Exercise # 1

Q.1 Ratio of O2 and N2 in a mixture .of these gases is 1 : 4, then what will be the ratio of numbers of molecules in
the mixture of the gases?
(1) 1:4 (2) 7 : 32 (3) 3 : 16 (4) 3:32
Q.2 What should be the ratio of root mean square velocity of molecular hydrogen and molecular oxygen, respec-
tively?
(1) 4 : 1 (2) 1 : 4 (3) 1 : 2 (4) 1 : 8
Q.3 Maximum number of molecules are present in
(1) 54 g of N2O5 (2) 28 g of CO (3) 36 g of H2O (4) 46 g of C2H5OH.
Q.4 Number of atoms in 12 gram of 6C12 is
(1) 6 (2) 6 x 1023 (3) 12 (4) 12 x 6 X 1023
Q.5 A gas at 30 C is Compressed to reduce its volume to half of its initial volume. At what temperature will it
become double of its initial volume?
(1) 60C (2)303C (3) 240C (4) 606C
Q.6 Volume of a gas at 35 C and 1 atmospheric pressure is 3.75 litre. If volume is to be made 3.0 litre at same
pressure, then the temperature will be
(1) 26.6C (2) 0C (3) 3.98C (4) 28C
Q.7 Which of the following is incorrect relation in the critical constants Vc, Tc and Pc?
(1) a = 3 PcVc2 (2) b = Vc/3 (3) Tc = 8a/27Rb (4) b = 3 x Vc
Q.8 At what temperature, the RMS velocities of hydrogen (1 atm. pressure) and oxygen (NTP) will be same
(1) 37 K (2) 17 K (3) 512K (4) 27 K
Q.9 5 grams each of HF, HCI, HBr and HI have been taken at 87 C and 750 mm pressure. Which of the following
should have maximum volume?
(1) HF (2) HCI (3) HBr (4) HI
Q.10 Temperature of 20 lit res of nitrogen at constant pressure is increased from 100 K to 300 K, then the change in
volume will be
(1) 80 litre (2) 60 litre (3) 40 litre (4) 20 litre
Q.11 Value of average free path at 1 atmospheric pressure is L, then what should be its value at 5 atmospheric
pressure?
(1) 2/5 L (2) 5 L (3) L/5 (4) Uncertain
Q.12 Equal molecules of N2 and O2 are kept in a closed container at pressure P. If N2 is removed from the system,
then the pressure will be
(1) P (2) 2P (3) P/2 (4) P2
Q.13 Order of the rate of diffusion of SO2, CO2, PCl3 and SO3 will be
(1) SO2> SO3 > PCl3 > CO2 (2) CO2 > SO2 > SO3 > PCI3
(3) PCl3 > SO3 > SO2 > CO2 (4) CO2 > SO2 > PCl3> SO3
Q.14 What should be the pressure of 2 mole of an ideal gas at 546 K and 44.8 litre volume? .
(1) 2 atm. (2) 1 atm. (3) 4 atm. (4) 5 atm.
Q.15 At 27 C and 750 mm pressure, volume of a gas is 38 ml, then its volume at STP will be
(1) 34 ml (2) 43 ml (3) 4.3 ml (4) 3.4 ml
Q.16 At which temperature, the average velocity of N2 molecules will be equal to the velocity of He molecules at 300
K?
(1) 2100 K (2) 1100 K (3) 420 K (4) None of the above
Q.17 What should be the partial pressure of H2 in a flask, if 2.016 gram of H2 and 16.0 gram of O2 are present in it?
(1) 1/8 of total pressure (2) 1/6 of total pressure
(3) 1/4 of total pressure (4) 2/3 or total pressure