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Similarly, the o values for each pair of salts having the
same different anions and a common cation is same, irrespective
of the cation.
Kohlrausch law :
o oc oa
initial concentration
conc. at equilibrium
or
eq. (i) & (ii) are the two expression of Ostwald’s dilu-law
of electrolytes.
For each electrolyte, the data are fitted in equation (i) to see
whether the value of Kd comes out to be constant or not :
2- Nature of solvent :
3- Concentration :
4- Temperature :
t( ) (Ω-1.cm-1) * 104
0 0.14
18 0.40
25 0.58
34 0.89
50 1.76
o
=
o