Leader Test Series / Joint Package Course: Distance Learning Programme

Paper Code : 0999DT110316001
DISTANCE LEARNING PROGRAMME

(Academic Session : 2016 - 2017)
LEADER TEST SERIES / JOINT PACKAGE COURSE

TARGET : JEE (Main + Advanced) 2017
Test Type : UNIT TEST TEST # 01 Test Pattern : JEE-Advanced
TEST DATE : 10 - 07 - 2016
Time : 3 Hours Maximum Marks : 270

READ THE INSTRUCTIONS CAREFULLY /   
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR / 
GENERAL / 

1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so.

2. Use the Optical Response sheet (ORS) provided separately for answering the questions.

(ORS) 
3. Blank spaces are provided within this booklet for rough work.

4. Write your name, form number and sign in the space provided on the back cover of this booklet.

5. After breaking the seal of the booklet, verify that the booklet contains 44 pages and that all the 23
questions in each subject and along with the options are legible. If not, contact the invigilator for
replacement of the booklet.

44 
23 

6. You are allowed to take away the Question Paper at the end of the examination.

OPTICAL RESPONSE SHEET / 
7. The ORS will be collected by the invigilator at the end of the examination.

8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.


9. Write your name, form number and sign with pen in the space provided for this purpose on the ORS.
Do not write any of these details anywhere else on the ORS. Darken the appropriate bubble
under each digit of your form number.



DARKENING THE BUBBLES ON THE ORS / 
10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.



11. Darken the bubble COMPLETELY. /   

12. The correct way of darkening a bubble is as : / 

:
13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct way.

14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase or "un-darken"
a darkened bubble.

15. Take g = 10 m/s2 unless otherwise stated. / g = 10 m/s2 
Please see the page 43 of this booklet for rest of the instructions / 
43 
Target : JEE (Main + Advanced) 2017/10-07-2016
SOME USEFUL CONSTANTS

Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
 Boltzmann constant k = 1.38 × 10–23 JK–1

1
 Coulomb's law constant = 9 ×10 9
4 0
 Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
 Speed of light in vacuum c = 3 × 108 ms–1
 Stefan–Boltzmann constant  = 5.67 × 10–8 Wm–2 –K–4
 Wien's displacement law constant b = 2.89 × 10–3 m–K
 Permeability of vacuum µ0 = 4 × 10–7 NA–2
1
 Permittivity of vacuum 0 =
0 c2
 Planck constant h = 6.63 × 10–34 J–s
Space for Rough Work / 
Note : In case of any correction in the test paper, please mail to dlpcorrections@allen.ac.in within 2 days along with Paper Code
& Your Form No.
(

Correction  Paper Code Form No.  Test Details 
dlpcorrections@allen.ac.in  mail)
LTS-2/44 0999DT110316001
Leader Test Series/Joint Package Course/10-07-2016
HAVE CONTROL  HAVE PATIENCE  HAVE CONFIDENCE  100% SUCCESS
PHYSICS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
     
-1 :  
SECTION–I(i) : (Maximum Marks : 18)
–I(i) : ( : 18)
 This section contains SIX questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options
is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases
   
  
   
  
(A), (B), (C) (D)  
    
               
       
 

   
 : +3           
 : 0         
  : –1    
1. Two particles are held in equilibrium by the gravitational and electrostatic forces between them.
Particle-A has mass ma and charge qa and particle-B has mass mb and charge qb. The distance
between the charges is d. Which of the following changes may cause the charges to accelerate
towards one another?
(A) ma is doubled and mb is halved. (B) ma is double and mb is doubled.
(C) qa is doubled and qb is doubled. (D) d is doubled.

A
ma  
qaB
mb qb 
d

(A) mb
mb  (B) ma 
mb
(C) qa 
qb (D) d 
0999DT110316001 LTS-3/44
2. A particle of mass m and charge –q is projected from the origin with a horizontal speed v into an
PHYSICS
electric field of intensity E directed downward. Choose the wrong statement. (Consider +y axis
in upward direction and x-axis in horizontal direction. Also neglect the effect of gravity)
y

E
x
(A) The kinetic energy after a vertical displacement y is qEy.
qE
(B) The horizontal and vertical components of acceleration are ax = 0, a y 
m
1  qEx 2 
(C) The equation of trajectory is y   
2  mv 2 
1
(D) The horizontal and vertical displacements x and y after a time t are x = vt and y  a yt 2
2
m 
–q 
v 
E 

(+y 
x 

)
y

E
(A) 
y 
qEy 
qE
(B) 
ax = 0, a y  
m
1  qEx 2 
(C) 
y   
2  mv 2 
1
(D)  t 
x = vt 
y a yt 2 
2
LTS-4/44 0999DT110316001
3. The hour hand of a clock is 6 cm long. The magnitude of the displacement of the tip of hour hand
PHYSICS
between 1:00 pm to 5:00 pm. is :

6 cm 
1:00 pm 5:00 pm 

(A) 6 cm (B) 6 3 cm (C) 4 cm (D) 3 3 cm

4. A particle is moving under the influence of force F  [iˆ  2j]N ˆ , is now moved from the point

(x, y, z) = (2, 1, 3) m to the point (x, y, z) = (3, 2, 4) m. How much work is done by the force F
 
during this time period? (W = F  s )
(A) 0 J (B) –1 J (C) 1 J (D) None of these

 F  [iˆ  2j]N
ˆ 
(x, y, z) = (2, 1, 3) m 
(x, y, z) = (3, 2, 4) m
  

F (W = F  s )
(A) 0 J (B) –1 J (C) 1 J (D) 
5. A non conducting infinite rod is placed along the z-axis : the upper half of the rod
(lying along z  0) is charged positively with a uniform linear charge density + while the lower
half (z < 0) is charged negatively with a uniform linear charge density –. The origin is located at
the junction of the positive and negative halves of the rod. A uniformly charged annular disc
(surface charge density : 0) of inner radius R and outer radius 2R is placed in the x-y plane with
its centre of the origin. The force on the rod due to the disc is :-
 z-z
 0 

+ 
z < 0 
– 


x-y 
R 
2R 
(
: 0) 
20 R 0  R 0  R 0  R
(A) 0 (B) 2 (C) 0 (D) 3
0 0
6. Water pours out at the rate of Q from a tap, into a cylindrical vessel of radius r. The rate at
which the height of water level rises when the height is h, is
Qr 
h


Q Q Q Q
(A) (B) (C) (D)
rh r 2 2r 2 r 2h
0999DT110316001 LTS-5/44
SECTION–I(ii) : (Maximum Marks : 20)
PHYSICS
–I(ii) : ( : 20)

 This section contains FIVE questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Negative Marks : –1 In all other cases.
   
 
   
  
(A), (B), (C)  (D)  
      
               
       
 


   
  : +4            
  : 0         
  : –1    
7. Refer the block diagram in which four function machines are shown. Which of the following
statements is/are true?

Input Output Output Output Output
(x) (y) (z) (u) (v)
Double the input Square root
of the Differentiate the Multiply the input
and add three input input with respect dy
to y with
dx
dz 1 dz 1
(A) u   (B) u  
dy 2 2x  3 dy 4 2x  3
dz dz dy 1 dz dz dy 1
(C) v     (D) v    
dx dy dx 2x  3 dx dy dx 2 2x  3

8. x and y are the angle made by a vector A with positive x and positive y-axis respectively.
Which set of x and y is /are not possible?

A 
x-
y-
x 
y 
x 
y 

(A) 60°, 60° (B) 45°, 60° (C) 30°, 45° (D) 30°, 30°
LTS-6/44 0999DT110316001
9. The electrical resistance R of a component varies with temperature T according to expression
PHYSICS
R = Roek/T, where Ro and k are positive constants. A graph of the variation of lnR with reciprocal
of temperature T is drawn and a straight line is obtained. In the graph lnR is plotted on the
ordinate. Which of the following statement(s) correctly describe the graph?
(A) Slope of the straight line is k.
(B) Slope of the straight line is lnk.
(C) The straight line cuts the ordinate at lnRo.
(D) The straight line cuts the ordinate at Ro.

R,T
R = Roek/T
Ro  k

lnR
lnR

(A) 
k (B) 
lnk
(C) 
lnRo (D) 
Ro
10. The vector î  xjˆ  3kˆ is rotated through an angle  and doubled in magnitude, then it becomes
4iˆ  (4x  2)jˆ  2kˆ . The values of x are :-
 î  xjˆ  3kˆ 

 
4iˆ  (4x  2)jˆ  2kˆ 
x

2 1 2
(A)  (B) (C) (D) 2
3 3 3
0999DT110316001 LTS-7/44
11. In a uniformly charged dielectric sphere a very thin tunnel has been made along the diameter as
PHYSICS
shown in the figure below. A charge particle – q having mass m is released from rest at one end
of tunnel. For the situation described, mark out the correct statement (s) :- [Neglect gravity]
(A) Charged particle will perform SHM about centre of the sphere as mean position
4 0mR3
(B) Time period of the particle is 2 .
qQ
(C) Particle will perform oscillation but not SHM.
Qq
(D) Speed of the particle while crossing-mean position is 4 0 mR
–q
C R Charge Q
                
m  – q 
(
)
(A) 
4 0mR3
(B) 
2 
qQ
(C) 
Qq
(D) 
4  mR 
0
LTS-8/44 0999DT110316001
SECTION–I(iii) : (Maximum Marks : 12)
–I(iii) : ( :
PHYSICS
12)
 This section contains TWO paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options is
correct.
   
  
   
 
   
  

  
(A), (B), (C) 
(D)  
   
               
       
 


   
  : +3           
  : 0         
  : –1    
Paragraph for Questions 12 and 13
12 13   
A physical quantity which is completely specified by a number (magnitude) in terms of an
appropriate unit is known as a scalar quantity. Certain physical quantities can only be completely
specified by a number (magnitude) alongwith a proper unit, as well as direction such quantities
are known as vectors.
The dot product of two vectors is defined as the product of the magnitude of two vectors multiplied
by the cosine of the angle between the two. Dot product between two vectors can be positive, zero
or negative according as the angle between them is acute, 90° or obtuse. For two vectors
   
A  A x iˆ  A y ˆj  A z kˆ and B  Bx î  By ˆj  Bz kˆ the dot product A  B  A x Bx  A y By  A z Bz . The dot
product of two vectors is the product of two quantities one of which is the modulus of the first
vector (or second) and the other is the projection of second vector along the first (or the first vector
along the second).



(cosine)
 


90°
A  A x iˆ  A y ˆj  A z kˆ
  
B  Bx î  By ˆj  Bz kˆ  
A  B  A x Bx  A y By  A z Bz   


0999DT110316001 LTS-9/44
12. If the vectors 4iˆ  ˆj  3kˆ and 2miˆ  6mjˆ  kˆ are perpendicular to each other, then the value
PHYSICS
of m is
4iˆ  ˆj  3kˆ 2miˆ  6mjˆ  kˆ 
m
3 1 2
(A) (B)  (C)  (D) 12
14 8 3
 
13. Work done by a constant force F for displacement s is given by W  F  s . What is the work

ˆ
done by a force F  (4iˆ  2jˆ  6k)N ˆ
when its point of application gets displaced by (iˆ  ˆj  3k)m ?
    

s F  W  F  s  ˆ
F  (4iˆ  2jˆ  6k)N 
 ˆ
(iˆ  ˆj  3k)m 
(A) 18J (B) 20J (C) 30J (D) 24J
LTS-10/44 0999DT110316001
14 15   
PHYSICS
 K  r  r  
Electric field in a region is given by following equation E    20 where r  xiˆ  yjˆ and
r  r0

r0  î  ˆj and an imaginary cube is made as shown in the diagram.
 K r  r   
 

E    20 
r  xiˆ  yjˆ 
r0  î  ˆj 
r  r0

z
y
(0,2,0)
14. Find total flux through this cube due to the given electric field.

(flux)
(A) 4K (B) 6K (C) 16K (D) 8K
15. Find total charge encloses in this imaginary shown cube.

(A) 4K0 (B) 8K0 (C) 6K0 (D) 2K0
0999DT110316001 LTS-11/44
SECTION–II : (Maximum Marks : 16)
–II : (  :
PHYSICS
16)
 This section contains TWO questions.
 Each question contains two columns, Column-I and Column-II.
 Column-I has four entries (A), (B), (C) and (D)
 Column-II has five entries (P), (Q), (R), (S) and (T)
 Match the entries in Column-I with the entries in column-II.
 One or more entries in Column-I may match with one or more entries in Column-II.
 The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below :
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
 For each entry in column-I, darken the bubbles of all the matching entries. For example,
if entry (A) in Column-I matches with entries (Q), (R) and (T), then darken these three bubbles
in the ORS. Similarly, for entries (B), (C) and (D).
For each entry in Column-I
Full Marks : +2 If only the bubble(s) corresponding to all the correct match(es) is (are)
darkened
Zero Marks : 0 In all other cases
   

  
     
 -I
-II
  -I 
 
(A), (B), (C)  (D) 
  -II 
 
(P), (Q), (R), (S) (T) 
  -I   
-II    
  -I  -II  
    4 
× 5 
  
: 
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
 -I             
-I 
(A) 
(Q), (R) (T) 
   
(B), (C)  (D)   
  
:
-I     
  : +2            
  : 0    
LTS-12/44 0999DT110316001
1. Column-I gives the variation of electric intensity at P described in column II as a function of r.
PHYSICS
Column-II specifies a point at distance r from the centre/axis of a symmetrical distribution of
charge. Match the columns.
Column-II Column-I
1
(A) E (P) P lies outside a cylinder having uniform volume charge density.
r2
1
(B) E (Q) P lies inside a spherical charged conductor.
r
(C) Er (R) P lies inside a spherical body having uniform volume charge density.
(D) E  r0 (S) P lies inside a plane infinite sheet of some thickness. The sheet is charged
uniformly throughout its volume.
(T) P lies outside a spherical body having uniform volume charge density.

-II 
P 
r 
-I 
-II 
r 

-II -I
1
(A) E (P) 
P, 
r2
1
(B) E (Q) 
P, 
r
(C) Er (R) 
P, 
(D) E  r0 (S) 
P, 

(T) 
P, 
0999DT110316001 LTS-13/44
2. Dotted surfaces are Gaussian surfaces and solid surfaces are material bodies. All the surfaces
PHYSICS
are spherical.
Column-I Column-II
(A) Electric field at point A is zero. (P) A dipole is placed as shown
1 2
A B
(B) Electric field at point B is zero. (Q) A point charge kept at centre
of neutral conducting shell as shown
2 1 +q A
(C) Flux through surface 1 is zero (R) A dipole kept at centre

of neutral conducting shell as shown
2
(D) Flux through surface 2 is zero (S) A point charge kept outside of
neutral conducting shell as shown
2 1 A
+q
(T) Non-conducting shell carrying
non-uniformly distributed +ve charge.
2 1 B A
LTS-14/44 0999DT110316001

PHYSICS

-I  -II
(A) 
A  (P) 
1 2
A B
(B) 
B  (Q) 

2 1 +q A
(C)  1  (R) 


B
A
1
2
(D)  2  (S) 

2 1 A
+q
(T) 

2 1 B A
SECTION–III : Integer Value Correct Type

–III : 
No question will be asked in section III / 
III 
0999DT110316001 LTS-15/44
SECTION–IV : (Maximum Marks : 24)
PHYSICS
–IV : ( : 24)

 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer in the ORS.
Full Marks : +4 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
   
   
    
0 9      

 
 
             
       
 


   
  : +4           
  : 0    
 
1. Two particle are moving with velocity v1  î  tjˆ  kˆ and v 2  tiˆ  tjˆ  2kˆ m/s respectively. Time
at which they are moving perpendicular to each other is _______ (sec.)
 

v1  î  tjˆ  kˆ  v 2  tiˆ  tjˆ  2kˆ m/s 

2. Electric field at the centre of uniformly charged hemispherical shell of surface charge density 

is then find the value of n.
n 0



n  
n 
0

+
R
C
LTS-16/44 0999DT110316001
3. A vector is shown in the figure. Its magnitude is R. Its x-component is of magnitude 4 3 units.
PHYSICS
R is equal to

R x-
4 3 
R
y
m
R
30°
x
4. In a 2-D region of x-y space, a uniform electric field exists, given by : E = (2 V/m) (3i + 4j).
A charged particle of mass 10 –2 g and charge 10 –5 C is fired from the origin with initial
velocity 10 m/s, directed along the negative y-direction. Find the minimum speed (in m/s) of the
particle during its subsequent motion. Neglect gravity.
x-y 
E = (2 V/m) (3i + 4j) 
10–2 g 
10–5 C 
10 m/s y-


(m/s 
) 

5. Two uniformly charged semi circular rings of radius R and linear charge density , are placed in

y–z and x–z plane as shown. Electric field intensity at point P is . Where point P is
n 0 R
intersection point of axis of both rings and at distance R from center of both rings. Find value
of n.

R 

y–z x–z 

P  
 P 
R 
n 0 R

n 
z
+ +
R
x
R P
y
0999DT110316001 LTS-17/44
6. The figure shows two ships at points A and B, which are in the same vertical plane with an
PHYSICS
aer oplane at point C. When t he height of t he aer oplane is 2 3 km, the angle of depression to A
is 60° and to B is 30°, find the distance between two ships in kilometers.

A
B
C
2 3 km, 
 A
60° 

B
30°

C
60° 30°
23 km
A B
LTS-18/44 0999DT110316001
PART-2 : CHEMISTRY
CHEMISTRY

-2 :  
–I(i) : ( : 18)
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
   
  
  

  (A), (B), (C) 
(D)  
    
               
       
 


   
  : +3           
  : 0         
  : –1    
+
1. Ratio of number of protons to neutrons present in 27.83 × 1029 molecules of ND4
(where D is 1H2).
ND4 27.83 × 1029 
+
D, H2 
1
27.83  1019
(A) (B) 1 (C) 27.83 (D) 27.83 × 1019
NA
2. An oxide of element 'A' was analysed and found to have mass ratio of 'A' to oxygen equal to
7 : 3. Then formula of oxide can be :
[Atomic mass of A = 56]
'A' 
'A' 
 
7 : 3 
[A 
= 56]
(A) A3O2 (B) A2O3 (C) AO (D) A2O
0999DT110316001 LTS-19/44
3. Equal mass of KClO3 undergoes different reactions in two different container-
CHEMISTRY
(i) 2KClO3(s)  2KCl(s) + 3O2(g) (ii) 4KClO3(s)  KCl(s) + 3KClO4(s)

Mass ratio of KCl produced in respective reaction is n : 1 value of 'n' will be -

KClO3 
(i) 2KClO3(s)  2KCl(s) + 3O2(g) (ii) 4KClO3(s)  KCl(s) + 3KClO4(s)

KCl 
n : 1 
'n'
(A) 4 (B) 2 (C) 74.5 (D) 90
4. Which of the following is correct IUPAC name of crotonic acid :
(A) But-3-enoic acid (B) But-2-enoic acid (C) Butanoic acid (D) Propenoic acid

IUPAC 
(A) 
-3- (B) 
-2-
(C) 
(D) 
COOH
5. Correct IUPAC name of is :

OH
(A) 3-carboxy cyclohex-4-en-1-ol
(B) 5-carboxy cyclohex-3-en-1-ol
(C) 5-hydroxy cyclohex-2-ene-carboxylic acid
(D) 3-hydroxy cyclohex-5-ene-carboxylic acid
COOH
IUPAC 
OH
(A) 3-
-4--1-
(B) 5-
-3--1-
(C) 5-
-2--
(D) 3-
-5--
6. Alcohol and phenol can be differentiated by :

(A) NaOH (B) NaHCO3 (C) Na (D) NaNH2
LTS-20/44 0999DT110316001
CHEMISTRY
–I(ii) : ( : 20)
darkened.
   
 
   
  
(A), (B), (C)  (D)  
      
               
       
 


   
  : +4            
  : 0         
  : –1    
7. Select the correct graph for Bohr atom -
momentum of e–
Angular
Radius
(A) (B)
Principal quantum no.(n) Principal quantum no.(n)

of electron
velocity of
electron
Energy
(C) (D)
(n) K.E. of electron

 e–   

 
(A) (B)



(n) (n)


(C) (D)
(n) 
K.E.
0999DT110316001 LTS-21/44
8. For two Bohr orbits n1 & n2 which follow the relationships,
CHEMISTRY
(n22 – n12) = 21 and (n2 – n1) = 3.

If an electron makes transition from n2 to n1 directly then :
(A) Third longest wavelength of Balmer series is emitted
(B) Longest frequency of Lyman series is emitted
(C) Longest frequency of Balmer series is emitted
(D) Only one spectral line is emitted

n1 n2 
(n22 – n12) = 21 (n2 – n1) = 3.
n2 n1 
:
(A) 
(B) 
(C)  
(D)   
9. Select the option having incorrectly named compound(s) :
(A) 3,3-dimethyl-1-hydroxy cyclohexane (B) 4-ethoxy-2-methoxypentan-3-one
(C) 2-ethyl-1,1-dimethyl cyclopentane (D) 4-amino-2-hydroxy-4-oxobutanal

(A) 3,3-
-1-
(B) 4-
-2-
-3-
(C) 2-
-1,1- (D) 4-
-2-
-4-
10. Which of the following is not the correct IUPAC name ?
(A) 2-ethyl-3-methyl pentane (B) 4-formly pentan-2-ol
(C) 3-Carboxy pentanoic acid (D) Cyclohexanoic acid

IUPAC 
(A) 2-
-3- (B) 4-
-2-
(C) 3- (D) 
11. Which of the following is/are incorrect IUPAC name.
(A) 4-Chloro-3-methyl cyclopentanol-1 (B) 1-Amino-3-bromo hexan-1-one
(C) 4-Chloro-3-methyl cycloxane carboxylic acid (D) 3-Bromo-1-methyl hexan-1-ol

IUPAC 
(A) 4-
-3-
-1 (B) 1--3-
-1-
(C) 4-
-3-
(D) 3-
-1-
-1-
LTS-22/44 0999DT110316001
CHEMISTRY
–I(iii) : ( : 12)
correct.
   
  
   
 
   
  

  
(A), (B), (C) 
(D)  
   
               
       
 


   
  : +3           
  : 0         
  : –1    
12 13   
In a H-like species there are two energy levels A and B above the ground state having principal
quantum numbers of n1 and n2 respectively. A sample of this H-like species has all atoms/ions in
excited levels A or B only and none in any other energy level. Energy of level B is greater than
that of level A and a total of 15 different lines are emitted from this sample on returning to
ground state out of which 6 lines are emitted due to electronic transitions between the levels n1
and n2 only. Also energy difference between levels n2 and n1, En2 – En1 = 4.53 eV.
 H-
A 
B, 
n1 
n2 
H-
A  B 

B A 

15 
6 
n1 
n2 
n2 
 n1
En – En = 4.53 eV 
2 1
12. The correct option is -
-
(A) n2 = 2, n1 = 5 (B) n2 = 6, n1 = 3 (C) n2 = 5, n1 = 2 (D) n2 = 3, n1 = 6
13. Calculate minimum wavelength in the above transition -


-
4 9 900 36
(A) (B) (C) (D)
3R H 8R H 11R H 35R H
0999DT110316001 LTS-23/44
CHEMISTRY
14 15   

NH2 CHO CN
NH2
H2NOC N OH
H
14. Total number of types of functional groups present in the given compound is/are :

(A) 5 (B) 6 (C) 7 (D) 8
15. The degree of unsaturation (D.B.E.) of above compound is :

(DB.E.) 
(A) 5 (B) 6 (C) 7 (D) 8

LTS-24/44 0999DT110316001
CHEMISTRY
–II : (  : 16)
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
darkened
   

  
     
 -I
-II
  -I 
 
(A), (B), (C)  (D) 
  -II 
 
(P), (Q), (R), (S) (T) 
  -I   
-II    
  -I  -II  
    4 
× 5 
  
: 
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)

 -I             
-I 
(A) 
(Q), (R) (T) 
   
(B), (C)  (D)   
  
:
-I     
  : +2            
  : 0    
0999DT110316001 LTS-25/44
1. Column-I Column-II
CHEMISTRY
–3
(A) 1 mole N (Nitride ion) (P) 10 mole electrons
–2
(B) 1 mole O (Oxide ion) (Q) 8 mole protons
(C) 1 mole CH4 (R) 6.023 × 1023 molecules
(D) 1 mole H2O (S) 10 mole protons
(T) 5 mole atoms

-I     
-II
(A) 1 
N–3 (
) (P) 10 
(B) 1 
O–2 (
) (Q) 8 
(C) 1 
CH4 (R) 6.023 × 1023 
(D) 1 
H2O (S) 10 
(T) 5 
LTS-26/44 0999DT110316001
CHEMISTRY
(A) Isobutane (P) Contains 1º carbon atoms
(B) Neohexane (Q) Contains 2º carbon atoms
(C) Isooctane (R) Contains 3º carbon atoms
(D) Isodecane (S) Contains 4º carbon atoms
(T) Parent carbon chain contains odd number of carbon
atoms in IUPAC
-I  -II

(A)  (P) 1º 
(B)  (Q) 2º 
(C)  (R) 3º 
(D)  (S) 4º 
(T)         
IUPAC 

–III : 
III 
0999DT110316001 LTS-27/44
CHEMISTRY
–IV : ( : 24)

   
   
    
0 9      

 
 
             
       
 


   
  : +4           
  : 0    
100x
1. An oleum sample is labelled as 103%. Mass % of free SO3 is , value of x is.
15
100x

103% 
SO3 
= 
x 
15

.
2. Polyethene can be prepared by CaC2 by the following sequence of reactions.
CaC2 + H2O  CaO + C2H2
C2H2 + H2  C2H4
nC2H4  (C2H4)n
(Polyethene)
The mass in kg of polythene that can be prepared by 20 kg CaC2.
Fill your answer as sum of digits (excluding decimal places) till you get the single digit
answer.

CaC2  
CaC2 + H2O  CaO + C2H2
C2H2 + H2  C2H4
nC2H4  (C2H4)n
(Polyethene)
20 kg CaC2 
kg

(
) 
LTS-28/44 0999DT110316001
3. 62.5 gm of a mixture of CaCO3 and SiO2 are treated with excess of HCl and 1.1 gm of CO2 is
CHEMISTRY
produced. What is mass % CaCO3 in the mixture.
CaCO3 SiO2 62.5 gm 
HCl 
1.1 gm CO2 

CaCO3  % 
4. Out of the following compounds how many can react with NaHCO3 :

NaHCO3 
OH COOH SO3H OH OH NH2
NO2
C2H5OH CH CH
NO2 COOH
5. How many carbon atoms are present in the parent chain of following compound.

COOH
6. Number of compounds having no any carboxyl (COOH) group.
(i) Citric acid (ii) Salicylic acid (iii) Barbituric acid (iv) Carbolic acid
(v) Ascorbic acid (vi) Nitrolic acid (vii) Picric acid (viii) Cinnamic acid
(ix) Aspirin (x) Benzene sulphonic acid

(COOH) 
(i)  (ii)  (iii) 
(iv) 
(v)  (vi)  (vii)  (viii) 
(ix)  (x) 
0999DT110316001 LTS-29/44
MATHEMATICS
PART-3 : MATHEMATICS

-3 : 
–I(i) : ( : 18)
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
correct.
   
  
  

  (A), (B), (C) 
(D)  
    
               
       
 


   
  : +3           
  : 0         
  : –1    
2 2
1. If A and B are two square matrices of order 3 such that AB = BA and A + AB = 2B . If det(A – B)0
–1
and det(B)  0, then det(AB ) is

3 
A 
B 
AB = BA 
A + AB = 2B 
2 2
det(A – B)0 
det(B)  0 
det(AB ) 
–1
-
(A) –2 (B) 0 (C) 8 (D) –8
2. If cos()sin() = cos()sin(), then the value of cot cot cot,
n
where (  , n  I) is -
2
n
cos()sin() = cos()sin() 
cot cot cot, 
(  , n  I) 
2

-
(A) –cot (B) tan (C) cot (D) 4tan
LTS-30/44 0999DT110316001
MATHEMATICS
3. Number of values of   [0, 2] satisfying the matrix equation
 1 
sin  
cos  sin    cos2 0   2
    is -
 sin   cos   sin  1   3 
  2  cos 

 1 
sin  
cos  sin    cos2 0   2

 sin   cos   sin  1     
  [0, 2] 
    3 
  2  cos 


-
(A) 2 (B) 3 (C) 4 (D) 6
log 2 (ab).log c  log 2 (bc) log a  log 2 (ca) log b

4. If log(abc) = 0, then the value of log c
(where a, b, c are not
log(a) log( b )
unity) is equal to -
log 2 (ab).log c  log 2 (bc) log a  log 2 (ca) log b

log(abc) = 0  log c
log( b )

log(a)
(
a, b, c 
)- 
(A) 1 (B) 0 (C) 3 (D) –3
0999DT110316001 LTS-31/44
MATHEMATICS
1 3
5. If   [0,2], tan    and tan    , then value of ( + ) can be -
4 5
1 3
  [0,2], tan    
tan    
( + ) 
4 5
 3 5 7
(A) (B) (C) (D)
4 4 4 4
6. Which of the following is INCORRECT -
(A) Orthogonal matrices are always invertible.
(B) Skew symmetric matrices of order (2n + 1) are always non invertible {n  N}.
(C) Idempotent matrices are always invertible.
(D) Involutary matrices are always invertible.

(A) 
(B) (2n + 1) 
{n  N}
(C) 
(D) 
LTS-32/44 0999DT110316001
MATHEMATICS
–I(ii) : ( : 20)
darkened.
   
 
   
  
(A), (B), (C)  (D)  
      
               
       
 


   
  : +4            
  : 0         
  : –1    
log16 2
7. Which of the following is/are greater than 4 ?

4
log 2

16
log16 2 log16 2 log2 4 log 4 16

(A) 2 (B) 16 (C) 16 (D) 2

8. If     and cos   cos   1 , then -
3

     
cos   cos   1 
-
3
1 2
(A) cos(  )  (B) | cos   cos  | 
3 3
1 1
(C) cos(  )   (D) | cos   cos  |  
3 2 3
0999DT110316001 LTS-33/44
MATHEMATICS
9. Which of the following determinant(s) reduces to zero-


-
1 a a 2  bc 1 2 3
(A) 1 b b  ca
2 (B) 51 52 53
1 c c 2  ab 201 202 203
0 a b bc a a  b b
(C) b  a 0 ca (D) p p  q q
cb ac 0 u u   
10. If tan12º tan24º tan48º = ktanxº, where k  I and x  (0, 180), then which of the following can be
true -
tan12º tan24º tan48º = ktanxº 
k  I 
x  (0, 180) 
-
(A) k = 1, x = 6 (B) k = 1, x = 174 (C) k = –1, x = 6 •(D) k = –1, x = 174
1 0 0
 
11. If matrix A =  1 0 1  , then choose correct option(s), (here det(X) denotes determinant of matrix X)
 0 1 0 
(A) A2 is a triangular matrix (B) det(A10 – I) = 0
 1 0 0 1 0 0 
 
(C) A  10 1 0 
20 8
(D) A  8 1 0 
10 0 1  8 0 1 
1 0 0
 

A =  1 0 1  
(
det(X) 
X 
 0 1 0 

)
(A) A2  (B) det(A10 – I) = 0
 1 0 0 1 0 0 
 
(C) A  10 1 0 
20 8
(D) A  8 1 0 
10 0 1  8 0 1 
LTS-34/44 0999DT110316001
MATHEMATICS
–I(iii) : ( : 12)
correct.
   
  
   
 
   
  

  
(A), (B), (C) 
(D)  
   
               
       
 


   
  : +3           
  : 0         
  : –1    
12 13   
Let ƒ(x)  4log7 x  3log7 x and P is smallest solution(s) of the equation ƒ(x) = x and
2
g(x) = x – (P – 2)x + P – 3.

ƒ(x)  4log x  3log
7 7 x

P, ƒ(x) = x 
g(x) = x – (P – 2)x + P – 3 
2
12. Number of solution(s) of the equation ƒ(x) = x is -

(A) 1 (B) 2 (C) 3 (D) infinite
 ƒ(x) = x 
-
(A) 1 (B) 2 (C) 3 (D) 
13. Number of integral value(s) of P for which roots of equation g(x) = 0 are imaginary, is -
P 
g(x) = 0 
-
(A) 0 (B) 1 (C) 2 (D) 3
0999DT110316001 LTS-35/44
MATHEMATICS
14 15   

1 1  0 2 1
 
Let A  1 2  & B is a matrix of order (2 × 3) such that AB   3 7 5 
1 4   5 13 9 
(where tr(X) denotes trace of X)
1 1  0 2 1
 
A  1 2  
B  AB   3 7 5  
(2 × 3) 
1 4   5 13 9 
(
tr(X), X 
)
14. tr(BA)
(A) is equal to zero (B) is equal to –3
(C) is equal to 2 (D) can't be determined
tr(BA)
(A)  (B) –3 
(C) 2  (D) 
2015
15. If X = BA, then sum of all elements in X is-
X = BA 
X 
2015
-
(A) 3 (B) 2015 (C) 2016 (D) 2017
LTS-36/44 0999DT110316001
MATHEMATICS
–II : (  : 16)
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
darkened
   

  
     
 -I
-II
  -I 
 
(A), (B), (C)  (D) 
  -II 
 
(P), (Q), (R), (S) (T) 
  -I   
-II    
  -I  -II  
    4 
× 5 
  
: 
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
 -I             
-I 
(A) 
(Q), (R) (T) 
   
(B), (C)  (D)   
  
:
-I     
  : +2            
  : 0    
0999DT110316001 LTS-37/44
MATHEMATICS
(A) Number of natural solution(s) of the equation (P) 5
|x + 3| + |x – 5| = 8, is
(B) If 3 sec80  sec10  4 tan x  , then minimum (Q) 6
x
possible positive value of is (R) 7
10
 
(C) Value of the expression log 2 16 2 8  7 8  7 8  .....  is (S) 8
 
16
(D) Value of the expression log 2
3

 log 4 10  4 6  is (T) 9
1
2

-I 
-II
(A)  |x + 3| + |x – 5| = 8     (P) 5

(B)  3 sec80  sec10  4 tan x   (Q) 6
x
      (R) 7
10
(C) log 2 16 2 8  7 8  7 8  .....   (S) 8

 
16
(D) log 2  log 4 10  4 6   
  (T) 9
3
1
2
LTS-38/44 0999DT110316001
MATHEMATICS
2. Consider a system of linear equations aix + biy + ciz = di(where ai,bi,ci  0 and i = 1,2,3 ) & ()
is its unique solution, then match the following conditions.
Column-I Column-II
2
(A) If ai = k, di = k , (k  0) and      = 2, then k is (P) 1
(B) If ai = di = k  0, then      is (Q) 2
(C) If ai = k > 0, di = k + 1, then      can be (R) 0
(D) If ai = k < 0, di = k + 1, then      can be (S) 3
(T) –1
 
aix + biy + ciz = di(
ai,bi,ci  0 
i = 1,2,3 ) 
()  
      

-I 
-II
(A)  ai = k, di = k2, (k  0) 
     = 2 
k  (P) 1
(B)  ai = di = k  0 
      (Q) 2
(C)  ai = k > 0, di = k + 1 
        (R) 0
(D)  ai = k < 0, di = k + 1  
        (S) 3
(T) –1

–III : 
III 
0999DT110316001 LTS-39/44
MATHEMATICS
–IV : ( : 24)

   
   
    
0 9      

 
 
             
       
 


   
  : +4           
  : 0    
1. Number of rational solutions of equation 7log2 |x 1| | x  1 |x 2 is
 7log |x 1| | x  1 |x 2      

2
x y 1
2. If y 1 x  0 , where x, y  {–2, –1, 0, 1, 2}, then the number of ordered pairs of (x, y) is
1 x y
x y 1
 y 1 x  0 , 
x, y  {–2, –1, 0, 1, 2} 
(x, y) 
1 x y
1 0 2 
3. If A.adj A  2 1 0  , then absolute value of sum of elements of adj A is
  2
 
1 0 1 
(where adj(X) denotes adjoint of matrix X)
1 0 2 
 A.adj  A 2
   2 1 0  
adj A 
1 0 1 
(
adj(X) 
X 
)
LTS-40/44 0999DT110316001
MATHEMATICS
1  sin 2 x cos2 x sin 2x
2 2
4. If maximum and minimum values of ƒ(x)  sin x 1  cos x sin 2x are a and b respectively,,
sin 2 x cos2 x 1  sin 2x
then the value of a2 – b19 is
1  sin 2 x cos2 x sin 2x
 ƒ(x)  sin x 1  cos x sin 2x 
2 2
a 
b 
a2 – b19
sin 2 x cos2 x 1  sin 2x

2
5. If  and  are angles such that     , then number of integers in range of (sin – sin + 4coscos)
3
is
2

 
 
  
(sin – sin + 4coscos) 
3

 7 1 
 
3 0  8 2 2
6. Let X    ,Y   and Z = YT X Y. If M  Y Z 2015 Y T where M = [mij] is a
3 3  1 7 
 
 2 2 8 
m 21  m 11  m 22
2 × 2 matrix, then sum of digits of  where   , is
32015
 7 1 
 
3 0  8 2 2

X  ,Y  
 1 

Z = YT X Y  M  Y Z 2015 Y T 
M = [mij], 2 × 2 
3 3 7
 
 2 2 8 
m  m 11  m 22

 
  21 2015 ,
3
0999DT110316001 LTS-41/44
MATHEMATICS
LTS-42/44 0999DT110316001
QUESTION PAPER FORMAT AND MARKING SCHEME /  
16. The question paper has three parts : Physics, Chemistry and Mathematics.

17. Each part has three sections as detailed in the following table.

Que. No. Category-wise Marks for Each Question / 
Maximum
Section Type of Full Marks Partial Marks Zero Marks Negative Marks of the
Que.   
Marks section
    
  

+3 0 –1
Single If only the bubble If none In all
correct option corresponding to of the other
 the correct option bubbles is cases
I(i)  6 is darkened — darkened  18
  
  
 
+4 0 –1
One or more If only the bubble(s) If none In all
correct corresponding of the other
option(s) to all the correct bubbles is cases
I(ii)
 5
option(s) is(are)
—
darkened  20
 darkened  
   
 
 

Paragraph +3 0 –1
Based If only the bubble If none In all
(Single corresponding to of the other
correct the correct option bubbles is cases
I(iii) option) 4 is darkened — darkened  12
   
   
  

+8 +2 0
Matrix If only the bubble(s) For darkeninga bubble In all
Match Type corresponding to corresponding to each other
 all the correct correct match is cases
match(es) is(are) darkened 
II 2 darkened  
— 16
  
 


+4 0
Single digit If only the bubble In all
Integer corresponding other
(0-9) to correct answer cases
IV  6 is darkened —  — 24
  
(0-9)  

0999DT110316001 LTS-43/44
NAME OF THE CANDIDATE / 

.............................................................................
FORM NO. / 

.............................................
I have read all the instructions I have verified the identity, name and Form
and shall abide by them. number of the candidate, and that question

paper and ORS codes are the same.
 
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LTS-44/44 Your Target is to secure Good Rank in JEE 2017 0999DT110316001

Leader Test Series / Joint Package Course: Distance Learning Programme

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Paper Code : 0999DT110316001

DISTANCE LEARNING PROGRAMME

LEADER TEST SERIES / JOINT PACKAGE COURSE

SOME USEFUL CONSTANTS

 Boltzmann constant k = 1.38 × 10–23 JK–1

Space for Rough Work / 

–I(ii) : ( : 20)

4iˆ  (4x  2)jˆ  2kˆ . The values of x are :-

 ˆi  xjˆ  3kˆ 

Space for Rough Work / 

Space for Rough Work / 

(C) Flux through surface 1 is zero (R) A dipole kept at centre

(C)  1  (R) 

SECTION–III : Integer Value Correct Type

–IV : ( : 24)

Space for Rough Work / 

Space for Rough Work / 

Space for Rough Work / 

(i) 2KClO3(s)  2KCl(s) + 3O2(g) (ii) 4KClO3(s)  KCl(s) + 3KClO4(s)

5. Correct IUPAC name of is :

Principal quantum no.(n) Principal quantum no.(n)

(n) K.E. of electron

Space for Rough Work / 

(n22 – n12) = 21 and (n2 – n1) = 3.

14 15   

(A) 5 (B) 6 (C) 7 (D) 8

(B) (P) (Q) (R) (S) (T)

(C) (P) (Q) (R) (S) (T)

(D) (P) (Q) (R) (S) (T)

-I  -II

SECTION–III : Integer Value Correct Type

–IV : ( : 24)

log 2 (ab).log c  log 2 (bc) log a  log 2 (ca) log b

log 2 (ab).log c  log 2 (bc) log a  log 2 (ca) log b

Space for Rough Work / 

log16 2 log16 2 log2 4 log 4 16

9. Which of the following determinant(s) reduces to zero-

(A) A2 is a triangular matrix (B) det(A10 – I) = 0

(A) A2  (B) det(A10 – I) = 0

Space for Rough Work / 

12. Number of solution(s) of the equation ƒ(x) = x is -

14 15   

(C) log 2 16 2 8  7 8  7 8  .....   (S) 8

SECTION–III : Integer Value Correct Type

–IV : ( : 24)

 7log |x 1| | x  1 |x 2      

Space for Rough Work / 

NAME OF THE CANDIDATE / 

FORM NO. / 

Space for Rough Work / 

LTS-44/44 Your Target is to secure Good Rank in JEE 2017 0999DT110316001

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