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Physics Department
8.044 Statistical Physics I Spring Term 2013
Final Exam, Solutions
a) Find the number of different ways of choosing the n α-sites to be vacated and occupied
by β atoms.
N!
#α =
n!(N − n)!
b) Find the number of different ways of choosing the n β-sites from which to take the β
atoms.
N!
#β =
n!(N − n)!
d) Find U (T, N ).
1 ∂S ∂S ∂n 2kB
= = = [−1 − ln n + 1 + ln(N − n)]
T ∂U N ∂n N ∂U N
| {z }
1/
n n
= − ln → = e−/2kB T
2kB T N −n N −n
1
Problem 2 (20 points) DNA Model
b) When kT one need consider only the lowest two energy states; this becomes an
energy gap dominated situation.
N
X e−n/kB T
hni = n
n=0
Z
≈ e−/kB T
d) In a similar manner
N
X e−n/kB T
hni = n
n=0
Z
N N
X n −n/kB T kB T X n −n/kB T
= e = e
n=0
kB T n=0
kB T kB T
kB T ∞ x
Z
≈ xe dx
0
| {z }
1
kB T
≈
2
Problem 3 (20 points) Spin Waves
a)
~ = Lx Ly Lz = V
D(k)
2π 2π 2π (2π)3
b)
~
#(ω) = (volume of sphere in k-space) × D(k)
D(ε)
4 3 V
= πk (ω) 3
use k = (ω/a)1/2
3 (2π)
V ω 3/2
=
6π 2 a
d#(ω) V
D(ω) = = 2
a−3/2 ω 1/2 0 ε
dω (2π)
c) Z ∞
U = h(ω)i D(ω) dω
0
Z ∞
V −3/2 ~ω
= 2
a ω 1/2 dω + Z.P. contribution
(2π) (e ~ω/kB T − 1)
0
3/2 Z ∞ 3/2
V 1 5/2 x
= (kB T ) dx + Z.P. contribution
(2π)2 ~a 0 ex − 1
| {z }
≡ I
3/2
∂U 5 kB T
CV (T, V ) = = 2 kB V I
∂T V 8π ~a
d) There is no energy gap behavior (CV ∝ T n e−∆/kB T ) because of the integration over a
continuous distribution of gaps (∆ = ~ω), some of which are less than kB T for any physical
T.
3
Problem 4 (20 points) Graphene
a)
~ = Lx Ly = A
D(k)
2π 2π (2π)2
b)
~
#() = 2 × (area of disk in k-space) × D(k)
A
= 2 × πk 2 () 2
use k =
(2π) ~v
2
A 1
= 2
2π ~v
2
d#() A 1
Dc () = =
d π ~v
c)
D(ε)
0 ε
d)
µ(T = 0) rests at the last filled state at T = 0 which is at the top of the valence band, so
µ(T = 0) = 0 .
4
e) Z ∞
U = hn(, T )i D() d
−∞
Z ∞
= 2 hn(, T )i Dc () d
0
2 Z ∞
A 1 1
= 2 d
π ~v 0 (e/kB T + 1)
2 ∞
x2
Z
A 1 3
= (kB T ) dx
π ~v (ex + 1)
|0 {z }
≡ I
2
A 1
= (kB T )3 I
π ~v
f)
5
Problem 5 (20 points) BEC
a)
Z ∞
N = < n > D() d
0
" 3/2 #
Z ∞
√
1 V 2m
= d
0 e(−µ)/kB T − 1 (2π)2 ~2
3/2 Z ∞ √
V 2m
= d
4π 2 ~2 e(−µ)/kB T − 1
0
3/2 Z ∞ √
V 2mkB T x
= −
dx
4π 2 ~2
0 e (x y) −1
| {z }
≡ I(y)
3/2
V 2mkB T
n = I(y)
4π 2 ~2
b) Bose-Einstein condensation begins when the above condition is satisfied with µ = 0 which
also means our dimensionless parameter y = 0.
3/2
V 2mkB Tc
nc = 2 I(y = 0)
4π ~2
c)
Now use Maxwell relation derivable from dF = ... on the information sheet: ∂S/∂N |T,V =
−∂µ/∂T |T,N . so
∂U ∂ µ 2 ∂ µ
∂(βµ)
=µ−T = −T =
∂ N V,T ∂T N,V ∂T T N,V ∂β N,V
In the Bose condensed phase µ = 0 and is independent of the temperature, so both terms in
∂U/∂N are zero.
6
d)
3/2 Z ∞ √ Z ∞ √
1 2mk 3/2 x dx N x dx
n= 2 T C × β 3/2 =
4π ~2 0 e(x−y) − 1 V 0 e(x−y) − 1
Both the term on the left and the term in () are positive definite. Thus dy/dβ > 0.
7
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