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where
The pressure is 1000 kPa or 106 Pa and temperature is 25◦ C or 298 K. As the gas
mixture follows ideal gas law, P V = nRT , one obtains
n P 106
c= = = = 0.4036 kmol/m3
V RT (8314) (298)
As the flux of N2 (gas B) is 20% of the flux of O2 (gas A) in opposite direction, we have
NB = −0.2NA and hence
NA NA
= = 1.25
NA + NB NA − 0.2NA
The eq.(1) takes the form
DAB c 1.25 − xA2
NA = (1.25) ln
z 1.25 − xA1
−6
(2.137 × 10 ) (0.4036) 1.25 − 0.2
= (1.25) ln
0.002 1.25 − 0.1
−5
= −4.904 × 10
Hence the flux of diffusion of oxygen is 4.904 × 10−5 kmol/(m2 s). The negative sign
indicates the direction of flux i.e. from 20 vol% to 10 vol%.