Professional Documents
Culture Documents
By
___________________
DEPARTMENT OF GEOSCIENCES
MASTER OF SCIENCE
1
STATEMENT BY THE AUTHOR
This thesis has been submitted in partial fulfillment of requirements for the
Master of Science degree at The University of Arizona and is deposited in the Antevs
Reading Room to be made available to borrowers, as are copies of regular theses and
dissertations.
Brief quotations from this manuscript are allowable without special permission,
provided that accurate acknowledgment of the source is made. Requests for permission
for extended quotation from or reproduction of this manuscript in whole or in part may be
granted by the Department of Geosciences when the proposed use of the material is in the
interests of scholarship. In all other instances, however, permission must be obtained
from the author.
__________________________________________ _____________
(author’s signature) (date)
Eric Seedorff
__________________________________________ _____________
Major Advisor (type name) (signature) (date)
Mark D. Barton
__________________________________________ _____________
(type name) (signature) (date)
Spencer R. Titley
__________________________________________ _____________
(type name) (signature) (date)
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ACKNOWLEDGMENTS
I would like to express my gratitude to Eric Seedorff, for his time, editorial
comments, and assistance in translation throughout the writing of this thesis. I would like
to thank Mark D. Barton and Spencer R. Titley for their comments and suggestions on
I would like to thank Mr. David Lowell for his financial support via the Lowell
Scholarship, and Bear Creek Mining for their financial support during my stay in the
United States, and especially to Andrew Swarthout for motivating me to come here.
I would like to thank to the people that motivated me in general. Thanks to Cesar
Rios, David Volkert, and Mike McClave for their comments on the paper. I thank Greg
Corbett for the use of some of his figures and for giving me some papers before arriving
in the U.S. I thank Edwin Gutierrez for his patience in helping me understand the
MineSight Software. I thank Luis Romero for his time helping me with some figures and
maps. I thank Rene Tonconi for his help with some figures and photos. I thank Doug
Kriener and Brad Christoffersen for their help with language and grammar issues in some
My most special thanks goes to Carolina, my wife. Thank you for your
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DEDICATION
Dedicated to my loved ones – the people who support and believe in me.
To my newborn Ana Camila, the one who inspires me to be responsible and who
To my father (El Abuelo), mother, and my sister for their love, support
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TABLE OF CONTENTS
LIST OF ILLUSTRATIONS……………………………………………………...8
LIST OF TABLES………………………………………………………………..10
ABSTRACT……………………………………………………………………….11
INTRODUCTION………………………………………………………………...13
EXPLORATION HISTORY……………………………………………………..16
METHODS………………………………………………………………………..17
Geologic mapping………………………………………………………………..17
Trenching…………………………………………………………………………18
Geophysical surveying…………………………………………………………...18
Petrography………………………………………………………………………19
Soil sampling……………………………………………………………………..19
Geologic modeling……………………………………………………………….19
EXPLORATION OPERATIONS……………………………………………….20
DISTRICT GEOLOGY…………………………………………………………..25
Overview…………………………………………………………………………27
Rock types……………………………………………………………………….27
Mesoscopic characteristics……………………………………………………..27
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TABLE OF CONTENTS-Continued
Petrography……………………………………………………………………...28
Structural geology…………………………………………………………………28
Mineralization……………………………………………………………………..29
Mode of occurrence………………………………………………………………29
Mineralogy……………………………………………………………………….30
Wall-rock alteration………………………………………………………………..32
GEOPHYSICAL CHARACTERISTICS………………………………………...35
Structural interpretation…………………………………………………………...37
Parageneses………………………………………………………………………..38
Geochemical environment………………………………………………………...40
Laykakota………………………………………………………………………..44
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TABLE OF CONTENTS-Continued
RESOURCE ESTIMATION……………………………………………………..45
Geostatistical analysis…………………………………………………………….45
Infrastructure……………………………………………………………………..47
Mining……………………………………………………………………………47
Metallurgy………………………………………………………………………..47
ECONOMIC POTENTIAL………………………………………………………48
CONCLUSIONS………………………………………………………………….49
REFERENCES……………………………………………………………………51
FIGURE CAPTIONS…………………………………………………………….58
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List of Illustrations
8
FIGURE 21. Surface photographs……………………………………………………… 83
9
List of Tables
10
Abstract
The Santa Ana project is an epithermal silver vein deposit in the Andes
discovered in 2006 by geologists of Bear Creek Mining. It comprises seven claims that
cover an area of 6,300 hectares. The main property anomaly is located 4 km south of the
village of Huacullani and about 120 km south of Puno, southeastern Perú, South
America. The mineralogy and geometry of the veins of this deposit show similarities with
The characteristics of the Santa Ana deposit are known primarily from outcrop
mapping, rock chip and soil sampling, and drilling. Mineralization is hosted by andesitic
lava flows of the Oligocene to Miocene Tacaza Group and associated dacitic dikes. The
veins contain sphalerite, galena, pyrite, minor chalcopyrite, and argentite and a late
carbonate. Most silver occurs as argentite that overgrows sphalerite. The veins are
these structures.
Most of the mineralized veins strike north to northeast and dip 15º to 60º west. The
principal veins range in width from centimeters to 2 meters, although the total width of a
mineralized interval, including zones of stockwork veins, breccias, and open- space
filling structures can be up to 40 meters. The highest silver values occur in areas of open-
space filling that may represent dilatant flexural zones associated with variations in strike
of the veins. Fluidized breccia dikes, hydrothermal magnetite veins (at depths >170m),
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and illite-pyrite alteration are present at Santa Ana, which some workers regard as
Santa Ana has characteristics in common with other Ag-Zn-Pb polymetallic vein
deposits of southern Perú. The mineralogy of Santa Ana has similarities with Pachuca,
Hidalgo, Mexico, the outer zones of Butte, Montana, and Laykakota, Perú, but the quartz-
poor character and lack of evidence for adularia at Santa Ana are distinctive. A resource
estimate based on the first 50 drill holes, made using MineSight® software is ~48 million
tonnes containing ~40 million ounces of contained Ag at an average grade of ~30 g/t Ag
and demonstrates that Santa Ana has the potential to be a bulk-minable deposit.
Metallurgical testing indicates the potential for cyanide leaching of ores at Santa Ana,
which is economically favorable and thus strongly encourages further exploration and
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Introduction
key information necessary to understand their genesis (Simmons et al., 2005), and the
location, size, grade, and metallurgical characteristics of deposits are important factors
relevant to their economic viability (e.g., Hoal et al., 2006). The Santa Ana project,
located about 120 km south of Puno in the Miocene andesite-dacite arc terrane
silver vein deposit discovered in 2006 by geologists of Bear Creek Mining with
structurally controlled in andesitic lava flows of the Eocene to Miocene Tacaza Group
and dacitic dikes, which are altered to chlorite-pyrite-illite assemblages. Elevations in the
area vary between 3800 and 4300 m above sea level (~14,000 ft).
at shallow depths and low temperatures (Lindgren 1922, 1933). Deposition normally
takes place within about 1 km of the surface in the temperature range of <100 to 320° C.
During formation of these deposits, fluids can reach the surface as hot springs.
Epithermal deposits are more common in areas of active volcanism, including volcanic
arcs. Epithermal deposits are important hosts of precious metals but also contain other
metals, such as Cu, Pb, Zn, and Bi. Comparison of the hydrothermal evolution of major
silver veins in Tertiary volcanic rocks reveals contrasting thermal histories, sulfidation
states, and degree of hydrolysis associated with ore fluids (e.g., Tayoltita and Guanajato,
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Mexico; Graybeal et al., 1986). Vein assemblages indicate little restriction on the
mineralization fall into a narrow range. In all deposits economic amounts of precious
metals are deposited at 250º - 300º C from solutions containing 10-2 to 10-3 total sulfur at
The Andes are a major producer of precious metals (Anonymous, 1972; Noble et
al., 1989, 1999; Noble and Vidal, 1994), and Perú is particularly known for its silver
production (Kamilli et al., 1977). Polymetallic veins in the Andes are sulfide - rich veins
containing sphalerite, galena, silver and sulfosalt minerals in a carbonate and quartz
gangue. Regional faults, fault sets, and fractures are important ore controls. The Miocene
volcanic arc in the Peruvian Andes is an important metallogenic province for precious
metal epithermal vein deposits such as Caylloma (Echavarria et al., 2006), Arcata
(Candiotti et al., 1990), Orcopampa (Gibson et al., 1990, 1995), and the recently
discovered Corani deposit. Veins largely form by several phases of open-space fillings of
usually present (Colqui, Perú; Kamilli et al., 1977). Veins commonly have complicated
parageneses and may exhibit spatial zoning with silver overlying base metal assemblages,
Mexico, but the quartz-poor character and lack of evidence for adularia at Santa Ana are
source of metals for the deposit. The size, grade, and metallurgical properties of the ores
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are economically favorable for possible future development of the deposit, thus
The purpose of this paper is to describe the geology of this new volcanic-hosted
and to make a preliminary resource estimate. I first describe the geologic setting of the
region and the district that contains the Santa Ana deposit, then document the methods
that Bear Creek Mining followed to make this discovery. I summarize the results of my
field work and describe the structure and mineralogy of the deposit. I compare Santa Ana
with other silver - polymetallic deposits and offer speculations on its origin. Finally, I use
data of the first 50 drill holes to make a resource estimate of the deposit with MineSight®
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Exploration History
The earliest work done at Santa Ana dates back to colonial times. Similar to many
of the early discoveries in Latin America, it was mined by the Spanish in the 1600’s.
Some miners returned in the earliest 1980’s, in which small workings mostly mined
In 2004, geologists of Bear Creek Mining Corporation became aware of these old
workings and took eight chip samples that returned values of up to 200 grams per tonne
of silver in a “crestone” structure (term used for vein-breccias with hackly texture).
Samples from rock chips returned values of 20-35 grams per tonne. Consequently, Bear
Creek decided to begin serious exploration during the second half of 2004. The areas
containing the most significant geochemical anomalies were given names designated by
km south of the main Anomaly B) (Fig. 2) contain some of the small mine workings that
were dug in the 1980’s (Fig. 3). Little is known about mining close to the Huacullani
District but “comuneros” (indigenous people who live in Huacullani, the closest village
to the project) said that people used to mine a gray colored mineral (supposed to be lead).
The focus of exploration completed to date has been on Anomaly B. Bear Creek
geologists started grid sampled (50 x 50 meters) in the Anomaly B zone, taking 446
samples that averaged 83 grams per tonne. Later, four trenches were dug totaling 160 m
in length. Three phases of drilling have been completed since then. More recently,
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Methods
Geologic mapping
Detailed mapping was completed at a scale of 1:2500 (meters) in 2004 (Fig. 4). A
more detailed map was made at a scale of 1:1000 for the main structural trend called
“East Breccia” because of the abundant structures present there (Fig. 5). Mapped
observations were plotted on two layers: one for structures and the other for outcrops and
alteration. Outcrops and mineralized structures where drawn in layers using Provisional
Sampling was done in an area of 2.8 kilometers long by 600 meters wide. A total
of 582 samples were taken in the area (“Anomaly A” and “Anomaly B” areas, see Fig.2),
with an average of 85.4 g/t silver. Samples include chip samples from outcrops and
structures. Samples were taken randomly (spaced 1.5 – 2 m) on outcrops. In the case of
structures, samples were collected continuously along a channel line perpendicular to the
structure. The footwalls and hanging walls were also considered for sampling of
structures. Each sample was described in the field; they later were recorded in an Excel
spreadsheet.
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Trenching
Trenching was done in order to check if the silver anomalies continue between
structures (Fig. 6). Four trenches were completed for a total of 224 m. Each sampled
interval was 1.5 – 2 m long. They were taken in a channel (25 – 30 cm wide) across the
different outcrops. Each sample was described and recorded in Excel spreadsheet.
Geophysical surveying
Valdor used induced polarization and resistivity (IP/Res), differential GPS and Total
Field Magnetic (TFM) methods covering 1.2 km of strike length along the north-south
corridor trend. Each section line (100 m spacing between lines) was interpreted in the
Lima office for future consideration of drill holes (Fig. 7 and Fig. 8)
Drilling occurred in three phases. Forty-two shallow core drill holes for a total of
5033.6 meters were drilled as of May 31, 2007 (Bear Creek is still drilling the project).
Holes were drilled with a L-250 model drill rig. Each HQ core interval was placed in a
carboard box and then was taken by truck to the field camp for geologic logging and
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rocks ore and gangue minerals, characteristics of the structures, and alteration. Each box
Petrography
main ore minerals and alteration products, paragenetic sequences, and textures relevant to
Soil sampling
Soil samples were made in a grid of 50 x 50 meters in the northern and southern
parts of Anomaly B (Fig. 12). Samples were collected from the B soil horizon in 1 x 1 x
0.8-meter pits dug with a pickax. Samples were then seived and then placed in a special
Geologic modeling
A 3-D solid was constructed using Mintec MineSight® software. Drilling and
geologic information from the first 50 drill holes were imported (Fig. 13, 14) to develop a
3-D solid of the initial shape of the deposit (Fig. 15). The data were then subjected to
geostatistical analysis (Fig. 16), and a 3-dimensional block model (Fig. 17, 18) was
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Exploration Operations
Trenching
Four trenches were excavated in the Anomaly B area with the following results:
Drilling
There have been three phases of drilling at Santa Ana since its discovery in 2006.
This paper is based on the first 42 drill holes (5033.6m) that Bear Creek completed as of
First phase: Eleven extremely widely spaced holes (more than 250 m apart on average)
were drilled by the contractor, Bradley, during June 2006. A total of 1120 m of HQ core
were drilled. The holes confirmed the possible bulk tonnage potential of the property and
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These holes (e.g., SA-2) indicated that the type and degree of alteration of lavas
and dike were similar at the surface and at depth. Small volcanic breccias (auto-
breccias?) were found in a few holes (e.g., SA-3) with the same alteration patterns:
feldspars are altered to illite-sericite, and mafics are chloritized. Similar patterns were
holes. Crackle breccias in drill holes correlate with the surface projection of crestones,
the vein-breccias that exhibit a hackly texture. The degree of fracturing, abundance of
barite, and abundance of jarosite correlate with presence of silver mineralization, though
they are not necessarily indicative of economic values. Most of the holes had an azimuth
between 100º and 300º, with a dip of -60º (to the E or W) and a depth of 100m. Sulfides
are predominantly oxidized in the upper 60 m, but in a few holes mixed zones appear
Second phase: Twenty-three additional holes were drilled before the end of 2006,
totaling 3191 m in this phase. Deeper holes were drilled (171.40m in drill hole SA-19A).
Holes were drilled mainly oriented between 130º and 180º with dips of -60º. Holes
oriented in a scissor pattern were drilled from some platforms (e.g., SA-3, SA-3A, SA-
3B, SA-3C). Lavas, volcanic breccias, and dikes were also found in this phase, with
similar characteristics and alteration patterns as in the first phase. The structures (veinlets
and veins, from mm up to 30 cm) observed dip at low angles (between 45 and 15º) to the
drill core axis. Oxidation persists to approximately 60 m. Good silver grades are related
21
Third phase: This paper considers holes drilled through SA-39A (as on May 31, 2007),
but drilling continued at least through all of 2008. Characteristics of host rocks and
alteration observed in this phase were similar to earlier phases. Lavas are intercalated
with volcanic breccias; both are clay – chlorite altered, and both are cut locally by the
dacitic dike. The best mineralization is restricted to low-angle centimetric structures and
dilational open-space filling. Barren Puno sandstones also were encountered in this phase
of drilling (drill hole SA-30A at 32m) for the first time. It is not clear yet what controls
the presence of these sedimentary rocks, but maybe there presence is related to a
secondary structure and associated uplift and erosion on the north-northeastern side of the
project.
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Regional Geology and Tectonics
constructed on the Altiplano as part of the Andes in southeastern Perú. Southeastern Perú
contains rocks that range from Paleozoic clastic sedimentary rocks to Recent volcanic
rocks, including immense volcanic centers that produced Late Miocene to Pliocene
Barroso pyroclastic rocks. There are different opinions about the importance of the
Cenozoic strike-slip faulting in southeastern Perú, especially in the Altiplano area (Herail
et al., 1996; Horton, 1996). Paleozoic sedimentation started with marine sandstones of
Early tectonic activity in the region occurred mainly in two phases. Early
formed the folds that are responsible for the angular discontinuity between Lower
Devonian rocks and the overlying deltaic sedimentary rocks of the Mississippian Ambo
rocks and overlying Permian sedimentary rocks is a result of strong folding north of Lake
Titicaca that formed during Late Hercynian orogenesis. The Paleozoic closed with the
Cretaceous rocks in the Yura basin, which was filled with terrigenous sediments of the
Yura and Lagunillas Groups. In the lower to middle Cretaceous, the site of deposition
23
shifted to the east from the Yura basin to the Putina basin, which continued into the lower
Cordillera (INGEMMET, 1995), forming rocks of the Tacaza Group (upper Oligocene to
lower Miocene), Sillapaca Group (middle Miocene), and Barroso Group (upper Miocene
Peruvian orogeny. Folds were formed in the Yura basin during epeirogeny and erosion
that define the Incaic orogeny, which started a phase of molasse facies deposition of the
Puno Group in the Altiplano that continued until the Oligocene (INGEMMET, 1995).
Five phases of the Neogene Quechuan orogeny are recognized on the basis of
stratigraphy and geochronology (INGEMMET, 1995): post- Puno/ pre-Tacaza (~30 Ma);
intra-Tacaza and pre-Palca (~22 Ma); post-Palca to post-Puno (~16 Ma); and post-Maure
to pre-Barroso (~7 Ma); and overthrusting of the Ayabaca Shale (<7 Ma).
(INGEMMET, 1995). Paleozoic rocks are mineralized with W, Mo, and Sb near post-
outcrops of the Tacaza Group, west of the Alto de Cabanillas. The principal metals
associated with the Tertiary mineralization are silver, lead, and zinc, with minor copper
and gold.
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District geology
The Santa Ana deposit contains continental sedimentary rocks that have been
assigned to the Puno Group, mineralized volcanic lava flows and auto-breccias of the
Tacaza Group, a pre-ore Cenozoic dacitic subvolcanic intrusive dome and dike, and post-
The Puno Group consists of a broad accumulation of arkosic red sandstones and
conglomerates with rounded clasts of fluvial origin. Shales, mudstones with intercalations
of calcareous beds, and evaporites are present locally. The Puno Group was deposited
between the Upper Cretaceous and the early Oligocene (83 - 35 Ma). In the Santa Ana
area, sandstones of the Puno Group are observed in the northeastern part of Anomaly B
(Fig. 2) and in drill hole SA-30A at 32 m. To date, sedimentary rocks of the Puno Group
commonly were deposited discordantly on Mesozoic rocks or rocks of the Puno Group.
Locally, however, rocks of the Tacaza Group were deposited on Paleozoic rocks. The
Tacaza Group is one of the main hosts for epithermal deposits across Perú (e.g., Corani
deposit in Puno; Yanacocha district in Cajamarca). In the Santa Ana area, the Tacaza
Group is the principal host of silver mineralization. Lavas of the Tacaza Group dip 15º to
60º west. The Tacaza Group is overlain by the Cenozoic tuffs of the Barroso Group.
25
The dacitic quartz-feldspar porphyry seems to be one of the Cenozoic intrusions
that occur in southeastern Perú. It is present in Santa Ana in the Anomaly B area as a
crescent-shaped dike and in the Anomaly A area as a lava dome (Fig. 21B).
closed the effusive and explosive volcanic Tertiary sequence in the Peruvian Andes.
breccias, agglomerates, and tuffs. The lavas are mostly basaltic andesites or hornblende
andesites. Some rocks of the Barroso Group are of interest because they host epithermal
Au-Ag mineralization. In the area of Santa Ana, a tuff of the Barroso Group is in the
western part of the Anomaly B (Fig. 2) overlies mineralization. No silver anomalies have
26
Geology of Anomaly B Area of the Santa Ana Deposit
Overview
Anomaly B is the most important area of mineralization at Santa Ana (Fig. 2 and
Fig. 21a). It is located approximately at 8158000 North and 466000 East UTM grid
coordinates using the PSAD 56 map datum (zone 19). Colonial workings are present
north - south by 500 m east - west. Recent drilling has shown that this area has been
extended by at least 200 m in both directions and still remains open in all directions.
Rock types
Mesoscopic characteristics: The main outcrops are andesitic lavas of the Miocene
Tacaza Group that are cut by a Cenozoic dacitic dike that is related to a dome located 1.5
km to the north-northeast. Felsic tuffs of the Barroso Group overlie the mineralized lavas.
Between the lava flows, it is common to find volcanic breccias (mostly monolithic
have been observed mostly found in drill holes. Hydrothermal intrusive(?) breccias have
been reported in recent drilling, although they were observed since the beginning of
exploration on a dump in the southern part of the area before any holes were drilled (A.
Swarthout, pers. commun., 2005) and at the end of drill hole SA-2A.
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phenocrysts and in a microcrystalline matrix, with different shapes from subhedral to
anhedral crystals and sizes up to 2,6 mm. Quartz, located in the groundmass, comprises
in the sample are zircon, sphene, and apatite. Hydrothermal minerals are observed and are
Structural geology
The main structures observed are vein-faults, and fracture sets that exhibit
are observed, the faults exhibit a normal sense of displacement. Two main orientations of
faults and fracture sets have been observed at Santa Ana: north-south and east-west.
hackly texture) have north-south strikes. Veins can be from 20 cm to 1.5 m wide at the
surface, although open space fillings and stockworks related to the veins can mineralized
wide. Similar widths of mineralization occur with the crestones. Mineralization also
occurs parallel to bedding in the lavas (15 – 60º to the west). Some north-south structures
main east-west structures (Fig. 22). The old workings continue south of Anomaly B (for
at least 1 km), where surface sampling is getting silver assays as high as 90 ppm.
28
The east-west trending structures are present as veins, veins-breccias, and lesser
crestones. These structures divide the north-south trend structures into blocks.
Mineralization
Mode of occurrence: Main structures in the area are the “East Breccia”, the
“Northwest Breccia” (Fig. 21a) with a predominantly trend of north-south, and the “East-
West Structure” in the southern part of Anomaly B (Fig. 22). These structures are
magnetite.
“crestones” (Fig. 4). At the surface, the dike is anomalous in silver (from 2 ppm to 21
ppm), but at depth high grade structures occur at the dike - lava contact or inside the dike,
with values up to 1000 ppm silver. Some old colonial workings (rich structures) are
present at the contact lava - dike. The dike can only be seen in an area of 600 m long by
15 m wide. Lavas are present in most of the area, and they are moderately fractured and
can have values up to 31 ppm silver, even when they are not close to the vein-breccias.
Jarosite (argentojarosite?), barite, and manganese after carbonates can be seen in those
fractures. Volcanic breccias (autobreccias) intercalated with the lavas contain the same
nearby.
29
To the east of Anomaly B, the same Tacaza lavas are exposed but no important
mineralization has been found. The truck route on the extreme eastern end of Anomaly B
may coincide with a major fault that is controlling the eastern limit of mineralization.
Only some spots of manganese can be seen in the eastern part of this Anomaly, but no
Outcrops samples in this area (335) average 43g/t Ag and mineralized structures
(78 samples) average 237 g/t Ag. Also, 25 samples taken from dumps average 154 g/t,
but these samples are not included in the general average of 85.4 g/t Ag. Silver anomalies
correlates with lead (0.37% average), zinc (0.32% average), and barium (up to 4200 ppm)
anomalies.
Mineralogy and texture: Veins that cut the lavas of the Tacaza Group are
pyrite. At the microscopic scale, galena fills the open space and microfractures of the
chalcopyrite, and sphalerite (Fig. 11a, 11b, 11c). Galena also fills some holes in
sphalerite. Sphalerite can be found disseminated and in the cleavages of the alteration
with magnetite and can be present as a weak alteration to leucoxene. Hematite is present
as radial aggregates and is included in gangue minerals (Fig. 11c), and in this way its
distribution is dispersed. There is also secondary hematite after magnetite. In few cases,
hematite can be observed replacing sphalerite. Chalcopyrite fills the interstices of the
gangue minerals. Argentite is present as veinlets filling the microfractures, and it replaces
30
sphalerite and galena (Fig. 11e). Pyrargyrite is possibly present as a dark ruby silver
At the surface, structures are in most cases veins-faults filled with barite-jarosite-
manganese-clay, and it is difficult to distinguish any silver mineral, although some people
reported seeing argentite and pyrargyrite on some dumps (G. Corbett, D. Volkert, A.
Swarthout pers. commun., 2007) At depth in the mixed sulfide-oxide zone (below 40m
depth in many cases), it is easier to see sphalerite, galena, and a little chalcopyrite. Silver
grades increase when light green sphalerite and galena occur with carbonate (ankerite?)
in veins that are at low angles to the core axis and when these reduced polymetallic
minerals are mixed with specular hematite. A positive correlation has also been observed
between vein width and silver grade in certain areas, but this is not a general correlation.
There is also a positive relation between silver grade and barite that occurs as invasive-
Quartz content increases with depth (generally deeper than ~60 m), where it has
been observed that chalcedonic silica (low-temperature quartz) that is typical of upper
zones changes to a comb quartz texture at depth. This change, however, has been
hematite-barite in the first 20 m, an oxide-mixed zone from ~20 to ~80 m with oxides,
carbonate, and intermediate sulfidation minerals , and a sulfide zone beginning at ~80-
100 m, where pyrite, low-iron sphalerite, galena, argentite, tetrahedrite(?), plus secondary
hematite appear together in some holes. Pyrite is present as 1-2% disseminated grains in
the host rock (lava), and there is not a clear increase in abundance except close to
31
structures (in the alteration halo) or in the structure (10-20%, e.g., DDH-SA6 @ 170 m).
Hydrothermal magnetite is present (e.g., DDH-SA6) in very few parts of the area (it may
The more abundant sulfide mineral in the host rock is pyrite, and in the structures are
Pyrite is a mineral that is present as 1-2% disseminated in the host rock (lava) and
there is not a clear increase of it until it is close to structures (as alteration halo) or part of
the structure (10-20%, e.g., DDH-SA6 @ 170 m). Hydrothermal magnetite is present
(e.g., DDH-SA6) in very few parts of the area (it may be detected where the chargeability
geophysical anomaly increased, e.g., DDH-SA6). The more abundant sulfide mineral in
the host rock is pyrite, and in the structures are sphalerite and pyrite, follow by galena.
Wall-rock alteration
the andesitic lavas of the Tacaza Group (Fig. 4) are illite-sericite as a product of alteration
of the plagioclase phenocrysts (Fig. 10), chlorite after ferromagnesian minerals, and
calcite associated with chlorite and possibly originating from alteration of ferromagnesian
minerals. Quartz is also present in trace amounts, giving the samples the common district
centimeters on each side. In the northwestern part of this area, there is a slight increase in
kaolin close to the old workings, where values can be as high as 20 ppm Ag.
32
Alteration in dacite dike: The dike presents the same alteration as the lavas. Its
feldspars are altered to illite- sericite and its mafics are altered to chlorite. Pyrite and
Surface mapping, sampling, and logging show few spatial variations in alteration.
chlorite halos in the northern and western parts of the area (more typical maybe in
crestones), with a more chlorite-clay-pyrite halos in the rest of the area. Illite may be
dependent of a supergene effect, and it clearly evident in some dumps and old workings
in the northern and west parts of the area. Adularia has not been observed either on the
surface or in drill holes to date. Quartz is found in minor quantities on some old dumps,
Veins, vein-breccias and open space fillings and stockworks wall rocks in Santa
Ana are mainly altered to chlorite-pyrite assemblages, although structures in core show
more abundant illite or other phyllosilicates near the surface, probably due to weathering
effects. Some structures are bleached for up to 1.5 m from structures in the upper parts of
the drill core, but this halo disappears at depths of 20 to 30 m. The only obvious change
in alteration is that halos of chlorite-pyrite alteration increase in width when the structure
is wider.
33
Geology of Anomaly A
This area is located north of Anomaly B (see Fig. 2 and Fig. 21A-B), and it is
about 800 m long by 300 m wide. Anomaly A is composed of lavas of the Tacaza Group
quartz feldspar porphyry (QFP) dome that is the root for the dike that crops out in
Anomaly B (see Fig. 21 and Fig. 4). The dome is outcropping with the same clay-chlorite
north-northeast, with sub-vertical dips. Many structures are located in the edges of the
dome, although others can be found in the center cutting the dome, with values up to 100
ppm silver. High dump values were also taken with results of 118, 160, 311 and 768 ppm
in silver. This area is considered as an important prospective area due to the number of
old workings present. Weak increase of silica and pyrite in the bottom parts of the dacite
dome are important in this area. Further deep holes should be drilled here to test for
possible increases in the grade of mineralization with depth and for the presence of a
34
Geophysical Characteristics
resistivity were completed in 2005. These surveys define an area of sulfide mineralization
underlying the geochemical anomaly, interpreted to contain >5% sulfides) (Bear Creek
The IP response suggests that vertical continuity is good and that the
mineralization is open to the south, where strongly anomalous silver was found in
outcrops at the limits of the sampling grid. Three chargeability anomalies are outlined by
the induced polarization-resistivity survey (Fig. 7). The chargeability responses range
from weak (7mV/V) to strong (20mV/V) with respect to the background. The
A hole (SA-6) drilled in the area of one of the strongest induced polarization
targets (Fig. 8) found 5% pyrite as disseminated grains and veinlets of pyrite + weak
observed.
35
Soil Samples
Soil samples were collected in two phases in 2006 and 2007. Samples were
Anomaly B. The first phase was done in the south-southwestern to southern part of
Anomaly B in a 1000 m x 1250 m area, and the second phase was in the northern part in
Bear Creek got good values (e.g., 12 ppm silver in soil sample # 51136) in a few
areas that are coincident with buried structures, the presence of which has been confirmed
36
Geologic Interpretations and Discussion
Structural interpretation
Many ore deposits are localized by major thoroughgoing structures that may
display variable activity histories, especially if the structural setting provides dilational
sites for the enhanced flow of hydrothermal fluid (Corbett, 1994; Corbett and Leach,
1998).
Santa Ana is a structurally controlled ore deposit. Veins at Santa Ana formed
during an episode of extension, as interpreted from the presence of normal faults and the
great thickness of some open-space filling veins and related extension fractures. In the
jog occurs further to the south, where there is a transition from northeasterly striking
Anomaly B; see Fig. 2). Such a variation within mineralized fractures would be
consistent with a component of dextral strike-slip movement that might facilitate the
development of ore shoots within flexures (Corbett, 2007) (Fig. 22), which is consistent
with good Ag grades in drill holes SA-3, SA-4, SA-12, and SA-15.
due to a collapse of the lava flows on the western margin (Corbett, 2007; possible border
of a diatreme?), where there are hydrothermal breccias (e.g., SA-38, SA-38A, SA-2A;
Photo 19A). Alternatively, bedding-parallel flow could have been promoted by bedding
37
plane shear due to a component of uplift or doming within the north-south structural
corridor (east side of Anomaly B), although no evidence has been found to support such
uplift. The hydrothermal breccias are characterized by slab-like breccia clasts, which are
1998). A common character in most holes at the southern part is the low-angle (15-25°)
between the millimeter- to centimeter-scale structures and the 60-70° inclination of the
drill holes. This sheeted character shows a dilatant character (Photo 23) due to the normal
bedding movement, and these sites localize polymetallic sulfides, carbonate minerals, and
The east-west striking structures present in the area divide the north-south
trending structures into blocks. Mineralized structures exploit the east-west shears and
strike-slip movement on the east-west structures in the area of the Spanish mine workings
Paragenesis
From the study of drill core and thin sections, hydrothermal minerals are
Stage I: Intrusive dome, dikes, tectonic breccias are interpreted to have formed
above the magma chamber, which may have increased the permeability of the rocks for
future flow of mineralized fluids. Fluidized breccias with a milled matrix (Fig. 19B) and
38
possibly intrusion-related hydrothermal breccias (Fig. 19A) that may border a possible
diatreme (Ríos, 2007 ) also may have influenced ground preparation. These ground
preparation features are coincident with the district-scale, weak to moderate intensity of
Stage II: Barite, low-temperature quartz and specular hematite are interpreted to
have formed prior to the main economic mineralization event but after tectonic
brecciation. Specular hematite can be difficult to distinguish from galena when it is fine-
grained. Hematite has a red streak (Fig. 19E), whereas boxwork after galena leaves a
Stage III: This is the main stage of deposition of ore minerals in the area, as
economic minerals overgrow barite and quartz. Pyrite, chalcopyrite, sphalerite, argentite,
galena are interpreted to be deposited in this stage. Hydrothermal activity may also have
Stage IV: Carbonates and amethystine quartz were deposited at the end of the
system perhaps from bicarbonate waters, and the mixing of these waters with rising ore
fluids may have promoted precious metal deposition (Corbett and Leach, 1998). This
39
Geochemical environment
The mineralogy of the silicates and sulfides at Santa Ana record the near-neutral
(e.g., 0.097 ppm Au in DDH SA-6, 120m) are spatially associated with specular hematite
and may also occur at deeper levels in the hydrothermal system, where hairline magnetite
veins are present at the southern part of Anomaly B, the site of the highest IP anomaly in
the area.
wide range of salinities (1-20 wt % NaCl equiv), although fluid inclusion data are not
available for Santa Ana. Fluids of moderate to high salinity are capable of transporting
significant quantities of silver and base metals (e.g., Seward and Barnes, 1997). The
epithermal deposits that have fluids of moderate to high salinities are either rich in base
metals or contain precious metals with subordinate amounts of base metals, such as
1991; Albinson et al., 2001). The high salinities in fluid inclusions could be interpreted to
be derived from either a magmatic source or interaction with evaporites. Much of the
Altiplano of southern Peru, including Santa Ana, is underlain by the Puno Group. The
Puno Group locally contains evaporites, so fluids with elevated salinities could have been
40
Inference about fluid sources and causes of ore deposition
precious metal precipitation, as supported by some fluid inclusion data, extensive isotopic
data, and numerical simulations (e.g., Robinson and Norman, 1984; Mancano and
Campbell, 1995; Hayba, 1997). Ore fluids in epithermal deposits may contain a
significant magmatic fluid component; for example, ore fluids in bonanza parts of the
Comstock Lode appear to have had a significant (30-75%) magmatic component (Taylor,
1973; Vikre, 1989; Simmons, 1995). Santa Ana is interpreted to have a significant
hypogene (specular) hematite (typical of deeper parts in polymetallic vein systems), and
illite-pyrite alteration (Corbett, 2007). Ore minerals may have been precipitated at Santa
Ana by dilution and cooling and, to a lesser extent, from changes in oxidation state and
Dilational zones are interpreted to have acted as sites for mixing of ore fluids with
bicarbonate waters because of its high grade and mineralogy (base metals-argentite with
carbonates; Photo 17, 18, 19, and 24). The quartz-poor character in Santa Ana may be
41
Classification and distinctive characteristics of Santa Ana
including by the sulfidation state of the contained minerals (Simmons et al., 2005). The
minerals in terms of sulfur fugacity (e.g., Barton and Skinner, 1979; Hedenquist et al.,
1994; Einaudi et al., 2003), and some authors use a three-fold classification of deposits
into low-, intermediate-, and high-sulfidation deposits (e.g., Sillitoe and Hedenquist,
polymetallic deposit. Intermediate sulfidation state minerals present at Santa Ana are
(Candiotti et al., 1990); San Cristóbal, Bolivia (Buchanan, 2000); the Comstock Lode
(Vikre, 1989) and Tonopah (Nolan, 1935; Bonham and Garside, 1979) in Nevada;
Creede, Colorado (Barton et al., 1977); and Pachuca-Real del Monte (Dreier, 2005),
Fresnillo (Simmons et al., 1988), and Tayoltita, Mexico (Smith et al., 1982). Santa Ana is
notable for its relatively quartz-poor character. Santa Ana also has similarities with the
carbonate – base metal Au-Ag deposits of the southwestern Pacific rim (Corbett and
42
Comparison of Santa Ana with other epithermal polymetallic vein deposits
has been active since 1550 (Geyne et al., 1963; Dreier, 1976, 1982, 2005). This deposit is
epidote, chlorite, adularia, albite, calcite, and pyrite, but quartz, adularia, and pyrite occur
as alteration envelopes around the veins. Orebodies are contained in a series of east-west,
occur where there are changes in vein strike and dip (Simmons et al., 2005). The veins
range in width from 0.5 to 5 m, although vein-filling fractures can span zones up to 35 m
wide. Quartz, chalcopyrite, galena, and sphalerite are the common vein minerals. Silver
occurs mainly in acanthite. Fluid inclusion homogenization temperatures range from 210°
Santa Ana shows similar structural control and a mixing environment between
magmatic water and bicarbonate waters at similar depths in the system. Adularia was not
seen in Santa Ana but low-temperature quartz suggests the influence of meteoric waters
similar mineralogy to Santa Ana (McClave, 2007). The presence of quartz, rhodochrosite,
carbonates, sphalerite, pyrite with silver minerals in open-space filling veins are shared
43
by both deposits, implying that a porphyry copper deposit could be located possible
1600’s. Mineralization is hosted by andesitic lavas of the Tacaza Group and occurs in
parallel, northeast-striking veins that dip to the east (INGEMMET, 1993). Veins are
between 1.5 and 5 m wide.. The ore minerals are galena, sphalerite, chalcopyrite, and
pyrite with barite and manganese. This deposit is significant for its relative proximity to
Santa Ana.
44
Resource Estimation
Fifty-five drill holes were used in the construction of a 3-D solid (Fig. 13, 14).
The total length of these drill holes is 9928 m. A database was constructed that contains
all the relevant data for each hole, such as drill hole locations and orientations, as well as
assays of each analyzed interval. The solid was constructed on the basis of silver values,
because silver is the most important metal economically in the deposit (Tables 3, 4, 5,
and 6). The dip angles of the mineralized structures were also taken into consideration.
Vertical sections and horizontal plans were made every 5 m using MineSight®
software. Both sets of slices were combined for construction of the 3-D solid. The shape
of the interpreted mineralized volume took into account the strike and dip of the
structures, constraints from field geology, the grades of the drill hole, and my
interpretation of grade continuity (Fig. 15). Two codes were used to differentiate
mineralized material from waste. Grades were interpolated only inside the volume of the
Geostatistical analysis
Conventional statistics and geostatistics were used to analyze silver assays from
holes drilled at the Santa Ana deposit. Using a cut-off grade of 18.50, the arithmetic mean
grade is 27.3 g/t. A variogram analysis for the deposit was done for silver to determine
45
the spatial continuity of the mineralization in the zones and to determine the parameters
for the grade interpolation of the block model. It was determined the variogram 3-D
considering horizontal grade of 30º and vertical grade of 22.5º. The variograms were
modeled using a single structure spherical model. The histogram shows that the average
The 3-D block model is based on the shape of the 3-D solid and geostatistical
analysis of the data. The 3-D block model for mineral resource estimation was built with
blocks of 10 x 10 x 10 m (Fig. 17, 18). The block model was interpolated using the
kriging method. The ellipsoidal search parameters for the interpolation process were 100
measured, indicated, and inferred categories (e.g., JORC, 2004). Because this model of
Santa Ana is based on only 55 drill holes that are widely spaced, this estimate is
drilling and geologic logging will provide new geologic insights and additional assay
data, which will eventually permit a better estimate of mineral resources in the future.
The total indicated and inferred resources from all zones in the deposit at a cut-off grade
of 18.50 g/t are 47.71 million tonnes of mineralized material grading 27.3 g/t of Ag,
totaling 41.9 million ounces of contained Ag. Additional drilling and economic inputs are
46
Other Economic Inputs
Infrastructure
The deposit is close to a paved highway and to Desaguadero (a medium to large city for
the Altiplano). Water for a potential future mining operation can be taken from a large
constructed from Santa Ana to an electrical sub-station located ~40 km away, which is
connected to the national grid. Construction will be relatively easy because the area has
Mining
At this moment Santa Ana is viewed potentially as an open pit operation. High-
grade veins at depth may be amenable to underground mining, concurrent with or after
Metallurgy
Two phases of metallurgical leach tests have been done to see if the material from
The first phase tested ten samples (representing both high- and low-grade
material) form different parts of five different core drill holes. The samples were crushed
to 70% passing 2mm. Three tests were made from these samples. The first tests were
performed by the ALS-Chemex laboratory in Lima and were cyanide-soluble shake tests.
The tests show that 55.5% leachable silver can be recovered (see results in Table 7). The
47
second tests were made in the Plenge metallurgical test laboratory in Lima and were
longer term, bottle roll tests performed on finely ground material. Results from the test
showed 85% recovery of silver of (see results in Table 8). Finally, the third tests were
made at McClelland Laboratories, Inc., in Sparks, Nevada, in which bottle roll tests were
performed on the un-ground course reject material. The average recovery of silver was
71% (see results in Table 9). Results from the three laboratories are summarized in Fig.
24.
The second phase of metallurgical testing was initiated with the objective of
evaluating samples in conventional heap leaching with and without pulp agglomeration.
The average silver recovery was 64.6%, achieved for the conventional column tests,
although in a conventional, commercial heap leach situation, the overall long-term silver
metallurgical optimization tests will be needed to establish the most economic crush size
for the heap leach. Standard flotation of lead and zinc will also be checked by future
metallurgical testing.
Economic Potential
An impressive resource has already been defined at Santa Ana, even though the
solid model was based on only 55 drill holes (as on May 31, 2007). The degree of
continuity of mineralization at Santa Ana may be an issue, which further drilling will
address. The metallurgical behavior of the material, based on heap leach tests performed
to date, also are encouraging. Hence further exploration of Santa Ana is certainly
warranted.
48
Conclusions
Peruvian Andes. The Ag-Zn-Pb mineralization occurs in vein-breccias and open space
fillings related to extensional zones hosted by andesites of the Tacaza Group. Veins
contain sphalerite, galena, pyrite, minor chalcopyrite, and argentite and a late mixed
(MgCa) carbonate and are thus of intermediate sulfidation in character. Most Ag occurs
propylitic alteration (chlorite, pyrite) which was cut by veins that have chlorite-pyrite-
illite(?) (sericite?) envelopes. The deposit is notable because the veins are relatively
quartz-poor, and adularia has not been observed. High silver values in drill core occur
where carbonates and chalcedony occur with base metals. Silver may have been
waters.
Supergene processes in Santa Ana affect the upper 80 m of the deposit, which is
responsible for the possible presence of argentojarosite and may have contributed to
for some intermediate deposits. Quartz-poor character of Santa Ana makes this
intermediate epithermal deposit unusual in its style and should be taken in consideration
in future subdivisions in epithermal deposit types. The lack of adularia, although rare in
this deposit type, is not unique to Santa Ana because some deposits in Philippines and
Papua New Guinea contain sericite rather than adularia, indicating higher temperatures
and limited boiling which could be the result of greater depth of formation. An estimate
49
of the resource that was based on the first 55, widely separated drill holes contained 41
grade of 27.3 g/t Ag. There is good potential to increase the size of the resource with
further drilling, and certain key, non-resource economic inputs (such as infrastructure,
50
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and stable isotope data, in Albinson, T., and Nelson, C. E., eds., New mines and
Barton, P.B., Jr., and Skinner, B.J., 1979, Sulfide mineral stabilities, in Barnes, H. L., ed.,
Geochemistry of hydrothermal ore deposits, 2nd Edition: New York, John Wiley
Barton, P.B., Jr., Bethke, P.M., and Roedder, E., 1977, Environment of ore deposition in
the Creede mining district, San Juan Mountains, Colorado: Part III. Progress
toward interpretation of the chemistry of the ore-forming fluid for the OH vein:
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http://www.bearcreekmining.com
Candiotti de los Ríos, H., Noble, D.C., and McKee, E.H., 1990, Geologic setting and
epithermal silver veins of the Arcata district, southern Perú: Economic Geology,
v. 85, p. 1473-1490.
Corbett, G.J., 2007a, Comments on the controls to mineralization at the Santa Ana
Corbett, G.J., 2007b, Comments on the controls to mineralization at the Santa Ana
51
Corbett, G.J., 2007c, Low sulphidation epithermal Au-Ag: Exploration implications of
Corbett, G.J., and Leach, T.M., 1997, Southwest Pacific Gold-Copper Systems: Structure,
Corbett, G.J., and Leach, T.M., 1998, Southwest Pacific Gold-Copper Systems: Structure,
Publication 6, 236 p.
Dreier, J.E., 1976, The geochemical environment of ore deposition in the Pachuca-Real
Arizona, 116 p.
Dreier, J.E., 1982, Distribution of wall rock alteration and trace elements in the Pachuca-
Real del Monte district, Hidalgo, Mexico: Mining Engineering, v. 34, p. 699-704.
Dreier, J.E., 2005, The environment of vein formation and ore deposition in the Purísima-
Colon vein system, Pachuca Real del Monte district, Hidalgo, Mexico: Economic
Echavarria, L., Nelson, E.P., Humphrey, J., Chávez, J., Escobedo, L., and Iriondo, A.,
2006, Geologic evolution of the Caylloma epithermal vein district, southern Perú:
Einaudi, M.T., Hedenquist, J.W., and Inan, E.E., 2003, Sulfidation state of fluids in active
Gagliuffi Espinoza, P.M., 2007, Estudio microscópico de doce (12) muestras de rocas
procedentes del Proyecto Santa Ana: Unpublished report to Bear Creek Mining.
52
Gemmell, J.B., 2006, Low- and intermediate-sulfidation epithermal deposits: Centre for
Tasmania, p. 1-4.
Gibson, P.C., Noble, D.C., and Larson, L.T., 1990, Multistage evolution of the Calera
epithermal Ag-Au vein system, Orcopampa district, southern Peru: First results:
Geyne, A.R., Fries, C., Jr., Segerstrom, K., Black, R.F., and Wilson, I.F., 1963, Geology
and mineral deposits of the Pachuca-Real del Monte district, State of Hidalgo,
Graybeal, F.T., Smith, D.M., Jr., and Vikre, P.G., 1986, The geology of silver deposits, in
Wolf, K.H., ed., Handbook of strata-bound and stratiform ore deposits, v.14, p. 1-
184.
Hayba, D.O., 1997, Environment of ore deposition in the Creede mining district, San
Hedenquist, J.W., Matsuhisa, Y., Izawa, E., White, N.C., Giggenbach, W.F., and Oaki,
53
Herail G., Baby P., Blanco J., Bonhomme M., Soler P., 1996, The Tupiza, Nazareno and
Estarca basins (Bolivia): strike-slips faulting and related basins in the Cenozoic
259:201-12.
Altiplano al Oeste del Lago Titicaca – Sur del Perú: INGEMMET, Boletín 42, p.
72-127
John, D.A., 2001, Miocene and early Pliocene epithermal gold-silver deposits in the
JORC, 2004, Australasian Code for Reporting of Mineral Resources and Ore Reserves
(The JORC Code), 2004 Edition, The Joint Committee of the Australasian
Australia, 20 p.
Kamilli, R.J. and Ohmoto, H., 1977. Paragenesis, zoning, fluid inclusion and isotopic
studies of the Finlandia vein, Colqui district, central Peru: Economic Geology, v.
54
Lewis, R., 1956, The geology and ore deposits of the Quiruvilca district, Perú: Economic
Lindgren, W., 1922, A suggestion for the terminology of certain mineral deposits,
McClave, M.A., 2007, Property report for the Santa Ana project for Bear Creek Mining
Noble, D.C., and McKee, E.H., 1999, The Miocene metallogenic belt of central and
Noble, D.C., and Vidal, C.E., 1994, Gold in Peru: Society of Economic Geologists
Noble, D.C., Eyzauirre, V.R., and McKee, E.H., 1989, precious-metal mineralization of
Cenozoic age in the Central Andes of Peru: Circum-Pacific Council for Energy
Nolan, T. B., 1935, Underground geology of the Tonopah mining district, Nevada,
Petersen, U., Mayta, O., Gamarra, L., Vidal, C.E., and Sabastizagal, A., 2004,
Ríos, C.C., 2007, Santa Ana drilling: Unpublished memorandum to Bear Creek Mining.
55
Robinson, R. W., and Norman, D. I., 1984, Mineralogy and fluid inclusion study of the
Seward, T. M., and Barnes, H. L., 1997, Metal transport by hydrothermal ore fluids, in
Barnes, H. L., ed., Geochemistry of hydrothermal ore deposits, 3rd Edition: New
Sillitoe, R.H., and Hedenquist, J.W., 2003, Linkages between volcanotectonic settings,
Sillitoe, R.H., 2004, Musings on future exploration targets and strategies in the Andes:
Simmons, S. F., 1991, Hydrologic implications of alteration and fluid inclusion studies in
the Fresnillo district, Mexico: Evidence for a brine reservoir and a descending
Simmons, S. F., Gemmell, J. B., and Sawkins, F. J., 1988, The Santo Niño silver-lead-
zinc vein, Fresnillo district, Zacatecas, Mexico: Part II. Physical and chemical
56
Simmons, S.F., White, N.C., and John, D.A., 2005, Geological characteristics of
Smith, D. M., Jr., Albinson, T., and Sawkins, F. J., 1982, Geologic and fluid inclusion
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84, p. 1574-1613.
57
Figure Captions
Fig. 1. Location map of the Santa Ana deposit. Map shows location within Puno
Fig. 2. Location map of Anomaly A and Anomaly B. Upper green square encloses
Anomaly A; below it is Anomaly B. The area now considered a new anomaly, Anomaly
Fig.3. Photographs of old workings. Top photograph shows southern part of Anomaly B,
with dumps visible in the distance. Bottom photograph shows close up of old workings
Fig. 4. Geologic map of Anomaly B. Area mapped at a scale of 1:2500 (Bear Creek
Fig. 5. Detailed geological map of eastern side of Anomaly B (Bear Creek unpublished
data, 2005). Geology, with a focus on structural measurements in the vicinity of the East
Tonconi).
58
Fig. 7. Interpretation of 3D induced polarization and resistivity survey. Plan view
Fig. 9. Photographs of representative drill core box. View shows two boxes of core
type of alteration. Calcite may be associated with chlorite, possibly originating from the
Gagliuffi).
hematite (hm) being replaced by sphalerite (ef), chalcopyrite (cp) can be observed as little
grains between the gangue minerals (GGs) and the sphalerite. B. Drill hole SA-03
(80.60m), galena (gn) replacing sphalerite. C. Drill hole SA-03 (80.60m), galena and
sphalerite replacing anhedral crystals of hematite. D. Drill hole SA-11 (6.60m), veinlet of
sphalerite that is partially replaced by galena. E. Drill hole SA-17 (66.45m), proustite
59
associated with argentite replacing sphalerite, with galena replacing all minerals. F. Drill
hole SA-05 (38.40m), sphalerite replacing hematite. Right side: hematite filling holes in
Fig. 12. Location map of soil samples, Anomaly B (Bear Creek unpublished data, 2007).
Fig.13. Projection of drill holes to plan view, MineSight Software (Figure by C. Ríos, E.
Gutierrez). Yellow color: 20g/t Ag average. Green Color: 20-40g/t Ag. Red Color: more
Fig. 14. Projection of drill holes to section view, MineSight Software (Figure by C. Ríos,
E. Gutierrez).Yellow color: 20g/t Ag average. Green Color: 20-40g/t Ag. Red Color:
Fig. 15. Solid shape from different views, MineSight Software. A. Looking north, 3D
view. B. Looking west, 3D view. C. N-S, Plan view (Figure by C. Ríos, E. Gutierrez).
Yellow color: 20g/t Ag average. Green Color: 20-40g/t Ag. Red Color: more than 40g/t
Ag.
Fig. 17. 3-D Block model, plan view (Figure by C. Ríos, E. Gutierrez). Yellow color:
20g/t Ag average. Green Color: 20-40g/t Ag. Red Color: more than 40g/t Ag.
60
Fig. 18. 3-D Block model, section view (Figure by C. Ríos, E. Gutierrez). Yellow color:
20g/t Ag average. Green Color: 20-40g/t Ag. Red Color: more than 40g/t Ag.
Fig. 19. Photographs of drill core. A. Hydrothermal breccia with intense illite-pyrite
galena and light green sphalerite with later carbonate gangue, SA-15, 97.9m. D. Crimson
barite-sulfide-carbonate vein with argentite within the carbonate vein portion, SA-2A,
75.7m. F. Chlorite shear with interlayered barite, SA-36A, 123m (G. Corbett,
Fig. 21. Surface photographs, A. Anomaly B, left side (dark color): East Breccia, right
upper part: post mineral Barroso tuff. B. Anomaly A, right center: QFP dome (Photos by
C. Ríos).
Fig. 22. Sketch of geological relationships including dilational splays. (G. Corbett,
61
Fig. 23. A. Conceptual geological model for Santa Ana. Figure illustrates the creation of
dilatancy within the pre-existing sheeted fractures where ore fluids (orange) have mixed
(orange) occurs in the absence of the fluid mixing environment. B. Dilational zone with
Fig. 24. Comparison of three phases of metallurgical test results (M. McClave,
62
Ríos, Figure 1, Location map of Santa Ana.
63
Ríos, Figure 2, Location map of Anomaly A and Anomaly B.
64
Ríos, Figure 3, Photographs of old workings, southern part of Anomaly B.
65
Ríos, Figure 4, Geologic map of Anomaly B.
66
Ríos, Figure 5, Detailed geological map of East Breccia.
67
Ríos, Figure 6, Photographs of trenches at Anomaly B.
68
Ríos, Figure 7, Interpretation of 3D induced polarization and resistivity survey.
69
Ríos, Figure 8, Interpretation of 3D induced polarization and resistivity section.
70
Ríos, Figure 9, Representative photograph of drill core.
71
Ríos, Figure 10, Photomicrographs of lavas.
72
Ríos, Figure 11, Photomicrographs of opaque mineralogy.
A B
C D
E F
73
Ríos, Figure 12, Location of soil samples, Anomaly B, scale 1:2500
74
Ríos, Figure 13, Projection of drill holes to plan view, MineSight® Software.
75
Ríos, Figure 14, Projection of drill holes to section view, MineSight® Software.
76
Ríos, Figure 15, 3-D Solid shape from different views, MineSight® Software.
B C
77
Ríos, Figure 16, Histogram of Ag assay values.
78
Ríos, Figure 17, 3-D Block model, plan view.
79
Ríos, Figure 18, 3-D Block model, section view.
80
Ríos, Figure 19, Photographs of drill cores, Anomaly B.
A B
C D
E F
81
Ríos, Figure 20, Stratigraphic column, Puno.
82
Ríos, Figure 21, Surface photographs.
83
Ríos, Figure 22, Sketch of geological relationships including dilational splays.
84
Ríos, Figure 23, Conceptual geological model for Santa Ana.
85
Ríos, Figure 24, Comparison of three phases of metallurgical test results.
100.0%
90.0%
80.0%
70.0%
60.0%
50.0%
40.0%
30.0%
20.0%
10.0%
0.0%
1 2 3 4 5 6 7 8 9 10
86
Table 1. Diagnostic Minerals and Textures of Various States of pH, Sulfidation and Oxidation State. Used to Distinguish
Epithermal Ore-Forming Environments (Giggenbach, 1997, Einaudi et al., 2003) (the use of hyphens between minerals
indicate an equilibrium assemblage for which all phases need to be present)
Acid pH Neutral pH
residual, vuggyquartz
Fe-poor sphalerite-pyrite
Oxidized Reduced
pyrite.
87
Table 2. Resource Estimate Determined with MineSight Software (50 drill holes)
88
Table 3. Drill holes results, Phase 1.
Silver
Drill Inclinatio Total Interval
Azimuth From To (grams Lead Zinc
Hole n Depth (m)
(degrees) (m) (m) per (%) (%)
# (degrees) (m) DTH
tonne)
SA-02 105 -65 101.00 0 52 52 34.2 nil 0.6
includes 28 34 6 133.7 nil 1.3
SA-03 0 -60 99.50 48 96 48 87.1 0.5 1.1
includes 50 60 10 199 0.6 0.8
and 72 80 8 102.6 1.2 2.6
SA-04 305 -50 96.00 4 10 6 112 0.7 0.3
22 38 16 87.1 0.6 0.4
42 52 10 43.5 1.3 0.8
SA-05 280 -50 99.00 0 40 40 77.8 0.3 0.6
includes 0 16 16 140 0.3 0.7
56 66 10 68.4 0.2 0.4
SA-07 145 -60 100.00 0 52 52 56 0.5 0.7
includes 22 32 10 127.5 0.7 0.9
SA-10 30 -70 80.50 48 72 24 82.2 0.1 0.3
Hole TDs in 72 g/t silver
SA-11 172 -65 75.50 0 12 12 189.7 0.4 0.2
36 54 18 34.2 0.4 0.7
89
Table 4. Drill holes results, Phase 2.
Interva Silver
Inclinatio Total
Drill Hole Azimuth From To l (grams Lead Zinc
n Depth
# (degrees) (m) (m) (m) per (%) (%)
(degrees) (m)
DTH tonne)
SA-3A 0 -75 106 48 106 58 84.2 0.6 1.0
includes 48 72 24 125.8 1.0 1.0
and 78 90 12 91.7 0.5 1.2
SA-10B 86 24 62 38 86.1 0.3 0.2
includes 38 52 14 163.1 0.4 0.2
SA-10C 86 0 86 86 38.4 0.2 0.3
includes 76 80 4 285.0 1.0 1.1
SA-12 0 -70 100 2 48 46 89.0 0.4 0.3
includes 16 22 6 172.0 1.0 0.7
and 42 48 6 418.0 0.7 0.2
SA-13 70 -70 152 10 82 72 40.2 0.2 0.2
includes 38 42 4 131.0 0.2 0.2
and 58 60 2 573.0 0.7 0.3
and 78 82 4 112.0 0.1 0.3
SA-13A 225 -70 169 8 44 36 35.3 0.1 0.2
includes 8 20 12 64.3 0.2 0.2
106 166 60 30.5 0.1 0.2
SA-15 280 -60 150 0 44 44 37.2 0.4 0.5
includes 34 40 6 113.3 1.2 1.1
114 122 8 50.8 0.2 0.3
136 146 10 56.6 0.3 0.3
SA-15A 100 -70 148 4 128 124 32.0 0.3 0.6
includes 4 16 12 66.7 0.2 0.4
and 104 120 16 82.8 0.5 0.8
SA-16 303 -70 153 6 114 108 35.0 0.3 0.4
includes 12 18 6 116.3 1.0 0.6
and 36 48 12 88.3 0.9 0.4
72 76 4 100.0 0.6 0.8
SA-17 270 -60 152 2 74 72 31.6 0.3 0.7
116 128 12 55.8 0.5 1.1
SA-19 123 -60 124 2 40 38 41.0 0.2 0.3
58 98 40 23.3 0.2 0.4
includes 72 76 4 88.5 0.2 0.3
90
Table 5. Drill holes results, Phase 3.
Silver
Total Interval
Drill Hole Azimuth Inclination From To (grams Lead Zinc
Depth (m)
# (degrees) (degrees) (m) (m) per (%) (%)
(m) DTH
tonne)
SA-29 270 -50 218 44 112 68 38.4 0.2 0.6
includes 80 104 24 73.2 0.3 0.7
150 168 18 218.1 0.5 0.7
200 206 6 37.7 2.0 1.0
SA-29A 90 -45 166 2 68 66 66.4 0.2 0.5
includes 24 40 16 119.5 0.4 1.0
and 60 66 6 286.3 0.2 0.1
SA-29B 90 -75 173 34 48 14 27.0 0.2 0.5
66 150 84 35.9 0.2 0.5
includes 68 72 4 82.5 0.4 1.0
and 88 102 14 82.4 0.2 0.4
SA-30 270 -40 185 18 30 12 59.0 0.2 0.3
64 94 30 102.5 0.4 0.8
includes 70 80 10 145.2 0.4 0.9
and 86 94 8 153.0 0.6 1.1
124 152 28 48.4 0.3 0.6
includes 124 130 6 77.0 0.1 0.3
SA-31 280 -40 213
includes 62 98 36 81.3 0.3 0.4
and 116 120 4 97.0 0.2 0.2
and 158 160 2 180.0 0.6 1.0
SA-31A 100 -60 141 4 94 90 24.9 0.1 0.2
includes 86 92 6 83.7 0.3 0.3
SA-32A 105 -60 156 32 102 70 48.3 0.5 0.8
91
Table 6. Drill holes results, Phase 3, continued.
Silver
Drill Total Interval
Azimuth Inclination From To (grams Lead Zinc
Hole Depth (m)
(degrees) (degrees) (m) (m) per (%) (%)
# (m) DTH
tonne)
SA-35 270 -60 257.2 0 244 244 29.5 0.3 0.5
includes 82 94 12 122.5 1.0 0.9
and 116 140 24 84.9 0.6 1.0
and 188 192 4 90.0 0.1 0.1
SA-35A 90 -60 257.0 44 50 6 35.3 0.2 0.3
58 68 10 30.8 0.2 0.4
98 100 2 78.0 0.6 0.6
130 162 32 36.4 0.2 0.3
180 220 40 182.1 0.4 0.4
includes 204 208 4 1532.0 2.4 2.4
SA-35B 180 -60 242.0 0 100 100 18.8 0.2 0.5
138 210 72 37.8 0.2 0.3
includes 184 208 24 65.0 0.3 0.3
SA-36 300 -60 204.9 14 34 20 46.0 0.2 0.3
52 66 14 39.7 0.5 0.9
138 188 50 34.2 0.2 0.3
includes 146 158 12 61.5 0.1 0.2
SA-36A 120 -60 210.0 10 190 180 17.6 0.1 0.3
includes 116 130 14 101.6 0.3 0.3
SA-37 270 -60 210.5 46 48 2 100.0 0.6 1.5
66 110 44 32.0 0.2 0.4
includes 100 108 8 72.8 0.3 0.6
SA-37A 90 -70 215.2 42 194 152 45.9 0.4 0.8
includes 56 64 8 140.8 1.3 2.0
and 130 154 24 114.2 0.6 1.3
and 178 182 4 96.0 1.0 1.4
SA-38 270 -60 161.0 60 126 66 51.8 0.3 0.5
includes 78 90 12 138.0 0.6 0.7
SA-38A 90 -60 224.0 34 216 182 30.3 0.3 0.5
includes 180 188 8 164.5 1.3 1.5
SA-38B 135 -60 200 54 78 24 53.8 0.7 1.1
90 106 16 53.4 1.0 1.8
114 144 30 90.0 0.9 1.7
SA-39 300 -60 223.0 0 14 14 12.6 0.3 0.3
and 104 164 60 14.0 0.1 0.1
and 196 214 18 17.5 0.1 0.3
SA-39A 120 -60 190 0 120 120 53.4 0.7 1.1
includes 66 72 6 325.0 1.2 3.1
140 154 14 51.9 0.5 0.3
92
Table 7. ALS Shaker Test.
93
Table 8. Plenge Bottle Roll Test.
94
Table 9. McClelland Bottle Roll Test.
Lime
Calculated Residue: Extraction NaCN Consumption
SAMPLE Head Ag (g/t) g/t Ag % Consumption kg/t kg/t
2205 57.89 15.33 73.5% 0.20 4.7
2209 156.55 61.33 60.8% 0.98 6.1
58537 220.08 34.67 84.2% 3.18 3.7
58542 75.82 17.67 76.7% 2.26 3.0
58775 123.75 37.67 69.6% 0.37 5.2
58795 70.94 32.33 54.4% 4.13 2.1
58929 159.96 49.33 69.2% 1.42 4.9
58942 61.12 18.33 70.0% 2.00 3.7
59083 53.14 17.67 66.7% 0.34 5.9
59142 109.06 13.67 87.5% 1.52 2.7
Average 108.83 29.80 71.3% 1.64 4.2
95