INSTITUTO POLITNICO NACIONAL

ESCUELA SUPERIOR DE INGENIERA QUMICA E

INDUSTRIAS EXTRACTIVAS

LABORATORIO DE TERMODINMICA BSICA

PRCTICA N9
FACTOR DE COMPRESIBILIDAD Z A PARTIR DE DATOS PVT.
PRCTICA N10
FACTOR DE COMPRESIBILIDAD Z POR CORRELACIONES
GRUPO: 1IV20
EQUIPO: N/A

INTEGRANTE:

ALVARADO GMEZ KEVIN

FECHA: 07/11/17

PROFESOR: FROYLN FABILA GUTIRREZ

PRCTICA N9
FACTOR DE COMPRESIBILIDAD Z A PARTIR DE DATOS PVT.

Objetivos

A travs de un experimento utilizando el equipo Ramsey-Young y las tablas de vapor de agua saturado el
estudiante obtendr valores de presin, temperatura y volumen especfico del agua en equilibrio con su vapor
para calcular valores del factor de compresibilidad Z.

Tabla de datos experimentales

Evento Temperatura de Temperatura

ebullicin (cm) ambiente
Teb(C) (C)
1 25 56.2
2 80 22.7 24.5
3 83 16
4 87 10.5 hbarom(m Hg)
5 88 7.5
6 90 5 0.585
7 92 0

CLCULOS

1.- = 13595.08 2.466 + 2

= 13595.08 2.466(24.5) + 24.52 = 13545.11838
3
2.- = ( )( )( )

= (13545.11838 ) (9.78 2 ) (0.585) = 77495.68576 3
3
3.- = ( )( )( )

= (13545.11838 3
) (9.78 2 ) (0.562) = 74448.8469 Pa


= (13545.11838 3
) (9.78 2 ) (0.227) = 30070.9755 Pa


= (13545.11838 3
) (9.78 2 ) (0.16) = 21195.4012 Pa


= (13545.11838 ) (9.78 ) (0.105) = 13909.4821 Pa
3 2

= (13545.11838 3
) (9.78 2 ) (0.075) = 9935.34433 Pa


= (13545.11838 3
) (9.78 2 ) (0.05) = 6623.56289 Pa


= (13545.11838 3
) (9.78 2 ) (0) = 0

4.- =

= 77495.68576 3 74448.8469 Pa = 3046.8389 Pa

= 77495.68576 3 30070.9755 Pa = 47424.7102 Pa

= 77495.68576 21195.4012 Pa = 56300.2845 Pa
3

= 77495.68576 13909.4821 Pa = 63586.2037 Pa
3

= 77495.68576 9935.34433 Pa = 67560.3414 Pa
3

= 77495.68576 3 6623.56289 Pa = 70872.1229 Pa

= 77495.68576 0Pa = 77495.6858 Pa
3

5.- & 6.

3046.8389 Pa = 0.03046839 bar

Pabs sat(bar) T(C) 3

Vg ( )

1 0.029857979 bar 24C 3
45.85837541

2 0.33638885 bar 26C 3
40.97290279

i 0.030468389 Pa 3
24.3228909C 46.64711266

1
= 1 + ( )( 1 )
2 1 2
0.030468389 bar 0.029857979 bar
= 24C + ( ) (26C 24C) = . C
0.33638885 bar 0.029857979 bar

1
= 1 + ( )( 1 )
2 1 2
3 0.030468389 bar 0.029857979 bar 3 3 3
= 40.97290279 +( ) (40.97290279 45.85837541 ) = .
0.33638885 bar 0.029857979 bar
47424.7102 Pa = 0.4742471 bar

Pabs(bar) T(C) 3
Vg ( )

1 0.437029676 bar 78C 3
3.675233908

2 0.513871027 bar 82C 3
3.158081734

i 0.4742471 bar 3
82.9686822C 2.90760368

1
= 1 + ( )( 1 )
2 1 2
0.4742471bar0.437029676 bar
= 78C + (0.513871027 bar0.437029676 bar) (82C 78C) =82.9686822C

1
= 1 + ( )( 1 )
2 1 2
3 0.4742471bar0.437029676 bar 3 3 3
= 3.675233908 +( ) (3.158081734 3.675233908 ) =2.90760368
0.513871027 bar0.437029676 bar

56300.2845 Pa = 0.56300285 bar

Pabs(bar) T(C) 3
Vg ( )

1 0.513871027 bar 82C 3
3.158081734

2 0.556351071bar 84C 3
3.931803074

i 0.56300285 bar 3
84.3131719C 4.82667832

1
= 1 + ( )( 1 )
2 1 2
0.56300285bar 0.513871027 bar
= 82C + ( ) (84 82) = 84.3131719C
0.556351071bar 0.513871027 bar

1
= 1 + ( )( 1 )
2 1 2
3 0.56300285bar 0.513871027 bar 3 3 3
= 3.158081734 +( ) (3.931803074 3.158081734 ) = 4.82667832
0.556351071bar 0.513871027 bar
63586.2037 Pa = 0.63586204 bar

Pabs(bar) T(C) 3
Vg ( )

1 0.601732617 bar 86C 3
2.724352044

2 0.650168691 bar 88C 3
2.533964433

i 0.63586204 bar 3
87.4092564C 2.39981196

1
= 1 + ( )( 1 )
2 1 2
0.63586204 bar0.601732617 bar
= 86C + (0.650168691 bar0.601732617 bar) (88 88) =87.4092564C

1
= 1 + ( )( 1 )
2 1 2

3 0.63586204 bar0.601732617 bar 3 3

3
= 2.724352044 +( ) (2.533964433 2.724352044 ) =2.39981196
0.650168691 bar0.601732617 bar

67560.3414 Pa = 0.67560341 bar

Pabs(bar) T(C) 3
Vg ( )

1 0.650168691 bar 88C 3
2.533964433

2 0.701817658 bar 90C 3
2.359058383

i 0.67560341 bar 3
88.9849072C 2.27292527

1
= 1 + ( )( 1 )
2 1 2
0.67560341 bar 0.650168691 bar
= 88C + ( ) (90C 88C) = 88.98490717
0.701817658 bar 0.650168691 bar

1
= 1 + ( )( 1 )
2 1 2

3 0.67560341 bar0.650168691 bar 3 3

3
= 2.533964433 +( ) (2.359058383 2.533964433 ) =2.27292527
0.701817658 bar0.650168691 bar

70872.1229 Pa = 0.70872123 bar

Pabs(bar) T(C) 3
Vg ( )

1 0.701817658 bar 90C 3
2.359058383

2 0.756843287 bar 92C 3
2.198213899

i 0.70872123 bar 3
90.2509221C 2.17803418

1
= 1 + ( )( 1 )
2 1 2
. 0.701817658 bar
= 90 + (0.756843287 bar0.701817658 bar) (92C 90C) = 90.2509221C

1
= 1 + ( )( 1 )
2 1 2
3 . 0.701817658 bar 3 3 3
= 2.359058383 +( ) (2.198213899 2.359058383 ) = 2.17803418
0.756843287 bar0.701817658 bar

77495.6858 Pa = 0.77495686 bar

Pabs(bar) T(C) 3
Vg ( )

1 0.756843287 bar 92C 3
2.198213899

2 0.815414806 bar 94C 3
2.050154828

i 0.77495686 bar 3
92.6185113C 2.00436672

1
= 1 + ( )( 1 )
2 1 2
. 0.756843287 bar
= 92C + (0.815414806 bar0.756843287 bar) (94C 92C) = 92.6185113C

1
= 1 + ( )( 1 )
2 1 2
3 . 0.756843287 bar 3 3
= 2.198213899 +( ) (2.050154828 2.198213899 ) = 2.00436672
0.815414806 bar0.756843287 bar
7.-
m3
Evento Pabs sat [Pa] Tsat exp [K] Tsat tablas[K] Vg[ ]
kg
1 3046.8389 299.15 298.472891 46.64711266
2 47424.7102 354.15 357.118682 2.90760368
3 56300.2845 357.15 358.46317 4.82667832
4 63586.2037 361.15 361.559256 2.39981196
5 67560.3414 362.15 363.134907 2.27292527
6 70872.1229 364.15 364.400922 2.17803418
7 77495.6858 366.15 366.768511 2.00436672

8.-

Pabs sat VS Texp ; Tsat tablas

90000

80000

70000

60000

50000
Pabs sat

40000

30000

20000

10000

0
290 300 310 320 330 340 350 360 370
Texp ; Tsat tablas
 Pabs sat VS Vg
50

45

40

35

30
Vg

25

20

15

10

0
0 10000 20000 30000 40000 50000 60000 70000 80000 90000
Pabs sat
10.-

= =

m3
3046.8389 Pa46.64711266 18
kg
= 3
=1.02860288
8314 299.15 K

m3
47424.7102 Pa2.90760368 18
kg
= 3
=0.84297585
8314 354.15 K

m3
56300.2845 Pa4.82667832 18
kg
= 3
= 1.64729271
8314 357.15 K

m3
63586.2037 Pa2.39981196 18
kg
= 3
=0.91477645
8314 361.15 K

m3
67560.3414 Pa2.27292527 18
kg
= 3
=0.91801756
8314 362.15 K

m3
70872.1229 Pa2.17803418 18
kg
= 3
=0.91774558
8314 364.15 K

m3
77495.6858 Pa2.00436672 18
kg
= 3
=0.91845558
8314 366.15 K

11.-

Presin de Temperatura Volumen

saturacin de tablas especfico
Pabs sat (Pa) T tablas (K) 3
Vg( )
3169.9293 299.15 43.3373125
47414.474 354.15 3.40515794
55635.1071 357.15 3.15808173
62595.0654 361.15 2.62915824
65016.8691 362.15 2.53396443
70181.7658 364.15 2.35905838
75684.3287 366.15 2.1982139

= =

m3
3169.9293 Pa43.3373125 18
kg
= 3
=0.9942258
8314 299.15 K

m3
47414.474 Pa3.40515794 18
kg
= 3
=0.98701428
8314 354.15 K

m3
55635.1071 Pa3.40515794 18
kg
= 3
=1.0621108
8314 357.15 K

m3
62595.0654 Pa2.62915824 18
kg
= 3
=0.98657859
8314 361.15 K

m3
65016.8691 Pa2.53396443 18
kg
= 3
=0.98491911
8314 362.15 K

m3
70181.7658 Pa2.35905838 18
kg
= 3
=0.98434004
8314 364.15 K

m3
75684.3287 Pa2.1982139 18
kg
= 3
=0.9837378
8314 366.15 K

12.-

% = 100

0.99422581.02860288
% = 100 =-3.45767326
0.9942258
0.987014280.84297585
% = 0.98701428
100 =14.5933478
1.06211081.64729271
% = 1.0621108
100 =-55.0961267
0.986578590.91477645
% = 0.98657859
100 =7.27789395
0.984919110.91801756
% = 0.98491911
100 =6.79259312
0.984340040.91774558
% = 100 =6.76539129
0.98434004
0.98373780.91845558
% = 0.9837378
100 =6.6361405
TABLA DE RESULTADOS

Evento Z experimental Z bibliogrfica %E Z exp

1 1.02860288 0.9942258 3.45767326
2 0.84297585 0.98701428 14.5933478
3 1.64729271 1.0621108 55.0961267
4 0.91477645 0.98657859 7.27789395
5 0.91801756 0.98491911 6.79259312
6 0.91774558 0.98434004 6.76539129
7 0.91845558 0.9837378 6.6361405
PRCTICA N10
FACTOR DE COMPRESIBILIDAD Z POR CORRELACIONES

Objetivos

A partir de datos experimentales y por medio de las correlaciones de la ecuacin virial truncada en el segundo
miembro, el estudiante calcular valores del factor de compresibilidad.

Tabla de datos experimentales

Evento Temperatura de Temperatura

ebullicin (cm) ambiente
Teb(C) (C)
1 25 56.2
2 80 22.7 24.5
3 83 16
4 87 10.5 hbarom(mm Hg)
5 88 7.5
6 90 5 585
7 92 0

Tc = Temperatura crtica: 647.13 K

Pc = Presin crtica: 220.64 bar

= factor acntrico de Pitzer: 0.345

CLCULOS

1. =
299.15
= 647.13 K = 0.46227188 K
354.15
= 647.13 K = 0.54726253 K
357.15
= 647.13 K = 0.55189838 K
361.15
= 647.13 K = 0.55807952 K
362.15
= = 0.5596248 K
647.13 K
364.15
= 647.13 K = 0.56271537 K
 366.15
= = 0.56580594 K
647.13 K

2.- =

0.031699293
= = 0.00014367 bar
220.64
0.47414474
= 220.64
= 0.00214895 bar
0.556351071
= 220.64
= 0.00252153 bar
0.625950654
= 220.64
= 0.00283698 bar
0.650168691
= 220.64
= 0.00294674 bar
0.701817658
= 220.64
= 0.00318083 bar
0.756843287
= 220.64
= 0.00343022 bar

3.-(

) = 0 + 1
0.422
0 = 0.083
1.6
0.422
0 = 0.083 = -1.36736227
0.46227188 K1.6

0.422
0 = 0.083 = -1.02413176
0.54726253 K1.6

0.422
0 = 0.083 = -1.00928975
0.55189838 K1.6

0.422
0 = 0.083 = -0.98999751
0.55807952 K1.6

0.422
0 = 0.083 = -0.98526087
0.5596248 K1.6

0.422
0 = 0.083 = -0.97588891
0.56271537 K1.6

0.422
0 = 0.083 = -0.96664984
0.56580594 K1.6
 0.172
1 = 0.139
4.2
0.172
1 = 0.139 = --4.2560018
0.46227188 K4.2

0.172
1 = 0.139 = --2.02424871
0.54726253 K4.2

0.172
1 = 0.139 = --1.94895021
0.55189838 K4.2

0.172
1 = 0.139 = --1.85353008
0.55807952 K4.2

0.172
1 = 0.139 = --1.83052379
0.5596248 K4.2

0.172
1 = 0.139 = --1.7854896
0.56271537 K4.2

0.172
1 = 0.139 = --1.74172339
0.56580594 K4.2

4.-

Evento 0 1 BPc/RTc
1 0.03169929 -1.36736227 -4.2560018 -2.83568289
2 0.47414474 -1.02413176 -2.02424871 -1.72249757
3 0.55635107 -1.00928975 -1.94895021 -1.68167757
4 0.62595065 -0.98999751 -1.85353008 -1.62946539
5 0.65016869 -0.98526087 -1.83052379 -1.61679158
6 0.70181766 -0.97588891 -1.7854896 -1.59188283
7 0.75684329 -0.96664984 -1.74172339 -1.56754441
5.-

= 1 + ( ) =
0.00014367
= 1 + (2.83568289) = 0.9991187
0.46227188
0.00214895
= 1 + (1.72249757) 0.54726253
=0.99323622
0.00252153
= 1 + (1.68167757) 0.55189838
=0.99231669
0.00283698
= 1 + (1.62946539) =0.99171667
0.55807952
0.00294674
= 1 + (1.61679158) 0.5596248
=0.99148668
0.00318083
= 1 + (1.59188283) 0.56271537
=0.99100166
0.00343022
= 1 + (1.56754441) 0.56580594
=0.99049671

Evento Pr Tr

1 0.00014367 0.46227188 0.9991187

2 0.00214895 0.54726253 0.99323622
3 0.00252153 0.55189838 0.99231669
4 0.00283698 0.55807952 0.99171667
5 0.00294674 0.5596248 0.99148668
6 0.00318083 0.56271537 0.99100166
7 0.00343022 0.56580594 0.99049671
6.-

Presin de Temperatura Volumen

saturacin de tablas especfico
3169.9293 299.15 43.3373125
47414.474 354.15 3.40515794
55635.1071 357.15 3.15808173
62595.0654 361.15 2.62915824
65016.8691 362.15 2.53396443
70181.7658 364.15 2.35905838
75684.3287 366.15 2.1982139

= =

m3
3169.9293 Pa43.3373125 18
kg
= 3
=0.9942258
8314 299.15 K

m3
47414.474 Pa3.40515794 18
kg
= 3
=0.98701428
8314 354.15 K

m3
55635.1071 Pa3.40515794 18
kg
= 3
=1.0621108
8314 357.15 K

m3
62595.0654 Pa2.62915824 18
kg
= 3
=0.98657859
8314 361.15 K

m3
65016.8691 Pa2.53396443 18
kg
= 3
=0.98491911
8314 362.15 K

m3
70181.7658 Pa2.35905838 18
kg
= 3
=0.98434004
8314 364.15 K

m3
75684.3287 Pa2.1982139 18
kg
= 3
=0.9837378
8314 366.15 K

7.-

% = 100

0.99422580.9991187
% = 0.9942258
100 = -0.49213167
0.987014280.99323622
% = 0.98701428
100 = -0.63037994
1.06211080.99231669
% = 100 = 6.571264505
1.0621108
0.986578590.99171667
% = 0.98657859
100 = -0.52079784
0.984919110.99148668
% = 0.98491911
100 = -0.66681314
0.984340040.99100166
% = 100 =-0.67676004
0.98434004
0.98373780.99049671
% = 0.9837378
100 = -0.68706418

Tabla de resultados

Evento Z bibliogrfica %E Z correl

1 0.9942258 0.9991187 -0.49213167

2 0.98701428 0.99323622 -0.63037994
3 1.0621108 0.99231669 6.571264505
4 0.98657859 0.99171667 -0.52079784
5 0.98491911 0.99148668 -0.66681314
6 0.98434004 0.99100166 -0.67676004
7 0.9837378 0.99049671 -0.68706418
Conclusiones

Durante el desarrollo de esta prctica pudimos calcular de dos diferentes formas los datos que se nos pedan, as
como tambin notamos que el fluido a menor presin se someta, a menor temperatura llegaba a su punto de
ebullicin, por lo cual podemos decir que la presin en el agua es directamente proporcional a la temperatura a
la que esta llega a su punto de ebullicin, tambin durante el desarrollo de la prctica con el barmetro de
forma experimental medimos los cm de Hg en funcin de la presin a la que se someta el sistema, y por medio
de este se interpretaron los datos para su anlisis y clculo de los subsiguientes datos correspondientes,
mientras menor era la presin del sistema, el barmetro marcaba lecturas ms altas indicando menor presin