LAMPIRAN PERHITUNGAN

NERACA MASSA
Perhitungan neraca massa produksi triacetin dari gliserol dilakukan dengan basis
perhitungan dan data konversi seperti di bawah ini :
ton
Kapasitas Pabrik = 30.000 tahun
kg
Kapasitas per Hari = 90909,09091 hari
kg
Kapasitas per Jam = 3787,878788 h

Operasi Pabrik = 330 hari

kg
Data berat molekul : Mr gliserol = 92,05 kmol
kg
Mr asam asetat = 60,05 kmol
kg
Mr triacetin = 218,21
kmol
kg
Mr asam asetat anhidrat = 102 kmol

Asumsi:
C3H8O3 terkonversi sebanyak 98.70 %
C9H14O6 selektivitas sebanyak 99,49%
Perhitungan mol :
a) Triacetin
kg kg
Mol Triacen = 3787,878788 / 218,21 kmol
h

kmol
= 17,35887 h

b) Gliserol
Mol gliserol terkonversi 98,7% menjadi triacetin, maka:
Jumlah mol gliserol x konversi = jumlah mol triacetin
Jumlah mol gliserol = jumlah mol triacetin / konversi
kmol
Jumlah mol gliserol = 17,35887 / 0,987 jam
kmol
= 17,5886892 jam
kmol kg
Massa gliserol = 17,5886892 92,05 kmol
jam
kg
= 1597,363 kmol
 kmol
Mol gliserol tidak terkonversi = (17,58453422 - 17,35886907) jam
kmol
= 0,228637588 jam
kmol kg
Massa gliserol tidak terkonversi = 0,228637588 92,05 kmol
jam
kg
= 21,03923089 jam

1) Reaktor II
Asumsi:
C3H8O3 terkonversi sebanyak 78.70 %
C9H14O6 selektivitas sebanyak 67,313%
C4H6O3 teruap sebesar 10,7123%

Neraca massa total:

- =

- = +
- = +
Neraca Massa Komponen:
a) Gliserol

=


(98.70 78,7) % =
17,5886892
= (0.987 0,787) 17,5886892 /
= 3,516907 /
Neraca massa komponen Gliserol:
=
 - = +
- 3.516907 / = + 0,228637588 /
kmol
= 3.516907 / + 0,228637588 jam

= 3,746138

b) Triacetin
Neraca massa komponen triacetin :
+ =
+ = +

+ 3.516907 = + 17,35886907

= 17,35886907 / 3.516907 /
= 13,84196207 /
2) Reaktor II
Asumsi:
C3H8O3 terkonversi sebanyak 78.70 %
C9H14O6 selektivitas sebanyak 67,343%
C2H4O2 teruap sebesar 5,7123%
 Neraca massa total:


- =

+ + - =

+ + - =
Neraca Massa Komponen:
c) Gliserol

=


(78.70 58,7) % =
17,5886892
= (0,787 0,587) 17,5886892 /
= 3,516907 /
Neraca massa komponen Gliserol:
=
+ + - =

0 + + 0 - 3.516907 = 3,7461388

kmol
= 3.516907 / + 3,7461388 jam

= 7,26364

d) Triacetin
Neraca massa komponen triacetin :
+ =
+ + - =

0 + + 0 + 3.516907 = 13,84196207


+ 3.516907 = + 13,84196207

= 13,84196207 / 3.516907 /
= 10,32386632 /
3) BUBBLE COLUMN
Asumsi:
C3H8O3 terkonversi sebanyak 58.70 %
 C9H14O6 selektivitas sebanyak 44%
C2H4O2 teruap sebesar 5,7123%

Neraca massa total:

- =

+ + - =

+ + - =
Neraca Massa Komponen:
e) Gliserol

=


(58,7) % =
17,5886892
= (0,587) 17,5886892 /
= 10,32386 /
Neraca massa komponen Gliserol:
 =
+ + - =

+ 0 + 0 - 10,32386 = 7,26364

kmol
= 10,32286 / + 7,26364 jam

= 17,5875

f) Triacetin
Neraca massa komponen triacetin :
+ =
+ + - =

+ 0 + 0 + 10,32386632 = 10,32386632

= 10,32386632 / 10,32386632 /
= 0
Dari neraca massa pada reaktor dan bubble column di dapat jumlah gliserol 17,5875
kmol/jam
pada kondisi reaksi dimana kami menggunkan rasio perbandingan mol antara gliserol :
asam asetat : asam asetat anhidrat 1 : 3 : 1,239
Perhitungan mol :
a) Gliserol
kmol
Mol gliserol = 1 17,35887 jam
kmol
= 17,35887 jam
kmol kg
Massa gliserol = 17,35887 92,05 kmol
jam
kg
= 1597,884 kmol
kmol
Mol gliserol yang terkonversi = 17,35887 98,2 %
jam
kmol
= 17,04641 jam
kmol kg
Massa gliserol terkonversi = 17,04641 92,05 kmol
jam
kg
= 1569,122 jam
kmol
Mol gliserol tidak terkonversi = (17,35887 - 17,04641) jam
kmol
= 0,31246 jam
 kg
Massa gliserol tidak terkonversi = (1597,884 - 1569,122) jam
kg
= 28,762 jam

b) Asetat Anhidrat
kmol
Mol asam asetat anhidrat = 1,239 17,58868 jam
kmol
= 21,787239 jam
kmol kg
Massa asam asetat anhidrat = 21,787239 102 kmol
jam
kg
= 2222,73401
jam

c) Asam Asetat
kmol
Mol asam asetat = 3 17,58867 jam
kmol
= 52,75360266 jam
kmol kg
Massa asam asetat = 52,75360266 60,05 kmol
jam
kg
= 3167,85384 jam

d) Triacetin
kg kg
Mol Triacen = 3787,878788 / 218,21 kmol
h

kmol
= 17,35887 h

4) Bubble Coulmn
Diketahui:
C3H8O3 terkonversi sebanyak 58.70%
C5H10O4 selektivitas sebanyak 2 %
C7H12O5 selektivitas sebanyak 54%
C9H14O6 selektivitas sebanyak 44%
Neraca massa total:


=

Neraca Massa Komponen:

a) Gliserol

=


58.70 % =
17.534 /
= 0.587 17,534101 /
= 10,2925173 /
Neraca massa komponen Gliserol:
=
(17,534101 / 10,2925173 / =
= 7,241583713 /
= 666.3705333 kg/h
b) Asam asetat
Neraca massa komponen asam asetat:
+ =

(17,534101 + (1 0,587)(3) =


21,72475114 =


= 21,72475114

= 8.331171863 /
c) Air
Neraca massa komponen air:
=

(17,534101 (1)(3) =


= 30,87755186

= 555,7959335 /
d) Monoacetin
Neraca massa komponen monoacetin:

(17,534101 )(0,02)(0,587) =


= 0,205850346

= 31,10432889 /
 e) Diacetin
Neraca massa komponen diacetin:

(17,534101 )(0,54)(0,587) =


= 5,557959335

= 1102,326111 /
f) Triacetin
Neraca massa komponen triacetin:

(17,534101 )(0,44)(0,587) =


= 4,528707606

= 1112,088056 /
g) Asam sulfat
Neraca massa komponen asam sulfat:
8,06743987 /
=
116,16

= 0,082278836

5) Reactor I
Asumsi:
C3H8O3 terkonversi sebanyak 78.70%
C5H10O4 selektivitas sebanyak 2 %
C7H12O5 selektivitas sebanyak 54%
C9H14O6 selektivitas sebanyak 44%
Neraca massa total:


=

Neraca Massa Komponen:

a) Gliserol

=


78.70 % =
17.534 /
 = (0.787 0,587) 17,534101 /
= 3,5068202 /
Neraca massa komponen Gliserol:
=
(7,2415837 / 3.5068202 / =
= 3,7347635 /
= 343,6729385 kg/h
b) Asam asetat
Neraca massa komponen asam asetat:
+ =

(21,72475211 + 3,5068202 + 0,6377153 + 3,8728446 =


= 29,74213115

= 1786,014976 /
c) Asetat Anhidrat
Neraca massa komponen Asetat anhidrat:
=

(17,580216 3,8728445 ) =


= 13,70737113

= 1398,426002 /
d) Monoacetin
Neraca massa komponen monoacetin:
=

(1,2754305 ) 0,63771525 =


= 0,637715253

= 100,7825006 /
e) Diacetin
Neraca massa komponen diacetin:
+ =

(628,55012 ) + 15,1564735 =


= 3,872844558

= 697,7065985 /
f) Triacetin
Neraca massa komponen triacetin:
+ =

(3,8728446 + +4,52870761 + 0,8872255 ) =


= 9,288777675

= 2106,216431 /
g) Asam sulfat
Neraca massa komponen Asam sulfat:
+ =

0,08227884 + 0 =


= 0,08227884


= 8,06743987

6) Reaktor II
Asumsi:
C3H8O3 terkonversi sebanyak 98.70 %
C5H10O4 selektivitas sebanyak 2 % dan konversi sebanyak 99.90%
C7H12O5 selektivitas sebanyak 54% dan terkonversi sebanyak 99%
C9H14O6 selektivitas sebanyak 44%

Neraca massa total:

=

Neraca Massa Komponen:

g) Gliserol

=


78.70 % =
17.534 /
= (0.787 0,587) 17,534101 /
= 3,5068202 /
Neraca massa komponen Gliserol:
=
(3,7347635 / 3.5068202 / =
= 0,2279433 /
= 20,97534366 kg/h
h) Asam asetat
Neraca massa komponen asam asetat:
+ =

(29,74221312 + 3,5068202 + 1,6902225 + 7,0419507) =


= 41,981125

= 2520,966529 /
i) Asetat Anhidrat
Neraca massa komponen Asetat anhidrat:
=

(8,5103285 7,04195073 =


= 1,4683777

= 149,8038966 /
j) Monoacetin
Neraca massa komponen monoacetin:
=

(1,7072954 ) 1,69022246 =


= 0,017073

= 2,2992385553 /
k) Diacetin
Neraca massa komponen diacetin:
=

(7,1130815 ) 7,04195073 =


= 0,0711308

= 15,53609492 /
l) Triacetin
Neraca massa komponen triacetin:
+ =

(9,28877768 + 70419507 + 0,8872255 ) =


= 17,217954

= 3722,8405 /
m) Asam sulfat
Neraca massa komponen Asam sulfat:
+ =

0,08227884 + 0 =


= 0,08227884

7) Distilasi I
Asumsi:
Monoacetin teruapkan sebesar 10%
Diacetin teruapkan sebesar 1%
Neraca massa total:


=

Neraca Massa Komponen:

a) Gliserol

=


78.70 % =
17.534 /
= (0.787 0,587) 17,534101 /
= 3,5068202 /
 Neraca massa komponen Gliserol:
=
(3,7347635 / 3.5068202 / =
= 0,2279433 /
= 20,97534366 kg/h
b) Asam asetat
Neraca massa komponen asam asetat:
+ =

(29,74221312 + 3,5068202 + 1,6902225 + 7,0419507) =


= 41,981125

= 2520,966529 /
c) Monoacetin
Neraca massa komponen monoacetin:
=

(0,01707295 ) (0,9) =


= 0,01536566

= 2,063147 /
d) Diacetin
Neraca massa komponen diacetin:
=

(0,07113082 ) (0,9) =


= 0,07041951

= 15,380734 /
e) Triacetin
Neraca massa komponen triacetin:
+ =

(17,2179539 + 0 ) =


= 17,217954

 = 3722,8405 /
f) Asam sulfat
Neraca massa komponen Asam sulfat:
+ =

0,08227884 + 0 =


= 0,08227884

8) Dsetilasi II
Asumsi:
Monoacetin teruapkan sebesar 10%
Diacetin teruapkan sebesar 1%
Neraca massa total:


=

Neraca Massa Komponen:

a) Gliserol

=


78.70 % =
17.534 /
= (0.787 0,587) 17,534101 /
= 3,5068202 /
Neraca massa komponen Gliserol:
=
(3,7347635 / 3.5068202 / =
= 0,2279433 /
= 20,97534366 kg/h
b) Asam asetat
Neraca massa komponen asam asetat:
+ =

(29,74221312 + 3,5068202 + 1,6902225 + 7,0419507) =


= 41,981125

= 2520,966529 /

c) Monoacetin
Neraca massa komponen monoacetin:
=

(0,0017073 ) (0,1) =


= 0,0001707

= 0,2292386 /
d) Diacetin
Neraca massa komponen diacetin:
=

(0,00071131 ) (0,01) =


= 7,113 06

= 0,1553609 /
e) Asam sulfat
Neraca massa komponen Asam sulfat:
+ =

0,08227884 + 0 =


= 0,08227884