Professional Documents
Culture Documents
Upcoming Events This newsletter emphasizes materials and chemistry R&D activities and expert
services offered by the following EPRI programs:
Staff Experts
Boiler Life and Availability Improvement (63)
Boiler and Turbine Steam and Cycle Chemistry (64)
Fossil Materials and Repair (87)
HRSG Dependability (88)
Our work is also applicable to the Steam Turbines, Generators, and Balance-of-Plant Program (65), the
Combustion Turbine and Combined-Cycle O&M Program (79), and additional EPRI fossil and nuclear programs.
On a daily basis, our guidelines, methods, and technologies are being applied to improve operations and
maintenance decisions at thousands of generating plants. At locations around the world, EPRI-funded
researchers are working to resolve today’s materials and chemistry problems and to develop new knowledge and
technologies required for clean and efficient power generation in the carbon-constrained future.
Periodically, we’ll send you this newsletter to keep you updated on crosscutting projects, demonstration
programs, and expert services. Each newsletter will feature one or two major chemistry and materials challenges
to give you a sense of how we are stitching discrete R&D activities together to deliver comprehensive and timely
solutions for critical operations, maintenance, and planning issues.
Barry Dooley
704.595.2199
bdooley@epri.com
To resolve materials and chemistry issues in conventional boilers and HRSGs, EPRI R&D addresses three key
areas:
Previous EPRI work has improved basic understanding and filled many critical knowledge and capability gaps,
leading to the creation of industry-standard reference manuals on topics such as boiler tube failure (BTF), header
and drum damage, and condenser tube failure. EPRI’s ongoing efforts focus on helping plant personnel apply
new science and technology to address fleet-wide and unit-specific operations, maintenance, inspection, life
assessment, repair, and fuel procurement tasks.
Mechanistic Priorities
Battling fatigue in a major focal point for EPRI’s
crosscutting fossil materials and chemistry programs
because corrosion fatigue represents the primary
BTF mechanism in subcritical boilers, thermal
fatigue has become a leading BTF mode in
supercritical units, and drum cracking is emerging as
a significant threat. More than 20 EPRI products
released in 2005-06, as well as a number of
continuing and new projects, are relevant to near-
term management and longer-term resolution of
fatigue damage.
This
Section: Corrosion Fatigue
Corrosion Current EPRI guidance for managing corrosion fatigue damage in subcritical boilers is based
Fatigue largely on work conducted more than a decade ago, in particular an extensive study of boiler
strain, temperature, and chemistry conditions during typical startup and shutdown cycles at the
Thermal Hazelwood Power Station in Australia (TR-105261; TR-106697; TR-100455, V5). As corrosion
Fatigue fatigue problems have continued and stresses attributable to unit cycling have intensified, the need
for updated guidance based on a new application of this monitoring approach has become
increasingly evident.
Drum
Cracking
In early 2005, a comprehensive 2-year investigation of the factors influencing waterwall tube
corrosion fatigue began at Big Sandy Unit 1, a 260-MW coal-fired boiler that entered into
Fatigue
commercial operation in 1963. In addition to American Electric Power (AEP), the plant’s owner,
Management
other major funders of the project include Dynegy, PacifiCorp, Detroit Edison, Tennessee Valley
Authority, Transalta (Canada), Western Power (Australia), Stanwell (Australia), Tarong (Australia),
Contacts & and ESB (Ireland).
Resources
The project is designed to achieve two technical goals—first, to unravel the connections between operating
parameters and the initiation and propagation of corrosion fatigue from the waterside surface; and second, to
develop a more reliable, two-stage NDE approach for detecting damaged areas and determining the length and
depth of cracking. Prior to project initiation, AEP staff had performed extensive video-probe analysis at Big Sandy
to identify where corrosion fatigue cracks are located and their likely orientation. To identify high-priority locations
for more detailed NDE, the EPRI project team supplemented this work with digital radiography analysis, a review
of industry experience and EPRI guidance, and an assessment of the unit’s inspection, failure, and repair history.
During 2006,
intensive data
evaluation is
planned to
accomplish the
following:
Develop
correlation
s between
strain/temp
erature
conditions,
cycle
chemistry
conditions,
and crack
initiation
and
propagatio
n
Determine
the relative
amounts of
damage
produced
by each
type of
operating
transient
Recomme
nd and test
approache
s for
preventing
or
minimizing
corrosion
fatigue
damage,
such as
“allowable
operating
limits”
during
transient
modes of
operation,
design
retrofits,
etc.
Based on this
comprehensive
study, EPRI plans
to issue updated
practical guidance
in early 2007 to
assist plant
personnel in
implementing
comprehensive
programs for
assessing and
monitoring
damage, avoiding
the most harmful
operating
conditions, and
otherwise
managing the risks
posed by corrosion
fatigue cracking.
Thermal Fatigue
To resolve thermal
fatigue cracking in
supercritical
boilers, planning is
under way for a
similarly exhaustive
assessment of the
connections
between real-world
operating
parameters,
materials stresses,
and damage
initiation and
propagation.
Means for
identifying unit-
specific root
causes of
circumferential
cracking and
growth must first
be identified before
effective remedial
measures can be
developed.
Thermal fatigue
cracking originating
from the fireside
surface is not
specific to boilers
with low-NOx
systems or
waterwalls with
extensive weld
overlays, but these
conditions can
increase maximum
tube temperatures.
Severe thermal
transients, such as
those associated
with slag removal,
account for the
fatigue component
of this damage
mechanism; an
ongoing EPRI
project focuses on
improving
understanding of
the effects of water
lances and
cannons on fatigue
(1010493).
Notwithstanding the ongoing corrosion fatigue project at Big Sandy Unit 1, recent operational information on
waterwall temperatures and thermal transients is relatively scarce. An EPRI project during the early 1990s
conducted extensive measurements of stress, strain, temperature, and heat fluxes in a supercritical boiler (TR-
104442). Maximum tube surface temperatures of up to 1000°F (540°C) were recorded, as were sudden spikes of
more than 200°F (90°C) attributable to slag shedding or removal. Even higher temperatures are routinely
experienced in locations where weld overlays have been applied.
Prior to the introduction of oxygenated treatment (OT), inadequate control of feedwater chemistry was a main
driver of thermal fatigue failures: Ripple magnetite deposits forming on internal tube surfaces alter flow
characteristics, increasing pressure drops and wall temperatures. Facilities that have adopted OT have largely
eliminated this problem, but some of these units are experiencing growth of a different type of oxide, in areas with
and without overlays, with similar effects. This oxide has even been observed in a relatively new supercritical
boiler.
In addition to weld overlays, oxide growth, and natural or forced deslagging, other factors that may contribute to
elevated waterwall temperatures and transient events include flame impingement, initial firing with oil burners,
startup/shutdown cycles, and additional operational factors acting on both fire- and water-side surfaces. Also to
be considered are the thermodynamic features of supercritical fluids, including specific heat, thermal conductivity,
enthalpy, viscosity, and density, which can change dramatically in response to even small changes in temperature
or other factors.
To support root-cause analysis of unit-
specific thermal fatigue problems, EPRI
plans to install thermocouples, strain
gauges, heat-flux meters, and acoustic
emission sensors at two locations in an
operating boiler, as was done in the early-
1990s study. The instrumentation will be
installed on tubes/panels, which will then
be placed into service in locations
susceptible to thermal fatigue. Also to be
employed is a new electrical resistance
probe array capable of assessing and
mapping key parameters— including tube
temperature, heat flux, and possibly crack
growth—over the entire waterwall.
Drum Cracking
The durability of steam drums, relative to other boiler components, cannot be attributed to stable, low-stress
operations: They operate in a very dynamic mode, especially during major transients. Aging, combined with cyclic
duty, is beginning to take its toll—the incidence of cracking is increasing for units 30 years and older. Grinding
and localized weld repair can address initial cracking problems, but extensive drum cracking poses a threat to the
structural integrity and continued safe and reliable operation of the unit.
In an initial effort to isolate the mechanisms for cracking of drum nozzles, EPRI reviewed industry experience and
conducted simple stress and fracture analyses. This work, begun in 2003, identified thermal fatigue as a plausible
cause but highlighted the need for detailed FEA, and fracture mechanics analysis of data from operating units
(1008039; 1008070). In 2004-2005, studies were launched on (1) a 275-MW Combustion Engineering (CE)
controlled circulation unit that began commercial operation in the 1959 and (2) a 215-MW Babcock & Wilcox
(B&W) natural circulation unit that began commercial operation in 1954.
Results indicate that pressure stresses and the environmental influence of corrosion fatigue play the dominant
role in drum cracking for both types of boilers. The B&W natural circulation drum had longer fatigue life for normal
startup/shutdown and was more tolerant of larger cracks (1013268), but its ligamented downcomer region was
less tolerant of thermal downshocks associated with bypassing feedwater heaters or topping off a partially full
drum than the larger nozzles in the CE controlled circulation unit. For the latter, the feedwater inlet nozzle and the
downcomer nozzle represent the life-limiting structural components for thermal fatigue (1011916).
Where cracking in boiler drum ligaments and nozzles is detected or suspected, EPRI’s improved crack growth
analysis capabilities will help plant personnel justify continued service with known flaws in place. The planned
2007 update of Header and Drum Damage: Theory and Practice (1004313) will offer detailed guidance for
damage mitigation and prevention.
Fatigue Management
Existing EPRI manuals provide step-by-step, industry-standard guidance for NDE, condition assessment,
monitoring, repair, and prevention of corrosion fatigue and thermal fatigue in boiler components (see partial list
below) and HRSG components (1010440). In addition, new products, techniques, technologies, and tools are
continuously being developed and demonstrated to enhance the decision-making capabilities of plant
management personnel. Readers are encouraged to visit www.epri.com for the latest information.
Lead Contacts
Key Resources
Corrosion Fatigue of Water-Touched Pressure Retaining Components in Power Plants (TR-106696, 1997)
Corrosion Fatigue Boiler Tube Failures in Waterwalls and Economizers (TR-100455, V1-5, 1992)
Circumferential Cracking on the Waterwalls of Supercritical Boilers: Volumes 1 and 2 (TR-104442, V1-2, 1995)
Thermal Fatigue of Fossil Boiler Drum Nozzles (1008039, 2004; 1008070, 2005)
Investigation of Cracking in Fossil Drums: Finite-Element and Fracture Mechanics Analyses (1011916, 2005)
Header and Drum Damage: Theory and Practice (1004313, V1-2, 2003)
Evaluation of Thermal-, Creep-, and Corrosion-Fatigue of Heat-Recovery Steam Generators (1010440, 2006).
Since the catastrophic failure at the Pleasant Prairie Plant in 1995, which also caused worker fatalities, FAC
mitigation has been a higher priority at conventional plants. At combined-cycle facilities, by contrast, FAC became
a point of emphasis almost immediately, as it was quickly identified as a leading cause of tube failures in heat-
recovery steam generators (HRSGs).
EPRI’s initial guidelines for controlling FAC in conventional fossil units were issued in November 1997. Relying
largely state-of-the-art knowledge of boiler tube failure (BTF) mechanisms (TR-105261) and on mechanistic
studies performed to address FAC in nuclear plants, these guidelines outlined a comprehensive approach for
managing cycle chemistry to reduce the long-term susceptibility of feedwater piping and tubing and for conducting
inspections to prevent failures of already damaged components. For HRSGs, the tube failure manual published in
2002 offered insight for diagnosing and remediating FAC issues (1004503).
Comprehensive FAC management guidelines, published in 2005, reflect knowledge and extensive industry
experience gained in the intervening years (1008082). They provide mechanistic information and specify a two-
pronged approach for cost-effective FAC control.
Basic Carbon steel piping, tubing, and vessels subject to water (single-phase) or wet steam (two-
Mechanisms phase) flows are susceptible to FAC. It occurs when the normally protective oxide layer
dissolves, leaving the base metal either more susceptible to attack or, in the worst case, fully
Comprehensive exposed. The corrosion process can be very rapid: Wall thinning rates as high as 3 mm/yr have
Solutions been observed. The actual rate of metal loss depends on many parameters.
Beneficial Two types of oxides can form on carbon steel materials: Magnetite (Fe3O4) forms in reducing
Applications environments, while ferric oxide hydrate (FeOOH) forms under oxidizing conditions. Under
typical situations, the normal and expected general corrosion results in the formation of a
Contacts & protective layer, and oxide growth and dissolution processes remain approximately in balance.
Resources FAC occurs when the rate of dissolution into the single-phase flow or the aqueous fraction of the
two-phase flow is greater than the rate of growth, and it can be aggravated when fluid conditions
cause exfoliation of the oxide layer.
The new guidelines outline similar roadmaps for FAC control in conventional and combined-cycle plants that have
already entered into service. The HRSG roadmap also incorporates recommendations for proactive FAC
management during the specification, design, and commissioning of new units.
For operating units, inspection programs serve two main functions: to establish a baseline for existing FAC
damage, if any, and to optimize long-term management of problems that cannot be eliminated. Cycle chemistry
programs are aimed at addressing root causes to halt existing corrosion processes and preventing further
damage. The shared first step is to identify and prioritize susceptible systems and components by gathering
information on plant design and materials and on operating, cycle chemistry, and maintenance experience. Key
inputs include inspection results, failure histories, and compliance with the EPRI-recommended limit for feedwater
corrosion product concentration at the economizer inlet for different metallurgies under the AVT(R), AVT(O), or
OT chemistries.
Follow-on inspection and cycle chemistry tasks occur in parallel. On the chemistry track, the immediate priority is
to monitor, adjust, and optimize unit chemistry to meet EPRI guidelines. On the inspection track, initial analysis
involves modeling to predict FAC rates and nondestructive evaluation to determine wall thinning and related
damage. (EPRI’s CHECUPTM/CHECWORKSTM codes and other commercial tools support predictive modeling for
conventional units; no predictive or analytical tools are currently available for HRSGs.) Materials sampling is then
required to confirm whether the observed indications are attributable to FAC, whether damage is progressing, and
whether immediate repair/replacement measures are required.
Once these initial, unit-specific FAC control measures have been implemented, EPRI’s recommended approach
requires cycle chemistry optimization, inspection, and analysis activities to continue on a long-term basis. Safe,
long-term unit operation can only be assured through consistent attention to areas susceptible to FAC attack and
to chemistry conditions.
Beneficial Applications
The new EPRI guidelines offer detailed, step-by-step guidance for implementing FAC control programs,
identifying and inspecting susceptible areas, remediating problems that demand immediate attention, optimizing
feedwater chemistry, maintaining vigilance, and benchmarking performance against industry standards. When
used in conjunction with other EPRI tools, these guidelines provide the industry with a comprehensive approach
for increasing worker safety while reducing availability losses and improving bottom-line performance for
conventional fossil plants and combined-cycle facilities.
Lead Contacts
Key Resources
Guidelines for Controlling Flow-Accelerated Corrosion in Fossil and Combined Cycle Plants (1008082, 2005)
Project Updates
This collaborative project, scheduled for EPRI-directed work has demonstrated the advanced materials,
completion in 2006, has created a solid fabrication, and welding technologies required to support
foundation for ongoing USC plant design commercial development of coal-fired boilers capable of
studies supported by EPRI’s CoalFleet ultrasupercritical operations.
Initiative. Initial work to develop materials
technology for steam turbines in USC plants
is also under way.
Boiler Tube Failures: Theory and Practice (TR-105261), the first in the series and one of EPRI’s most popular
products since its publication in 1996, is currently undergoing a comprehensive revision. When completed in early
2007, the new book will provide updated guidance for minimizing O&M costs and availability losses attributable to
boiler tube failure (BTF) in conventional fossil steam-electric plants, combined-cycle units, and other types of
boilers. BTF mechanisms that have gained prominence in recent years, such as those relating to low-NOx
operation, will be covered, as will recent advances in cycle chemistry, nondestructive evaluation, inspection,
condition assessment, tube materials, and repair technology. The new manual also will incorporate the latest
information for tube failure mitigation in heat-recovery steam generators, updating the current EPRI manual
(1004503) on this topic. (Contact: Barry Dooley, bdooley@epri.com, 704.595.2199)
Header and Drum Damage: Theory and Practice (1004313), first published in 2003, provides a definitive
reference for understanding, addressing, and preventing damage caused by known mechanisms and for
implementing long-term strategies to optimize the lifetime of aging components. Work on updated version is
scheduled to begin next year, reflecting industry experience as well as new knowledge gained through ongoing
research on drum cracking and other topics. (Contact: Rich Tilley, rtilley@epri.com, 704.595.2097)
Full-Time, Real-Time, and Lifetime Cycle Chemistry Control for Combined-Cycle Units
Three new EPRI products provide operators and chemists with comprehensive assistance for controlling cycle
chemistry over all timescales and operating regimes relevant to maximizing the productivity of combined-cycle
(CC) generating assets.
Cycle chemistry problems in CC plants influence about 70% of heat-recovery steam generator (HRSG) tube
failures (HTF). In many instances, HRSGs have been commissioned with non-optimum chemistries, which results
in HTF early in life and at accelerated rates over time. EPRI’s new guidelines and real-time monitoring software
represent tools for optimizing unit chemistry upon commissioning and continuously thereafter.
Cycle chemistry
optimization in CC
units requires
more than proper
selection and
optimization of
operating
chemistry,
particularly for
plants subjected to
peaking service.
EPRI’s Cycle
Chemistry
Guidelines for
Shutdown, Layup,
and Startup
(1010437) identify
the keys to
protecting the
water- and steam-
touched
components of
today’s assets in a
manner consistent
with operating
chemistries and
shutdown
requirements. This
report includes a
guidance roadmap
that allows users
to assess and
apply four types of
protection. For
short-term
shutdowns,
keeping the
system hot and
maintaining
condenser vacuum
eliminates the
need to change
water chemistry
while these
conditions can be
maintained. For
longer shutdowns,
options include dry
protection with
warm,
dehumidified air,
dry protection with
nitrogen, and wet
protection with a
nitrogen cap.
CC ChemExpert, Version 1.0 (1010439) incorporates EPRI’s latest guidance within a real-time cycle chemistry
monitoring tool. This new software, tested successfully at a number of facilities, may be applied to trend and
analyze data and make adjustments to normal chemistry conditions. It also may be used to generate alarms for
out-of-limit conditions and to deliver expert advice in the form of messages and corrective operating procedures.
Technology Innovation
Materials and Chemistry: Each year, a small percentage of EPRI’s overall collaborative R&D funding is set
Investing in Innovation aside to support the Program on Technology Innovation (TI), which conducts basic
work in crosscutting disciplines and sponsors proof-of-concept studies to explore
Oxide Growth and whether novel ideas merit further development.
Exfoliation: Controlling
Shedding
In the fossil plant materials and chemistry arena, more than 2 decades
of previous strategic R&D investments by EPRI have yielded major
returns: The value delivered by today’s programs and products
addressing cycle chemistry control, boiler tube failure mitigation,
condition assessment, component repair, and other critical issues
rests largely on previous work supported by the TI program and its
precursors (Strategic Science & Technology; Office of Exploratory and
Applied Research). Ongoing materials and chemistry projects
supported by TI address a wide variety of topics.
Findings from this work are available to all EPRI members. Information
on recent, continuing, and new TI-funded projects is available on
www.epri.com.
Featured Products
Metallurgical Guidebook for Fossil Power Plant Boilers (1011912)
The Metallurgical Guidebook compiles essential information on basic steel metallurgy culled from design codes,
industry experience, and previous EPRI reports. It reviews the fundamental concepts of materials selection and
incorporates separate subsections devoted to carbon steels, chromium-molybdenum steels, austenitic steels, and
advanced ferritic steels. It represents a single-source reference to support design, materials selection, and
run/repair/replace decision-making for boiler tubing, drums and headers, piping, and other components.
The Grade 22 Handbook represents the first in a complementary series of alloy-specific references for use in day-
to-day operations to improve the performance, reliability, and ultimately the profitability of fossil power plants.
Available in pocket-sized format, it focuses on several key areas, including standards and codes, metallurgy,
mechanical properties (new and service-exposed), and fabrication and welding issues. Handbooks planned for
publication in 2006 will address carbon steels and stainless steels.
Advanced strain gage technology is needed to better understand, monitor, and manage real-time and long-term
strains and stresses in high-temperature fossil plant components. EPRI recently completed a review of the state
of the art in this area, and it has subjected new strain gage designs to controlled mechanical testing at 1000°F,
(540°C), to assess their accuracy and drift. In addition, monitoring devices have been installed in an operating
plant to assess bending and fatigue stresses in a repaired main steam line girth weld. This report presents
findings from initial work aimed at the development of high-temperature strain gages capable of supplying data to
inform operations, maintenance, and design decision-making for boiler and HRSG systems.
Evaluation of Filler Materials for Transition Weld Joints Between Grade 91 and Grade 22 Components
(1009758)
Advanced alloys undergo extensive testing before being qualified for use in power plants, but welding and repair
capabilities typically lag behind field applications of these materials. To date, weldments between Grade 22 (2-
1/4Cr-1Mo) and Grade 91 (9Cr1MoV) alloys have exhibited unsatisfactory performance. This report presents
findings from successful research to determine the optimum filler metal, welding procedure, and joint design for
Grade 22-Grade 91 transition welds.
Deposits of corrosion products on heat transfer surfaces can reduce efficiency and increase heat rates, as well as
trigger a variety of damage mechanisms. EPRI’s cycle chemistry guidelines are effective in minimizing deposition,
but they do so indirectly by reducing impurity ingress and corrosion product transport to acceptable levels. This
report presents the latest findings from continuing experimental and theoretical research aimed at advancing the
science of deposition and creating a first-principles model.
Complementing deposition rig studies conducted under all-volatile and oxygenated chemistries, the recent work
evaluated deposition rates as a function of heat flux and iron and copper oxide concentrations in a reducing
environment. Previous work includes a review of the Russian and Soviet literature (1004193) and of the state of
knowledge in critical areas (1004194; 1004930). Together, these efforts will support an updating of EPRI’s
guidelines to enable more precise control of the water-steam cycle parameters that influence corrosion, transport,
and boiler deposition processes.
Recent Deliverables
Listed below are materials and chemistry products completed from January 1 – May 31, 2006.
Upcoming Events
Listed below are a few events scheduled for upcoming months. Visit “Events” for registration and technical information on
conferences, workshops, classes, teleconferences, and advisory meetings sponsored by EPRI’s materials and chemistry
programs.
Listed below are EPRI staff members, main program affiliations, contact information, and areas of
expertise: