Properties of Molecular systems II: ASEOTROPTC DATA The tables in this section give the properties of the various binary and ternary azeotropes at 760 torr (mm ig) formed by the liquids included in the table of the properties of solvents and common liquids (p. 4). in the various sources for these data much discrepancy was found. The data on boiling points were much more reliable than those on percent composition but nevertheless contained enough disctepancies to justify the reporting of bp values only to the nearest degree. In some casag this discrepancy was resolved by finding agreement in two, three, or four of the sources, although usually it was impossible to determine if the data had come from the same original source. By far the most reliable figures appear in Azeotropic Data, Vols. T and II, Advances in Chemistry Series, Nos. 6 and 35, Atterican Chemical Society, Washington, D.C., 1952 and 1962, from which most of the information appearing here was obtained, When a Severe discrepancy could not be resolved, the azeotrope was not included in this table. A binary azeolrope index'is given on page 18. The column entitled "No." in the tables below refers to entries in the main table of the properties of solvents and common liquids (p. 4). Composition of azeotropes is in weight percent. A. Binary Azeotropes No, Components Bp % | No. Components Bp 45 acetaldehyde ao 728 | 47 Acetic acia or 28 101 thy] ether 24 | 159 Toluene nR 47 Acetic acid so 2 | 47 Acetic acia se of 137 Benzene 98 | 28 Trichloroethylene 96 47 Acetic acid are 93 | 68 Acetone 43 33 132 Bromobenzene 5 | 25 Carbon disulfide 67 47 Acetic acid 120 43 | 68 Acetone se 88 100 1-Butanol 37 7 Carbon tetrachloride 12 47 Acetic acid 76.2 | 68 Acetone es 2d 7 Carbon tetrachloride 98 | 12 Chloroform 59 47 Acetic acia eo 2 | 88 Acetone a6 15 143. cyclohexane 98 | 73 1-Chioropropane 85 47 Acetic acid 11g 58 | 68 Acetone 53 67 41 1,2-Dibromoethane 45 | 143 cyclohexane 33 47 Acetic acid 93 16 | 68 Acetone a 36 15. Dibromomethane 84 | 114 Cyclopentane 64 47 Acetic acid aig 80 | 68 acetone se 30 92 1,4-Dioxane 20 | 42 1,1-Dichiorcethane 70 47 acetic acid 92 33 | 68 Acetone so 170 Heptane 67 | 146 Hexane a1 47 Acetic acia 133 51 | 68 Acetone se 0 11 Pyridine 49 | 170 Heptane 10 47 Acetic acia 107 39 | 68 Acetone se | 88 27 Tetrachlorcethylene 61 | 23. Methanol 12