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A R T I C L E I N F O A B S T R A C T
Article history: Lubrication oil used in refrigerant compressors forms oil mist in the compressor shell. Some
Received 22 May 2016 of the oil mist is discharged into a refrigeration cycle with refrigerant and causes degra-
Received in revised form 24 August dation of heat transfer in heat exchangers. Since the generation of the oil mist is related
2016 to the Weber number, it is necessary to measure the surface tension of the oil/refrigerant
Accepted 5 September 2016 mixture before discussing the oil mist generation in the compressor. In this study, the
Available online 9 September 2016 maximum bubble pressure method was adapted to measure the surface tension of PAG
(polyalkylene glycol) oil/CO2 mixture. The density of the mixture needed for the measure-
Keywords: ment was also carried out. It was found that the surface tension of PAG/CO2 mixture sharply
Oil mist decreases with an increase in the concentration of the refrigerant in the mixture. The surface
Weber number tension of the mixture under 10 MPa and 100 C is estimated to be 14.6 mN m1 by an
Surface tension extrapolation.
Oil/refrigerant mixture 2016 Elsevier Ltd and IIR. All rights reserved.
Maximum bubble pressure method
* Corresponding author. Department of Mechanical Engineering, Shizuoka University, Hamamatsu, Shizuoka, 432-8561, Japan. Fax: +81
53 478 1054.
E-mail address: fukuta.mitsuhiro@shizuoka.ac.jp (M. Fukuta).
http://dx.doi.org/10.1016/j.ijrefrig.2016.09.004
0140-7007/ 2016 Elsevier Ltd and IIR. All rights reserved.
126 international journal of refrigeration 73 (2017) 125133
Fig. 7 Experimental setup for density measurement. Fig. 9 Received signal by ultra sonic sensor.
130 international journal of refrigeration 73 (2017) 125133
Fig. 10 Density of PAG/CO2 mixture. tension of PAG is shown in Fig. 12 measured by the MBPM,
changing its temperature. The surface tension of PAG linearly
decreases with temperature. Fig. 13 shows the surface tension
of CO2 obtained by REFPROP ver. 9.1 (Lemmon et al., 2013). The
surface tension of CO2 is much smaller than that of PAG and
decreases with temperature, becoming 0 mN m1 at 31 C of
the critical temperature. When the temperature of CO2 exceeds
31 C, CO2 enters a super-critical condition and the surface
tension cannot be defined. Fig. 14 shows the surface tension
of the PAG/CO2 mixture at 30 C and 70 C. Since the surface
tension of CO2 is very small (1.2 mN m1 @ 20 C) compared
1
mix = (6)
1C C
+
oil ref
where, mix, oil, ref are densities of the PAG/CO2 mixture, PAG,
and CO2, and C is the mass fraction of the CO2 in the mixture.
The calculated density of the mixture decreases with an in-
crease in the CO2 mass fraction because the density of CO2 is
much less than that of PAG. On the other hand, the mea-
sured density of the mixture is almost constant at each
Fig. 13 Surface tension of CO2.
temperature, even though the concentration of CO2 increases.
In this study, the density of the PAG/CO2 mixture is assumed
to be constant against the concentration of CO2 and is only the
function of temperature. Fig. 11 shows an approximation of the
change in the density of the PAG/CO2 mixture against the tem-
perature. The density used in Eq. (1) is calculated from the
approximation curve shown in Fig. 11. It is found from Eq. (1)
that the error of surface tension caused by the error in the ap-
proximation of the density is 0.3% when the approximation
error of the density is 2% under the given condition.
with that of PAG, the surface tension of the PAG/CO2 mixture Although the experimental results are scattered mainly due to
steeply decreases with the increase of CO2 dissolved in the insufficient accuracy of the sampling method, it is shown that
mixture. The surface tension of the mixture becomes about half relatively good agreement of the calculated surface tension with
of that of pure PAG when the concentration of CO2 is 20%. The the experimental one is obtained at all temperatures when n = 3
surface tension of the mixture at 70 C is lower than that of in Eq. (7). Jensen and Jackman (1984) proposed a correlation equa-
30 C, and is also lower than the surface tension of pure PAG. tion similar to Eq. (7) and the index factor n of 0.5 is used for
In this study, the correlation between the surface tension combinations of R113 and several kinds of oil. It may happen
of the PAG/CO2 mixture and the concentration of refrigerant that the decrease of the surface tension of oil by dissolving re-
in the mixture is shown by Eq. (7). frigerant largely depends on the combination of oil and refrigerant.
Since the surface tension of oil decreases steeply when it con-
= r + ( o r ) (1 C)n (7) tains dissolved refrigerant and its change is expressed by Eq.
(7), the change of the surface tension can be used to detect the
where, C is the concentration of refrigerant in the mixture, n refrigerant concentration, and the maximum bubble pressure
is the index factor, and ref and oil are the surface tensions of method is utilized to develop a refrigerant concentration sensor.
refrigerant and oil respectively. Note that the surface tension The surface tension measurement of the mixture under high
of CO2 at the temperature above the critical point (31 C) cannot temperature and pressure condition as occur inside an actual
be defined and is regarded as 0 N m1 in this study. working compressor with a high pressure shell is very diffi-
Fig. 15 shows the surface tension measured by MBPM at each cult. The surface tension of the PAG/CO 2 mixture in a
temperature. The surface tension calculated by Eq. (7) is also compressor used in a heat pump water heater, therefore, is
shown in Fig. 15, using the index factors of 2, 3 or 4 in Eq. (7). estimated from the surface tension obtained in this study. The
132 international journal of refrigeration 73 (2017) 125133
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