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30 Properties of Molecular Systens No. Components Bp % | No. Components Bp ‘ 7 Carbon tetrachloride 84 | 55 Bthanol 8 77 1-Propanol 65 11} 93 Bthyl acetate 70 83 216 water 5 | 216 water 3 12 Chloroform 91 | 55 Bthanol 14 55 Ethanol 78 5] 89 Ethyl methyl ketone 73 © 75 216 Water 4 | 216 water na 12 Chloroform 81 | 55 Ethanol 33 23° Methanol 53 15) 170 Heptane 6a 61 216 Water 4 | 216 water 6 143 cyclohexane 60 | 55 Ethanol 12 89 Ethyl methyl ketone 64 35 | 146 Hexane 56 85 216 water 5 | 216 Water 3 143 cyclohexane 33 | 55 Ethanol 37 23 Methanol 51 18 | 159 Toluene 74 81 71 Methy) acetate 49 | 216 water 12 143 cyclohexane 71 | 89 Sthyl methyl ketone a8 106 -Butyl alcohol 65 21 | 78 2-Propanol 23 1 216 Water 8 | 216 water n 143 Cyclohexane 82 | 89 xthy2 methyl ketone 22 77 1-Propanol 67 10 | 146 Hexane ss 77 216 Water a | 216 Water 1 143 cyclohexane 74 | 146 Hexane 59 78 2-Propanol 64 29 | 23 Methanol 450 1d 216 Water 7 | 71 Methyl acetate 27 43 1,2-Dichloroethane 77} 78 2-Propanol 38 55 Ethanol 68 16 | 159 ‘Toluene 76 49 216 water 7 | 216 Water 13 43. 1,2-Dichloroethane 73 78 2-Propanol 70 19 216 Water 8 III, EMPIRICAL BOILING POINT-PRESSURE RELATIONSHIPS A. Approximate Changes in Boiling Point with Pressure for Unassociated The table on pages 32 and 33 provides a rapid estimation of bp as a function of pressure, For example, a substance with bp 250° at. 760 mm will distill biquids at 93° under 2 mm.

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