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APEX CLASSES FOR IIT-JEE

ALKYL HALIDE & ORGANOMETALLIC COMP.
D.P.P. - 3

1. Identify the products:

2. Identify A, B, C, D, E, and F.

3. It required 0.70 gm of hydrocarbon (A) to react completely with 2 gm Br2; On treatment of A with
HBr, it yields mono bromoalkene (B). The same compound (B) was obtained when (A) was treated
with HBr in the presence of peroxide write down the structural formula of (A) and explain the
reactions envolved.
4. RCl is treated with Li in ether to form R – Li, R – Li reacts with water to form Isopentane. R- Cl also
reacts with Na to form 2, 7 – dimethyl octane. What is the structure of R – Cl.
5. Identify the product: PhMgBr + CH 2 − C = CH 2 → ?
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Br Br
6. An ole finic hydrocarbon (A) adds Cl2 to give a compound (B) which when treated with sodamede
gives a hydrocarbon (C). C is treated with dil. H2SO4 in the presence of HgSO4 and then D is
obtained D. On reaction with alkaline hypochlorite gives an acid (E). (D) on reduction with LAH
gives (F) which on dehydrocarbon (G) which is isomeric with (A) and which on ozonlysis gives two
moles of acetaldehyde. How do you account for these reactions.
CH3
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7. What are products in following reac . H 3 C − C − Cl + OCH 3 →
n
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CH3
8. Write the structure of nucleophillic substitution products.

9. Identify A, B, --------- H.

10. Write down products.

(a) (CH 3 )3 CCl + OCH 3 → (b) (CH 3 )3 CO − + CH 3 X → .

APEX CLASSES for IIT-JEE 3F RESTAURANT, KABIR NAGAR, DURGAKUND, VARANASI.