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Concentracin (mM) tensin Ln(C1)

0.01 72.5 -4.6051702 CALCULAR:


0.05 71 -2.9957323 1) EXCESO SUPERFCIAL Y A
0.08 69.5 -2.5257286 2) Calcular CMC
0.1 68 -2.3025851
0.2 64 -1.6094379
0.3 57 -1.2039728
0.5 51 -0.6931472
1 44 0
1.2 40 0.18232156
1.5 36 0.40546511
2 35.2 0.69314718
2.5 35 0.91629073
2.7 35.2 0.99325177
3 35.1 1.09861229
3.2 35 1.16315081

Concentacin Vs Tensin
75
70
65
60
55
50
45
40
35
30
0 0.5 1 1.5 2 2.5 3 3.5 -5 -4 -
) EXCESO SUPERFCIAL Y Ao A CONDICIONES DE SATURACIN
) Calcular CMC

Concentracin vs Lc C1
TENSIN (GIBBS) V
75
55
70
65 f(x) = - 13.2629360208x + 42.4006525554
50
R = 0.9677608396
60
55 45
50
45 40

40
35
35
30
-5 -4 -3 -2 -1 0 1 2 30
-0.8 -0.6 -0.4 -0.2 0
TENSIN (GIBBS) Vs ln C1
55

f(x) = - 13.2629360208x
50 + 42.4006525554
R = 0.9677608396

45

40

35
f(x) = - 0.2935795999x + 35.3856208204
R = 0.2884732144
30
-1 -0.5 0 0.5 1 1.5

TENSIN (GIBBS) Vs ln C1 TENSIN Vs Ln C1 (4)


55 36

= - 13.2629360208x + 42.4006525554 35 f(x) = - 0.2935795999x + 35.3856208204


50
0.9677608396 R = 0.2884732144
34
45
33
40
32

35
31

30 30
.6 -0.4 -0.2 0 0.2 0.4 0.6 0.6 0.7 0.8 0.9 1
S.E
Sat. Yc= -13.263 _ 42.401
Yc= -0.2936 _ 35.386
0= -12.9694 _= 7.015
Xc= 0.54088855
CMC = 1.7175323

Datos: C K
=1/(/( 1)) T= 20 293.15
R 8.314 J/molK
9x + 35.3856208204 m= -13.263
= 0.00544179 5.4417909E-06
1 1.5 ^2

PARA Ao
# Avogadro 6.02E+23
=(1 10 ^20)/(+)

Ao= 3.05E+01
Ao= 61.0204325 ^2

TENSIN Vs Ln C1 (4)

35795999x + 35.3856208204
32144

0.8 0.9 1 1.1 1.2


1.00E-03
Surfactante no-ionico
Cu Agua, 25 C Calcular las constates caracteristic
C1(mol/ dm^3)/10-7 Tensin (J/m2) Ln(C1) SUPERFICIAL
1.-cmc
6.07E-07 0.0714 -14.314737 2.-tensin minima y teorica
1.02E-06 0.06 -13.796689 3.-rmax
2.05E-06 0.052 -13.097183 4.-Ao min
5.-Grficas
5.56E-06 0.0406 -12.100092
1.51E-05 0.0292 -11.10307
2.04E-05 0.0292 -10.801447
2.81E-05 0.0292 -10.481379

Concentracin Vs Tensin Concentrac


0.08

0.07

0.06

0.05

0.04

0.03

0.02

0.01

0 -15 -14 -13


0.00E+00 5.00E-06 1.00E-05 1.50E-05 2.00E-05 2.50E-05 3.00E-05

La grfica cuatro no se realizo porque son nos


mdaria pntos lineales y la ecuacin no se
cumpliria . Por lo tanto haciendo uso de la
ecuaci+n y va a aser igual aal valor de b y lo
podemos observar en la grafica numero cinco

TENSIN (GIBBS) Vs ln C1
0.07

0.06
f(x) = - 0.0114345628x - 0.0977596436
R = 0.9999999933
0.05

0.04

0.03
f(x) = - 9.56759130562581E-18x + 0.0292
R = 0 0.02

0.01

0
0.04

0.03
f(x) = - 9.56759130562581E-18x + 0.0292
R = 0 0.02

0.01

0
-14 -13.5 -13 -12.5 -12 -11.5 -11 -10.5 -10

=(1 10 ^20
Calcular las constates caracteristicas de SATURACIN
SUPERFICIAL
1.-cmc
2.-tensin minima y teorica
3.-rmax
4.-Ao min
5.-Grficas

Concentracin Ln (C1) Vs Tensin TENSIN (GIBBS) Vs ln C


0.08

0.07
f(x) = - 0.0114345628x - 0.0977596436
0.06 R = 0.9999999933

0.05

0.04

0.03

0.02

0.01

0
-15 -14 -13 -12 -11 -10 -9 -14 -13.5 -13 -12.5 -12 -11.5

Yc= -0.0114 Xc -0.0978


Yc= 0 Xc 0.0292
0= -0.0114 Xc= -0.127
Xc= -11.14035088 mol/ dm3
CMC= 1.451467E-05 mol/ dm3

=1/(/1)
Datos :
C K R(J/molk) m
25 298.15 8.314 -0.0114

r= 0.000004599 mol/m2

Para Ao
Datos:
#Avogadro 6.02E+23
=(1 10 ^20)/(#)

Ao= 3.61E+01 ^2
TENSIN (GIBBS) Vs ln C1
0.07

0.06
345628x - 0.0977596436
933
0.05

0.04

0.03

0.02

0.01

0
3 -12.5 -12 -11.5 -11 -10.5 -10