TANGGAL ANALISA : 29-Jan-2018

Pelarut yang digunakan adalah metanol + 1% Asam Asetat

Semua sampel dilakukan:

- melarutkan 4 mg kurkuminoid standard (Merck) dalam 10 mL NADES = 400 mg/L = 400 ppm
faktor pengenceran = 100 x WAKTU AWAL ULTRASONIK
Waktu Interval pH Pelarut
No Tipe NADES Pengambilan diukur dari Percobaan (MeOH+1%
ke-
Sampel t=0 AcOH)
FG-H2O = 1:1:7
1
2 kurkuminoid dilarutkan dlm NADES: 8:35 5 menit 3.407
29-01-2018
2

1
8:55 21 menit 3.407
2

1
9:22 52 menit 3.407
2

1
10:26 112 menit 3.407
2

1 3.407
11:30 3 jam
2 3.481

1
14:30 6 jam 3.481
2

1
20:30 12 jam 3.805
2

1
8:43 24 jam 3.487
2

1
11:00 26,5 jam 3.487
 1
11:00 26,5 jam 3.487
2

1
12:30 28 jam 3.504
2

1 3.504
14:30 30 jam
2 3.419

1
18:30 34 jam 3.419
2

1
6:47 46 jam 3.491
2

1
9:33 49 jam 3,491
2

1
13:32 53 jam 3.491
2

1
16:32 56 jam 3.491
2

1
6:52 70 jam 3.478
2

1
9:30 73 jam 3.478
2

1
13:30 77 jam 3.446
2

1
16:32 80 jam 3.446
16:32 80 jam 3.446
2

1
82 jam
2

1
93 jam
2

1
96 jam
2
WAKTU AWAL ULTRASONIK 8:15 pencampuran sempurna
Tanggal Penambahan
pH Larutan
Tanggal ukur pH dan (MeOH+1% Vol. Curcumin
AcOH) pembuatan buffer pH Acetic acid
absorbansi + curcumin 400 ppm (μL)
pelarut 4,01 glacial (tetes)

29 Januari 2018 3.534 29 Januari 2018 100 - 3

29 Januari 2018 3.629 29 Januari 2018 100 - 8

29 Januari 2018 3.708 29 Januari 2018 100 - 11

29 Januari 2018 3.6 29 Januari 2018 100 - 5

29 Januari 2018 3.671 29 Januari 2018 100 - 10

29 Januari 2018 3.637 29 Januari 2018 100 - 7

29 Januari 2018 3.668 29 Januari 2018 100 - 8

29 Januari 2018 3.68 29 Januari 2018 100 - 8

29 Januari 2018 3.644 29 Januari 2018 100 - 8

29 Januari 2018 3.64 29 Januari 2018 100 - 8

29 Januari 2018 3.579 29 Januari 2018 100 - 6

29 Januari 2018 3.593 29 Januari 2018 100 - 6

29 Januari 2018 3.752 29 Januari 2018 100 - 15

29 Januari 2018 3.818 29 Januari 2018 100 - 15

30 Januari 2018 3.644 30 Januari 2018 100 - 10

30 Januari 2018 3.692 30 Januari 2018 100 - 13

30 Januari 2018 3.663 30 Januari 2018 100 - 10

30 Januari 2018 3.663 30 Januari 2018 100 - 10

30 Januari 2018 3.658 30 Januari 2018 100 - 10

30 Januari 2018 3.624 30 Januari 2018 100 - 9

30 Januari 2018 3.671 30 Januari 2018 100 - 10

30 Januari 2018 3.649 30 Januari 2018 100 - 10

30 Januari 2018 3.649 30 Januari 2018 100 - 10

30 Januari 2018 3.576 30 Januari 2018 100 - 5

30 Januari 2018 3.61 30 Januari 2018 100 - 7

### 3.654 ### 100 - 8

### 3.608 ### 100 - 6

### 3.733 ### 100 - 10

### 3.748 ### 100 - 12

### 3.724 ### 100 - 10

### 3.857 ### 100 - 19

### 3.648 ### 100 - 8

### 3.713 ### 100 - 10

01 Februari 2018 3.68 01 Februari 2018 100 - 10

01 Februari 2018 3.672 01 Februari 2018 100 - 10

01 Februari 2018 3.645 01 Februari 2018 100 - 8

01 Februari 2018 3.669 01 Februari 2018 100 - 8

01 Februari 2018 3.584 01 Februari 2018 100 - 5

01 Februari 2018 3.615 01 Februari 2018 100 - 8

01 Februari 2018 3.703 01 Februari 2018 100 - 10

01 Februari 2018 3.632 01 Februari 2018 100 - 7

01 Februari 2018 01 Februari 2018 100 -

01 Februari 2018 01 Februari 2018 100 -

### ### 100 -

### ### 100 -

### ### 100 -

### ### 100 -

pencampuran sempurna (t = 0) 8:30
ABS
Vol. Total pH larutan
Larutan (mL) final 1 2 3 4 Average

0.599 0.602 0.603 0.596 0.600

10 3.49
9:39 9:40 9:41 9:41
0.681 0.680 0.679 0.681 0.680
10 3.468
9:56 9:57 9:58 9:58
0.61 0.605 0.612 0.614 0.610
10 3.499
10:33 10:34 10:35 10:35
0.639 0.634 0.632 0.621 0.632
10 3.488
10:45 10:46 10:47 10:47
0.6 0.601 0.602 0.601 0.601
10 3.459
10:58 10:59 10:59 11:00
0.633 0.636 0.639 0.641 0.637
10 3.5
11:10 11:12 11:12 11:13
0.673 0.677 0.674 0.66 0.671
10 3.478
11:25 11:26 11:27 11:27
0.631 0.627 0.633 0.655 0.637
10 3.499
11:41 11:42 11:43 11:44
0.718 0.715 0.711 0.72 0.716
10 3.462
11:54 11:55 11:56 11:56
0.732 0.726 0.725 0.728 0.728
10 3.494
12:08 12:09 12:10 12:11
0.694 0.698 0.701 0.692 0.696
10 3.443
14:52 14:53 14:53 14:54
0.688 0.684 0.682 0.681 0.684
10 3.473
15:01 15:01 15:01 15:03
0.768 0.767 0.769 0.774 0.770
10 3.486
20:51 20:52 20:52 20:53
0.726 0.731 0.723 0.727 0.727
10 3.498
20:59 21:00 21:01 21:01
0.925 0.925 0.922 0.917 0.922
10 3.438
9:36 9:36 9:37 9:37
0.958 0.953 0.955 0.95 0.954
10 3.408
9:54 9:55 9:55 9:56
0.831 0.835 0.829 0.837 0.833
10 3.445
10 3.445
12:15 12:17 12:17 12:19
0.803 0.805 0.800 0.801 0.802
10 3.433
12:23 12:24 12:25 12:26
0.788 0.766 0.772 0.766 0.773
10 3,432
12:49 12:50 12:51 12:51
0.789 0.786 0.792 0.784 0.788
10 3.446
12:55 12:57 12:57 12:58
0.905 0.905 0.914 0.902 0.907
10 3.447
15:20 15:21 15:22 15:23
0.85 0.853 0.846 0.852 0.850
10 3.412
15:34 15:35 15:36 15:36
0.678 0.692 0.695 0.706 0.693
10 3.443
18:41 18:42 18:43 18:44
0.846 0.848 0.847 0.846 0.847
10 3.429
18:46 18:47 18:48 18:48
0.708 0.705 0.695 0.701 0.702
10 3.481
7:37 7:38 7:39 7:39
0.795 0.786 0.775 0.784 0.785
10 3.483
7:58 7:58 8:00 8:01
0.776 0.769 0.765 0.774 0.771
10 3.481
9:51 9:52 9:52 9:53
0.803 0.808 0.811 0.811 0.808
10 3.496
9:59 10:00 10:00 10:01
0.467 0.477 0.47 0.468 0.471
10 3.486
13:46 13:47 13:48 13:48
0.476 0.473 0.466 0.463 0.470
10 3.483
14:07 14:08 14:09 14:11
0.442 0.433 0.446 0.442 0.441
10 3.436
16:46 16:47 16:48 16:49
0.437 0.429 0.43 0.435 0.433
10 3.478
16:54 16:55 16:55 16:56
0.453 0.457 0.452 0.451 0.453
10 3.458
7:36 7:37 7:38 7:38
0.48 0.471 0.466 0.466 0.471
10 3.427
7:44 7:45 7:45 7:46
0.612 0.613 0.627 0.625 0.619
10 3.465
10:04 10:05 10:05 10:06
0.558 0.553 0.557 0.552 0.555
10 3.443
10:13 10:14 10:15 10:16
0.436 0.435 0.433 0.443 0.437
10 3.438
14:58 14:59 15:00 15:01
0.432 0.43 0.433 0.431 0.432
10 3.434
15:04 15:05 15:05 15:06
0.462 0.468 0.475 0.459 0.466
10 3.479
17:25 17:26 17:27 17:27
 0.483 0.489 0.482 0.48 0.484
10 3.463
17:39 17:39 17:40 17:40
#DIV/0!
10

#DIV/0!
10

#DIV/0!
10

#DIV/0!
10

#DIV/0!
10

#DIV/0!
10
TANGGAL ANALISA : 15/12/2017

Waktu Pengambilan Interval diukur dari Percobaan

SAMPEL pH larutan*
Sampel t=0 ke-
1 3.49
FG-H2O = 1:1:7 8:35 5 menit
2 3.468

1 3.499
8:55 21 menit
2 3.488

1 3.459
9:22 52 menit
2 3.5

1 3.478
10:26 112 menit
2 3.499

1 3.462
11:30 3 jam
2 3.494

1 3.443
14:30 6 jam
2 3.473

1 3.486
20:30 12 jam
2 3.498

1 3.438
8:43 24 jam
2 3.408

1 3.445
11:00 26,5 jam
2 3.433

1 3432
12:30 28 jam
2 3.446
12:30 28 jam
2 3.446

1 3.447
14:30 30 jam
2 3.412

1 3.443
18:30 34 jam
2 3.429

1 3.481
6:47 46 jam
2 3.483

1 3.481
9:33 49 jam
2 3.496

1 3.486
13:32 53 jam
2 3.483

1 3.436
16:32 56 jam
2 3.478

1 3.458
6:52 70 jam
2 3.427

1 3.465
9:30 73 jam
2 3.443

1 3.438
13:30 77 jam
2 3.434

1 3.479
16:32 80 jam
2 3.463

1 0
0:00 82 jam
2 0
0:00 82 jam
2 0

1 0
0:00 93 jam
2 0

1 0
0:00 96 jam
2 0

Waktu
Pengambilan Interval diukur
dari t=0
Sampel

8:35 5 menit

8:55 21 menit

9:22 52 menit

10:26 112 menit

11:30 3 jam

14:30 6 jam

20:30 12 jam

8:43 24 jam
8:43 24 jam

11:00 26,5 jam

12:30 28 jam

14:30 30 jam

18:30 34 jam

6:47 46 jam

9:33 49 jam

13:32 53 jam

16:32 56 jam

6:52 70 jam

9:30 73 jam

13:30 77 jam
13:30 77 jam

16:32 80 jam

0:00 82 jam

0:00 93 jam

0:00 96 jam
 (xi-xav)^2
Run-1 Run-2 Run-3 Run-4 average
Run-1 Run-2 Run-3
0.599 0.602 0.603 0.596 0.600 1.00E-06 4.00E-06 9.00E-06

0.681 0.68 0.679 0.681 0.680 5.63E-07 6.25E-08 1.56E-06

0.61 0.605 0.612 0.614 0.610 6.25E-08 2.76E-05 3.06E-06

0.639 0.634 0.632 0.621 0.632 5.62E-05 6.25E-06 2.50E-07

0.6 0.601 0.602 0.601 0.601 1.00E-06 0.00E+00 1.00E-06

0.633 0.636 0.639 0.641 0.637 1.81E-05 1.56E-06 3.06E-06

0.673 0.677 0.674 0.66 0.671 4.00E-06 3.60E-05 9.00E-06

0.631 0.627 0.633 0.655 0.637 3.03E-05 9.03E-05 1.23E-05

0.718 0.715 0.711 0.72 0.716 4.00E-06 1.00E-06 2.50E-05

0.732 0.726 0.725 0.728 0.728 1.81E-05 3.06E-06 7.56E-06

0.694 0.698 0.701 0.692 0.696 5.06E-06 3.06E-06 2.26E-05

0.688 0.684 0.682 0.681 0.684 1.81E-05 6.25E-08 3.06E-06

0.768 0.767 0.769 0.774 0.770 2.25E-06 6.25E-06 2.50E-07

0.726 0.731 0.723 0.727 0.727 5.62E-07 1.81E-05 1.41E-05

0.925 0.925 0.922 0.917 0.922 7.56E-06 7.56E-06 6.25E-08

0.958 0.953 0.955 0.95 0.954 1.60E-05 1.00E-06 1.00E-06

0.831 0.835 0.829 0.837 0.833 5.70E-03 5.11E-03 6.01E-03

0.803 0.805 0.8 0.801 0.802 2.23E-03 2.05E-03 2.53E-03

0.788 0.766 0.772 0.766 0.773 9.07E-03 5.37E-03 6.28E-03

0.789 0.786 0.792 0.784 0.788 3.34E-03 3.69E-03 3.00E-03

0.789 0.786 0.792 0.784 0.788 3.34E-03 3.69E-03 3.00E-03

0.905 0.905 0.914 0.902 0.907 2.25E-06 2.25E-06 5.62E-05

0.85 0.853 0.846 0.852 0.850 6.25E-08 7.56E-06 1.81E-05

0.678 0.692 0.695 0.706 0.693 2.18E-04 5.63E-07 5.06E-06

0.846 0.848 0.847 0.846 0.847 5.63E-07 1.56E-06 6.25E-08

0.708 0.705 0.695 0.701 0.702 3.31E-05 7.56E-06 5.26E-05

0.795 0.786 0.775 0.784 0.785 1.00E-04 1.00E-06 1.00E-04

0.776 0.769 0.765 0.774 0.771 2.50E-05 4.00E-06 3.60E-05

0.803 0.808 0.811 0.811 0.808 2.76E-05 6.25E-08 7.56E-06

0.467 0.477 0.47 0.468 0.471 1.22E-05 4.23E-05 2.50E-07

0.476 0.473 0.466 0.463 0.470 4.22E-05 1.22E-05 1.23E-05

0.442 0.433 0.446 0.442 0.441 1.56E-06 6.01E-05 2.76E-05

0.437 0.429 0.43 0.435 0.433 1.81E-05 1.41E-05 7.56E-06

0.453 0.457 0.452 0.451 0.453 6.25E-08 1.41E-05 1.56E-06

0.48 0.471 0.466 0.466 0.471 8.56E-05 6.25E-08 2.26E-05

0.612 0.613 0.627 0.625 0.619 5.26E-05 3.91E-05 6.01E-05

0.558 0.553 0.557 0.552 0.555 9.00E-06 4.00E-06 4.00E-06

0.436 0.435 0.433 0.443 0.437 5.63E-07 3.06E-06 1.41E-05

0.432 0.43 0.433 0.431 0.432 2.50E-07 2.25E-06 2.25E-06

0.462 0.468 0.475 0.459 0.466 1.60E-05 4.00E-06 8.10E-05

0.483 0.489 0.482 0.48 0.484 2.50E-07 3.03E-05 2.25E-06

0 0 0 0 0.000 0.00E+00 0.00E+00 0.00E+00

0 0 0 0 0.000 0.00E+00 0.00E+00 0.00E+00

 0 0 0 0 0.000 0.00E+00 0.00E+00 0.00E+00

0 0 0 0 0.000 0.00E+00 0.00E+00 0.00E+00

0 0 0 0 0.000 0.00E+00 0.00E+00 0.00E+00

0 0 0 0 0.000 0.00E+00 0.00E+00 0.00E+00

0 0 0 0 0.000 0.00E+00 0.00E+00 0.00E+00

konsentrasi kurkumin average

dilakukan average
curcumin pH sampel dilarutkan recovery SD (%) RSD (%)
pengukuran %recovery
(ppm) dlm NADES (ppm)

4 3.49 1/29/2018 1/29/2018 3.371 84.29% 0.32% 0.53%

4 3.468 1/29/2018 1/29/2018 3.839 95.98% 0.10% 0.14%

4 3.499 1/29/2018 1/29/2018 3.431 85.78% 0.39% 0.63%

4 3.488 1/29/2018 1/29/2018 3.555 88.88% 0.76% 1.20%

4 3.459 1/29/2018 1/29/2018 3.377 84.43% 0.08% 0.14%

4 3.5 1/29/2018 1/29/2018 3.589 89.72% 0.35% 0.55%

4 3.478 1/29/2018 1/29/2018 3.785 94.64% 0.75% 1.12%

4 3.499 1/29/2018 1/29/2018 3.584 89.61% 1.26% 1.98%

4 3.462 1/29/2018 1/29/2018 4.048 101.20% 0.39% 0.55%

4 3.494 1/29/2018 1/29/2018 4.116 102.91% 0.31% 0.43%

4 3.443 1/29/2018 1/29/2018 3.933 98.32% 0.40% 0.58%

4 3.473 1/29/2018 1/29/2018 3.860 96.49% 0.31% 0.45%

4 3.486 1/29/2018 1/29/2018 4.360 108.99% 0.31% 0.40%

4 3.498 1/29/2018 1/29/2018 4.110 102.76% 0.33% 0.45%

4 3.438 1/30/2018 1/30/2018 5.250 131.26% 0.38% 0.41%

4 3.438 1/30/2018 1/30/2018 5.250 131.26% 0.38% 0.41%

4 3.408 1/30/2018 1/30/2018 5.436 135.89% 0.34% 0.35%

4 3.445 1/30/2018 1/30/2018 4.730 118.25% 8.49% 10.20%

4 3.433 1/30/2018 1/30/2018 4.551 113.77% 5.55% 6.91%

4 3432 1/30/2018 1/30/2018 4.380 109.50% 9.32% 12.06%

4 3.446 1/30/2018 1/30/2018 4.466 111.65% 6.82% 8.66%

4 3.447 1/30/2018 1/30/2018 5.159 128.97% 0.52% 0.57%

4 3.412 1/30/2018 1/30/2018 4.831 120.77% 0.31% 0.36%

4 3.443 1/30/2018 1/30/2018 3.912 97.81% 1.15% 1.66%

4 3.429 1/30/2018 1/30/2018 4.810 120.26% 0.10% 0.11%

4 3.481 1/31/2018 1/31/2018 3.968 99.19% 0.56% 0.80%

4 3.483 1/31/2018 1/31/2018 4.450 111.25% 0.82% 1.05%

4 3.481 1/31/2018 1/31/2018 4.369 109.21% 0.50% 0.64%

4 3.496 1/31/2018 1/31/2018 4.586 114.64% 0.38% 0.47%

4 3.486 1/31/2018 1/31/2018 2.616 65.41% 0.45% 0.96%

4 3.483 1/31/2018 1/31/2018 2.610 65.26% 0.60% 1.28%

4 3.436 1/31/2018 1/31/2018 2.443 61.07% 0.55% 1.25%

4 3.478 1/31/2018 1/31/2018 2.396 59.91% 0.39% 0.89%

4 3.458 2/1/2018 2/1/2018 2.516 62.89% 0.26% 0.58%

4 3.427 2/1/2018 2/1/2018 2.618 65.44% 0.66% 1.40%

4 3.465 2/1/2018 2/1/2018 3.484 87.09% 0.78% 1.27%

4 3.443 2/1/2018 2/1/2018 3.109 77.73% 0.29% 0.53%

4 3.438 2/1/2018 2/1/2018 2.420 60.49% 0.43% 1.00%

4 3.438 2/1/2018 2/1/2018 2.420 60.49% 0.43% 1.00%

4 3.434 2/1/2018 2/1/2018 2.389 59.72% 0.13% 0.30%

4 3.479 2/1/2018 2/1/2018 2.590 64.75% 0.71% 1.52%

4 3.463 2/1/2018 2/1/2018 2.692 67.30% 0.39% 0.80%

4 0 2/1/2018 2/1/2018 -0.127 -3.18% 0.00% #DIV/0!

4 0 2/1/2018 2/1/2018 -0.127 -3.18% 0.00% #DIV/0!

4 0 2/2/2018 2/2/2018 -0.127 -3.18% 0.00% #DIV/0!

4 0 2/2/2018 2/2/2018 -0.127 -3.18% 0.00% #DIV/0!

4 0 2/2/2018 2/2/2018 -0.127 -3.18% 0.00% #DIV/0!

4 0 2/2/2018 2/2/2018 -0.127 -3.18% 0.00% #DIV/0!

 RSD = SD/ average
)^2 *pH larutan = setelah di adjust dgn buffer
Ʃ(xi-xav)^2 SD (%) RSD (%) recovery % recovery
Run-4
1.60E-05 3.00E-05 0.32% 0.53% 3.371 84.29%

5.63E-07 2.75E-06 0.10% 0.14% 3.839 95.98%

1.41E-05 4.48E-05 0.39% 0.63% 3.431 85.78%

1.10E-04 1.73E-04 0.76% 1.20% 3.555 88.88%

0.00E+00 2.00E-06 0.08% 0.14% 3.377 84.43%

1.41E-05 3.68E-05 0.35% 0.55% 3.589 89.72%

1.21E-04 1.70E-04 0.75% 1.12% 3.785 94.64%

3.42E-04 4.75E-04 1.26% 1.98% 3.584 89.61%

1.60E-05 4.60E-05 0.39% 0.55% 4.048 101.20%

6.25E-08 2.88E-05 0.31% 0.43% 4.116 102.91%

1.81E-05 4.88E-05 0.40% 0.58% 3.933 98.32%

7.56E-06 2.87E-05 0.31% 0.45% 3.860 96.49%

2.02E-05 2.90E-05 0.31% 0.40% 4.360 108.99%

6.25E-08 3.28E-05 0.33% 0.45% 4.110 102.76%

2.76E-05 4.28E-05 0.38% 0.41% 5.250 131.26%

1.60E-05 3.40E-05 0.34% 0.35% 5.436 135.89%

4.83E-03 2.16E-02 8.49% 10.20% 4.730 118.25%

2.43E-03 9.23E-03 5.55% 6.91% 4.551 113.77%

5.37E-03 2.61E-02 9.32% 12.06% 4.380 109.50%

3.94E-03 1.40E-02 6.82% 8.66% 4.466 111.65%

3.94E-03 1.40E-02 6.82% 8.66% 4.466 111.65%

2.03E-05 8.10E-05 0.52% 0.57% 5.159 128.97%

3.06E-06 2.88E-05 0.31% 0.36% 4.831 120.77%

1.76E-04 3.99E-04 1.15% 1.66% 3.912 97.81%

5.63E-07 2.75E-06 0.10% 0.11% 4.810 120.26%

1.56E-06 9.48E-05 0.56% 0.80% 3.968 99.19%

1.00E-06 2.02E-04 0.82% 1.05% 4.450 111.25%

9.00E-06 7.40E-05 0.50% 0.64% 4.369 109.21%

7.56E-06 4.28E-05 0.38% 0.47% 4.586 114.64%

6.25E-06 6.10E-05 0.45% 0.96% 2.616 65.41%

4.23E-05 1.09E-04 0.60% 1.28% 2.610 65.26%

1.56E-06 9.08E-05 0.55% 1.25% 2.443 61.07%

5.06E-06 4.48E-05 0.39% 0.89% 2.396 59.91%

5.06E-06 2.08E-05 0.26% 0.58% 2.516 62.89%

2.26E-05 1.31E-04 0.66% 1.40% 2.618 65.44%

3.31E-05 1.85E-04 0.78% 1.27% 3.484 87.09%

9.00E-06 2.60E-05 0.29% 0.53% 3.109 77.73%

3.91E-05 5.68E-05 0.43% 1.00% 2.420 60.49%

2.50E-07 5.00E-06 0.13% 0.30% 2.389 59.72%

4.90E-05 1.50E-04 0.71% 1.52% 2.590 64.75%

1.23E-05 4.50E-05 0.39% 0.80% 2.692 67.30%

0.00E+00 0.00E+00 0.00% #DIV/0! -0.127 -3.18%

0.00E+00 0.00E+00 0.00% #DIV/0! -0.127 -3.18%

0.00E+00 0.00E+00 0.00% #DIV/0! -0.127 -3.18%

0.00E+00 0.00E+00 0.00% #DIV/0! -0.127 -3.18%

0.00E+00 0.00E+00 0.00% #DIV/0! -0.127 -3.18%

0.00E+00 0.00E+00 0.00% #DIV/0! -0.127 -3.18%

0.00E+00 0.00E+00 0.00% #DIV/0! -0.127 -3.18%

konsentrasi
waktu average average average RSD
waktu (jam) (menit) terdeteksi

R eco very ra ta -ra ta (% )

%recovery SD (%) (%) (ppm)

0.08 5 90.13% 0.21% 0.33% 3.605

0.33 20 87.33% 0.57% 0.92% 3.493
0.87 52 87.07% 0.22% 0.34% 3.483
120%
1.87 112 92.12% 1.01% 1.55% 3.685
3 180 102.05% 0.35% 0.49% 4.082 110%
6 360 97.41% 0.36% 0.52% 3.896
100%
12 720 105.88% 0.32% 0.43% 4.235
24 1440 133.58% 0.36% 0.38% 5.343 90%
26.5 1590 116.01% 7.02% 8.56% 5.083
80%
28 1680 110.58% 8.07% 10.36% 5.083
30 1800 124.87% 0.41% 0.47% 4.995 70%
34 2040 109.03% 0.62% 0.89% 4.361
60%
46 2760 105.22% 0.69% 0.92% 4.209

ku rku m in o id te rd ete ks i (p p m )
49 2940 111.93% 0.44% 0.56% 4.477
53 3180 65.34% 0.53% 1.12% 2.613
56 3360 60.49% 0.47% 1.07% 2.420
70 4200 64.17% 0.46% 0.99% 2.567
73 4380 82.41% 0.72% 1.33% 3.296
77 4620 60.11% 0.72% 1.33% 2.404
80 4800 66.03% 0.54% 0.90% 2.641
7.0
82 4920 -3.18% 0.54% 0.90% -0.127
93 5580 -3.18% 0.00% #DIV/0! -0.127 6.5
96 5760 -3.18% 0.00% #DIV/0! -0.127 6.0

5.5

3.2 ppm 5.0

4.4 ppm 4.5

4.0

3.5

3.0
5.0

4.5

4.0

3.5

3.0
elah di adjust dgn buffer or AcOH

y = 0,1715 x + 0,0218 R2 = 0.9981

recovery dihitung berdasarkan kurva linear pd linearisasi
slope = 0.1715
intercept = 0.0218
R eco very ra ta -ra ta (% )

120%

110%

100%

90%

80%

70%

60%
0 20 40 60 80 100 120
waktu (jam)
ku rku m in o id te rd ete ks i (p p m )

7.000

6.500

6.000

5.500

5.000

4.500

4.000

3.500

3.000
0 10 20 30 40 50 60 70 80 90 100

waktu (jam)
5.000

4.500

4.000

3.500

3.000
0 10 20 30 40 50 60 70 80 90 100

waktu (jam)