Aits 1718 PT II Jee Main Sol

1 AITS-PT-II-PCM-Sol -JEE(Main)/18
FIITJEE JEE(Main)-2018
ANSWERS, HINTS & SOLUTIONS
PART TEST II
(Main)
Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

1. C 31. B 61. A
ALL INDIA TEST SERIES
2. B 32. C 62. A
3. D 33. B 63. C
4. B 34. B 64. A
5. A 35. B 65. B
6. B 36. D 66. C
7. C 37. D 67. D
8. B 38. C 68. C
9. C 39. C 69. D
10. B 40. A 70. B
11. B 41. A 71. B
12. A 42. D 72. B
13. B 43. A 73. C
14. A 44. B 74. B
15. A 45. C 75. A
16. C 46. A 76. C
17. D 47. B 77. A
18. A 48. D 78. B
19. C 49. C 79. C
20. D 50. D 80. A
21. B 51. C 81. C
22. C 52. A 82. B
23. B 53. C 83. D
24. C 54. B 84. B
25. A 55. C 85. D
26. B 56. D 86. B
27. B 57. C 87. A
28. C 58. C 88. D
29. D 59. B 89. B
30. D 60. C 90. C
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AITS-PT-II-PCM-Sol-JEE(Main)/18 2
Physics PART I
5R
1. QAB = nCPT = 2 2T0 T0 5RT0
2
In the process BC, PT2 = constant
PP2V2 = constant
PV2 = constant
R 3R R
molar heat capacity, C = Cv
1 x 2 1 2
R
C
2
R
QBC = nCT = 2 (T0 2T0 ) RT0
2
QAB 5RT0
5
QBC RT0
2. In steady state 3T0 T T + dT T0

Q dT
kA
t dx
x dx
Q dT
TA
t dx
T0
Q
t
dx A
0
TdT
3T0
Q
4AT02 (i)
t
Similarly,
/2 T
Q
t dx A TdT
0 3T0
Q (9T02 T2 )
A (ii)
t 2 2
Dividing (ii) by (i)
9T02 T2 4T02
T2 5T02
T 5T0
3. Given PT3 = constant

T 3
T constant
V
V = kT4
The coefficient of thermal expansion is
dV 4kT 3 4

VdT kT 4 T
4. Equilibrium temperature of mixture is 0C.

Total heat released by water = m wSw = 5 1 40 = 200 kcal
Heat taken by ice to increase its temperature from 20C to 0C = 4 0.5 20 = 40 kcal
200 40 160
mass of ice melted = 2 kg
80 80
water content in the equilibrium mixture = 5 + 2 = 7 kg
5. Given
C = CV + T2
RT dV
CV CV T 2
V dT
T dV
dT nk

R V
T 2
n(kV)
2R
T 2
kV e 2R
T 2

2R
Ve = constant
6. The net electric potential due to external charge inside the cavity and the induced charge on the
surface of the cavity at any point outside the cavity is zero. If V is the electric potential due to
induced charge on the surface of cavity at point P.
kq
V 0
5a
kq
V
5a
dT
7. mS AT 4
dt
4 dT
R3 S 4R 2 T 4
3 dt
T0 /2 t
dT 3

T0
T 4

SR
0
dt
T /2
1 0 3
3 t
3T T0 SR
8 1 9t
3
3
T0 SR
T0
7SR
t
9T03

8. The electric field due to P1 at the position of P2 is
KP1
E1
r3
force of inter action between the dipoles is
dE1
F P2
dr
3kP1P2
F=
r4
dQ
9. dS
T
2T0
dT
dS nc P
T0
T
5R 25
S 4 n2 10Rn2 10 0.69
2 3
25 2.3 57.5 J/k
10. The electric flux through the right end plane surface.
q q 4
PS 2(1 cos ) 1
40 20 5
q
PS
100
Hence, the electric flux through the curved surface of the cylinder is
q
CS PS
20
q q 4q
=
20 100 100
2q
CS
50
k(2Q)2 kQ2 k(2Q)Q

11. Ui
2a 4a 2a
2kQ2 5kQ2

a 4a
13kQ2
Ui
4a
k(3Q)2 9kQ 2
Uf
4a 4a
Total heat dissipated, H = Ui Uf
13kQ2 9kQ2

4a 4a
4kQ2 kQ2

4a a
q q 40 q 120 q q q 40 40 q
12. 10
5 2 2 C1 = 5F C2 = 2F
6q
90 = 10 V
5 120 q q 120
q = 75 C
magnitude of charge flown through the battery C3 = 2F
is
q = 100 75 = 25 C
13. The electric potential of shell B is zero Q+q

q
VB = 0
q
kq kQ C
0 0
2a 4a B 0
Q A a
q
2
2a
4a
14. The cell will deliver maximum power to the network if Req = r
3R
r
2
2r 2
R =
3 3
15. The equivalent circuit just after 2 2

closing the switch S is
Req = 3 + 2 = 5
10
I0 2A 3
R eq 5
= 10V

16. Since the particle exists the magnetic field region with a velocity v (3i 3 3j) m/s
3 3
tan
3

3

The angular displacement of the particle in the magnetic field region is
3
qB
Angular velocity, =
m
m
t
3qB

17. Since B is constant in the region
The net magnetic force experienced by the conducting wire MN is

F I Leff B

Where, L eff 6Ri

F I 6Ri B(k)

F 6BIR( j)
18. The net magnetic moment of the loop is

M I2 (i k)

The net magnetic torque experienced by the loop is

MB
= I2 (i k)
Bj

BI2 (k i)
19. The net magnetic field at the centre O of the circular arc is
I 3 I I
B0 0 0 0
4 R 8R 8R
0I 3 0I

8R 8R
I 1 3
B0 = 0
8R
20. When r R 3
r j = r

B2r 0 j2rdr
0 r
B
5 B
r
Br 0
5 R
B
r 4
B 0 ,rR
5
when r > R
R

B2r 0 j2rdr
0
R
Br 0 r 3rdr

0
0 R5
Br
5
0 R5
B ,r>R
5r
R R 4
at r , B1 0
2 80
0 R 4
at r = 2R, B 2
10
B2
8
B1
21. The emf induced between the points A and D is

B ( eff v)
Ba 2v sin 45
v
= Ba 2 Bva 2Ba2
2
22. When r R
r B = krt
d
E2r
dt
B2rdr
0
r E
E
O R
d ktr 3
Er
dt 3 E
kr 2
E , when r R
3
When r > R
R
d
B2rdr
E2r
dt
0

R
d
Er krtrdr

dt
0
kR3
E , where r > R
3r
R kR 2
at r , E1
2 12
kR2
at r = 2R, E 2
6
E2
2
E1
q
23. Bv S M
C
q C( Bv )
dv B
Now, m Bi v
dt
mdv = Bidt
q +q m,
v q
m dv B dq
C N
0 0
mv = Bq
mv
q (ii)
B
From (i) and (ii)
mv
C CBv
B
CB
v
(m CB 2 2 )
d
24. E2r = (ktr 2 ) B = kt
dt
a E
kr
E ,rR E
2 O R
at r = a q, m
ka E
E
2
To keep the ring stationary
qEa = mga
qka
mg
2
kqa

2mg
kqa
min
2mg
25. When the current through the inductor is +C/2 C/2

maximum A
di C
VL L 0
dt imax
Hence capacitors A and B will be in parallel
Now, using conservation of energy +C/2 C/2
1 2 1 2 1 2
C 2 C Limax C B
2 2 4 2
2
C 1 2
Limax
4 2
C
imax
2L
di1 di
26. L1 L2 2
dt dt
i1 i2

L1 di1 L 2 di2
0 0
L1i1 L2i2 (i)
i1 i2 i (ii)
L
i1 1 1 i
L2
L2 L1
i1 i and i2 i
L1 L2 L1 L 2
1 2
L1i1
U1 L L2 L
2 1 22 2
U2 1 2 L2L1 L1
L i
2 22
27. Rms current through resistor R1 is

50 5
I1(rms) A
2 10 2 2
Average power developed in the resistor R1 is
2
2 5 250
P1 I1(rms)R1 10 62.50 W
2 4
28. Current through the potentiometer wire is

6
I
R5
63
V
(R 5)
18
2
R5
R+5=9
R=4
29. Let the initial charge on the spherical conductor A is Q.

kQ
V
a
kQ = Va (i)
When switch S is closed, the total charge Q will appear on the outer surface of shell B.
Final potential of the spherical conductor A is
kQ Va V
V
6a 6a 6
30. Given process is

VT2 = constant
VP2V2 = constant
PV3/2 = constant
molar heat capacity
R 5R R
C CV
1 x 2 3
1
2
C = R/2
Heat supplied to the gas is
R
Q = nCT = 2 300 300 R
2
Increase in internal energy of the gas is
5R
U = nCVT = 2 300 1500R
2
U 1500R
The ratio 5
Q 300R
Chemistry PART II
31.

N CH2 N CH2 N CH2
N CH2 N CH2
32. The carboxylic acid group stabilizes the conjugate base and I of other groups at closest
distance.
34. Total chiral centres = 3

2n = 23 = 8
O
35. In B all alkyl groups are at equatorial positions so most stable.

Most stable will have least heat of combustion.
37. Glyptal is made from polymerization of ethylene glycol and pthalic acid.
38.
Br

NH MeI +

excess
N Me
CH2 Me
CH2
H2 N CH2
Moist Ag2 O

CH2NMe 2
39. Cl
H

Cl

42.
O OCH3 O D O D HO D
D D
D H
D

44. OCH3 O
AlCl 3
OCH3
OH
O
O
46. H

H
O O
OH OH OH
47. Cl
Cl
Cl
2

h

1 1
Cl
x 10
2 GI 2 GI
4 OI Cl
4 OI
Cl
Cl
Cl2

h
1 1
Cl
y4
1 Cl
1
48. CHO
ONa O O
H3C C O C CH3
CHO O O
O C O C CH3

CH3
CHO CHO
O O
O O
O C CH3 O C CH2
CH3 COO Na H2O

50.
MeOH

O O O O OH O
MeO
Re d P
Br2
Br
H2 N
NH3

COOH
O
O ONH4 O
MeO
H 2N
H3 O
HOOC COOH
NH2
51. Br
MgBr
Mg

Elimination
Br
Br
52. Cl
Alc. AgNO
3 AgCl

HO
Cl Cl
NaOH

Cl
COOH
Oxidation

Cl
53. COOH
CH2 OH
H OH
O H
H Br
HO H
H 2
H O
2
H OH
OH H
OH
OH H OH
CH2OH
H OH
55. + +
Cl Cl Cl Cl Cl Cl
C C C C C C
H H H H H H
In cis form attraction between both chlorine leads to stability.
56. H
Tollen's reagent
H 3C C C CH white ppt.
H2 C CH3
H O HO
O3 /H2O2 LAH

CO2
Me C C OH
Et

H /

57. (ii), (vi) will not give Cannizzaro test.
58. Rate of reaction depends upon migration aptitude.
60. Intermolecular aldol reaction.
Mathematics PART III
p p
61. tan
1 q q 1
1
1 tan 2

tan 2
p tan q
1 p2 p2
= q
p2 q 12 q 1
1
q 12
1
=
2
p q 1
2 p 2
p2 q 1 q q 1
2
q
62. f(x) = (x 1)(x cos )(x sin )
2 + 2 + 2 = 1 + sin2 + cos2 = 2
63. x 2 1 (x + 1)2 = 2
x4 + 3x3 3x2 9x + 6 = (x2 + x 4)(x2 + 2x 1) + 2 = 2
64. x = r cos , y = r sin

r2 sin cos r2(cos2 sin2 ) = r2
4
r2 4 cosec 4 4
sin 4

65. sec 2 cosec 2 sec 2 cosec 2
8 8 8 8
a = b a + b = 0
2ab C C
66. x cos
ab 2 a
1 1 1 b
ra rb ab sinC
2 2 2
1 C C r r
2 ab sinC 2ab sin cos A B
r 2 2 2 x sin C I
ab ab 2
2 abc
r r
ab 4R2 sin A sinB
1
67. cos x = 0 or sin x 0
x
1
x or x n infinite solution
2 x
68. f x
cosec x 1 2
=
cot x 4
0 ; x R n, n I
cosec x 1 1 cot x cot x 1 cot x
2 2
3 5 199
x 2n 1 , , , .....,
2 2 2 2 2

Sum = 1 3 5 ..... 199 5000
2
69. p = 1, a2 = 4 b = 4 A
p = 2, a3 = 4 c = 4
is isosceles
15 4 4
15
r1 , r2 15 r3
sa 3 sb
B C
r2 = r3 = 3r1 2

70.

tan1 2
4
tan 1

1
tan 1 1 = tan1 r 1 tan1 r 1
4r 3 r 2 3 1 1 2 2
4 1 r 2 r 2

n
4 1 1
tan1 4r 2 3 tan1 n 2 tan1 2
r 1

4
tan1 4r 2 3 tan1 2
r 1
1 1 A
71. A 2x cos x sin x2 sin2
2 2
x2
Max A x x
2

B C
3
72. Lines intersect at 3, which is centre of required circle. Given circle x2 + y2 4x 3y = 0
2
3 5
whose centre is 2, , r
2 2
For just sufficient circle d = |r1 r2|
5 15 9 225
r 5 r 9 k k = 45
2 2 4 4
a2 a2 d12
73. If acute angle = cos
2a2

2a2 d12 2a2 cos d1 2a2 2a2 cos 2acos
2

Similarly, d2 2a2 1 cos 2a sin and d1d2 = a2
2
1
4 sin cos 1 sin
2 2 2
2
74. Let log 3
tan x t t 3 1 , t < 0
t
2 1
t 2 3 1 3t2 + 2t 1 = 0 t 1,
t 3
1
log 3 tan x 1 tan x x
3 6
sin B C
2R sin A a
75. tanB tanC
cosB cos C 2R cosB cos C 2RcosB cos C
2R cos B cos C = k
Locus of orthocentre is a line parallel to BC
1 3
76. 2 a = SP = a 2a = 3
2 2
77. (1, 1) lies on y + x = 0. Hence only one rational point
2
78. x2 y 2 2y 1 x 2 y 1 = distance between (x, y) and (0, 1)
x 2y 3
The distance from (x, y) to x 2y + 3 = 0 is
5
2 x 2y 3 5
x 2 y 1
5
5 5
e for hyperbola 1

<5
ab
79. a b a2 b2
2
4 a 2
b for a = 5, a = 6, b = 8
a4
1
ab 24
2
1 A
80. BD2 = 22 + 52 225 B
2 2
1
= 32 + x2 23x 5 x
2
19 = x2 + 3x + 9 3
x2 + 3x 10 = 0 C
D
x=2
1 2 2cos sin
81. 4 2
2 5 2
PA 10 2 2
82. AB is a diameter
PB 10 2 2
83. 2b tan a2 sec 2 b2 tan2

1
e2 1
3
PA PB
84. PA PB
2
PA + PB 2PT
y y
85. a x c 1 0
2 2
= 1, = 2 and 4( + ) = 2 + 2 1
=8
++=7
x
86. Equation of tangent is cos y sin 1
3 3
3 3 1
S . It is minimum at
cos sin 6
1
87.
Orthocentre (h, k) = 2a a t12 t 22 t1t 2 , at1t 2 t1 t 2 where t 2 t1
k = a(t1 + t2)
k2
2
h 2a a t1 t 2 t1t 2 2a a 2 1
a

ah = 3a2 + k2
88. Sides of squares will be perpendicular tangents to the ellipse. So vertices of square will lie on
diameter circle
Diameter of circle = 2 a2 3 a 4 2a2 2a2
a2 + a + 1 = a2
a = 1
But a2 > 3 and a > 4
a

89. C , A = 15, B = 75
2
1 1 1 1 1 5
90. 2
2
2
2
1
OA OB a b 4 4

Aits 1718 PT II Jee Main Sol

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1 AITS-PT-II-PCM-Sol -JEE(Main)/18

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

2. In steady state 3T0 T T + dT T0

3. Given PT3 = constant

4. Equilibrium temperature of mixture is 0C.

k(2Q)2 kQ2 k(2Q)Q

13. The electric potential of shell B is zero Q+q

15. The equivalent circuit just after 2 2

21. The emf induced between the points A and D is

25. When the current through the inductor is +C/2 C/2

27. Rms current through resistor R1 is

28. Current through the potentiometer wire is

29. Let the initial charge on the spherical conductor A is Q.

30. Given process is

N CH2 N CH2 N CH2

34. Total chiral centres = 3

35. In B all alkyl groups are at equatorial positions so most stable.

57. (ii), (vi) will not give Cannizzaro test.

58. Rate of reaction depends upon migration aptitude.

60. Intermolecular aldol reaction.

Mathematics PART III

64. x = r cos , y = r sin

77. (1, 1) lies on y + x = 0. Hence only one rational point

83. 2b tan a2 sec 2 b2 tan2

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