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11

Heavy Oil and Viscous Oil


Craig Smalley

1 INTRODUCTION AND Classifying heavy oil on the basis of gravity is


DEFINITIONS useful for the refining industry, because the API
gravity correlates with fundamental refining value
No book on modern petroleum technology would drivers: for example, the lower the API gravity,
be complete without a section on heavy oil. Volu- the lower the likely yield of valuable refined prod-
metrically, heavy oil is very important: there is ucts such as gasoline, and the higher the yield of
probably more heavy oil on Earth than any other low value products such as tar or coke. Gravity
petroleum resource. Furthermore, technology is may also correlate with the content of undesir-
key to the production of heavy oil; it is only able components such as asphaltenes, sulphur and
through the application of modern, and future, metals like nickel and vanadium. However, gravity
petroleum technology that the Earths vast heavy itself does not usually present a problem to the
oil resources will be fully exploited. oil production process; here viscosity is far more
important.
1.1 What is Heavy Oil?
1.2 What is Viscous Oil?
The definition of heavy oil is not consistent,
varying between authors. The word heavy relates Again, definitions are very woolly. Various sources
to the high density of the oil, as usually measured quote viscosities of 10 centipoise (cP), 100 cP
by the API gravity scale. A common definition or 1000 cP (measured at reservoir conditions) as
(see, e.g., [1]) is that heavy oil refers to oil with being the cut off between conventional and viscous
API gravity < 20 ; this seems like a good arbi- oiltwo orders of magnitude variation! When it
trary value it is a round number. However, other comes to behaviour in the reservoir, viscosities as
sources of authoritative data use different cut-offs: low as 5 or 10 cP can make a big difference to
for example, the World Energy Council classifies ease and amount of recovery.
oil as being heavy if its API gravity is < 22.3 (i.e. Heavy oil and viscous oil are not completely
a density above 0.920 [2]). Petroleum liquids with interchangeable terms, because viscosity is not
API gravities of < 10 are often classed separately perfectly correlated with API gravity (Fig. 11.1).
as bitumen or extra-heavy oil. This is because of the many ways in which heavy
Edited by Richard A. Dawe. Published on behalf of the Institute of Petroleum. Modern Petroleum Technology 2000 John Wiley & Sons Ltd.
2 Modern Petroleum Technology

50 gravity is sufficiently low to become a problem


45 when trying to refine or market it. Oil is viscous
40 if its viscosity is sufficiently high to become a
35
problem for flowing the oil out of the reservoir and
API gravity

30
25
through surface pipework. That said, the general
20 range covered in this chapter is oil of < 23 API
15 gravity and > 10 cP viscosity.
10
5
0
0.1 1 10 100 1000 10000
2 THE RESOURCE BASE
Live oil viscosity (cp)
The consensus is that there may be more than
Fig. 11.1 Oil API gravity versus viscosity at reservoir 6 trillion barrels of heavy oil on Earth, although
conditions. Each point represents an oilfield (from Oil & confirming this is made difficult by the inconsis-
Gas Journal 1994 EOR database). At any single API tencies in the definition of heavy oil and in the
gravity value, there may be two orders of magnitude reporting style by different countries and agencies.
variation in viscosity. This compares to total initial reserves estimates
of 1.75 2.3 trillion barrels for conventional oils,
oil has been created (discussed later) as well as the 3040% of which has already been produced [2].
effect of external factors (e.g. reservoir temper- The locations of the main viscous and heavy
ature) on viscosity. Classifications such as Oil oil resources are shown in Fig. 11.2. Several
is considered heavy if . . . its viscosity is greater lands have tens of billions of barrels in place:
than . . . (reference shall remain nameless!) are three Canada, Russia and Venezuela are esti-
thus completely meaningless. mated to have over one trillion.
My feeling is that precise cut-off values should Canada has the largest heavy oil resource,
be avoided if possible. Oil is heavy if its API with some 1.7 trillion barrels of extra-heavy oil

Key
Alaska Barrels in place:

Russia 1 billion
UK
Netherlands
Canada E. Europe 10 billion
Italy
Turkey
USA Lower 48 Jordan Kuwait
Iran 1 trillion
Egypt
Mexico
Saudi India
Trinidad Arabia
Venezuela
Colombia
Indonesia
Brazil Angola

Argentina Madagascar

Australia

Fig. 11.2 Major heavy and viscous oil resources.


Heavy Oil and Viscous Oil 3

(270 billion tonnes) situated in the oil sands producible reserves for the four main areas are
of Alberta, plus a further 25 billion barrels of 265 billion bbl in Machete, 220 billion bbl in
heavy oil in the 10 22.3 API gravity range [2]. Hamaca, 500 billion bbl in Zuata, and 215 billion
Production in Canada was about 160 million bbl in Cerro Negro (Fig. 11.4). Various produc-
barrels in 1996, less than 0.0001% of the total tion methods have been employed, especially hori-
volume. This is clearly a resource for the future. zontal wells with periodic thermal stimulation
Canadas heavy oil and bitumen is situated in using steam. Much of the heavy oil is blended
the Athabasca, Wabasca, Peace River and Cold with lighter liquids for sale or export, while the
Lake areas of Alberta, and the Lloydminster area extra heavy oil is predominantly exported in the
of Saskatchewan (Fig. 11.3). The oil is produced form of an easily transported wateroil emulsion
by a variety of methods, ranging from surface (Orimulsion) for burning in power plants. Some
mining to high-tech thermal processes (discussed 17 million barrels of oil were exported in this form
later). Much of the heavy oil is processed through in 1996, produced from the Cerro Negro area of
upgrading plants, producing a much lighter syn- the Orinoco Belt (Fig. 11.4).
thetic crude oil. About 280 mbopd of this syn- Compared to Canada and Venezuela, Russia
crude were produced in 1996. the other heavy oil giantis way behind in
Venezuela has around 1.2 trillion barrels of exploiting its vast resources, which includes appro-
extra-heavy oil in the 400 mile long Orinoco Belt aching 200 billion barrels of bitumen and extra-
(known as the Faja) in the east of the country heavy oil. The Yarega field, in the TimanPechora
(Fig. 11.4), plus up to 250 billion barrels of heavy area, produces about 10 000 b/d of bitumen and
oil in other areas. In the Orinoco Belt, reported extra-heavy oil, some by surface mining.

NWT
BC Alberta Saskatchewan

Athabasca

Peace Wabasca
river
Cold lake
Edmonton

Lloydminster

Calgary
250 km
Canada
USA

Fig. 11.3 The main heavy oil and bitumen deposits in Canada.
4 Modern Petroleum Technology

Caribbean sea
Guiria
Caracas
Jose Caripito

El tigre
Cerro negro
Machete Hamaca
Zuata
Puerto ordaz
ver
oco ri
Orin

100 kms(approx)

Fig. 11.4 The Orinoco Belt of extra-heavy oil accumulations in Venezuela.

3 ORIGINS OF HEAVY OIL A comparison of fresh and biodegraded oil is


shown in Fig. 11.5, a set of gas chromatograph
Heavy oil is not a genetically distinct grouping traces. This figure clearly shows the disappearance
there are several routes by which heavy oil may of the lighter compounds (to the left) during
be created, or by which light oils might become degradation. If the original oil contains sulphur
heavier. These are described below. and metals such as nickel and vanadium, these will
be up-concentrated in the residual oil, leading to
3.1 Biodegradation unattractively high levels of these elements.
Biodegradation is limited to temperatures at
The huge volumes of heavy oil in places like which bacteria can thrive, usually < 70 C, and
Canada, Venezuela and Alaska, owe their low is thus restricted to relatively shallow oil accu-
API gravity to biodegradation. Biodegradation mulations (generally < 2.5 km, although there are
occurs when microbes attack components of the exceptions in cold environments such as Alaska).
oil. Unfortunately, the most easily metabolized Bacteria require a source of energy in order to
components of crude oil are the smallest metabolize the oil. The main group of bacteria that
and simplest ones; that is, the lightest and eat oil are aerobic, and they require a constant
most valuable components. With progressive source of oxygen; aerobic biodegradation thus
biodegradation the easily metabolized compounds occurs where a shallow oil accumulation is over-
are gradually stripped from the oil. Normal lain or underlain by an active aquifer carrying
alkanes are the first compounds to disappear, dissolved oxygen. Anaerobic biodegradation can
followed by the more complex cyclic and aromatic occur through a fermentation-type process, where-
compounds. The largest and heaviest compounds by oxygenated compounds in the oil are broken
in oilthe asphaltenesare relatively resistant to down, with methane and carbon dioxide as by-
microbial attack. Thus, in the most severe cases products.
of biodegradation, all that is left of the oil is Biodegradation van be a very variable process,
a tarry residue rich in resins and asphaltenes. even within a single reservoir; consequently
Heavy Oil and Viscous Oil 5

MCH Degree of biodegradation:


None
7
6

5
8
T 9

11
13
4
17 18
Pr Ph 25
33

Minor

11 13
17 18
T
5 Pr Ph 25
4 33

Extensive

MCH

Fig. 11.5 Gas chromatograms, showing the effect of biodegradation on an oil from South Pass 61 field, Gulf of
Mexico (modified from Holba et al. [35]). Biodegradation increases from top to bottom. On these plots, each peak
is a specific compound in the oil; the larger, more complex, molecules lie to the right. The carbon numbers of the
n-alkanes are noted, with thick lines joining key peaks. These become difficult to identify in the heavily degraded
sample, where alkanes have all but disappeared.

biodegraded oil can have widely variable 3.2 Low-maturity Oil


compositions from place to place within a single
field. This is a often a major challenge to Some oil source rocks, particularly calcareous
determining the value of the resource and its ones, begin generating oil at relatively low
optimal production strategy (see e.g. [3,4]). temperatures. Such source rocks can generate large
6 Modern Petroleum Technology

volumes of low-maturity oil that is relatively barrels of heavy oil may be situated within these
heavy (15 23 API) and viscous (note it is heavy oil legs, currently ignored because of the
not usual for very heavy or extra-heavy oils huge quantities of light oil above. In coming years,
to be generated in this way, unless they are as the lighter oil becomes depleted, production
subsequently biodegraded). One example of this of the heavy oil will no doubt be attempted,
is the Cretaceous La Luna source rock that particularly as the production infrastructure is
has sourced many of the moderately heavy already in place.
oil accumulations in western part of Venezuela,
around Lake Maracaibo.
4 TECHNICAL CHALLENGES
3.3 Gravity Segregation
Why is heavy oil classified separately from other
In some oilfields, particularly those that have petroleum fluids? It is because heavy oils and
a large column height and good vertical viscous oils carry with them a unique set of
permeability, gravity segregation may occur, technical challenges when it comes to exploiting
where heavier components of the oil (e.g. resins, them. These challenges were recently highlighted
asphaltenes) sink towards the base of the oil by a survey conducted within BP Amoco and
column. This is exacerbated in situations where partner organizations; the findings were reported
asphaltenes have been encouraged to precipitate, at a United States Department of Energy Work-
for example by a late gas charge into the field. shop [5], and confirmed by the outcomes of that
The end result can be a distinct accumulation of workshop. These technical challenges are summa-
heavy oil at or close to the oil-water contact. Many rized and discussed in the subsequent sections.
of the worlds giant fields have these heavy oil legs
at the base: Prudhoe Bay (Alaska), Gharwar (Saudi 4.1 Reservoir Issues
Arabia), Burgan (KuwaitFig. 11.6) and Soroush
(Iran) to name but a few. In many cases, billions of 4.1.1 Fluid Characterization and Prediction
Heavy and viscous oils are notoriously difficult to
API gravity characterize. For one thing, oil samples may be
10 15 20 25 30 35 40 difficult to acquire, particularly reservoir-condition
3400 samples for PVT work, as some of the standard
3500 Burgan sampling tools are unreliable in heavy oils. Further,
3600 NE Burgan the cost of sample acquisition may be difficult
3700 to support in low flow rate, low value wells.
3800 Next, the actual measurements are more problem-
Depth (ft)

3900 atic in heavier oils. Relatively simple measure-


ments such as API gravity can suffer from the
4000
difficulty of being able to separate oil or gas
4100
effectively from the oil, particularly where emul-
4200
sions have formed through the use of electric
4300 submersible pumps. Standard viscosity measure-
4400 ments also break down in very viscous oils;
4500 specialized techniques must be applied to obtain
reliable results, although this is not always done in
Fig. 11.6 Decrease in oil API gravity with depth in the service laboratories.
Burgan field, Kuwait, due to gravity segregation (after
Kaufman et al. [36]). The basal 100 ft or so could be Direct detection of oil using seismic techniques
classed as heavy oil. The cross-sectional area of the field is becoming an increasingly important tool in
increases with depth, so this represents a lot of oil. reservoir development. However, this does not
Heavy Oil and Viscous Oil 7

work well in heavy oils due to the similar densities the possibility of pressure support from reservoir
between the oil and water. compaction which, though beneficial, can be
A further problem is that the fluids in a heavy difficult to simulate accurately.
oil reservoir may be much more variable than
in a conventional reservoir. For example, in the 4.1.3 Performance Prediction
Schrader Bluff reservoir in Alaska, produced fluids There are a number of specific problems that make
vary between 14 and 24 API, and between 15 and performance prediction (e.g. rates and recovery
600 cP at reservoir conditions [3]. This constitutes factors) difficult in heavy and viscous oils. These
the difference between an attractive mobile oil, and relate to the unusual production technologies that
an unattractive oil that is very difficult to produce. must be used to mobilize the oil (e.g. thermal
Hence new approaches, using geochemical tech- processes, discussed later), and unusual PVT prop-
niques for example, that can help predict the loca- erties of the oils. One example of the latter is the
tions of oil quality sweetspots, can be very valuable formation of a third petroleum liquid phase during
for designing commercially attractive heavy oil miscible flooding of heavy oils [6], a situation that
developments. some reservoir simulators cannot handle.

4.1.2 Rock Characterization 4.1.4 Recovery Processes


As well as suffering from all the same reser- Primary recovery factors for heavy oils in the
voir description issues as conventional oil develop- 1423 API gravity range are very low, generally
ments, heavy oil fields have some additional issues. in the 510% range (Oil & Gas Journal 1994 EOR
These are mainly related to the fact that heavy oil, database). For extra heavy oils, production may
particularly that formed by biodegradation, is often not be possible at all without supplying energy
situated in shallow, unconsolidated sands. Apart to the oil. Consequently, heavy oil production
from sand production problems, discussed below, almost always involves some form of improved
there are two other issues peculiar to unconsoli- recovery process. These include waterflooding in
dated sands: the less-viscous end of the spectrum, and many
processes peculiar to heavy oil such as steam
Soft sands are very difficult to core and, even stimulation and steam-assisted gravity drainage.
when using state-of-the-art soft sand coring These recovery processes will be discussed in more
procedures, there is clear evidence that conven- detail later. Here it is relevant to note that there are
tional core analyses may give anomalous results challenges related to generating the expertise and
(BP Amoco, unpublished data). Generally, soft infrastructure for these unusual recovery processes,
sands yield porosities that are too high and a well as problems with simulating and predicting
permeabilities that are too low compared to their outcome, in turn leading to a high degree
(a) modelled values, or (b) extrapolations from of risk in development decisions. The latter is
their consolidated equivalents. Great care must particularly the case with the newer experimental
thus be taken in using core-derived reservoir recovery processes (e.g. VAPEX). Note too, that
quality data for predicting volumetrics or well many of the thermal processes are very energy-
deliverabilities, and the uncertainty taken into intensive: perhaps 25% of the produced oil may
account. Log-derived properties may also be have to be burnt to generate the energy needed for
suspect due to dilation of the soft rock in the production; this skews development economics yet
near-wellbore region. further away from heavy oils.
Unconsolidated sands often have high compress-
ibilities. This can lead to a range of concerns, 4.2 Well Issues
including potential surface subsidence as the
reservoir pressure is drawn down, permeability There are four interlinked challenges related to
modification as the reservoir compresses, and well design for heavy oil production: the well
8 Modern Petroleum Technology

and completion type, the artificial lift process, the Used previously for moving viscous fluids in the
strategy for dealing with sand production and all foodstuffs industry (e.g. cherry pie filling!), PCPs
these feed into the overall well rate and cost. The are suited to lifting viscous oil and are more
well rate and cost balance is a delicate one. Wells tolerant of sand though they can still fail with
can be designed for optimal rate, but then they may high sand cuts. PCPs are favoured in cold (i.e.
be too costly. Wells can be de-scoped stripped not thermally stimulated) production projects in
of everything unnecessary and scaled down in Canada (see, e.g., [8]). These are mainly surface-
hardware to a bare minimum cost but then rate driven PCPs, where the motors are situated on
may be compromised. In each heavy oil devel- the surface and the downhole pumps are operated
opment, the optimum rate/cost balance must be by a long rotating rod. Such pumps are relatively
determined. easy to unseat, clean out, retrieve, and the motor
The need for a sand management strategy is is easily accessible for service. Surface-driven
linked to the fact that unconsolidated heavy oil pumps are less attractive in deeper reservoirs,
reservoirs are prone to sand production. Sand can particularly those with curved well trajectories,
be controlled downhole by using screens or gravel as these are more susceptible to rod wear and
packs to prevent sand from entering the wellbore. failure. In such reservoirs, downhole-driven Elec-
However, these add cost to the well and may intro- trical Submersible PCPs may be favoured, though
duce a well skin factor that reduces flow rate. Sand with concomitant increased cost of pump failures.
production can also be minimized by using hori- Other types of artificial lift that have been used
zontal wells with a small drawdown, with slotted for viscous oils include gas lift, water or oil-
liners with a slot size designed to exclude sand, powered hydraulic pumps, and jet pumps.
or induced fractures filled with resin coated prop- A consequence of the need for artificial lift
pant. Alternatively, sand production can be toler- in heavy oil fields is that the wells may often
ated or, in the case of the cold production process, be pumped below the bubble point of the oil.
encouraged, often with gains in well productivity. This leads to gas coming out of solution in the
However, this can generate cost and environmental near-wellbore region, leaving that oil gas-depleted,
concerns over disposal of the oily sand at the and thus more viscous. In time a bank of gas-
surface, as well as playing havoc with any pumps depleted dead oil can develop around the well,
in the well. dramatically decreasing well flow rate (the so-
Many heavy oils require artificial lift in order called viscous skin effect). The PVT properties
to be produced to the surface. In some fields, of the oil are thus another set of parameters that
Electrical Submersible (or Submergible) Pumps, or need to be taken into account in optimizing this
ESPs, are favoured because of the large drawdown complex system.
they can produce (e.g. Schrader Bluff, Alaska; The key message when it comes to well issues
see [7]). ESPs comprise a series of rotating turbine- for viscous oils, is that the wells need to be seen
type blades. These pumps have the drawback of holistically, as a system that involves the forma-
being very sensitive to even small amounts of tion, the completion, the well and the lift process.
sand production, and pump failures can form the Only by achieving an integrated view of these
major component of operating expenditure in such elements and their interactions can the optimal
fields. Recent advances in pump retrievability, cost/rate design be selected and implemented.
including wireline and tubing conveyed ESPs, will
reduce the cost associated with replacing failed 4.3 Processing Issues
pumps, enabling them to be pulled without the
need for a full scale rig. Progressive Cavity Pumps Processing here refers to the things that have to be
(PCPs) have a rotating spiral shaft that is shaped done to the oil once it has been produced, before
to produce a low pressure zone on the under- it can be exported or marketed. There are several
side of the spiral and draw the fluid upwards. relatively minor issues that fit here: for example
Heavy Oil and Viscous Oil 9

sand carry-over into the surface facilities may be Separation time in a conventional separator can be
a problem in wells prone to sand production, and shortened by heating the oil, by adding demulsi-
corrosion may be a risk in oils produced by certain fying chemicals, or by increasing residence time
EOR processessuch as CO2 flooding or in situ in the separator (by making the separator larger or
combustion, where elevated CO2 contents in the modifying the internal geometries).
fluids may increase the corrosion rate. However, The rheology of viscous oils, and in particular
the two processing issues that are most specific for mixtures of viscous oils and other fluids (water,
heavy or viscous oils are oil water gas separation low-viscosity oil etc.) is very poorly understood.
and oil upgrading. The lack of predictive behaviour for viscous oil
separation arises from the fact that bottle tests take
4.3.1 OilWater Gas Separation no account of dynamic factors such as shearing and
shear history. This lack of understanding makes it
The separation of produced heavy/viscous oil from
difficult to generate predictive models for separator
co-produced water is difficult because the separa-
performance in heavy oils under different oper-
tion process usually relies on density segregation,
ating conditions. This in turn makes it important
but in heavy oils the density difference between
to design the separation facilities with sufficient
the oil and water may be very small, making sepa-
flexibility (e.g. designing conventional separators
ration very slow. The high oil viscosity itself also
to handle a range of different internals) in order
makes the separation process slower; the higher the
to avoid costly retrofitting. Designed-in flexibility
viscosity of the oil-water emulsion, the poorer the
involves up-front costs, but some recent studies
separation efficiency (Fig. 11.7). These problems
have shown that, for offshore viscous oil fields,
are exacerbated with the use of certain produc-
tion processes (e.g. using ESPs for artificial lift) this investment is worth it. This is because the
that create intimately mixed oilwater emulsions, penalty for over-sizing facilities is small relative
or cold heavy oil production that may produce a to the penalty for under-sizing them limiting the
foamy mixture of oil and gas. The susceptibility of entire subsequent revenue stream.
viscous oil wells to water coning where there is an It is often the case that production chemistry has
underlying aquifer also leads to high water cuts. a far greater influence on the performance of a sepa-
rator performance than its size. This would include
features such as emulsions, waxes, asphaltenes and
10
solids. Considerable effort has been made over the
9
years to develop oil-water separation models which
Separation efficiency (%)

8 5000 G
7 take account of field conditions and factors such as
6 shear, dropletdroplet coalescence and emulsion-
5 forming tendency, but this is still a key uncertainty
4 in separator design.
1G
3 In some cases it may not be possible
2 to deal with heavy oil separation problems
1 simply by making the conventional separator
0 bigger or more complex. Such situations would
0 10 20 30 40 50 60 70
Viscosity (cSt) include: (1) onshore developments where some
degree of near-well processing is required or
Fig. 11.7 Separation efficiency for separating water where the central process facilities are size-
from an oil-continuous oil-water emulsion as a function constrained (e.g. environmentally sensitive areas
of emulsion viscosity. The 1G curve illustrates sepa- where facilities footprint must be kept small);
ration efficiency under a natural gravity field, i.e. a
conventional separator. The 5000 G curve illustrates the (2) offshore satellite developments where the
effect of a centrifuge separating system (modified from facilities need to be modified to receive higher-
Dhuldhoya et al. [37]). viscosity oil, but where there is no platform
10 Modern Petroleum Technology

space to retrofit larger separation facilities; (3) new Delayed coking. This process uses rapid heating
offshore developments where high oil viscosity to 400500 C, producing lighter fluids and large
would necessitate prohibitively large, heavy or amounts of coke this is usually a drawback.
expensive conventional equipment; (4) modular Visbreaking. This is a relatively mild thermal
flexible developments. In these cases compact cracking operation (450500 C at elevated pres-
separation technologies are required. There have sure), which breaks off the long paraffinic side
been some recent advances in the application chains attached to aromatic rings, thus reducing
of compact separators to heavy and viscous oil, viscosity. The drawback of this process is that
including centrifuges. These improve oilwater the products may be unstable and unattractive to
separation efficiency by replacing the natural a refinery without subsequent hydrotreating.
gravitational force on the oil with a centrifugal
Hydrocracking. A hydrogen-in process that
force several thousand times greater (Fig. 11.7).
occurs at 300400 C in the presence of catalysts
(Co/Mo/Ni/zeolite), to produce lighter oil.
4.3.2 Oil Upgrading
Hydrotreating. A relatively mild operation (280
Upgrading here refers to pre-refinery processes that 420 C at high pressure, in the presence of Co/Mo/
are designed to raise the API gravity and/or lower alumina catalysts) that saturates olefins with
the viscosity of the oil to make it either more trans- hydrogen and reduces sulphur content.
portable or more easily marketable. Upgrading is
necessitated in some situations because, without There are also various hybrid processes. One
it, the produced oil is too viscous to flow in a such is Aquaconversion, a process developed in
pipeline. In other cases, it is market considera- Venezuela by PDVSA. This is a catalytic hydro-
tions that make upgrading necessary. Upgrading visbreaking process that involves heating the crude
the oil from, say, 10 API to 25 API may help it oil in the presence of water and a catalyst, with
compete more effectively with conventional crudes hydrogen being released from the water and being
for specific markets, and thus realize a higher added to the oil. Other related processes have been
price: on average the per-barrel price rises by $0.40 developed that use varying degrees of heat and
per API gravity degree. In some cases, upgrading pressure treatment severity and different hydrogen
may occur as the first stage of treatment in the donorsmethane, for example.
refinery. Upgrading systems vary from massive plants
Various processes are available for oil upgrading capable of handling > 100 000 barrels of crude
(see [9] for further details). These are two main per day (e.g. the Canadian Syncrude and Suncor
types of processes. Carbon-out processes use vary- plants), to small mobile units that can be placed
ing severity of heat and pressure treatment, often near a wellhead. Most of the latter are currently at
in the presence of catalysts, to break up (crack) the experimental stage. Taking the process one step
high molecular weight substances into lighter and further, another potential development is downhole
heavier fractions. The lighter components make the upgrading, for example by placing a catalyst bed
oil lighter, while carbon is removed from the oil into the wellbore and making use of the natural
in the form of heavier carbon-rich species such heat of the reservoir (see, e.g., [10]). It is likely
as coke. Hydrogen-in processes add hydrogen to to be some time before such possibilities become
the oil by exposing oil to a hydrogen donor (e.g. commercially viable.
hydrogen gas and water), usually in the presence
of a catalyst . Examples include: 4.4 Transport Issues
Catalytic cracking. This involves heating the Transporting heavy or viscous oil is made difficult
heavy oil to 500 600 C in the presence of a because of their sluggish flow properties, and their
catalyst (e.g. zeolite) to produce lighter comp- propensity to precipitate undesirable substances
ounds and coke. such as asphaltenes. There are two categories of
Heavy Oil and Viscous Oil 11

problem: transport of heavy oil in its own in a 30% water, and a surfactant additive that stabi-
pipeline or flowline; and addition of heavy oil to lizes the emulsion. Orimulsion, once formed,
an existing conventional oil pipeline. can be pumped, transported, stored and finally
The first of these is a problem when exporting burnt as a fuel in power plants using virtu-
heavy oil from large heavy or extra-heavy oil ally conventional equipment. Orimulsion has
provinces where there is little or no lighter oil been generated in the Cerro Negro area of
production to dilute it with. In such cases, the Venezuela (Fig. 11.4) and exported to markets
very viscous oil will not flow in a pipeline unless in various countries since 1988. Growth in sales
something is done with it first. Various options has been constrained by environmental issues
include: related to emissions of particulates and sulphur
compounds.
Upgrading. Discussed above, the process here is
to perform the first step of refining prior to trans-
port, to reduce the oil viscosity and improve its 4.5 Environmental Issues
flow characteristics. This occurs in some of the
large Canadian projects (e.g. Suncor, Syncrude). A number of oil companies are driving to reduce
Advantages: a more marketable product. Disad- the environmental impact of their operations. When
vantage: large up-front capital expenditure req- it comes to heavy oil production, there is a real
uired that can be crippling to project economics. challenge to reach similar standards as would be
expected for lighter oil production, simply because
Dilution. Here, the viscous oil is mixed with heavy oils face natural disadvantages. The main
a low-viscosity fluid to improve its flow prop- disadvantage is that heavy oil reservoirs do not
erties. In some cases a natural diluent may be give up their resources easily. Just to get the oil
present locally; for example, lighter oil from to flow from the reservoir into the wellbore often
a deeper reservoir unit, or methanol generated requires coaxing through the use of heat. When in
from nearby gas. This may be attractive, but the the wellbore, artificial lift is often required to bring
positive effect for transportation of the viscous the oil to the surface, through the use of pumps
oil has to be weighed up against the loss in or gas lift, requiring compression. At the surface,
value of the light oil or methanol by contami- flow lines and processing equipment may need to
nating it with the heavy oil. The economics of be heated to keep the oil mobile and to facilitate
this will vary from case to case. Where there is separation from water and gas. Finally, heavy oil
no local supply, diluent would have to be trans- export in pipelines may require additional pumping
ported in, requiring a second pipeline (one for or heating. All of these factors require energy; the
diluent in, the other for diluted crude out). The energy consumed to lift and process a barrel of
capital cost of the second pipeline negatively heavy oil may equate to 20% or more of the oil
affects economics; also the cost of the diluent, produced, several times more than is needed to lift
or the cost of separating the diluent from the a barrel of conventional oil. This energy consump-
crude for re-use, has to be factored in. This type tion produces CO2 ; if heavy oil is being burnt
of process has been proposed for extra heavy oil in the field (for example, in steam boilers) then
developments in Venezuela. this may also produce emissions of sulphur and
Trucking. A low capital-cost, low-tech solution metals.
that will only work for very short transport These natural disadvantages are not insurmount-
distances. able: they can be tackled through the innovative
Orimulsion. Orimulsion is a concept developed use of technology. One example of this is the
in the 1980s by PDVSA in Venezuela for the possibility of extracting the CO2 from flue gases
purpose of transporting and exploiting the vast from power generators or compressors, and using
Orinoco extra heavy oil resources (Fig. 11.4). it for re-injection into the reservoir as an IOR
Orimulsion is an emulsion of 70% heavy crude, solvent [11]. Much work is being carried out on
12 Modern Petroleum Technology

this at present, and this may soon develop into 5.1 Primary Recovery
a way of making CO2 do useful work, while
becoming sequestered safely in the subsurface. Primary recovery is the simple production of the
Another environmental impact of heavy oil oil, with no artificial addition of reservoir energy.
production is its areal footprint. Because well flow Primary production can benefit from natural pres-
rates are generally low, and reserves per well sure support if underlain by large aquifers, but even
too, many more wells are required to develop a so, the recovery factors associated with primary
heavy oil field than an equivalent conventional production of heavy oil are very low, almost
oil field. In onshore fields, this has often trans- always < 10% (Table 11.1). As discussed previ-
lated in the past to very small well spacings: ously, heavy and viscous oils are often situated
16 or 8 acre spacing is not uncommon. This can in shallow under-compacted sands which can have
make an obvious visual impact on the landscape very high compressibilities; with pressure reduc-
that would not be tolerated in a new development tion due to production, this can lead to a degree of
today. Again, new technologies can help. Some support from compaction drive. This can be signif-
new and proposed developments in environmen- icant in fields that start out highly overpressured;
tally sensitive areas, such as Arctic tundra and otherwise the pressure drop is not large enough
South American rain forest or wetlands, utilize to do more than add a couple of percent to the
horizontal well technology to reduce the number of recovery from compaction drive.
wells needed, as well as allowing several wells to Primary recovery requires the least initial
be drilled from a single site, minimizing footprint. capital outlay of all the recovery processes,
In addition, the use of new types of compact facil- unless complex well designs are needed to
ities further reduces the need for large processing provide sufficient production rate. However, in
plants. the absence of pressure support, reservoir pressure
However responsible the industry is in producing decline will reduce well flow rates, increase
and processing heavy oil, the fact is that sooner gas production if the oil goes below bubble
or later much of it is going to be burnt as fuel. point, and this will then increase the viscosity
The high carbon/hydrogen ratio of heavy oil means of the gas-depleted remaining oil. Furthermore,
that, when burnt, it produces more CO2 than the large reservoir drawdowns increase the potential
equivalent amount of conventional oil, and a lot for sand production and the costs entailed with
more than natural gas. In the grand scheme of managing it. Primary recovery is most likely to be
things, heavy oil is thus much better suited to attractive in fields with high initial pressure and a
use as a feedstock for petrochemicals than as strongly undersaturated oil, or in the initial phases
a fuel. of development prior to making decisions about
later EOR.
The primary production of heavy oil, without
5 RECOVERY PROCESSES FOR thermal stimulation, has become known as cold
HEAVY AND VISCOUS OIL production or CHOP (cold heavy oil produc-
tion). In some cases, CHOP involves the inten-
Much of the problem with exploiting heavy and tional production of sand, because this is seen to
viscous oil revolves around extracting sufficient
amounts at sufficient rates to be commercially
Table 11.1 Recovery factors (%) for heavy oils
competitive. This is why so much effort has been
(Oil & Gas Journal 1994 EOR database) for
put into various production processes for heavy primary and incremental waterflood recovery
oils, and why a separate section is devoted to them
here. The different processes are dealt with individ- API gravity Primary Waterflood Total n
ually; a basic description of the process is given, 10 15 API 4.9 1.7 6.6 28
together with the advantages and disadvantages of 15 20 API 8.1 7.4 15.5 44
eachbecause none of them is the panacea. 20 23 API 9.6 12.2 21.8 37
Heavy Oil and Viscous Oil 13

increase the rate of oil production. Unexpectedly Foamy oil is still poorly understood, and is
high production rates and recovery factors have only recently starting to be replicated in the
been found during CHOP in some reservoirs. laboratory [12,13]. Support for this mechanism
History matching the simulations of such well comes from the fact that chocolate mousse
behaviours often requires unrealistic adjustment has been produced from some CHOP wells (see
of the measured parameters, such as increasing e.g., [15]).
the measured permeability by an order of magni- 2. Wormholes. The alternative explanation of
tude or more. Clearly, there must be an additional CHOP behaviour is the development of
phenomenon at work. There are two schools of wormholes or areas of dilation around the well.
thought about the reasons for this: The idea is that the production of viscous
oil through the unconsolidated sand creates a
1. Foamy oil. One explanation is foamy oil drag force that overcomes the cohesive forces
behaviour [12 15]. This phenomenon is thou- holding the formation together. The result is
ght to be due to gas coming out of solution due sand production: as much as 10 m3 during the
to production below the bubble point, but the initiation of some CHOP wells [8], stabilizing
gas is unable to separate into a free gas phase with time to < 1 m3 per day (cf. Fig. 11.8).
because of the viscosity of the oil. The result Where does this sand come from? Log data
is an oil-continuous foam resembling choco- and geomechanical modelling indicate that the
late mousse, with a viscosity much lower than sand production does not merely create a cavern
that of the original oil. The foam is thought around the well. Rather, there is either a zone
to form in the formation, greatly enhancing the of dilated sand (i.e. where sand has yielded
mobility of the oil as it flows into the well. and expanded due to reduced effective stress

500 10

450 9

400 8
Rate (bbl oil / day

Sand cut- %

350 7

300 6

250 5

200 4

150 3

100 2

50 1

0 0
A B C
Time

Fig. 11.8 The oil production rate from an oil well in Alaska undergoing a cold production trial, involving the
intentional production of sand. Note that in the early stages of the trial (time A) little sand has been produced and
oil rates are low. At time B the PCP pump was adjusted to give a greater drawdown, initiating significant sand
production; this was accompanied by a distinct rise in oil rate. After a while (time C) sand production stabilised to a
low background level, and oil rate levelled off.
14 Modern Petroleum Technology

and liquefaction processes, resulting in higher oils in the 10100 cP range; they are less popular
porosity and permeability [16]) around the well, for oils with > 100 cP viscosity and API gravities
or a radiating network of tubes (wormholes) < 15 (Plates 11.111.3). In a database of over
extending out from the well or a combination 400 enhanced oil recovery projects in fields with
of both. These phenomena greatly increase oils with API gravity < 23 , some 32% employed
the contact area between the well and the waterfloods of some form or another; 25% were
formation, thus enhancing rate and recovery. straight waterfloods, the remainder employed an
Support for this mechanism is derived from the additional process (Fig. 11.9).
clear relation in some wells between amount of A variant of waterflooding is polymer flooding
sand produced and well flow rates (Fig. 11.8). [19]. The idea of this is that the addition of small
In practice, more than one mechanism may concentrations of high molecular weight poly-
contribute to the behaviour of CHOP wells. mers, such as polyacrylamides and xanthan gum,
Horizontal wells are becoming popular to use increases injection water viscosity to improve the
during primary recovery as a way of increasing water oil mobility ratio (typical mobility ratio
well rate without having to use excessive draw- reductions are 2 to 9 times for polymer solutions
down. compared to pure water) and thus increase sweep
Examples of heavy oil fields that have had efficiency. Polymer flooding is best suited to low
a significant primary production phase include reservoir temperatures, since polymers degrade at
Quiriquire Shallow (Venezuela), and some of the high temperatures. Because the polymers work
heavy oil reservoirs from the Lloydminster area by increasing the viscosity of the water, this
of Canada (Fig. 11.3 [17]) and the Hamaca area can create injectivity problems in low perme-
of the Orinoco Belt in Venezuela (Fig. 11.4). ability formations: oil viscosities of < 200 cP and
However, there are many hundred heavy oil fields permeabilities of > 20 mD are general screening
that had a primary production phase before going criteria, with reservoir temperatures < 95 C for
on to other recovery processes. polyacrylamides and < 70 C for xanthan gums.
Other problems with polymer deployment include
5.2 Waterflood reduced effectiveness in high-salinity waters and
degradation with shearing in surface equipment,
The well known, tried and tested, process of and the high cost of the polymers. Polymer floods
injecting water into reservoirs for pressure support are rare in fields with viscosities > 100 cP and
has been applied to many viscous oil reservoirs,
API gravities < 20 (Plates 11.1 11.3). However,
especially those in the higher API gravity part
polymer-assisted waterfloods account for about 5%
of the range. Recovery factors vary, decreasing
of EOR projects in heavy oil fields (Fig. 11.12).
dramatically in higher viscosity oils (Table 11.1)
Another variant of waterflooding is alkaline
as the wateroil mobility ratio becomes worse
(note that mobility is the effective permeability flooding (or caustic flooding [20]). This involves
divided by the viscosity), leading to greater viscous the injection of high pH chemicals (e.g. sodium
fingering and poorer sweep. In viscous oils, the hydroxide or sodium orthosilicates) along with the
time taken for the pressure support from an injector water. The alkali reacts with acidic components
to be seen at a producer, and to be reflected in (organic acids) in the crude oils to form surfac-
enhanced flow rates, is longer; this makes injec- tants, resulting in transient reductions in interfa-
tors sometimes difficult to justify commercially, cial tension (IFT) between the aqueous caustic
even if the long-term recovery is there. solution and the crude oil. Lower IFT mobilizes
Examples of fields being developed as water- the oil. Additional benefits may be achieved from
floods are Schrader Bluff in Alaska [7] and the wettability changes and a degree of emulsification.
offshore Captain Field in the North Sea [18]. Results from field trials of alkaline floods have
Waterfloods are a popular recovery process for been fairly discouraging. The process works best
Heavy Oil and Viscous Oil 15

CO2 immiscible
CO2 miscible 1% HC miscible
1% 0% Horizontal
SAGD
3%
1%
Steam horiz
1% Combustion
5%

Cycilc steam
5%

Waterflood
25%

Hot water
Steam 2%
51%

Polymer
5%
Alkaline
0%

Fig. 11.9 The popularity of recovery processes for fields with oil < 23 API gravity. Taken from a 1994 database of
417 fields.

in crudes with a high Total Acid Number (TAN) pore volumes (320% PV ) here, the micelles
of > 0.5. become a surfactant stabilized dispersion of either
While an alkaline flood looks to create water in hydrocarbon or hydrocarbon in water.
surfactants in situ in the reservoir through reaction Rapid displacement of all the contacted oil occurs
of the alkali with the oil, a surfactant flood as the surfactant becomes diluted and the process
injects surfactants directly with the injected reverts to a low-concentration surfactant flood.
water. Two mechanisms are involved: (1) low Field results indicate high concentration surfactant
concentration surfactant injection for large pore (micellar) floods are more effective than low-
volumes (1560% PV ), where the surfactant concentration surfactant floods.
dissolves in either the water or oil and is in The surfactants used are usually petroleum
equilibrium with aggregates of the surfactant sulphonates in low-concentration injection, while
(micelles) here, it is the reduced IFT between high-concentration surfactant floods have formula-
water and oil that increases oil recovery; (2) high tions containing three basic components (hydro-
concentration surfactant injection over smaller carbon, surfactant and water), together with
16 Modern Petroleum Technology

optional co-surfactant (usually alcohol) and elec- A description of immiscible gas injection, as it
trolytes (usually inorganic salts) for preparing the applies to CO2 , is given in Mungan [21].
micellar solutions or microemulsions. Surfactant Gas injection may be applicable in thin reser-
floods have been more popular in field testing than voirs where thermal processes would be imprac-
alkaline floods. tical due to excessive heat loss. Indications for the
The recovery mechanisms include oilwater use of immiscible gas injection are a ready supply
IFT decrease, lower capillary number, lower resi- of inexpensive gas, good reservoir quality to allow
dual oil and enhanced oil mobility. The process is good contact between the gas and the oil, lack of
favoured by the following conditions: oil viscosity fractures or prominent thief zones, and the lack of
< 30 cP, temperature < 120 C, permeability > a large underlying aquifer. With very viscous oil,
20 mD. There may be sensitivity to brine compo- gas injection suffers from mobility ratio problems.
sition and salinity. Recent novel variants of surfac- Immiscible injection has better performance with
tant flooding include injecting solvent-in-water higher initial oil saturations; Soi > 50% is typi-
emulsions, using natural gas condensate or petro- cally recommended. Specific problems with CO2
leum naphtha as solvents, to reduce oil viscosity injection are the potential for asphaltene precipi-
through solvent dilution and to control mobility tation in the reservoir or in production equipment,
through emulsion droplet trapping. and corrosion. Estimates of CO2 requirements vary
Hot water injection has been applied in some between 2 and 12 scf/bbl incremental oil.
field trials, typically recovering 4 15% of OOIP. Examples of immiscible gas injection (all CO2 )
This can be used as a potential preheating treat- include Halfmoon field Wyoming (17 API, 118 cP
ment before steam injection, and can be used to oil), Lick Creek, Arkansas, and parts of Bati
reduce fuel requirements for mature steam floods. Raman (13 API) in Turkey.
However, hot water injection is a much less effi-
cient way of heating the oil than steam, since it 5.4 Miscible Gas
does not have any of the latent heat benefits of
Miscible gas flooding involves injecting a gas, or
steam (i.e. water temperature drops as heat is lost).
cocktail of gases, that will mix with the reservoir
About 2% of heavy oil EOR projects use hot water
oil and form a mixed hydrocarbon phase with
(Fig. 11.12).
much more favourable flow properties. The gas
injection process may be operated as a continuous
5.3 Immiscible Gas Injection injection, or be alternated with water injection. It
may also be operated as a cyclic huff-and-puff
The injection of immiscible gas carries a number of process rather than a well-to-well flood.
benefits, besides helping maintain reservoir pres- Miscible gas injection may utilize CO2 , hydro-
sure. If some of the gas dissolves in the oil, this carbon gases or mixtures of both. CO2 , which
can swell the oil, reducing residual oil saturation is a liquid under some shallow heavy oil reser-
and making the oil more mobile. With subsequent voir conditions, may be favoured due to its lower
blowdown, the gas may be liberated to form a cost, and also because significant amounts of CO2
solution gas drive. There is the additional benefit may be sequestered in the reservoir, contributing
that this can provide a means for sequestering to reduced atmospheric emissions [11]. It is an
undesirable gasesprincipally CO2 . A variety of efficient displacement mechanism, leading to high
injection gases has been used, including flue gas potential recovery due to low residual oil; the
(85 mole% N2 , 15% CO2 ), pure CO2 , nitrogen process reduces capillary and viscous forces to
and methane. Flue gas combines the benefits of a allow efficient oil displacement. Miscible gas injec-
N2 displacement mechanism with CO2 solubility. tion is advantageous in low-permeability forma-
Gas injection can be combined with intermittent tions where water injectivity is too low.
water injection, and can be used as a single well A miscible CO2 flood works by stripping C5 C30
stimulation as well as an inter-well flood process. components from the crude oil to form a miscible
Heavy Oil and Viscous Oil 17

bank at the CO2 oil front; C2 C4 components are 10000


easily extracted by the dense CO2 and these aid in
the generation of miscibility. The CO2 density influ- 1000
ences the extraction of oil components, with higher

Viscosity (cP)
density CO2 (at higher pressure) extracting more 100
and heavier hydrocarbons. CO2 slug sizes typically
range from 15 25% of pore volume, with 12
10
stock tank barrels of oil recovered per reservoir
barrel of CO2 left in reservoir. Using CO2 above 12API
1 20API
its critical temperature of 31 C (critical pressure is 30API
1073 psi) results in a larger CO2 reservoir volume
and higher oil recovery per unit mass of CO2 , but 0.1
0 50 100 150 200 250 300
lower degrees of CO2 sequestration.
Temperature (C)
A hydrocarbon gas flood can be first contact
miscible at high pressure or if injected gas is Fig. 11.10 The dependence of oil viscosity on temper-
sufficiently enriched with C2 C6 components. ature (after Archer and Wall [1]).
Vaporizing gas drives achieve multiple contact
miscibility at the oilgas front by stripping C2 C6 continuous steam injection) uses steam to transfer
components from the crude oil. Condensing gas heat to the oil and thus greatly reduce its viscosity
drives achieve multiple contact miscibility at (Fig. 11.10), concomitantly enhancing oil flow
the rear of an oilgas slug by condensing out rates and overall recoveries. Water has a large
C2 C6 components from the gas. A disadvantage heat content per unit mass (high specific heat
of the hydrocarbon process is that in some and latent heat of vaporization). Steam is thus
cases the hydrocarbon gases themselves may have an efficient way of transferring heat to the oil; it
considerable value. There will be mobility ratio remains at high temperature as it condenses. Steam
problems in viscous oils, and the poor vertical and flooding is a continuous process that involves the
horizontal sweep efficiencies may requiring large use of dedicated injection and production wells.
slug volumes, decreasing economic performance. Steam flood technology is described in depth by
Mobility control may be achieved by beginning Hong [22] and Pratts [23].
with water injection, followed by alternating As the steam moves through the reservoir from
gas and water injection. For the CO2 process, injector to producer, it creates several variable
asphaltene precipitation may be a problem. regions of differing temperature and fluid satura-
There have been many applications of this tech- tion (Fig. 11.11). Around the injector is a steam-
nology, the largest in the world being that in saturated zone, with a temperature close to that of
Prudhoe Bay, Alaska, but the great majority of the injected steam. This zone gradually grows as
these projects (including Prudhoe Bay) are in more steam is injected. Here, oil saturations are the
light oils. With heavy oils the technology is less lowest. Oil is moved from here to the next zone
widespread and more experimental, but there have by steam distillation; just ahead of the steam front,
been some commercial successes in hydrocarbon a solvent bank forms from the distilled light ends
miscible and CO2 miscible projects. An example from the steam-saturated zone. Ahead of the steam-
of the latter is Nagylengyel field in Hungary. saturated zone, the steam condenses to water as
heat is lost to the reservoir; this is the hot conden-
5.5 Steam Flood sate zone. Some heat is carried beyond this into the
cooler regions of the reservoir until the condensed
The viscosity of oil decreases with increasing water finally equilibrates to the initial reservoir
temperature (Fig. 11.13). This effect is even more temperature. The solvent bank formed ahead of the
dramatic in viscous oils. Steam flooding (or steam zone dissolves more oil from the formation
18 Modern Petroleum Technology

200 a zone of higher injectivity (beneficial) or heat


Tsteam thief zone (detrimental) depending on the reservoir
Temperature (C)

geometry.
100 Some reservoir formations may be sensitive to
steam, and to condensate from steam which, being
Treservoir
very low salinity, is different from the original
0 formation water. Steam or steam condensate may
80 facilitate reactions between natural carbonate and
Oil saturation (%)

A B C D E
aluminosilicate minerals in the formation, gener-
ating formation-damaging phases such as swelling
40 Soi clays, as well as generating CO2 from the break-
Sor down of the carbonate [24,25]. This formation
damage can greatly reduce well flow rates. It
0
Injector Producer is thus wise to conduct formation compatibility
studies prior to embarking on any steam-based
Fig. 11.11 Typical temperature and saturation profiles process.
between injection and producer wells in a steam flood
process. Zones: A, steam zone; B, solvent bank; C, hot
water bank; D, oil bank; E, reservoir fluid zone. Zones B
and C together form the hot condensate zone; zone D is
5.6 Cyclic Steam Stimulation (CSS)
the cold condensate zone (after Hong [22]).
Cyclic steam stimulation (or cyclic steam injection,
steam soak or huff-and-puff) is a form of well
to form a miscible flood front. It is the high temper- stimulation that involves transfer of heat to the
atures in this zone, which expand the oil and reservoir oil by the periodic injection of steam into
make it less viscous, that leads to the low satu- production wells. As with steam flood (above), the
rations in the steam zone, significantly lower than addition of heat to the viscous oil greatly reduces
the residual saturations seen in heavy oil water- its viscosity, enhancing oil flow rates when the
floods. In the oil bank that is mobilized and pushed well is brought back into production. Not only
ahead of the advancing steam and hot water fronts rates are enhanced, but so is the overall recovery
(Fig. 11.11), oil saturations are often higher than before the well falls below economic flow rates.
they were initially. The now cooled water in this An excellent and in depth description of CSS is
zone displaces the oil bank in a process analogous given in Hong [22].
to a waterflood. Total recovery from steam flooding CSS was discovered almost by accident [26].
can exceed 80% in the swept areas. A steam flood pilot was being operated in the
Screening criteria rank reservoir thickness and Mene Grande field in Venezuela in 1956, when
low operating pressure as the most important indi- the project suffered a crisis: steam broke through
cations for steam flooding. Thin reservoirs will to the surface. To relieve reservoir pressure, the
lose heat to the surrounding rocks, wasting energy. steam injection wells were opened and allowed to
Steam processes are favoured by low pressure, produce, and it was discovered that these wells
because the water boiling point is lower. The flowed oil profusely. Subsequently, CSS has grad-
higher the reservoir pressure, the higher the water ually gained in popularity.
temperature has to be to generate steam, and In CSS, the steam injection phase may last for
thus the process is less energetically favourable. a few weeks to months; this is then followed
It is for this reason that virtually no steam-based by a soak period before the well is put back
EOR schemes have been implemented in reservoirs on production for a few months to over a year.
deeper than 4000 ft (Fig. 11.10). Good reservoir The cycle may be repeated from 3 to 15 times.
transmissibility (> 100 mD.ft/cP) is an advantage, With each cycle, the initial peak production rate
while the presence of bottom water can be either gradually decreases. After a certain number of
Heavy Oil and Viscous Oil 19

cycles the process becomes uneconomic and may steam is injected, a steam chamber forms above
be converted to a steam flood. CSS has been used the wells, with approximately the same tempera-
in both vertical and horizontal wells. It is a popular, ture as the injected steam (Plate 11.4). The steam
tried and tested process (Fig. 11.10). gradually rises over a period of months until it
CSS has better short-term economics than steam reaches the top of the reservoir. The steam chamber
flood due to the immediate production response, then expands laterally, until it becomes limited
and the fact that all of the wells produce oil. by heat loss to the surroundings or interference
Up-front capital expenditure can be kept to a from adjacent well-pairs. At the margins of the
minimum by utilizing small portable steam boilers steam chamber, the steam condenses, and trans-
that can be moved around from well to well. mits heat to the surrounding oil. The condensed
Typical recoveries are 1025% of total OOIP. steam slumps to the base of the chamber and
Examples of CSS include Kern River, California, is produced in the lower well, along with the
and numerous fields in Venezuela it being the heated oil, which drains by gravity along the
main enhanced recovery process for Venezuelan outer margin of the chamber down to the produc-
heavy and extra-heavy crudes. tion well.
During upward growth of the steam chamber
5.7 Steam-assisted Gravity Drainage (0.1 and 1 year steps in Fig. 11.15), a ceiling
drainage process operates, where heated oil is
(SAGD)
pulled away from the roof of the chamber and
In 1982, AOSTRA (the Alberta Oil Sands Tech- slumps almost vertically down to the producer.
nology and Research Authority) began develop- The rate at which the steam chamber propagates
ment of an underground test facility to demonstrate upwards is a function of the steam temperature
new technologies for producing heavy oil. SAGD, and the reservoir vertical permeability. In this
a process that had been mooted some years earlier stage, oil production rate increases rapidly. Oil
(see, e.g., [27]) was one of the first processes to be rate continues to rise slowly, or stay constant,
tested in this facility, with three well-pairs being as the steam chamber spreads laterally (24 year
drilled and completed in 19861987, and produc- steps in Fig. 11.15). Gradually, slope drainage
tion testing following from 1987 to 1990. Results takes over as the mechanism for moving the oil to
were deemed successful, and commercial pilots the production well; as the slope becomes shal-
followed. The method has increased in popularity lower, the oil has further to travel, though this
to the extent that between 1993 and 1997 some is balanced by the greater area of the interface
28 SAGD well-pairs were completed, mainly in between the steam chamber and the surrounding
Canada, but some also in Venezuela and California, oil. Oil rate decreases when the lateral spread of
and another 50 or so well-pairs were at the plan- the chamber becomes limited (68 year steps on
ning stage in 1998. Fig. 11.15). Factors that influence SAGD perfor-
SAGD is a combined conduction-convection mance include reservoir permeability, oil viscosity,
process (see Butler [28] for more details of the reservoir heterogeneity and gas/oil ratio.
process). In its initial form, it consists of a pair Recovery factors for SAGD projects are typi-
of horizontal wells, one drilled directly above the cally estimated to be in the 5570% range. Well
other at a constant spacing. Depending on the flow rates might be in the region of 1500 b/d for
thickness of the reservoir and the oil viscosity, the a properly performing SAGD well pair, an order
optimal well offset can be from a few metres up to of magnitude more than would be achieved from
several tens of metres. The second horizontal well a conventional horizontal well.
is drilled using special magnetic measurement- Variants of SAGD include the use of vertical
while-drilling technology to detect the first well injectors combined with a horizontal producer, and
and ensure constant offset. The upper well is a single-well SAGD. The latter is a process that
steam injector, the lower one an oil producer. As utilises a single horizontal well. Steam is injected
20 Modern Petroleum Technology

continuously into the formation from the toe of of the remaining oil. This is an in situ upgrading
the well, via insulated tubing. The heated oil and process which may increase the value of the
steam condensate then drain back into the annulus produced oil.
of the horizontal wellbore to be produced. Other Because Vapex operates at reservoir temperature
variants involve the addition of additives to the and pressure, the process is much more energy effi-
steam, or replacement of steam by solventsas cient than a thermal process, consuming < 5% of
in the VAPEX process discussed next. the energy of an equivalent steam-based process
(note that early descriptions of the process indi-
cated the use of hot water in addition to solvents;
5.8 Vapour Extraction (VAPEX) subsequent testing indicated the use of heat was
The Vapex process [29] is emerging as a rival not generally necessary). The well completions
for thermal processes in the exploitation of extra- will also be less expensive than those needed to
heavy oil, particularly in thin formations where support a thermal process. Vapex does not suffer
thermal processes are inefficient. Vapex involves from the formation damage problems (e.g. swelling
the injection of a solvent vapour into the reser- clays) that can affect steam floods. Vapex also has
voir, usually via a horizontal well, with production a great advantage over steam in reservoirs that are
from a second horizontal well beneath (Fig. 11.12), underlain by an aquifer. Steam will condense and
analogous to the thermal SAGD process. Solvents dissipate into the aquifer, while the Vapex solvent
could include light hydrocarbons such as ethane, will float on the aquifer and continue to help
propane and butane, and various mixtures. The recover oil. The solvents can easily be recovered
solvents dissolve into the oil and dramatically from the oil at the surface and recycled. Recovery
reduce its viscosity. The diluted oil then drains factors are thought to be similar to those modelled
downwards into the production well. With time, for SAGD.
the solvent chamber grows (cf. Fig. 11.15), mobi- Disadvantages of this process are the high
lizing oil from progressively larger areas of the cost of the solvent, and permeability loss due to
reservoir. asphaltene precipitation. An overlying gas cap will
The process may also lead to a certain degree absorb Vapex solvent and make the process less
of in situ solvent de-asphalting when the solvent efficient. Although demonstrated extensively in the
mixes with the oil; asphaltenes precipitate from laboratory, field tests have only recently got under
the oil in the reservoir, increasing the API gravity way. It is likely that, in places where there is an
accessible source of solvent, and a thick homoge-
neous reservoir, this may develop quickly into the
process of choice for heavy-oil recovery.
Solvent
vapour
chamber
5.9 In situ Combustion
In situ combustion, or fire flooding, is a process
Solvent-diluted that involves injection of air into the reservoir,
Horizontal injector deasphalted oil
drains to initiating a combustion reaction in the oil itself,
producer thus creating heat in situ within the reservoir.
In some cases the oil may start to burn sponta-
neously on contact with injected air; in other cases
Horizontal producer Heavy oil a heater or chemical treatment may have to be
placed in the injection well to initiate combustion.
The main way of controlling the combustion, once
Fig. 11.12 A schematic of the Vapex process; a view initiated, is by tuning the amount of air injected.
parallel to the wells. As the oil begins to burn, the heat of combustion
Heavy Oil and Viscous Oil 21

preferentially vaporises the lighter fractions of the of combustion also vaporises water in the combus-
crude oil, driving them ahead of the combustion tion zone, generating steam in situ. Together with
front. In this way, it is the residual heavier fractions the air combustion products (nitrogen and CO2 ),
that end up being burnt. Hence, in situ combus- this forms a kind of steam drive with some immis-
tion has an element of oil upgrading associated cible/miscible gas displacement mixed in. This
with it, because the oil that is produced may be drives the oil, with its viscosity reduced due to
24 API degrees lighter than the initial crude, and the heat (Fig. 11.13), from the injectors toward the
have lower sulphur and metals contents. The heat producers.

3 2 1W 0 1E 2

Northern
north
61N
sea
Clair

West of
shetland

Viking g
Shetland islands

Bressay
raben
East
shetland 60
platform

Mariner
way
UK
Nor

Gryphon
harding

59
Orkney islands Fladen
ground
spur

Captain
Halibut horst
Moray firth

58
Alba
Cen
tral

Central
north
g
rabe

Scotland sea
n

Fields
Basins Heavy oil
Highs Other Gannet E
100 km Mid north 57
sea high

Fig. 11.13 The heavy oil fields of the North Sea area.
22 Modern Petroleum Technology

In situ combustion has the potential for high other failure reasons. Safety is a concern too: with
recovery factors, perhaps the highest of all the high-pressure air compressors, there is a potential
thermal processes (up to 90%), it providing a very for air injector explosions.
efficient drive mechanism. Furthermore, energy
consumption is much less than for steam injection:
5.10 Downhole Electrical Heating
perhaps 1/4 to 1/3 the cost of steam generation
and placement for a typical 1000 psi reservoir. For many years, there has been interest in ways
This may, in turn, lead to an overall lower total of stimulating well productivity in viscous oils by
environmental impact. heating the near-wellbore region without the need
Screening criteria for in situ combustion are for steam, thus avoiding the high initial infras-
depth > 300 ft (to avoid air breakthrough to the tructure cost associated with steam boilers and
surface), net pay > 10 ft, oil viscosity < 1000 cP, compressors. One possibility is downhole elec-
porosity > 20%, oil density < 45 API, initial oil trical heating, which actually consists of several
saturation > 50%, permeability > 100 mD, oper- distinct processes, each with their own advantages
ating pressure > 250 psi and spacing < 40 acres. an disadvantages. The main variants are electro-
A uniform clean sand greater than 10 ft thick is resistive heating, inductive heating, and microwave
ideal. heating.
In situ combustion is in theory applicable to Electro-resistive heating covers a variety of indi-
deeper reservoirs than steam processes. For one vidual techniques and geometries. Basically, it
thing, there are no wellbore heat losses, which involves using a segment of well casing as an elec-
would be very significant for steam in deeper reser- trode to introduce electrical current into the area of
voirs. The higher pressures would, though, incur the formation requiring simulation. This segment
additional operating costs (injection and lifting). of casing must be electrically isolated from the rest
In situ combustion is a highly complex process, of the well. This could mean, for example, placing
with the degree and style of oxidation depending a fibreglass casing section above and below the
on the temperature and the amount of oxygen reservoir interval, with regular steel casing acting
available. Greater heat losses from thin layers as an electrode over the reservoir interval. Power
may cause a shift from high-temperature oxidation is sent from the surface to the isolated segment of
to low-temperature oxidation, resulting in poten- casing via a cable. The electrical energy penetrates
tial formation of surfactants causing emulsions from the casing into the formation (via the water
to form (hard to pump, hard to break), plug- phase), causing it to heat up. This in turn heats the
ging the formation and potentially stalling the oil, reducing its viscosity (Fig. 11.13), increasing
combustion front. Poor ignition can lead to oxygen well flow rate, and breaking any viscous skin effect
contacting cold oil, causing pre-oxidation with that has built up. A simulation of the heating effect
formation of a refractive asphaltene-rich or coke of this method is illustrated in Plate 11.5. The
phases which can cause reservoir plugging. Also, simulation shows that the heating effect in the near-
reservoir heterogeneities can cause fingering of the wellbore region of the reservoir is counteracted to
combustion front, leading to poor areal sweep and some extent by the influx of cool oil, restricting
premature breakthrough of air to the producers. high temperatures to within a few feet of the well.
In situ combustion is experiencing a lull in The deepest penetration of elevated temperatures
activity, reflecting the lack of commercial success in actually occurs in or close to the encasing shales,
previous projects. Why have previous projects been which have high water saturation (thus acting as a
disappointing? Difficulty in controlling the process channel for the electricity) and are not cooled by
is one key aspect. This makes in situ combus- the influx of oil.
tion commercially risky compared to steam-based On paper, this looks to be a promising tech-
processes. Insufficient air supply and well patterns nology. However, the limited field experience indi-
being too large (< 40 acre spacing is desirable) are cates that, although enhanced oil rates are achieved
Heavy Oil and Viscous Oil 23

for a while, the system is susceptible to frequent be in a fluid-free ceramic casing string; this adds
failures (see, e.g., [30]). Most often this is due cost and the risk of mechanical failures.
to casing insulation failure. Scoping economics In conclusion, none of the downhole heating
suggest that, for this system to be economic, it processes are currently stable technologies. There
must function trouble-free for roughly 2 years; is promise, but extensive field testing is needed to
this compares to average failure rates of about minimize costly equipment failures.
6 months (unpublished data). A secondary problem
that is identified through simulation of the process
5.11 Surface Mining
is that, because water is the carrier for the power,
this is where the heat is concentrated. What can Two large plants operate in Canada, strip mining
happen is that the water vaporises under the heat, oil sands at the surface and then upgrading the
leaving the formation very insulating. This reduces heavy oil to produce a lighter synthetic crude.
the effectiveness of the process or stops it alto- The Suncor plant started up in 1967, the larger
gether. More development work is needed before Syncrude plant in 1978. Total output from the two
this becomes a routine process. plants was 280 000 b/d of synthetic crude in 1997.
Resistive heating involves hanging a powerful In the TimanPechora district of Russia,
induction coil, or set of coils, in the well, oppo- bitumen deposits in the Yarega field are being
site the formation(s) to be stimulated. The coils produced at a rate of about 10 000 b/d through
are connected by cable to a power source at the a combination of surface mining and in situ
surface. The magnetic field from the coil induces production.
eddy currents in the steel well casing, causing the
casing to become hot. Heat is transmitted to the
formation and to the oil by conduction. 6 OFFSHORE VISCOUS OIL
The disadvantage of this process is that the DEVELOPMENTS
heating effect is limited to the area very close to
and inside the well. While this still yields distinct The vast majority of heavy and viscous oil produc-
improvements in well rate, this is not as much tion worldwide occurs onshore. However, the past
as could be achieved by placing the heat further decade has begun to see offshore developments
out into the formation. However, a big advantage start up, and with new discoveries offshore, there is
of resistive heating is its reliability; it does not the potential for much more in the future. Offshore
depend on electrical contact with the formation, or heavy oil developments carry their own list of
on insulated casing joints and so does not suffer the special problems and concerns, warranting sepa-
problems of electro-resistive heating. This process rate discussion here.
is presently undergoing extensive testing. The main problem with offshore heavy or vis-
The other main downhole heating technology cous oil developments is that, being platform-
is microwave heating. Microwaves are generated based, they are limited in the number of wells
either at the surface, and piped down to the reser- that can be used, and must make rapid economic
voir through a wave guide tube, or down hole, with return to pay back for the high facility costs.
a subsurface microwave generator. Microwave These limitations are critical, because in onshore
heating is a promising process [31]: it is energet- fields, the low well rates and recoveries are usually
ically efficient, heats the reservoir fluids directly mitigated by drilling many closely spaced wells.
and is relatively controllable. The big disadvan- A fundamentally different approach must be taken
tage is initial cost. It requires a wave guide, a offshore.
shielded conduit for the microwaves, which has Offshore heavy and viscous oil development
to be 2025 cm in diameter, thus necessitating a has been pioneered in the UK Continental Shelf,
large-diameter and expensive well. The slotted end where several successful field developments have
of the wave guide (to emit the microwaves) must been carried out (Fig. 11.13), in gradually more
24 Modern Petroleum Technology

challenging oils [32]. In general, the limitations common feature of several of these UK heavy-
on well number have been counteracted by using oil developments. Water injection supplies pressure
very long, highly productive horizontal wells. This support; water from a shallow aquifer is used rather
helps with an additional problem that some of the than seawater, to avoid barite scale. In Harding,
UK fields have overlying gas gaps and under- the produced oil is exported via tanker. The oil
lying active aquifers, both of which could cone viscosity in Harding is not that high (510 cP,
into the wells if drawdowns were too high. Coning at 1921 API), and this is mitigated by the very
problems are often worse in viscous oil fields than permeable reservoir.
in conventional ones, partly because the wells have The Alba Field development followed similar
to be pumped harder to obtain equivalent produc- lines, though the lack of a gas cap meant the
tion, and partly because the adverse water-oil and wells could be placed higher in the reservoir, away
gas-oil mobility ratios exacerbate coning effects. from the OWC. Alba contains > 500 MMbbl of
Furthermore, the viscosity of the oil and, with 20 API, 7 cP oil in high quality Eocene sands. The
heavy oils, the small density difference between Gannet E Field, containing 20 API, 20 cP oil, was
water and oil, can make coning very slow to heal developed as a satellite tied back to the existing
by simply reducing production rate. Gannet complex, which contains light oil. This
The Gryphon Field, containing 300 MMbbl is the only one or the fields to be exported by
STOOIP, started up in 1993. Its main reservoir pipeline, once the oil has been diluted with Gannet
is high quality hydrostatically pressured sands light oil.
of the Eocene Balder Formation, at a depth of The fields described so far all contain marginally
5500 ft sub-sea. Gryphon has been developed with heavy and viscous oil, combined with very for-
eight horizontal producers and three water injec- giving reservoirs. Offshore viscous oil develop-
tors, drilled from a sub-sea cluster; production of ment achieved another level in 1997 with Texacos
the 21 API, 6 cP oil is through a FPSO (floating pioneering development of the Captain Field, con-
production, storage and offloading facility). FPSOs taining 88 cP oil (19 API). Again, EWTs were
have solved a key problem in the North Sea heavy important, demonstrating sustained deliverability
oilfields: how to export the oils to shore, avoiding [33]. The Captain EWT well 13/22a-10, drilled in
the need for a long cold sea-bed pipeline. Produced 1993, consisted of a 5532 ft horizontal section; it
water is re-injected, but seawater injection has not produced at a stunning average rate of over 10 000
been used due to its high scaling potential with the bopd for 90 days. Subsequent development has
high-barium formation water. used long horizontal wells, lifted with ESPs into
The Harding Field came on stream in 1996. a FPSO. The field is being waterflooded, using a
It actually consists of four accumulations. The mixture of produced and aquifer water. However,
two first to be developed, the Central and South simulations show rapid slumping of injected water
pools, contain over 320 MMbbl STOOIP; gas to the bottom of the reservoir in this wide low-
caps are present in both. The reservoir is highly relief structure. To improve the waterflood perfor-
permeable, unconsolidated Eocene sands, similar mance, use of polymers has been considered [18].
to Gryphon. It was developed using ten long hori- Several other North Sea fields viscous oil fields
zontal wells. Where the gas cap was present, wells are currently under appraisal. They are becoming
were placed about 75 ft beneath the gas cap. High gradually more challenging: Mariner B has 540 cP
well productivity indices (PIs) in the region of oil, while the development of Bressay (1000 cP)
1000 bopd/psi mean that the wells can be pulled may still be some way off. Although the North Sea
very gently to achieve high oil rates while avoiding developments have pioneered offshore production
early coning. A key part of the planning process technologies for viscous oil, there are many other
was the drilling of a horizontal extended well parts of the world where offshore viscous oil is
test (EWT) that demonstrated producibility and emerging: some of the shallow oil accumulations
reduced risk on reservoir deliverability. This is a in the deepwater Gulf of Mexico and offshore
Heavy Oil and Viscous Oil 25

West Africa are good examples for us to watch is the Orinoco oil incorporated into Orimulsion,
unfold in the coming years. burning will produce sulphur compounds that, if
emitted, can contribute to acid rain. Hence, costs
are incurred by the need for sulphur scrubbers in
7 USES OF HEAVY OILPAST the flues of such power plants. Carbon dioxide
PRESENT AND FUTURE taxes will add further financial disincentives to the
burning of heavy oils.
Heavy oil has had possibly the longest history of As the lighter petroleum liquids become deple-
usage of any of the petroleum resources, mainly ted, heavier oil production may well expand to fill
because it was the surface seeps that were most the gap [34]. From an environmental perspective,
accessible to man, and these seeps are often heavy it would make sense if the heavier oils were used
due to biodegradation in this shallow environment. as refinery feedstock rather than simply a fuel for
In fact, mankinds very existence could be due to burning. Growth in heavy-oil production will be
heavy oil seeps in the Middle East, for without undoubtedly be limited by the amount of energy
its coating of tar, Noahs Ark might have sunk required to produce heavier and heavier oils and
(Genesis 6 : 14)! Surface deposits of heavy oil, process them into a useful form: there will be an
bitumen, tar or pitch (e.g. the La Brea tar lake in economic cut-off where so much of the energy in
Trinidad) have been used for centuries for water- the oil is consumed by processes before it reaches
proofing less critical boats. the consumer, that it is not worth producing at
The heaviest oils, natural bitumens, are used all. New technologies that can produce or process
directly in road making. The dubious quality of heavy oils more efficiently will be key in enabling
roads in Trinidad is certainly not due to the quan- the full potential of heavy oils to be realized.
tity or quality of the natural bitumen used. In
Canada, oily sand that has been co-produced with
the heavy oil is frequently used in road-making. 8 CONCLUSIONS
However, the bitumen used for this purpose in
many parts of the world is not natural, but is actu- Heavy and viscous oils constitute a vast petroleum
ally the heavier products of light crude oil refining. resource, perhaps four times greater in size than
Today, most of the heavy oil produced is turned that of remaining conventional oil, that is currently
into refined petroleum products. It may be diluted under-exploited. This is partly due to the technical
with lighter oils prior to refining in a conven- difficulties, but mainly this is related to commer-
tional refinery, or it may be upgraded first, either cial pressures; the technical challenges add cost to
remotely in a purpose-built upgrading plant, or in production, transport and processing of the heavy
the earliest stages of a refinery tuned to handle oil, and after all this the price realized for the
heavy oil. The cost of the upgrading step, and the heavy oil is still lower than for conventional oil.
low per-barrel yields from heavy oil, means that In the near term, it appears that exploitation of
it is not the most attractive feedstockhence the heavy oil will remain patchy, restricted to the most
discounted per-barrel price of heavy oil compared easily accessible accumulations. In the longer term,
to lighter liquids. High sulphur and metals contents as conventional oil becomes depleted and world
only add to the problem. energy demand increases, greater exploitation of
Another use of heavy oil is as fuel. Orimulsion heavy oil exploitation may become commercially
has revolutionised this process, making heavy oil viable. Some predictions have heavy oil produc-
easier to transport to power stations for burning. tion growing to 10 billion barrels per year by the
However, heavy oil carries the disadvantage of end of the next century [34]. Whether such predic-
a high carbon to hydrogen ratio, meaning that, tions materialize will depend to a large extent on
compared to lighter oils or natural gas, it produces the development of energy-efficient new technolo-
much more carbon dioxide per unit of energy gies for heavy oil production and processing, and on
produced. If the heavy oil is high in sulphur, as environmental considerations: whether the drive for
26 Modern Petroleum Technology

lighter and cleaner fuels outweighs the impetus for of the 10th European Symposium on Improved Oil
those counties hosting the giant heavy oil resources Recovery, Brighton, UK, 18 20 August 1999.
to supply the demand for increasing energy. 9. G.H. Gary and G.E. Handwerk 1994 Petroleum
Refining: Technology and Economics. New York:
Marcel Dekker.
10. J.G. Weissman, R.V. Kessler, R.A. Sawicki, J.D.M.
ACKNOWLEDGEMENTS Belgrave, C.J. Laureshen, S.A. Mehta, R.G. Moore
and M.G. Ursenbach 1996 Down-hole catalytic up-
Many colleagues in BP Amoco have contributed grading of heavy crude oil. Energy & Fuels 10,
knowingly or unknowinglyto the content of 883 889.
this chapter. Their efforts, including work on the 11. T.A.M. McKean, R.M. Wall and A.A. Espie 1998
Viscous Oil Technology Project, have been of great Conceptual evaluation of using CO2 extracted from
flue gas for enhanced oil recovery, Schrader Bluff
value. BP Amocos Western North Slope Business Field, North Slope, Alaska. In: Greenhouse Gas
Unit (Alaska) have much to answer for in getting Control Technologies (B. Eliasson, P.W.F. Riemer
me interested in viscous oil in the first place, and in and A. Wokaun, eds). Amsterdam: Pergamon Press,
supporting technology development over the past pp. 207 215.
5 years. Thanks also go to Geoff Warren (currently 12. D. Urgelli, M. Durandeau, H. Foucault, and J.-F.
with Schlumberger), who influenced much of the Besnier 1999 Investigations of foamy-oil effect
from laboratory experiments. SPE Paper 54083,
material on recovery processes.
presented at the 1999 SPE International Thermal
Operations and Heavy Oil Symposium, Bakersfield,
California, 17 19 March.
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