium REEs (MREEs), and terbium (Tb), dysprosium
up to 30 wt% CeO2 . The associated redox reaction aids
(Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium
in the conversion of NOx, CO, and unburned hydrocar-
(Yb), lutetium (Lu), and yttrium (Y) are the heavy REEs
bons into less harmful compounds.
(HREEs) (see also Chakhmouradian and Wall 2012 this
issue). HREEs are much rarer than LREEs or MREEs, partly Polishing media. Significant amounts of CeO2 are utilized
due to their lower crustal abundances. They occur in small in the polishing of glass, mirrors, TV screens, computer
displays, and the wafers used to produce silicon chips.
When used in fi ne-powder form, the CeO2 reacts with
the surface of the glass to form a softer layer (the so-called
* Technology Metals Research LLC, 180 S. Western Ave #150 mechanochemical effect), thus making it easier to
Carpentersville, Illinois 60110, USA polish the surface to a high-quality fi nish.
Innovation Metals Corp, Suite 1801, 1 Yonge Street
Toronto, ON M5E 1W7, Canada
E-mail: ghatch@techmetalsresearch.com
In addition to making electrical machines more efficient Ceramics 3000 1500 2000 500 7000
and to enhance performance, rare earth magnet mate-
rials have made it possible to miniaturize motors, loud- Other 3500 500 1500 500 6000
speakers, hard-disk drives, and other applications that
Total demand 70,000 10,500 18,000 6500 105,000
use permanent magnets to operate. The magnetic field
strength of rare earth magnets can be several times Market share 68% 10% 16% 6% 100%
greater than that of ferrite magnets of the same shape
Source: Kingsnorth (2012)
TABLE 2 FORECASTED GLOBAL RARE EARTH DEMAND IN 2016 In August 2012, the MOC published the quota allocations
(in tonnes of TREO 20%) for the remainder of 2012, with all but one of the compa-
Japan & nies that received provisional quotas passing the required
End Use China USA Others Total
SE Asia inspections, thus receiving confi rmed quotas. The fi nal
Permanent magnets 28,000 2000 4500 1500 36,000 total of allocations for 2012 was 31 kt, slightly higher than
for 2011 (Hatch 2012b).
Metal alloys 23,000 2000 3000 2000 30,000
A B
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