Professional Documents
Culture Documents
Pre-Feasibility Report
For
Proposed Establishment of Synthetic
Organic Chemicals Manufacturing Facility
By
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
Table of Contents
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
List of Annexures
Annexure Description
I Land allotment / possession letter
II Process chemistry, Block diagram, Description
III Effluent treatment system block diagram
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
1 EXEC UT IV E SU MMA RY
Shree Pushkar Chemicals & Fertilizers Ltd(formerly known as Shree Pushkar Petro
Products Ltd.) (SPCFL), founded in 1994 is an established market leader in the
manufacture of Dyes & Dyes Intermediates. We have been a late entrant into
manufacturing of Dyes Intermediates; however, we have created a niche for ourselves in
the dyestuff market. This can be attributed to our dedication to the dyestuff business
and our professional set-up to support our Customers. Today, we have become a force
to reckon with and are on our way of reaching and sustaining a position of leadership.
SPCFL are progressing and growing with a policy of innovation, invention and
consistent quality supplies. Our future development will have emphasis on safety and
harmony with the environment.
SPCFL supply products to a global clientele including major Dyes producers and
Merchant Traders. We also serve our Customers as an integrator of small manufactures
in India offering a "one stop" source of all their chemical requirements.
SPCFL manufacturing facilities are located near the commercial capital of India, i.e.
Mumbai. SPFCL have an aggregate installed capacity of 10000 MT of various Dyes
Intermediates. With a team of highly trained and qualified professionals, we guarantee
our customers not only high quality products, but also 110% service commitments via
our robust Manufacturing, Buy-Cycle and Post sales operational processes.
SPCFL are dedicated to the dyestuff business and set high future goals. We are an
achievement oriented organization and are proud of our track record. Infrastructure
developed by us and with policies that fuel growth, we have a very positive outlook for
the future. Our future plans include consolidating our capacities and enhancing our
product range. We are also in the process of extending our Product Reach capabilities
via Stock & Sale facilities at major consuming & trading centers. Our eventual goal is to
develop long term associations and also engage into Toll manufacturing under secrecy
agreements.
Our Manufacturing facilities are capable of providing a range of Chemical reactions such
as Sulfonation, Reduction, Nitration, Condensation, Isolation, Hydrolysis, Amination,
Fusion, Acetylation etc. These ranges of reactions make us ideal for Toll Manufacturing.
It gives us the flexibility to manufacture a wide range of products. The same is evident
from our product manufacturing capability Tree.
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
The project brief is summarized in the table below Project summary at a glance
Sr No Particulars Details
1 Name of Company Shree Pushkar Chemicals and
Fertilizers Limited
2 Products Reactive Dyes, H-acid, Vinyl
Sulphone ester, Phthalocyanine
Pigments (Crude CPC Blue, Alpha
blue, Beta Blue, Pigment Green -
7)*
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
SPCFL has its manufacturing plants located at MIDC Industrial Area, Lote-Parshuram
Tal. Khed, Dist Ratnagiri Maharashtra as under:
3. Unit III Reactive Dyes Division: at plot No B-97 at MIDC Lote Parshuram,
manufacturing Reactive dyes. It also has 2 plants for the manufacture of H-Acid
and Vinyl Sulphone for captive consumption in the manufacture of reactive Dyes.
PROJECT DESCRIPTION
SPCFL is already into the manufacture of Dye Intermediates and Reactive Dyes.
Based on SPCFLs presence in the market for nearly a decade, its base of existing
& prospective customers, the present orders and enquiries in hand as also
looking to the demand for its products SPCFL is confident of an optimistic market
situation, which is expected to persist in the foreseeable future.
SPCFL is thus in the process securing a firm place for itself in this emerging
scenario, and has therefore planned to expand its activities with state of the art
manufacturing plants, in key product areas which have significant growth in
demand.
SPCFL thus proposes to expand its activities into setting up the new plants on a
new plot of land admeasuring 40,000 M2 allotted to it within the additional Lote
Parshuram MIDC Industrial Area.
The company has already paid a sum of Rs. 70 Lacs and is in the process of
paying the balance amount and taking possession of the plot.
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
2.3 Need of the Project and Its Importance to the country and/or
Region
The products proposed (Dyes, Pigments etc) above are imported to India on a regular
basis. The quantum of imports varies from product to product but the manufactured
goods will be import substitutes.
The products proposed are expansion of the companys current product range
(manufactured at other sites) as also backward integration into manufacture of some
items of raw material, and have a great demand both global and domestic. The demand
is envisaged to increase rapidly in the domestic market.
BUSINESS PROSPECTS
Healthy demand for dyes & bright prospects for dye intermediate industry
After remaining sluggish for two years, the volume growth of the nearly Rs 400 bn
domestic dyes and pigments industry has bounced back in FY14 which has led to a pick-
up in export demand. The industry has healthy prospects in the medium to long term,
driven by
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
Global short supply has led to pick-up in exports, increase in margins of local dye
intermediate players
Implementation of tough environmental control norms in China has led to the shutdown
of a number of polluting units of dye intermediates. The same has also been observed in
the domestic market wherein a number of small/ unorganized units which were unable
to comply with the pollution control norms have been shut down. This has led to supply
shortage globally and a sharp increase in the prices of key dye intermediates. This has
benefited organized Indian players as
(a) Exports of key dye intermediates have increased over FY14-H1FY15, and
(b) Increase in sales price has led to an increase in operating profitability.
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3.2 Location
(Map showing general location, specific location, and project boundary and
project site layout) with co ordinates
The proposed project site is at additional Lote Parshuram MIDC. The plot is in
allotted by MIDC, However the plot layout is not yet submitted by MIDC to
SPCFL, which is in process.
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The project is proposed at Plot No B-29, Additional MIDC Lote Parshuram, Dist.
Ratnagiri, Maharashtra.
This site is in premises of additional MIDC (Lote Parshuram) area which is meant for
these types of Industries.
SPCFL is currently importing various raw material including bulk items through these ports.
SPCFL has its own EXIM & Logistics departmentfor transportation of the Raw material &
Finished goods from factory to the port &vice versa.
The plot is thus most suitable for the products proposed specifically considering a complex
catering to in-house availability of some of the key Raw Materials such as Dye Intermediates
and Sulphuric Acid, as also from the point of view of ease in Management & control within
in the same locality.
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
Products
1 Reactive Dyes 12,000 TPA
2 H-Acid 3,000 TPA
3 Vinyl Sulphone ester 5,000 TPA
4 Phthalocyanine Pigments (Crude CPC Blue 5400 TPA, 7,800 TPA
Alpha blue 900 TPA, Beta Blue 600 TPA, Pigment Green
-7 900 TPA)
By products
1 Copper Sulfide 48 TPA
2 Ammonium Sulphate 3000 TPA
3 HYPO(Sodium Hypo Chlorite NaOCl ) 12 TPA
4 Copper 24 TPA
5 Poly Aluminum Chloride (PAC) 900 TPA
Raw Materials:
The basic raw material for the product capacity is submitted herein below.
Mode of Transport of Raw Materials: Few of the raw materials will be transported
Locally and few will be imported from the International Market. Mode of transport to
site is by road truck/tankers.
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Estimated
Sr. Physical Storage
Item consumption Unit Source / Vendor Name
No. state means
MTA
1 H-Acid 3240 MT solid bags Self Manufactured
2 Vinyl Sulphone Ester 6000 MT solid bags Self Manufactured
RCF/ Indian Oxalate/ R.R.
3 Sodium Nitrite 624 MT solid bags Enterprises, Mumbai./
Triveni Chemicals, Vapi
4 Cynauric Chloride 2208 MT solid drums Desmo Exports. Mumbai.
5 Aromatic Amines 1920 MT solid bags Hind Prakash
Shri Ram Industries
6 Lime Stone Powder. 9990 MT Solid bags
(Jodhpur)
Sodium Bi Sulphite Shalibhadra Intermediates
7 7450 MT Solid bags
22.0 % Pvt Ltd(Ahmedabad)
Dhruvika Chemicals Trading
8 Phthalic Anhydride 5832 MT Solid bags
P. Ltd.
Hazel Mercantile Ltd /M K
9 Caustic Flakes 4080 MT Solid bags Trading
Corporation(Mumbai)
10 Urea 3618 MT Solid bags
HurisonPharma
11 Naphthalene 2010 MT Solid bags First Chemicals(Mumbai)
12 Iron Powder 2010 MT Solid bags Dyechem Industries (Karad)
Pesticides &Brevers Ltd / P
13 Soda Ash 1710 MT Solid bags
G Exim Pvt Ltd(Mumbai)
AnmolColourChemChattral,
14 Aluminum Chloride 1413 MT Solid bags
Gujrat
Shalibhadra Intermediates
15 Na2SO4 1320 MT Solid bags
Pvt Ltd(Ahmedabad)
16 Cuprous Chloride 972 MT Solid bags Swami Narayan Industries,
Chattral , Gujrat
17 Vacume Salt 360 MT Solid bags Ravji Salt Suppliers
AmmonuimMolybdate
18 54 MT Solid bags
(Catalyst) Ganesh Trading
19 Cupric Chloride 45 MT Solid bags Ganesh Trading
20 Surfactant 33 MT Solid bags HitelChem, Mumbai
Gujarat Narmada Valley
Fertilisers& Chemicals Ltd /
21 Aniline Oil 4950 MT Liquid tank
Amos Corporation
(Ahmedabad)
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Thionyl Chloride 2260 MT Liquid tank Self Manufactured
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
Estimated
Sr. Physical Storage
Item consumption Unit Source / Vendor Name
No. state means
MTA
Excel Industries / Atharv
52
HCl MT liquid tank Chemicals(Lote), Mamta
23 Enterprises(Pune)
Hazel Mercantile Ltd /M K
24 Caustic Lye 5000 MT Liquid tank Trading
Corporation(Mumbai)
Shri Ram Industries
25 Hydrated Lime 3990 MT Solid Bags
(Jodhpur)
Gujarat Narmada Valley
26 Acetic Acid 3550 MT Liquid tank Fertilisers& Chemicals Ltd
/Urmi Chemicals(Mumbai)
Deepak Fertilisers&
27 Nitric Acid 2250 MT Liquid tank Petrochemicals / Sulphocid
(Mumbai)
Nandadeep Chemicals Pvt
28 Methanol 1590 MT Liquid Barrels
Ltd (Mumbai)
Reliance Industries Limited
29 Ethylene Oxide 1400 MT Liquid tank
(Mumbai)
Gujarat Narmada Valley
30 Acetic Acid 660 MT Liquid tank Fertilisers& Chemicals Ltd
/Urmi Chemicals(Mumbai)
BenzoChem Industries P.
31 Dichloro Toluene 162 MT Liquid tank
Ltd.
Kempar Energy /
32 Xylene 28 MT Liquid Barrels
SksGlochem (Mumbai)
33 Mono Chloro Benzene 27 MT Liquid Barrels Chemie Organic Chemicals
Antares Chem P. Ltd.
34 Solvent Butanol 24 MT Liquid Barrels
Ghatkopar
35 Ice 23400 MT Solid Open Local Supplier
Proposed bulk storages at site (Major) for raw material and finished goods shall be as
follows,
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
1) Water
The total water requirement is 412 cmd for domestic, process, Boiler and cooling
and green belt maintenance purpose.
2) Energy
Steam / Process heat Requirement: The steam requirement and process heat
requirement for the proposed set up shall be met from the steam generating boilers and
Thermic Fluid heaters.
In addition to above, there will be one hot air generator (coal fired).
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3) Power
Proposed power requirement is 1250 KW for the proposed site operation which will be
supplied by MSEDCL.
1) Waste Water
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(*) Note: Above quantities are rough estimate, will be firmed up during EIA study
Ash content is based on 15 % ash in coal.
3) Hazardous waste
Category Type of Waste Quantity UOM Mode of Disposal
5.1 Used Oil 16 TPM Authorized
reprocesser/CHWTSDF Taloja
21.1 Process residue 50 TPM CHWTSDF Taloja
Spray Dryer
21.1 Process residue 25 TPM CHWTSDF Taloja
Pigment Plant
26.1 Gypsum 1500 TPM Cement manufacturers
26.1 Iron sludge 400 TPM CHWTSDF Taloja
33.1 Drums/ Barrels 500 No.PM Cleaned and Reused a site
35.3 ETP sludge 200 TPM CHWTSDF Taloja
(*) Note: Above quantities are rough estimate, will be firmed up during EIA study
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4 S IT E A NALYS IS
4.1 Connectivity
Proposed establishment project is planned at its newly acquired plot at additional Lote
Parshuram MIDC of the company. The nearest town / cities are Khed (21kms)/ Chiplun
(about 10 kms)/Pune approx. 250 kms and Panvel/Mumbai 210/250 kms respectively.
The industrial area are provided with good infrastructure like road connectivity to
National Highways (NH-66, old NH-17), railways (nearest station is Khed/Chiplun about
18/10 kms) / un-interrupted power supply as well water supply.
The land in possession with the company. The land doesnt fall under CRZ.
Existing land use pattern, Forest, water bodies details are as follows
Sr. No. Particulars Details
1. Town Lote MIDC
2. Taluka Khed
3. District Ratnagiri
4. Nearest water bodies River Vashishti (about 4 km in southwest direction)
5. Nearest Highway NH 66 = 1 km towards West
6. Nearest Railway Khed / Chiplun on Konkan railway which is
station approximately 18/10 km
7. Nearest Airport/ Mumbai International Airport 250 KM towards NW
Airbase Pune Lohegaon Airport / Airbase 134.5 KM towards NE
Existing Land use Pattern: The Land is reserved for Industrial use & the proposed
project shall be at the same plot.
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Infrastructure like water, electricity, telephone facility, roads already available in the
area. Other Infrastructure like, hospital, school, housing, entertainment, daily needs are
available easily at nearby Chiplun Town.
Additional Lote Parshuram MIDC provides many basic facilities like uninterrupted
water supply, power and Road Network. When various sites were seen, this site
appeared to be environmentally best as also from the business angle and therefore this
option was finally adopted. This site is inside the campus of the MIDC and means safe
transportation, less need of Utilities, less constructing buildings and roads, less water
with optimization of infrastructure.
There is no sensitive establishment in the vicinity such as health resort, hospital, and
archaeological monuments.
4.3 Topography
District Ratnagiri is one of the coastal districts of Konkan region of Maharashtra, spread
over an area of 8208 km2. It shows variation in topography from high altitudinal
Sahyadri hill ranges to coastal plains. The most predominant rock formation of the
district is the Konkan laterite, formed from the original trap and so the soils produced
from it is predominantly Lateritic. According to location and, extent of admixture of
different rocks, soils in Ratnagiri are graded as Rice, Varkas, Garden and Coastal Alluvial
soils. District receives average 3029 mm annual rainfall mostly contributed by
southwesterly monsoon. These climatic and edaphic conditions support different types
of forests. As per Champion and Seths classification, following forest types are generally
found in the district.
According to bio-geographic zone classification of India, study area falls under Deccan
Peninsula Central Plateau.
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soils in the south. Along the coast are the alluviums. There are small patches of salt
lands developed near the creeks.
Lateritic Soils
Lateritic soils which are predominant in the district, vary in color from bright red to
brownish red owing to the preponderance of hydrated iron oxides. They are always
acidic, the PH value ranging from 4.5 to 6.5. Lime is deficient or almost absent.
Usually they have very low phosphorus and potash content, but are fairly well
supplied with nitrogen and organic matter. Their texture is loamy and depth varies
from one foot to three feet. They are porous and not retentive of moisture and are
found all over the district except in Mandangad taluka which consists mainly of
forests. These soils, however, are found in several grades, which depend upon their
(soils) location and the extent of admixture of different rocks. The following of these
grades are of special significance.
Rice Soil
These soils have various names which are identified with their location. Those
situated at higher levels are usually known as mal, while those at slightly lower levels
are called kuryat soils. Near the water courses, which have a fair supply of water
during the rabi season, are the panthal or vaingan soils. All these soils benefit by
liming and give high response to the application of phosphatic and potassic
fertilisers. Only a kharif crop of paddy can be taken on these soils. On the panthal
soils, however, a crop of rabi pulse (wal) or summer (vaingan) paddy can also be
taken.
Varkas Soil
These soils are situated on the slopes of the hills and are partly eroded, yellowish red
and poor in fertility. Further, they are shallow in depth and coarse in texture. Ragi
(nagli) is the principal crop in these soils and it responds well to supplies of nitrogen
and phosphate. Cashewnut grows in plenty in this area. It is on these soils that the
world renowned Alphonso mangoes are grown. On the mountain tops are the
perennial forests, where the soils are rich in humus because of their being protected
from erosion. They are reddish-brown in colour.
Garden Soil
These soils are usually of mixed origin, varying from yellow-red to brown and are
located in the basins at the bottom of the hill ranges. They are light, easily workable,
well-drained and fairly fertile. Arecanut and cocoanut gardens thrive well in these
soils and are located in areas which have plenty of water supply and good drainage.
These crops respond well to application of nitrogen, phosphorus and potash.
Coastal Alluvium
The coastal strips in Dapoli, Guhagar, Ratnagiri and Rajapurtalukas are covered with
soils of recent deposits and are locally known as pulanwat. They are deep sandy
loams and cocoanut gardens and arecanut gardens thrive well in them. Paddy is also
taken here to some extent.
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Salt Land
Due to the inundation of the sea, a part of the coastal soils has "become salty. They
are locally known by several names like khar, khajan, kharvat, etc. In Deogad, Malvan
and Vengurlatalukas, the entire western strips are salty while in other coastal talukas
only salt patches which are suited to the coarser types of paddy are to be noticed.
Since these salt lands have not yet become alkaline, they can be reclaimed for
cultivation. With a view to making khar lands fit for cultivation Government enacted
the Bombay Khar Lands Act, 1948 and passed the Bombay Khar Lands Rules, 1949 to
provide for protection and improvement of khar and khajan lands and reclamation of
tidal lands in the State by construction and maintenance of and repairs to
embankments of the lands. The act was brought into force with effect from 11th July
1949 in the district. Under the provisions of the Act, the Government established the
Khar Lands Development Board on 11th July 1949. The Revenue Department
administers the Act, and sanctions individual Khar Lands Scheme thereunder
approved and prepared by the Board. The schemes so sanctioned are executed and
completed by the Board. The Act provides for a Government subsidy of 40 per cent,
of the cost of the schemes; the remaining 60 per cent, to be contributed by the
beneficiaries. The Board also recovers a small annual cess called "Khar BandistiAkar"
from the beneficiaries, being the cost of maintenance of the embankments
constructed under the scheme. By 1958, the Board had reclaimed in this district
about 1,959 acres covered by 13 schemes at a cost of Rs. 1,51,305.
Meteorological data are available for four stations in the district, viz., Harnai,
Ratnagiri, Deogad and Vengurla. Being a coastal district the variation of temperature
during the day and through the seasons is not large.
In the hot season temperature rises slowly from March, and May is the hottest
month. With the onset of the monsoon, temperature drops by three to four degrees.
Day temperatures during the monsoon are lower than those in the cold season. In the
post monsoon months of October and November, day temperatures increase and
days in November are as hot as in May. Night temperatures are the lowest in January.
Areas within 20 to 25 kilometres of the coast are the most pleasant particularly in
the hot months with the sea breeze blowing, nearly throughout the day. Further
inland during the hot months both days and nights can be oppressive and more so in
the tract at the foot of the Western Ghats. Along the coast the maximum temperature
rarely goes beyond 38C but in the interior may reach 40 or 41C.
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During the monsoon, skies are heavily clouded to overcast. But in the rest of the year
skies are clear or very lightly clouded.
Winds:
Winds are very strong and are mainly westerly or south westerly during the
monsoon. In the rest of the year winds blow from directions between north and east
in the mornings and between west and north-west in the afternoons.
Special weather phenomenon
During the pre and post monsoon months the district experiences very strong winds
sometimes reaching gale force particularly near the coast and heavy rain in
association with cyclonic storms which develop in the Arabian Sea and move in close
proximity to the coast. Thunderstorms are common in the post monsoon months and
the latter part of the hot season.
The regional distribution of rainfall is mainly explained by the relief of the land and
the direction of the rain bearing winds. The supply of rain to the inland areas is
considerably more than to the coastal areas. It becomes heavier or lighter, according
to the nearness or otherwise of the station to the great Sahyadri range which
powerfully attracts the rain clouds. Mandangad is, however, an exception though its
distance from the sea-is just about 14 miles. The average rainfall recorded by this
station appears to be quite high as compared to the averages of Deorukh, Chiplun,
Rajapur and Khed which are so near the Sahyadri hills.
Ante-monsoon or "mango" showers occur in April-May. Although the amount of
precipitation is small, these showers have great value in so far as the preliminary
kharif operations are concerned. The south-west monsoon is the main rainy season,
commencing by about the middle of June and lasting till the end of September.
Winter fall, resulting from the retreating monsoon, is almost negligible, which
explains why rabi cultivation is practiced on an insignificant scale. Most of the rabi
crops are brought to maturity mainly by irrigation.
The length of the rainy season has an important bearing on the agricultural
operations and output of the district. In a normal rainy season, there are about 100
rainy days. A substantial portion of which runs to waste because of its extreme
concentration during a certain part of the season which reduces the effectiveness of
the rainfall commensurately. From the point of view of agriculture, effectiveness of
rainfall depends on many factors such as, the normal rainfall, length of the rainy
season, occurrence of rain at the right time during the agricultural season, its spacing
during the season, nature of the soil, rate of evaporation, etc.
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5 PL A NNING B RIEF
In 2011, Ratnagiri had population of 1,615,069 of which male and female were 761,121
and 853,948 respectively. In 2001 census, Ratnagiri had a population of 1,696,777 of
which males were 794,498 and remaining 902,279 were females. Ratnagiri District
population constituted 1.44 percent of total Maharashtra population. In 2001 census,
this figure for Ratnagiri District was at 1.75 percent of Maharashtra population.
There was change of -4.82 percent in the population compared to population as per
2001. In the previous census of India 2001, Ratnagiri District recorded increase of 9.89
percent to its population compared to 1991.
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Prefeasibility Report Shree Pushkar Chemicals and Fertilizers limited
6.5 Connectivity
Refer 4.1 above
The total water requirement is about 412cmd (fresh & recycled) for Domestic,
boiler/cooling, Greenery and process. The source of water shall be from MIDC.
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The proposed activities are in the newly acquired plot of the company which is located
in additional Lote Parshuram MIDC area. It does not require acquisition of Land and the
Infrastructure so there is no any kind of activity of Rehabilitation and Resettlement
carried out.
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The various plants are expected to be commissioned one after the other starting from
November 2018 onwards and are expected to be fully operational by December 2019.
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Annexure I
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Annexure II
PROCESS OF MANUFACTURE
1. Vinyl Sulphone:The Manufacturing process for Vinyl Sulphone consists of six main
stages namely:
Sulphonation
Filtration
Reduction
Filtration and Centrifuge
Esterification
Drying & Packing
Sulphonation:
Acetanilide is Sulphonated with Chloro sulphonic Acid & Thionyl Chloride in a sulphonator
at controlled temperature.
The mass is then transferred to a dumping vessel and washed. The washed mass is charged
with required quantity of crushed ice so as to maintain the temperature within 00 to 30C; the
mass is then transferred to filtration.
Filtration:
The dumping mass is filtered in a Nutche filter where the cake is separated. The filtrate
containing spent acid (dilute Sulphuric acid) is transferred to the storage tank from where it is
taken for manufacture 1 Amino 3-6 Disulphonic 8 Napthalene Acid. The Cake containing
ASC is further taken for reduction and. Pre-determined quantity of Sodium Bi-Sulphite is
dissolved in water in the reduction vessel. The cake (Acetyl Sulphonyl Chloride) is added to
the reactor for about 6 hours along with Caustic Lye to maintain the PH at 7.
Reduction:
The Sulphonyl chloride wet cake is slowly added to an aqueous solution of sodium bisulphite
in a S.S. jacketed reduction tank. Caustic lye (48%) is added simultaneously to maintain the
pH at 7.5. The mass is stirred till pH stabilizes at 7.5 and then it is heated to 50C and
maintained at that temperature.The mass is then transferred to Ethoxylation vessel where
Ethylene oxide gas is passed at a controlled rate and the PH is maintained at 7 by continuous
addition of Sulphuric acid.
Esterification:
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The dried cake together with Sulphuric acid is charged in an Esterification vessel and heated
to 1700C. After the Esterification reaction is complete the mass is filtered.
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The 1 Amino 3-6 Di-sulphonic 8 Naphthalene Acid slurry obtained is drained in a Nutche
filter & given 2 to 3 washes to obtain 1 Amino 3-6 Di-sulphonic 8 Naphthalene Acidwet cake
which is subjected to Flash Drying.
Packing
The 1 Amino 3-6 Di-sulphonic 8 Naphthalene Acidof consistent quality is then packed in
poly lined plastic bags for dispatch.
Reaction steps for manufacture of1 Amino 3-6 Di-sulphonic 8 Naphthalene
Acid
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3. The general process for manufacture of Reactive Dyes consists of five main stages:
i. Diazotization.
ii. Preparation of Coupler.
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iii. Coupling.
iv. Condensation
v. Concentration & spray drying.
Diazotization
The reactive component, an Aromatic Amine, is diazotized by adding sodium nitrite solution
and HCl at lower temperatures (00 to 50 C - crushed ice is directly used to maintain
temperature).
Preparation of Coupler
i. The coupler an Aromatic Amine is neutralised with caustic Lye and then acetylated by
using acetic Anhydride at 300 to 350 C,
In another process the Coupler organic component containing hydroxy/ sulphonic/ amino
group is cynurated with Cyanuric chloride at 00 to 50 C.
Coupling
The coupler is thereafter coupled with the diazotized base. The same is neutralised with light
solution of soda Bi Carb and soda ash resulting into the Dye solution.
Condensation
In the case of cynurated coupler the reaction mass is condensed with a third aromatic amine
at 500 to 600 C resulting into the Dye solution
Concentration & spray drying.
The Dye solution is thereafter concentrated to slurry in multi effect evaporators and is finally
spray dried to yield the final product. (Removing extra water which is recirculated)
Blending &Sieving
The final Reactive Dye obtained from different batches are blended and sieved for product
consistency and are finally send to the packing line.
Packing
The dye of consistent quality is then packed initially in plastic bags and thereafter in poly
lined cartons.
STEP 2 DIAZOTIZATION
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STEP 3 COUPLING
STRUCTURE - A
STEP -4 CONDENSATION
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2. Alpha Blue:
Stage 1 (Acid process):
98 % Sulphuric acid is taken in a jacketed reaction vessel, to which crude Copper
Phthalocyanine is charged slowly. The temperature is maintained just below 85 deg C so
as to dissolve it completely.
The mass is stirred further for 2-3 hrs at 60 deg C and then cooled to room temp by
external circulation of water in jacket.
Recycled water is then introduced as a thin spray into the vessel slowly, taking care to
maintain the temp below 60 deg C.
The CPC separates out in the required form and is filtered off.
During filtration process the mother liquor generated contains 20 % sulphuric acid,
which is used in the manufacture of CPC blue.
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The CPC cake obtained in stage 1 is taken in another vessel and washed with water. It
is then stirred with fresh water to obtain an aqueous slurry which is acidic in nature. The
same is neutralized using ammonia solution and caustic lye to a pH of 8 to 8.5 and stirred
with emulsifier at 60 - 90 deg C for 2 Hrs.
The above slurry is filtered and the cake is washed with large amount of fresh water.
The wet cake is dried and pulverized to obtain CPC Alpha Blue.
The aqueous filtrate goes to ETP. Where after it is discharged into CETP.
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3. Beta Blue:
Stage 1 (Milling) :
The 98 % CPC is charged in a ball mill. The crude is milled for 24 Hrs. After grinding the
milled blue is discharged for Pigmentation. (Stage 2)
Stage 2 (Pigmentation):
The milled blue obtained above is charged into a MS vessel, containing caustic water,
Surfactants and solvent. The mass is heated under stirring and refluxed for 2 Hrs.
The solvent is thereafter recovered. The pigmented mass is filtered through filter
press, washed with water till the pH is neutral. The pressed cake is dried in spin flash
dryer.
4. Phthalocyanine Green G
Step 1
AlCl3 and Vacume salt are taken in a glass lined reactor, and heated upto 1600C for
melting of the mass. CPC and Cupric Chloride are charged in the molten mass and the
temperature maintained at 1700C.
Take water in the dumping vessel and drown the above mass.
Filter the mass in filter press and wash upto neutral PH.
Step2
The filtered cake is mixed with water in a vessel to which is added caustic Lye, a
surfactant and solvent (butyl Alcohol). The mass is heated upto reflux and is kept in
reflux mode for 5 Hrs.
The mass is thereafter put on distillation mode to recover the entire solvent. Thereafter
water is added to the mass and is subjected to filtration in the filter press, with hot water
washing till neutral PH. The cake is thereafter dried in a spin flash dryer and packed.
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RAW MATERIAL
For manufacture of Reactive Dyes the main Raw materials required are various types of
Dye-intermediates mainly different aromatic Amines such as VS, 1 Amino 3-6
Disulphonic 8 Napthalene Acid, Gamma Acid, MUA etc.
Whereas for Manufacture of H-Acid& VS the main raw material requirement would be
Naphthalene & Aniline oil. In addition the other items required are Nitric Acid, Oleum
65%, Sulphuric Acid 98%, Acetic Acid, Methanol, HCl, Iron powder, Caustic Flakes &,
Hydrated Lime As regards Sulphuric Acid, Oleum & Chloro Sulphonic Acid the same
would be met internally from the proposed Acid Complex (inorganic Products to be
manufactured under Consent to establish from MPCB) . The Company is already using
all the aforesaid raw material for its existing activities and as such has a well set
procurement system and no difficulty is envisaged in this regard.
All the raw materials are available indigenously from the open market without any difficulty.
At its existing plants at B-102/103, SPCFL is already manufacturing Dye Intermediates like
Gamma Acid, K-Acid, H- Acid, MUA, VS, etc. As also a Reactive dye manufacturing unit at
B-97. Further it also has an acid complex manufacturing Sulphuric and its derivative acids
Oleum & Chloro Sulphonic Acid with a nominal Capacity of 125 MT /day. As such the
existing procurement set up would be utilized for the raw material procurement.
The proposed plants for VS and H-Acid, are mainly to meet captive needs. The residual
portion would be sold in the market.
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Corporation(Ahmedabad)
Kempar Energy / Sks Glochem (Mumbai)
10 Ethylene Oxide Reliance Industries Limited(Mumbai)
11 Methanol Nandadeep Chemicals Pvt Ltd (Mumbai)
12 Hydrated Lime 90% Shri Ram Industries (Jodhpur)
13 Soda Ash Pesticides & Brevers Ltd / P G Exim Pvt Ltd(Mumbai)
14 Sodium Nitrite RCF/ Indian Oxalate/ R.R. Enterprises, Mumbai.
15 Cyanuric Chloride Desmo Exports. Mumbai.
16 Cast Iron Powder Dyechem Industries (Karad)
17 Refined Naphthalene First Chemicals(Mumbai)
18 Sodium Bi Sulphite Powder Shalibhadra Intermediates Pvt Ltd(Ahmedabad)
19 Phthalic Anhydride Dhruvika Chemicals Trading P. Ltd.
20 Technical grade Urea Hurison Pharma
21 Cuprous Chloride Swami Narayan Industries, Chattral , Gujrat
22 Cupric Chloride Ganesh Trading
23 Ammonium Molybdate Ganesh Trading
24 Aluminum chloride Anmol Colour Chem Chattral, Gujrat
25 Xylene Kempar Energy / Sks Glochem (Mumbai)
26 Butyl Alcohol Antares Chem P. Ltd. Ghatkopar
27 Solvents CHEMIEORGANIC CHEMICALS
28 Surfactants Local Supplier
29 Ice Local Supplier
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ANNEXURE III
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