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Center Site Facility-Wide Hourly, Daily, 30-Day, and Annual Emissions During Normal Operations
Houly Uncontrolled Houly Controlled Rate Maximum Daily Maximum Daily Annual Average Rate Annual Average Rate
Rate (1) (2)
Uncontrolled Rate (3) Controlled Rate (4) 30-Day Average Rate (5) (6) (7)
Table C.2.5
Center Site LM6000 Modeled Stack Parameters - Startup Conditions
Stack Height Stack Temp. Exhaust Flow Stack Velocity Stack Diam.
(ft) (m) (deg-F) (K) (acfm) (ft/s) (m/s) (ft) (m)
80 24.4 680 633.2 446121 56.0 17.1 13 3.96
Notes:
Exhaust temp from "Catalyst Design (C06-135-GE Rev 2-Non Calc).xls", case 115.
Exhaust flow rate estimated for 12 minutes of startup from startup curve, with remaining 52 minutes at full load.
Stack diameter from "SCE 5XLM600 - BOP Equipment Only_Aug 09 06.doc", page 6.
Table C.2.6
Center Site LM6000 Modeled Stack Parameters - Commissioning
Stack Height Stack Temp. Exhaust Flow Stack Velocity Stack Diam.
(ft) (m) (deg-F) (K) (acfm) (ft/s) (m/s) (ft) (m)
80 24.4 680 633.2 237467 29.8 9.1 13 3.96
Notes:
Exhaust temp from "Catalyst Design (C06-135-GE Rev 2-Non Calc).xls", case 115.
Exhaust flow rate estimated to be 50% of full load during commissioning.
Stack diameter from "SCE 5XLM600 - BOP Equipment Only_Aug 09 06.doc", page 6.
Table C.2.7
Startup load factors by minute
factor of flow
full load (1) (ACFM) minute
0 0 1
0 0 2
0 0 3
0 0 4
0 0 5
0 0 6
0.28 132981.3 7
0.5 237466.7 8
0.86 408442.7 9
0.86 408442.7 10
0.86 408442.7 11
1 474933.3 12
124696534 13-60 < multiply flow rate times 52 minutes
446120.7 average flow rate during a startup hour
0.939 ratio of startup hour to a full load hour
(1) Based on startup curve.
Table C.2.8
Data from Waukesha "Environmental Products 9" Spec Sheet:
Table C.2.9
AP-42 SO2 and PM10 Calculations (assume 4SLB):
Houly Uncontrolled Houly Controlled Rate Maximum Daily Maximum Daily Annual Average Rate
Rate (1) (2)
Uncontrolled Rate (3) Controlled Rate (4) 30-Day Average Rate (5) (6)
Table C.2.11
Center Site LM6000 Hourly, Daily, 30-Day, and Annual Emissions Including Startup and Shutdown Operations
Houly Uncontrolled Houly Controlled Rate Houly Controlled Rate Maximum Daily Maximum Daily Annual Average Rate
Rate (1) SU (2) SD (3) Uncontrolled Rate (4) Controlled Rate (5) 30-Day Average Rate (6) (7)
Table C.2.13
Center Site LM6000 Hourly Emission Calculations During Startup Conditions
Total Emissions During Maximum Houly
Startup (1) Duration of Startup Rate (2)
Pollutant (lb) (min) (lb/hr)
NOx 4.30 12 7.82
CO 3.70 12 8.82
PM10 0.91 12 4.53
VOC 0.33 12 1.37
SO2 0.05 12 0.27
(1) NOx and CO totals during startup provided by vendor; VOC assumed to be uncontrolled for first 6.5 minutes;
Uncontrolled VOC emissions back-calculated assuming 33.3% control from oxidation catalyst;
PM10 and SO2 assumed equal to normal operations.
(2) Normal operation emissions assumed for 48 minutes after startup is complete.
Table C.2.14
Center Site LM6000 Hourly Emission Calculations During Shutdown Conditions
Total Emissions During Duration of Maximum Houly
Shutdown (1) Shutdown Rate (2)
Pollutant (lb) (min) (lb/hr)
NOx 2.80 8 6.61
CO 2.40 8 7.95
PM10 0.60 8 4.53
VOC 0.23 8 1.36
SO2 0.04 8 0.27
(1) NOx and CO totals during shutdown provided by vendor; VOC assumed to be uncontrolled for last 5.5 minutes;
Uncontrolled VOC emissions back-calculated assuming 33.3% control from oxidation catalyst;
PM10 and SO2 assumed equal to normal operations.
(2) Normal operation emissions assumed for first 52 minutes of shutdown.
Table C.2.15
Center Site LM6000 Hourly Emission Calculations During Commissioning
Table C.2.17
Center Site LM6000 PTE Calculations for Criteria Pollutants: After Commissioning
Hours at Normal
SU SD Number of SU/SD Normal Operations Ops PTE
Pollutant (lb/hr) (lb/hr) Events (lb/hr) (hr) (tpy)
NOx 7.82 6.61 120 4.40 1379 3.90
CO 8.82 7.95 120 6.40 1379 5.42
PM10 4.53 4.53 120 4.53 1379 3.67
VOC 1.37 1.36 120 1.30 1379 1.06
SO2 0.27 0.27 120 0.27 1379 0.21
Note: assumes that 120 SUs and 120 SDs occur separately during the year
AP-42 Emission
Factor (1) Emission Rate (2)
MHU MHC MAC MAC
Pollutant CAS (lb/MMBtu) (lb/hr) (lb/hr) lb/yr ton/yr
1,3-Butadiene 106-99-0 4.30E-07 1.90E-04 1.90E-04 3.07E-01 1.54E-04
Acetaldehyde 75-07-0 4.00E-05 1.77E-02 1.77E-02 2.86E+01 1.43E-02
Acrolein 107-02-8 6.40E-06 2.83E-03 2.83E-03 4.58E+00 2.29E-03
Benzene 71-43-2 1.50E-05 6.63E-03 6.63E-03 1.07E+01 5.36E-03
Ethylbenzene 100-41-4 3.20E-05 1.41E-02 1.41E-02 2.29E+01 1.14E-02
Formaldehyde 50-00-0 7.10E-04 3.14E-01 3.14E-01 5.08E+02 2.54E-01
Naphthalene 91-20-3 1.30E-06 5.74E-04 5.74E-04 9.30E-01 4.65E-04
PAH [as benzo(a)pyrene] 50-32-8 2.20E-06 9.72E-04 9.72E-04 1.57E+00 7.87E-04
Propylene Oxide 75-56-9 2.90E-05 1.28E-02 1.28E-02 2.07E+01 1.04E-02
Toluene 108-88-3 1.30E-04 5.74E-02 5.74E-02 9.30E+01 4.65E-02
Xylene 1330-20-7 6.40E-05 2.83E-02 2.83E-02 4.58E+01 2.29E-02
HAP Total (3) 0.46 0.46 736.80 0.37
Ammonia Slip (4)
Ammonia 7664-41-7 --- 3.20E+00 3.20E+00 5.18E+03 2.59E+00
Notes:
(1) AP-42 Section 3.1, Table 3.1-3 dated April 2000.
(2) 0% control from the oxidation catalyst was assumed for all toxics except ammonia for MHC.
(3) Ammonia is not a HAP and is not included in the HAP Total.
(4) Ammonia slip lb/hr rate from Express Integrated Technologies performance data for case #115;
Represents 5.0 ppm ammonia slip.
CATEF Emission
Factor (1) Emission Rate
MHU MHC MAC MAC
Pollutant CAS (lb/MMscf) (lb/hr) (lb/hr) (lb/yr) (ton/yr)
1,3-Butadiene 106-99-0 3.67E-01 1.12E-03 1.12E-03 1.57E-02 7.87E-06
Acetaldehyde 75-07-0 5.29E-01 1.62E-03 1.62E-03 2.27E-02 1.13E-05
Acrolein 107-02-8 5.90E-02 1.81E-04 1.81E-04 2.53E-03 1.26E-06
Benzene 71-43-2 2.18E-01 6.67E-04 6.67E-04 9.34E-03 4.67E-06
Benzo(a)pyrene 50-32-8 2.70E-06 8.27E-09 8.27E-09 1.16E-07 5.79E-11
Benzo(b)fluoranthene 205-99-2 4.09E-05 1.25E-07 1.25E-07 1.75E-06 8.77E-10
Benzo(g,h,i)perylene 191-24-2 7.54E-06 2.31E-08 2.31E-08 3.23E-07 1.62E-10
Benzo(k)fluoranthene 207-08-9 7.83E-06 2.40E-08 2.40E-08 3.36E-07 1.68E-10
Chrysene 218-01-9 1.43E-05 4.38E-08 4.38E-08 6.13E-07 3.06E-10
Dibenz(a,h)anthracene 53-70-3 2.70E-06 8.27E-09 8.27E-09 1.16E-07 5.79E-11
Ethylbenzene 100-41-4 7.11E-02 2.18E-04 2.18E-04 3.05E-03 1.52E-06
Formaldehyde 50-00-0 4.71E+00 1.44E-02 1.44E-02 2.02E-01 1.01E-04
Indeno(1,2,3-cd)pyrene 193-39-5 7.17E-06 2.20E-08 2.20E-08 3.07E-07 1.54E-10
Naphthalene 91-20-3 2.51E-02 7.69E-05 7.69E-05 1.08E-03 5.38E-07
Propylene 115-07-1 5.38E+00 1.65E-02 1.65E-02 2.31E-01 1.15E-04
Toluene 108-88-3 2.39E-01 7.32E-04 7.32E-04 1.02E-02 5.12E-06
Xylene 1330-20-7 6.46E-01 1.98E-03 1.98E-03 2.77E-02 1.38E-05
HAP Total 0.04 0.04 0.52 0.00026
(1) 4-Stroke, lean burn, >650 hp CATEF factors obtained 10/18/06.
Note: The emission factors were compiled by running the California Air Resources Board's EMFAC2002
(version 2.2) Burden Model. A weighted average of vehicle types was used to calculate emission factors
for passenger vehicles, and emission factors for heavy heavy-duty diesel trucks were used for delivery trucks.
All the emission factors account for the emissions from start, running and idling exhaust. In addition, the VOC
emission factors take into account diurnal, hot soak, running and resting emissions, and PM10 emission factors
take into account tire and brake wear.
c
PM2.5 emission factor [lb/hr] = PM10 emission factor [lb/hr] x PM2.5 fraction of PM10
PM2.5 Fraction of PM10 in Diesel Engine Exhaust = 0.920 from FinalMethodology to Calculate Particulate Matter (PM) 2.5
PM2.5 Fraction of PM10 in Gasoline Engine Exhaust = 0.928 and PM 2.5 Significance Thresholds, SCAQMD, October 2006
Table C.2.21
Motor Vehicle Entrained Paved Road PM10 Emission Factors
On-Road
Average PM10 PM2.5
Vehicle Silt Emission Emission
Weight Loading Factor Factor
Vehicle Type (tons)a Road Type (g/m2)b (lb/mi)c (lb/mi)d
On-Site Pickup Truck 2.7 Local 0.24 0.0034 0.0000
Off-Site Dump Truck 2.7 Collector 0.037 0.0010 0.0000
Off-Site Concrete Truck 2.7 Collector 0.037 0.0010 0.0000
Off-Site Delivery Truck 2.7 Collector 0.037 0.0010 0.0000
Off-Site Construction Worker Commute 2.7 Collector 0.037 0.0010 0.0000
a
Weight of on-site vehicles based on vehicle class. Off-site average vehicle weight from
Methodology 7.9, Entrained Paved Road Dust (1997)
b
From ARB Emission Inventory Methodology 7.9, Entrained Paved Road Dust (1997)
c
Emission factor [g/mi] = 7.26 (Silt Loading/2)0.65 (Weight/3)1.5,
from ARB Emission Inventory Methodology 7.9, Entrained Paved Road Dust (1997)
d
PM2.5 emission factor [lb/hr] = PM10 emission factor [lb/hr] x PM2.5 fraction of PM10
PM2.5 Fraction of PM10 in Paved Road Dust = 0.169 from FinalMethodology to Calculate Particulate Matter (PM) 2.5
and PM 2.5 Significance Thresholds, SCAQMD, October 2006
Table C.2.22
Indirect Operational Emissions
Emissions
One-way CO VOC NOx SOx PM10 PM2.5
Vehicle Type Miles (lb) (lb) (lb) (lb) (lb) (lb)
Ammonia Delivery Truck 30 2.1381 0.0027 0.0736 0.0386 0.0613 0.0000
Wastewater Delivery Truck 0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Off-Site Construction Worker Commute 30 0.0817 0.0005 0.0830 0.0048 0.0613 0.0000
Total 2.2197 0.0033 0.1566 0.0434 0.1226 0.0000