Professional Documents
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Absorption Chiller
Installation & Operation Manual
V5.1
Cooling water: Clean fresh water, with its quality complying with Table 8-1
Warning:
1. The chiller is a type of vacuum equipment and all valves on it have been
firmly sealed before shipment from factory. Any forms of modification to
these valves are prohibited, that may damage or even destroy the chiller.
2. The chiller should be stored at a place where it is protected from rain and
the relative humidity is not greater than 85%, otherwise the electrical
elements may be damaged.
3. The chiller should be unpacked only by our companys professional
commissioning personnel or properly trained individuals.
4. Do install a strainer (60-80 meshes) at the steam inlet.
5. Do install a check valve at the steam inlet.
6. The customers chilled water pump and cooling water pump are required to
be in linkage with the chiller, otherwise the freezing of tubes may occur.
1. Working principle
Any liquid absorbs heat from its surroundings as it vaporizes. And the lower the
atmospheric pressure, the lower the vaporizing temperature. For example, water vaporizes at
100 under one atmospheric pressure, but under the 0.00891 atmospheric pressure, it
vaporizes at 5.
That is the basic working principle of a LiBr absorption chiller. Water (the refrigerant)
vaporizes in the high-vacuum absorber and absorbs heat from the water to be chilled. The
refrigerant vapor is then absorbed by the LiBr solution (the absorbent) and circulated by pumps
to keep the process going cyclically.
Steam in
Low-temp
Condenser generator
Cooling water
out High-temp
1 generator
1 High-temp generator pressure
Evaporator Absorber
Cooling water inlet temp
Chilled 7 6 Cooling water inlet target flowmeter
water in Condensate heat
exchanger Chilled water inlet temp
3 7 Chilled water inlet target flowmeter
6
Chilled water outlet temp
Cooling
Low-temp
heat exchanger
8 Chilled water outlet target flowmeter
water in Condensate out
F3
F1 5
purge device
4
Automatic
Cooler
Oil
trap
F2 F6
High-temp heat exchanger
F1 Main purge valve
Solution
Vacuum
pump
F4 Refrigerant
pump
F5 F2 Ultimate vacuum purge valve
pump F3 Absorber purge changeover valve
F4 Refrigerant water sampling valve
Concentrated F5 Solution sampling valve
solution Chilled water Cooling water
F6 Refrigerant water regereration valve
Intermediate Refrigerant water Steam
solution
2. Cooling cycle
The working principle of a steam-fired double-effect LiBr absorption chiller is shown as
Figure 2-1. The diluted solution from the absorber, pumped by the solution pump, passes the
low-temperature heat exchanger (LTHE), condensed water heat exchanger (CWHE) and
Table 3-1
S/N Part Name Function
Boils the solution with the working steam to generate the primary refrigerant
vapour which will enter LTG and concentrates the solution into the
1 HTG intermediate solution which will flow to HTHE.
Working condition: absolute pressure700mmHg
solution temperature155C
Uses the concentrated solution to absorb the refrigerant vapour from the
5 Absorber
evaporator, with the heat being taken away by the cooling water.
Refrigerant Circulates the refrigerant water, making it dispersed evenly on the heat
11
pump transfer tube bundle in the evaporator.
Electric valve Regulates the input of working steam or cuts off the working steam
13
set
Electric control Accommodates components of the control system.
14
cabinet
1. General properties
Lithium bromide (LiBr) is similar to sodium chloride (NaCl) in property. As a stable
substance, it is nonperishable, non-decomposable and nonvolatile in the atmosphere. Its
solution is a clear, transparent, and nontoxic liquid, which has a bitter taste and can cause slight
itching on the skin. LiBr solution becomes slight yellow after lithium chromate (Li2CrO3) is
added in, and remains clear with lithium molybdate (Li2MoO4). Avoid touching it directly with
skin, splashing it into eyes and tasting it.
The quality of the LiBr solution decides the chiller performance to a large extent.
Therefore, strict measures must be taken to control its quality, which should meet the following
standards:
Concentration: 500.5%
Alkalinity: pH 9.0~10.5
Li2CrO3 content: 0.10.3% ( Li2MoO4 content: 0.012~0.018%)
Maximum content of impurities:
ChlorideCl-: 0.05%
SulphateSO4-: 0.02%
BromateBO4-: non-reaction
AmmoniaNH3: 0.0001%
BariumBa: 0.001%
CalciumCa: 0.001%
MagnesiumMg: 0.001%
2. Solubility
The concentration of the saturated LiBr solution is about 60% at normal temperature. At a
given concentration, crystals separate out from the solution when the temperature drops. And at
a given temperature, crystals separate out when the concentration rises. Crystallization must
be avoided during the chillers operation and shutdown period. See Appendix 3 for the
solubility curve of LiBr solution.
3. Specific gravity
The specific gravity of LiBr solution is greater than that of water and is a function of the
concentration and temperature of the solution itself. So once the specific gravity and
6
4. Causticity
Though LiBr solution has little caustic effect on common metals under vacuum condition,
it causes severe corrosion with presence of an extremely little amount of oxygen within the
chiller. Therefore, preventing air leaking into the chiller is the fundamental measures for
anti-corrosion. Adding proper amount of Li2CrO3(Li2MoO4) in the LiBr solution and keeping
pH value at 9.0~10.5 also effectively reduces its caustic effect on metals.
Real-time test and Parameters such as temperature, flow and liquid level are
6 display monitored and displayed in real-time mode.
Three-level password protection system (power-on password,
7 Password protection parameter correction password and parameter setting password)
prevents unauthorized operations.
When the load varies, the steam input and circulating solution
8 Auto load-adjusting amount are automatically controled, making the chiller operating
at the best status.
Remote control Control and monitoring of the chiller can be conducted from a
14 (extended function) remote place and or via a DCS/PLC system.
Fault management
Timed operation
System function
Remote control
Manual run
Auto run
Cooling
10
Note: A single-effect absorption chiller doesnt have the long-time low liquid level fault in
HTG, high-pressure fault in HTG and false liquid level fault in HTG.
11
6. Grounding requirement
To ensure safe and reliable operation of the chiller, the chiller is required to have a special
ground pole with the grounding resistance not greater than 10. The grounding terminals of
the chillers electrical devices should be securely connected to this pole. Without a special
ground pole (or a neutral line), the chiller may be damaged and people be injured.
12
1. Machine room
Try to select a machine room which is close to the steam source and to where the
chilled water is used.
The machine room should have enough brightness and good ventilation with the
relative humidity less than 85%. In case the chiller is installed outside the room, the
electrical devices and measuring instruments should be protected from moisture, rain,
sunshine, etc.
Sufficient space should be reserved around the chiller for maintenance: 1m in the
lengthwise direction, 0.2m above the chiller, 1.2m on the control cabinet side and
0.5m on other sides. And on either end of the chiller, a tube-drawing apace, not less
than the distance between the two tube sheets, should be kept so that the heat transfer
tubes can be drawn out.
The machine room should be equipped with necessary devices like electric outlets and
water taps. And there should be drains around the chiller.
2. Placement of chiller
degree should not be greater than 0.002. The level
degree can be regulated through the cushion block
13
Flexible connectors and manometers should be mounted at the inlets/outlets of the chilled
water and cooling water. If the dryness of the working steam is less than 0.90, a steam-water
separator should be mounted. At the inlets of chilled and cooling water there should be
strainers with 3-6mm meshes, or the cooling capacity may decrease and frozen tubes may
occur. And at the inlet of the working steam, there should be a strainer with 60-80 meshes,
otherwise failure in the electric valve may occur.
The steam piping is suggested as below:
Pipe
Strainer Strainer reducer
(80-100 meshes) (80-100 meshes)
Steam
In certain cases the steam supply cannot be cut off suddenly, for it may affect the
production process or the system. In such cases, replace the motorized two-way valve with a
three-way valve (as shown below).
HTG end
Cut-off
enclosure
valve
Strainer
Pipe
Strainer (80-100
reducer
Steam (80-100 meshes) meshes)
to cooling equipment
when the chiller stops
3-way steam valve piping diagram(for reference)
14
15
Do not start the solution pump or refrigerant pump before the LiBr solution is fully
charged into the chiller. Otherwise, the pump will be seriously damaged.
17
To prevent the heat transfer tubes in the evaporator from being frozen due to stop of
cooling water flow, observe the following items:
Confirm that the target flow switch works normally before starting the chiller.
When starting the chiller, start the chilled water pump (and confirm it has run)
first and then the cooling water pump.
After dilution and shutdown, stop the cooling water pump first and then the
chilled water pump.
19
20
5. Purging
In cooling cycle
Ejector
In cooling operation, purge valves 1 and 2 are closed.
When the liquid level in the gas tank falls below the
sight glass or the control cabinet operation panel requires,
Solution in
the vacuum pump should be started for purging. Purging
steps are:
1) Start the vacuum pump and keep it running for about Oil
Gas takn
trap
half a minute; Purge
valve
2 2
2) Open valve 1 and pump for at least three minutes; Purge
valve1 1
3) Open valve 2 and keep pumping until the cooling
effect recovers; Sight glass
4) Close valve 1 first and then valve 2;
Vacuum
5) Let the vacuum pump run for another half an hour,
pump
and then stop it.
Attention: If valve 2 is not closed, non-condensable gases in the gas tank will return to
the inside of the chiller through it.
In shutdown period
During a long period of shutdown, the purging should be performed once every month,
each time for about one hour. The method is: start the vacuum pump and open valves 1 and 2.
After purging, close valve 1 first and then stop the vacuum pump and close valve 2, otherwise
the vacuum pump oil will be pumped into the chiller and degrade the cooling performance
greatly.
T
he
chiller
must
be
kept
highly
airtight
and the
air
in
itmust
be
pumped
out
timely,
21
Replacement of diaphragms
1) If a water layer emerges at the bottom of the vacuum pump oil, drain it out slowly.
During the pumping of the vacuum pump, the gas ballast valve on it should be left
open so that the water vapor can be removed out of the pump.
2) If the vacuum pump oil is emulsified and turns white, replace it.
22
23
Note
2. Operation management
Management of solution
In the initial stage of the operation of the chiller, the content of lithium chromate (or
lithium molybdate) in the solution would decrease due to the generation of the protective film.
And if there is rust or air in the chiller, even an extremely little amount, will lead to chemical
reactions, which in turn will raise the pH value of the solution and even accelerate corrosion of
the chiller. Therefore, the solution should be sampled to check the content of lithium chromate
(or lithium molybdate), iron ion, copper ion, chlorine ion, etc. as well as the pH value of the
solution after the chiller has run for a period of time.
If the content of lithium chromate (or lithium molybdate) drops below 0.1% (or 0.012%),
add some more in time. And the pH value should be kept between 9.0 and 10.5. If its too high,
adjust it with hydro bromic acid (HBr); if its too low, adjust it with lithium hydroxide ( LiOH).
Replenishment of octanol
Octanol is insoluble in the solution. After the chiller has run for some time, part of octanol
will float on the surface of the refrigerant water and the solution. And since octanol is a volatile
substance, the running of the vacuum pump will bring some octanol out of the chiller, thus
reducing its circulating amount and affecting the chillers performance. Therefore, octanol
should be replenished as required.
The method for charging octanol is similar to that for the solution. Remember to start the
vacuum pump after the charging to remove the air that might leak into the chiller during the
charging.
25
26
1. Crystallization
During cooling cycle, when crystallization occurs in the concentrated solution in LTHE or
pipes, the temperature of the automatic de-crystallizing tube will rise and an alarm will be
given, while the temperature of the concentrated solution pipe leading to the absorber fall
dramatically.
Remedy
Stop the cooling water pump and chilled water pump, and close the steam cut-off
valve to 40%. Now the high-temperature concentrated solution coming out of LTG
flows directly into the absorber via the de-crystallizing tube and heats the diluted
solution in the absorber. The heated diluted solution then enters LTHE, heats the
concentrated solution there and melts the crystals.
For crystals in pipes, melt them by heating them directly with steam,
high-temperature water or flames.
27
aNo power is connected to the aCheck the main power supply and
Chiller cant control cabinet control switch
1
be started bFuse in the control cabinet bCheck the grounding wiring or short
blows circuits, and replace the fuse
a Poor sealing causes air a Start the vacuum pump to pump air
leakage into the chiller out and eliminate the leakage
b Refrigerant water is b Examine the density of refrigerant
polluted water. If it is over 1.02, regenerate it
c Circulating amount of the c Increase the frequency of the
diluted solution is too small inverter
Cooling d Vacuum pump is poor in d Test the vacuum pumps
capacity lower pumping performance performance and repair the fault
2
than the set e Spraying device is blocked e Clean or replace spraying device
point f Scaling or clogging of heat f Eliminate scales and impurities on
transfer tubes the inside wall of heat transfer tubes
g Cooling water temp is too g Regulate the cooling tower and
high check the cooling water system
h Cooling water flow rate is h Raise the cooling water flow rate
too small i Increase the vapor pressure
i Vapor pressure is too low
a External load is greater a Decrease external load
than the chillers cooling b Increase the cooling water flow rate
capacity or decrease its temp
b Cooling water flow rate is c Reset the set point of the chilled
too small or its temp is too water temp
Chilled water
high d Add octanol
3 outlet temp is
c Set point of the chilled e Start the vacuum pump to pump out
too high
water is too high non-condensable gases
d The amount of octanol
decreases
e There are non-condensable
gases in the chiller
a Circulating amount of the a Regulate the frequency of the
solution sent to HTG is too inverter
Refrigerant large and liquid level in b Decrease the amount of the cooling
4 water is HTG is too high water
polluted b Cooling water temp is too
low and cooling water
amount is too large
28
29
30
4Regular check
The chiller should be checked periodically, during both operation period and shutdown
32
33
34
5. Maintenance rule
Maintenance should be performed strictly in accordance with the Operation
Instruction.
Maintenance should be performed by or under the direction of qualified personnel.
36
37
Working steam in
Cooling tower
Condensate out
Pressure
reducing Check valve Steam trap Electric Cut-off Filter Flexible Thermo- Pressure
valve valve valve connector meter gauge
38
75.0
50.0
25.0
0.0
-25.0
-50.0
50.0 55.0 60.0 65.0 70.0 50.0
39
Control cabinet for Hope Deepblue steam-fired absorption
chiller
Q131 Q132 Q141 Q142 Q151 Q152
Chilled
water pump Cooling
water pump Cooling
tower fan
run command
run command
run command
Non-voltage
output
Note: : 1AC250V,5A
1. The capacity of the output relays for the linkage terminals of above
()
water pumps is AC 250V, 5A (resistance load).
2. Q131, Q132, Q141, Q142, Q151 and Q152 are code numbers for wires
in the control cabinet. Please pay attention not to misconnect them.
3. While running the unit, make sure the chilled water pump and cooling
3
water pump are in linkage control.
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JXP 01 02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33
PE NN L1 L2 L3 U2 V2 W2 VP E241U4 V4 W4 NN A07 PE NN A03 T0A T0BT0C T1AT1B T1C T2A T2B T2C T3A T3B T3C T4A T4BT4C
41
A132 A142 A152
T5A T5B T5C VP E21 VP E22 VP E07 U5 V5 W5 A172THR YW1 YW2 YW3 YW4 YW5 A131 A141 A151 A11 NN A12 NN
JXP 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63
A132 A142 A152
T5A T5B T5C VP E211E21 VP E22 VP E07 U5 V5 W5 A172THR YW1 YW2 YW3 YW4 YW5 A131 A141 A151 A11 NN A12 NN
Appendix 5Control cabinet I/O terminals
p. 41
Appendix 6Electrical principle diagram
42