KRISHNA INSTITUTE OF ENGINEERING & TECHNOLOGY

APPLIED THERMODYNAMICS (SECTION - C)

ASSIGNMENT SHEET-1

Set-1

Q1. Derive the conditions for exact differential.

Q2. For a perfect gas, show that

= [ + ( )T ]( )p = pv + ( )T

Where is the co-efficient of cubical/volume expansion.

Set-2

Q1. Derive Maxwell Relations.

Q2. Determine the change in internal energy when a gas obeys Van der Waals equation.

Set 3

Q1. Derive the two Tds equations.

Q2. Determine the change in enthalpy when a gas obeys Van der Waals equation.

Set- 4

Q1. Explain the co-efficient of Expansion and its determination from p-v-T data.

Q2. Determine the change in entropy when a gas obeys Van der Waals equation.

Set- 5

Q1. Explain compressibility and its determination from p-T diagram.

Q2. Derive the following relation:

( )S =

Where = Co efficient of cubical expansion, and K= Isothermal compressibility

Set- 6

Q1. Explain the joule Thomson co-efficient and derive its expression.

Q2. . Derive the following relation:

( )s = -

Where = Co efficient of cubical expansion, andK= Isothermal compressibility

Set-7

Q1. State the significance of Clausius-Claperyon equation and derive its expression.

Q2. Using Clausius Claperyons equation, estimate the enthalpy of vaporisation. The following data is given:

At 200C; vg = 0.1274 m3/kg; vf = 0.001157m3/kg; ( ) = 32/