Given

Component initial mass (g) Molar Mass (g/mol) Boiling Point density (g/ml)
Toluene 122.65 92.14 110.6 0.865
1-Octene 100.82 114.23 121 0.715
223.47

Feed Experiment Data

Component mole mole fraction
Toleune 1.3311265466 0.6013043389 Distillation
1-Octene 0.8826052701 0.3986956611 Bottom
Total 2.2137318166 1 Feed

Distilltation
Toleune
1-Octene
Feed Volume 279.955580916

Equailibrium Curve
Bottom Distillation
P_s (T) 801.342114153 mmHg P_s(T) 280.3275095329
P_s (O) 590.796427757 mmHg P_s(O) 195.9134007674
Alpha 1.3563760316 Alpha 1.4308746029

x y
0 0
0.0738653535 0.1
0.1521488818 0.2
0.2352592078 0.3
0.3236569471 0.4
0.417863249 0.5
0.5184700778 0.6
0.626152665 0.7
0.7416846825 0.8
0.8659568611 0.9
1 1
Chart Title
1
 Chart Title
1
0 0
0.5 0.5
0.9
1 1

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
 mass %
0.5488432452
0.4511567548

Total mass(g) Initial Drop Temeprature Stop Temperature

118.67 T_B 112.5 113
104.8 T_D 78.9 109
223.47

Distillation
Component Mass Fraction
Toleune 0.7963
1-Octene 0.2037
Avag. Alpha 1.393127423 Sum 1

Bottom
Component Mass Fraction
Toleune 0.4431
1-Octene 0.5569
Sum 1

x
0.8289540478

Title
 Title

0.5 0.6 0.7 0.8 0.9 1

 Data Mass %
G1 53.87
G2 44.31 Bottom
G3 70.63 Distillation
G4 63.6
G5 65.77

Mass Mole Mole Fraction

94.496921 1.025579781 0.8289540478
24.173079 0.211617605 0.1710459522
118.67 1.237197386 1

Mass Mole Mole Fraction

46.43688 0.503981767 0.4965787004
58.36312 0.510926377 0.5034212996
104.8 1.014908143 1

y
0.8289540478
0.8289540478
 mole fraction of vial 1 (feed)

toluene
1-octene
sum

mole fraction of vial 2 (Bottom)

toluene
1-octene
sum

mole fraction of vial 3 (Distillation)

toluene
1-octene
sum

mole fraction of vial 4 (Sample1)

toluene
1-octene
sum

mole fraction of vial 5 (Sample2)

toluene
1-octene
sum

log P = A- (B/T+C)
Antoine equation paramater
toluene
1-octene

T_1 (Bottom)
T_2(Top)
Distillation
Bottom
Feed
Sample1
Sample2
Mass balance for experimental data
L'o = D + L'
Xi,d = Yi
Xi,o * L'o = Yi*D + Xi* L' => Xi = ((Zi* L'o)- (Xi,d*D))/L'

Sample1
Sample2
Sample 3

Flash Calculation
sample
Sample 1
Sample 2
Sample 3

table with distillate and bottom composition using mass balance

sample
sample 1
sample 2
sample 3

sample
sample 1
sample 2
sample 3

Bottom
 mass fraction
0.5387
0.4613
1

mass fraction
0.4431
0.5569
1

mass fraction
0.7063
0.2937
1

mass fraction
0.636
0.364
1

mass fraction
0.6577
0.3423
1

A
6.95464
6.93263

Celcius
112.5
78.9

Total mass(g)
 118.67
104.8
223.47
90.32
112.5

> Xi = ((Zi* L'o)- (Xi,d*D))/L'

initial bottom mass (g)
223.47
223.47
223.470

y_toluene
0.680
0.701
0.746

om composition using mass balance

distillate composition Yi = Xi,d

y_toluene
0.680
0.701
0.746

table with distillate and bottom composition using flash calculation

distillate composition Yi = Xi,d
y_toluene
0.680
0.701
0.746

Using Rayleigh equation to calculate for the liquid in the bottom

Assume constant alpha
Using composition from mass balance

mol of the feed or L'o (g)

2.035
 molecular weight (g/mol) mole (mole)
92.14 1.195
112.24 0.840
2.035

molecular weight (g/mol) mole (mole)

92.14 0.983
112.24 1.014
1.997

molecular weight (g/mol) mole (mole)

92.14 1.567
112.24 0.535
2.101

molecular weight (g/mol) mole (mole)

92.14 1.411
112.24 0.663
2.074

molecular weight (g/mol) mole (mole)

92.14 1.459
112.24 0.623
2.082

B C
1344.8 219.482
1353.486 212.764

P_sat of Toleune P_sat of 1-Octene

801.3421141526 590.7964277567
280.3275095329 195.9134007674

Mole (mol)
 2.101
1.997
2.035
2.074
2.082

Mass of Distillation (g) experimental D

90.32 90.32
112.5 112.5
118.670 118.670

K_toluene Mass of distillate

1.0543975186
1.0543975186 #REF!
1.0543975186 #REF!

tion Yi = Xi,d bottom composition

Y_1-octene X_toluene
0.320 0.492
0.299 0.422
0.254 0.348

tion Yi = Xi,d bottom composition

Y_1-octene X_toluene
0.320 0.645
0.299 0.665
0.254 0.707

x_io x_Toluene
0.587 0.492
 mole fraction of the feed Zi = Xi,o
0.587
0.413
1.000

mole fraction of the feed Zi = Xi,o

0.492
0.508
1.000

mole fraction of the feed Zi = Xi,o

0.746
0.254
1.000

mole fraction of the feed Zi = Xi,o

0.680
0.320
1.000

mole fraction of the feed Zi = Xi,o

0.701
0.299
1.000

Alpha Avg. Alpha

1.3563760316
1.3931274226
1.4308746029

Component initial mass (g)

 Toluene 122.65
1-Octene 100.82

experimental L' X_toluene,d

133.15 0.680
110.97 0.701
104.8 0.746

Mass of bottom x_toluene

0.6452488146
#REF! 0.6645020281
#REF! 0.7070491369

bottom composition mass of bottom

X_1-octene L' (mol)
0.508 1.301
0.578 1.069
0.652 0.996

bottom composition mass of bottom

X_1-octene L' (g)
0.355 0.000
0.335 0.000
0.293 0.000

Constant Alpha ln(L'/L'o)

1.393 -1.183
density (g/ml)
 0.865
0.715

X_toluene bottom (mass frac) X_toluene (mol fraction)

0.4426150206 0.4916943824
0.374517833 0.4217598664
0.3045182803 0.3478409063

mass of distillate
D (mol)
0.734
0.965
1.039

mass of distillate
D (g)
0.007
0.000
0.000

RayLeigh equation experimental data

L'(mol) D (mol) L' (mol) D (mol)
0.623 1.412 1.301 0.734