R10

1st Year Chemistry Ch. # 11

21-03-2016 40 1 hour
Q.No.1. Choose the correct option. 1x12=12
(i) The specific rate constant of a first order reaction depends on the
(A)concentration of the reactant (B)concentration of the product
(C)time (D)temperature
(ii) When there are changes in refractive indices of the substance taking part in the chemical reactions
then the method is called as____method.
(A)optical rotation (B)reflection (C)refractrometric (D) Dilatometric
(iii) The reaction takes place among the molecules when they have
(A)energy equal to activation energy (B)concentrated (C)properly oriented (D)both A and C
(iv) In method of large excess one reactant should be ____ at one time and other reaction change at the same time
(A)increases (B)decreases (C)constant (D)all
(v) CaCO3 reacts with H2SO4 more effective when it will take in _____ form.
(A)powder (B)big pieces (C)bulk (D)Chips
(vi) Hydrogenation of vegetable oil is accelerated by nickel, the catalytic activity of Nickel can be increased by using
(A)Magnesium (B)Thallium (C)Copper (D)ferric
235
(vii) The Radio active disintegration of 92U is _____ order
(A)Zero (B)first (C)second (D)third
(viii) In zero order reaction, the rate is independent of
(A)temperature of reaction (B)concentration of reactants
(C)concentration of products (D)none of these
(ix) If the rate equation of a reaction 2A +B  products is, rate= K[A[2 [B], and A is present in large
excess, then order of reaction is
(A)1 (B)2 (C)3 (D)3.5
(x) The rate of reaction
(A)increases as the reaction proceeds. (B)decreases as the reaction proceeds.
(C)remains the same as the reaction proceeds. (D)may decrease or increase as the reaction proceeds.
(xi) With increase of 10ºC temperature the rate of reaction doubles. This increase in rate of reaction is due to:
(A)decrease in activation energy of reaction (B)decrease in the number of collisions between reactant molecules
(C)increase in activation energy of reactants. (D)increase in number of effective collisions.
(xii) The unit of the rate constant is the same as that of the rate of reaction in
(A)first order reaction. (B)second order reaction
(C)zero order reaction (D)third order reaction

Q.No.2.Answer the short questions. 𝟏𝟎 × 𝟐=20

i. Differentiate between enthalpy change and activation energy of reaction.
ii. Rate of chemical reaction is an ever changing parameter under the given conditions.
iii. The unit of rate constant of a second order reaction is dm3 mol-1S-1, but the unit of rate of reaction is mol dm-3S-1 . Justify
iv. Define activation of catalyst.
v. A catalyst is highly specific it it’s action justify.
vi. A finally divided catalyst is more effective give examples.
vii. What is method of large excess.
viii. Define order of reaction. Give example of fraction order.
ix. What is meant by energy of activation
x. What is instantaneous and average rate of reaction?

Q.No.3. Extensive questions.

i. How Arhenius equation is helpfull in determining energy of activation of reaction. 4
ii. Write a note on half life method for determining order of reaction. 4