Q10 When AG+ for a reaction is negative, the reaction must be :

Answer : D. Spontaneous

Q11 Consider the reaction

NH4Br(S) →NH3(g) + HBr(g)

Which row gives the correct signs for the values of ∆𝐻 and ∆𝑆 ?

Answer : ∆𝑆 > 0 +

∆𝐻 +

A. ∆𝐇 + 𝐯𝐞 ∆𝐒 + 𝐯𝐞

Q12 The Born-Haber cycle for the formation of potassium fluoride includes the steps
below

I K(g) → K+(g) + e-
1
II 𝐹 (g) → F(g)
2 2

III F(g) + e- →F-(g)

IV K+(g) + F-(g) → KF (s)

Answer :

I K(g) → K+(g) + e- ∆𝐻 = −
1
II 𝐹 (g) → F(g) ∆𝐻 = 0
2 2

III F(g) + e- → F-(g) ∆𝐻 = −

IV K+(g) + F-(g) → KF (s) ∆𝑆 < 0(−) ∆𝐻 = −

B. III and IV only

Q13 When the subtances H2(g), O2(g) and H2O2(I) are arranged in order of increasing entropy
values at 25oC, what is the correct order?

Answer : C. O2(g), H2(g), H2O2(l)

Q14 Which one of the following would have a standard enthalpy change of formation that
is not zero

Answer : C. F2(g) (tidak berwarna)

Q15 Which of the following must have a negative value for an exothermic reaction ?

Answer : A. Enthalpy change, ∆𝑯-

Q16 The bond entalpies for H2(g) and HF(g) are 435 kj mol-1 and 565 kj mol-1,
1 1
respectively. For the reaction 2 H2(g) + 2 F2(g) → HF (g), the enthalpy of reaction is -268
kj mol-1 of HF produced. What is the bond energy of F2 in kj mol-1 ?

Answer :

Reaktan – produk

Kiri - kanan – energi ikat – (pemutusan)

½ H2(l) + ½ F2(g) → HF(g)

∆𝐻 = kiri – kanan

- 268 = ½ H2 + ½ F2 – HF

- 268 = ½ . 435 + ½ F2 – 565

- 268 = 217,5 + ½ F2 - 565

½ F2 = - 268 + 565 – 217,5

½ F2 = 79,5

F2 = 79,5 X 2

= D. 159

Q17 In a reaction, Pbl2(s) → Pb2+(aq) + 2l-(aq) , the solubility of Pbl2 is determined by the
tendency of the reaction system to attain wich of the following ?

Answer : B. Maximum entropy and minimum enthalpy

Q18 Which equation shows a reaction in which there an increase in enthropy ?

Answer : D. Na(s) + H2O(l) → Na+(aq) + OH-(aq) + ½ H2(g)

Q19 The standard enthalpy of formation of sodium fluoride corresponds to wich reaction ?
𝟏
Answer : D. Na(s) + 𝟐 F2(g) → NaF(s)

Q20 For the raection, C(s) + CO2(g) → 2CO(g), which is pontaneous only at temperatures
higher than 1100 K, one would conclude which of the following ?

Answer : C(s) + CO2(g) → 2CO(g)

∆𝐺 = ∆𝐻 − 𝑇. ∆𝑆

∆𝐺 = ∆𝐻 − 1100𝐾. ∆𝑆

− = − − +
 D. ∆𝑯 is negative and ∆𝑺 is positive

Q21 Which of the following is the correct equation for the standard enthalpy change of
formation of carbon monoxide ?
𝟏
Answer : B. C(g) + 𝟐 O2(g) → CO2(g)

Q22 For a reaction 2NO(g) + O2(g) → 2NO2(g) at one atmosphere pressure, the values of
∆𝐻 and ∆𝑆 are both negative and the process is spontaneous at room temperature,
which of the following is also true ?

Answer :

2NO(g) + O2(g) → 2NO2(g)

Temperatur ∆𝐺 karena perubahan

+ = - entalpi tergantung

- = + reaksi

B. The change in entropy is the driving force of reaction

Q23 Which one of the following processes is not exothermic ?

Answer : C. Br(g) + e- → Br-(g)

Q24 Which of the following processes would be expected to have an entropy change value
close to zero ?

Answer : C. Br2(g) + Cl2(g) → 2BrCl(g) ∆s = seimbang