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Abstract ............................................................................................................................................... 1
1. Introduction ................................................................................................................................ 1
2. Electrocoagulation process ......................................................................................................... 2
3. Removal of arsenic by Electrocoagulation .................................................................................. 3
4. Comparison of Electrocoagulation and Chemical coagulation ................................................... 4
5. Conclusion ................................................................................................................................... 5
6. References .................................................................................................................................. 6
Abstract
Arsenic is suspected to be carcinogenic. Drinking arsenic contaminated water can
cause skin and lung cancer. Arsenic in ground water is a recognized problem in India.
There are various methods to being down the concentration of arsenic below
permissible limit, for example, lime precipitation, coagulation followed by filtration,
adsorption, ion exchange etc. Electrocoagulation process (EC) is an encouraging
technology for the effective removal of arsenic from aqueous solution. In this paper
removal of arsenic by electrocoagulation method has been discussed and result has
been compared with chemical coagulation. EC process was found to have higher
removal efficiency but, it had the problem of passivation of electrodes.
1. Introduction
Arsenic pollution is a result of geological processes. Arsenic dissolves from solid state
in soil grains to liquid state in water. Arsenic comes into soil by weathering of rocks
and minerals. It reaches into groundwater and surface water by leaching and runoff.
Further, the problem may have been modified by use of certain fertilizers. Arsenic
concentration in water is controlled by many factors such as redox potential (Eh),
adsorption/ desorption, precipitation/ dissolution, pH, presence of other ions etc.
In deeper levels (below 20 meters) arsenic is naturally present in water. This water is
extracted by tubewells and used for drinking. Water present in upper layers is
relatively less contaminated as it has spent less time in ground and absorbed less
amount of arsenic.
Bihar, Jharkhand, Uttar Pradesh in flood plain of river Ganga; Assam and Manipur in
flood plain of river Brahmaputra; and Imphal and Rajnandan village in Chattisgarh have
been reported to be exposed to arsenic contamination. In this region water extracted
from tubewells have been found to contain arsenic concentration above the
permissible limit of 50g/L.
Arsenic has many uses in agriculture, medicine and industry. Some of them are listed
below
(i) Production of semiconductor, glass, transistors, paper
(ii) Processing of dyes, pigments, paper, wood, glass
(iii) Pesticide, insecticide, wood preservatives and herbicides
(iv) Cotton desiccant, hide tanning process, pharmaceuticals
Following effect on human health have been noted in Arsenic polluted areas
(i) Itching skin, burning and watering of eyes, weight loss, appetite loss,
weakness
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(ii) Chronic respiratory complaints were also common. Chronic cough was
evident in more than 50%
(iii) Gastrointestinal symptoms of anorexia, nausea, dyspepsia, altered taste,
pain in abdomen, enlarged liver and spleen, and ascites (collection of fluid
in abdomen)
(iv) Moderate to severe anemia was evident in some cases
2. Electrocoagulation process
Electrocoagulation (EC) involves many physical and chemical processes. Metals
(aluminium, iron, zinc) are used as a sacrificial electrodes to generate coagulant. When
a potential is applied between two electrodes; oxidation of electrode occurs at anode;
releasing metal cations and electrons in same proportion. This reaction is given as
+
+
22 4 + + 2 + 4
2
Figure 1 Pollutant removal mechanism
3
Anions present in water also affect the removal of arsenic. Fluoride ion reduced the
efficiency of the process significantly (Vasudevan et al., 2010b), but the presence of
sulfate ions in the water medium did not affect the arsenic removal efficiency of EC
process (Wan et al., 2011; You and Han,2016).
The main floc, Fe(OH)2, Fe(OH)3 and Al(OH)3 formations also depends on the pH
conditions. Ferrous hydroxide starts to precipitates at pH of 5. Increase in pH,
increases the concentration of ferrous hydroxide concentration. The concentration of
insoluble ferrous hydroxide is maximum at pH 12 and decreases with increases in
solution pH. Similarly, the minimum pH required for the precipitation of ferric
hydroxide and aluminium hydroxides are 1 and 4, respectively.
The major pollutant removal mechanisms in an EC system are sweep floc coagulation;
and adsorption and charge neutralization. arsenite (As3+) is more toxic than arsenate
(As5+). That is why oxidation is recommended as first step in arsenic removal. Initially,
concentration of arsenat (As5) increases due to conversion of arsenite (As3+) to arsenat
(As5). After sometime concentration of both the arsenate and arsenite decreases due
to adsorption on hydroxide flocks.
5. Conclusion
In India, seven states namely, West-Bengal, Jharkhand, Bihar, Uttar Pradesh in the
flood plain of Ganga River; Assam and Manipur in the flood plain of Brahamaputra and
Imphal rivers and Rajnandgaon village in Chhattisgarh state have so far been reported
affected by arsenic contamination in groundwater above the permissible limit of 50
g/L.
EC process is very efficient process for arsenic removal. Highest efficiency of removal
was with iron and aluminium electrodes and efficiency depends upon pH of solution.
Efficiency of Chemical coagulation was much less than that of EC process, although
removal mechanism was same. Even though EC process is very effective for the
elimination of arsenic and its compounds from water medium, the passivation of
electrodes is a major drawback. The recent study by van Genuchten et al. (2016) gave
an excellent explanation for the electrode passivation during the arsenic removal by
EC process. The authors checked the electrodes used for arsenic removal in laboratory
experiments and in real field; and observed significant differences on the surface layer
size and texture of laboratory and field electrodes. The laboratory electrodes had a
light orange surface coating and were able to clean the surface with very less mass
reduction. On the other hand, the surface of the field electrodes was coated densely
and was able to remove the coating by chipping it. This produced black coloured flakes
with area 10 cm2 and several mm thicknesses. The surface of the field electrodes was
also in black colour, even after the chipping process. This indicates that the electrodes
were more corroded in field conditions than in laboratory conditions.
Another problem with real field water treatment is the absence of dissolved oxygen in
water medium. The conversion of ferrous to ferric ions accelerates in the presence of
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dissolved oxygen. Also, the aeration of EC system increases the efficiency of the
process, even in the case of real field water (Parga et al., 2005). Therefore, aeration of
EC system is an important step for enhancing the process efficiency. The aeration also
helps to increase the collision between the contaminant and floc, which shoot up the
subsequent removal of contaminant.
6. References
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of groundwater in parts of the Bengal basin in India and Bangladesh: the role of
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pp.11271137.
Acharyya, S. K., Chakraborty, P., Lahiri, S., Raymahashay, B. C., Guha, S. and Bhowmik,
A., (1999), Arsenic poisoning in the Ganges delta. Nature, 401, pp. 545546.
Sanchez Calvo, L., Leclerc, J.P., Tanguy, G., Cames, M.C., Paternotte, G., Valentin, G.,
Rostan, A., Lapicque, F., 2003. An electrocoagulation unit for the purification of soluble
oil wastes of high COD. Environ. Prog. 22, 57e65.
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Malakootian, M., Mansoorian, H.J., Moosazadeh, M., 2010. Performance evaluation of
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Vasudevan, S., Sozhan, G., Ravichandran, S., Jayaraj, J., Lakshmi, J., Sheela, S.M., 2008.
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process. Ind. Eng. Chem. Res. 47, 2018e2023.
Vasudevan, Lakshmi, J., Sozhan, G., 2012a. Simultaneous removal of Co, Cu, and Cr
from water by electrocoagulation. Toxicol. Environ. Chem. 94, 1930e1940.
Kamaraj, R., Ganesan, P., Vasudevan, S., 2013b. Removal of lead from aqueous
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Zhang, P., Tong, M., Yuan, S., Liao, P., 2014. Transformation and removal of arsenic in
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You, H.J., Han, I.S., 2016. Effects of dissolved ions and natural organic matter on
electrocoagulation of As(III) in groundwater. J. Environ. Chem. Eng. 4, 1008e1016.
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