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Module 29: Acid-Base Fundamentals
Module 29 – Acid-Base Fundamentals....................................................................... 876
Lesson 29A: Acid-Base Math Review ................................................................................... 876
Lesson 29B: Kw Calculations: H+ and OH─....................................................................... 879
Lesson 29C: Strong Acid Solutions ....................................................................................... 883
Lesson 29D: The [OH─] in Strong Acid Solutions .............................................................. 888
Lesson 29E: Strong Base Solutions........................................................................................ 891
Lesson 29F: The pH System................................................................................................... 894
Practice
Do the problems below without looking at the rules. If you find that you need to look back,
write a summary of the 7 rules above, recite your rules, then continue with the practice.
To speed your progress, do every second or third problem. If you cannot solve easily, do
more parts of that problem. Check your answers at the end of this lesson.
Try problems 1-7 without a calculator.
5. Write the decimal equivalents of these fractions. Practice so you can answer these from
automatically from memory.
a. 1/2 = b. 1/20 = c. 1/3 = d. 1/4 =
6. Convert your final answer to scientific notation. Need a hint? See Rule 6.
7. Convert all values below to scientific notation, then try to solve without a calculator.
8. Use a calculator for the numbers, but not the exponentials. Convert answers to
scientific notation.
c. 10─14 = d. 10─14 =
2.4 x 103 4.3 x 10─4
ANSWERS
1a. (10─8)(10+2) = 10─6 1b. 10─15 1c. 10─2 1d. 10─5
3a. 324 x 10+12 = 3.24 x 10+14 3b. 5.0 x 10─13 3c. 6.5 x 10─8 3d. 8.79 x 10─3
4a. 5,260 = 5.26 x 10+3 4b. 0.010 = 1.0 x 10─2 4c. 0.0075 = 7.5 x 10─3
5a. 1/2 = 0.50 5b. 1/20 = 0.05 5c. 1/3 = 0.33 5d. 1/4 = 0.25
5e. 1/5 = 0.20 5f . 1/50 = 0.020 5g. 1/8 = 0.125 5h. 1/80 = 0.0125
6a. (2.0 x 101) (3.0 x 10─11) = 6.0 x 10─10 6b. 5.0 x 10─19 6c. 3.3 x 10─11
6d. 5.0 x 10─7 6e. (2.5 x 10─2)[OH─] = 10 x 10─15 ; [OH─] = 4.0 x 10─13
7d. (0.0125) [OH─] = 1.0 x 10─14 ; [OH─] = 1.0 x 10─14 = 0.80 x 10─ 12 = 8.0 x 10─13
1.25 x 10─2
8a. 1.0 x 10─14 = 0.31 x 10─9 8b. 1.0 x 10─14 = 0.11 x 10─10
3.25 x 10─5 = 3.1 x 10─10 8.8 x 10─4 = 1.1 x 10─11
8c. 10─14 = 1.0 x 10─14 = 4.2 x 10─18 8d. 2.3 x 10─11 8e. 1.5 x 10─3
2.4 x 103 2.4 x 103
8f. (1.25 x 10─7)[OH─] = 1.0 x 10─14 ; [OH─] = 1.0 x 10─14 = 0.80 x 10─7 = 8.0 x 10─8
1.25 x 10─7
* * * * *
However, even at these low concentrations, small changes in the balance between H+ and
OH─ can have a large influence on reactions that are important in chemistry and biology.
Water’s Ionization Constant: Kw
K = [H+][OH─]
[H2O]
However, in aqueous solutions (those where water is the solvent), the concentration of the
non-ionized water molecules is high (about 55 M) for the relatively dilute solutions used in
most lab experiments, and it does not change substantially during dilution or reactions.
In equilibrium constants, concentrations that remain close to constant during reactions are
generally included as part of the numeric value for K and omitted from the K expression.
The result is a simplified equilibrium constant expression (labeled Kw) for the relationship
between H+ and OH─ in an aqueous solution:
K (55 M) = Kw = [H+][OH─]
At room temperature (25oC), the value for Kw is 1.0 x 10─14. This small numeric value
(0.000 000 000 000 010) indicates that the reaction favors the reactants: very few water
molecules separate into ions.
As temperature increases, the molecules of water collide with higher energy, the bonds
bend and stretch more vigorously, and the bonds break more often. Of importance in
biology, at body temperature in mammals (37˚C), the [H+] in water is about 1.6 x 10─7, as
opposed to 1.0 x 10─7 at 25oC.
However, for acid-base calculations in chemistry, you may assume that conditions are at
25oC unless otherwise noted. In acid-base calculations, we will use this Kw equation:
This relationship between [H+] and [OH─ ] is an inverse proportion. If substances are
added to water to make one ion concentration increase, the other must decrease in the same
proportion: if one triples, the other must become 1/3 of its original concentration.
Acid-Base Terminology
In pure water, the concentration of H+ and OH─ ions must be equal. However, if acids or
bases are dissolved into water, this balance is upset.
By what are termed the classical definitions of acids and bases:
• An acid is a substance that ionizes in water and forms [H+] ions.
• A base is a substance that ionizes in water and forms [OH─] ions.
These are also called the Arrhenius definitions for acids and bases, after the Swedish
chemist Svante Arrhenius who first proposed the existence of electrically charged particles
(ions).
When acids or bases are added to water, the water continues to ionize slightly, and the Kw
equation will continue to predict the relationship between the [H+] and [OH─] ions. In an
acidic or basic solution, if either [H+] or [OH─] is known, the concentration of the other ion
can be calculated using the Kw equation.
A useful rule is: in calculations that include both [H+] and [OH─] in the WANTED and
DATA, write the Kw equation. We will call this the
Some problems will ask for the [H+] and [OH─] in acid or base solutions very
approximately, and those calculations can be done by mental arithmetic. Try this problem.
WANT: [H+]
DATA: [OH─] ≈ 10─2 M
SOLVE: Solve the equation for the wanted symbol, then plug in the DATA.
Kw Check
When using the Kw equation, do a check at the end: estimate [H+] times [OH─] (circled
above). The result must = 10.0 x 10─15 or 1.0 x 10─14 . Try multiplying the circled
values above in your head. Does the answer check?
Practice: Do parts b and d of both, plus problem 3. Need more practice? Do more parts.
1. In these aqueous solutions, find the [H+] if the [OH─] is
3. If 20.0 millimoles of OH─ ions are dissolved in 400. mL of solution, find the [OH─] and
[H+].
ANSWERS
1 a. Since [H+][OH─] = 1.0 x 10─14 ; [H+](10─11) = 10─14 ; [H+] = 10─3 M
[H+][OH─] = 1.0 x 10─14 ; [H+](1.0 x 10─2) = 1.0 x 10─14 ; [H+] = 1.0 x 10─12 M
c. 5.0 x 10─11 M = [OH─] ; WANT [H+]; the equation relating the two symbols is
write [H+][OH─] = 1.0 x 10─14 ; (1.0) [OH─] = 10─14 ; [OH─] = 1.0 x 10─14 M
[OH─] = 1.0 x 10─14 = 1.0 x 10─14 = 0.33 x 10─9 = 3.3 x 10─10 M OH─
[H+] 3.0 x 10─5
Strong Acids
In chemistry, we often have a need for strong acid solutions. The strong acids most
frequently encountered are HCl, HNO3, and H2SO4.
• HCl and HNO3 are strong monoprotic acids. Both are highly soluble in water and
ionize essentially 100% to release one H+ ion.
Other strong monoprotic acids include HClO, HClO4, and HMnO4, but because
these substances may undergo redox as well as acid-base reactions, they are used
less often for reactions that require a strong acid.
• H2SO4 is a strong diprotic acid. When H2SO4 is dissolved in water, the first proton
ionizes essentially 100%, but the second ionizes only partially.
The ionization of acids is more complex than the ionization of other ionic compounds in
part because the bond of the H in acids has a balance of ionic and covalent character.
Because of the mixed nature of bonds to hydrogen, to calculate ion concentrations in acidic
solutions, we need three sets of rules:
• one for strong acids (such as HCl and HNO3) that ionize completely,
• one for weak acids, in which ionization goes to equilibrium, and
• one for polyprotic acids (such as H2SO4) in which some H atoms ionize more easily
than others.
Our rules for bases will parallel these acid rules. Let us start with the rules for solutions of
the strong acids HCl and HNO3.
In addition, there is a very small amount of OH─ ion in solution (more on that later).
Calculating Ion Concentrations In Strong Acid Solutions
The ionization of a strong acid parallels what happens to other ionic compounds that
separate into ions essentially 100% when dissolved in water (see Lesson 12B). The key rule
for calculations involving such compounds is:
For Substances Separating 100% Into Ions, Write the REC Steps
In calculations involving [ions], if a substance ionizes ~100%,
• R: Write the balanced ionization Reaction equation. After the equation, write
• E: The Extent of the reaction (“goes ~100%”). Below each particle, write
• C: The Concentration of the particle, based on the coefficient ratios.
If a reaction goes to completion, the coefficients supply the mole ratios of reactants used up
and products formed. For the 100% dissociation reactions of strong acids, since all of the
reaction particles are in the same constant volume of solution, the coefficients also supply
the mole per liter reaction ratios.
Example: In 0.15 M HNO3 , what are the [ions]? Write the REC steps.
Q. If 0.030 moles of HNO3 is mixed with water to form 150 mL of solution, find
Answer (In problems with parts, you may list either the WANTED or the DATA first.)
Practice A
1. In a 0.50 M solution of nitric acid (HNO3), what will be the
a. [H+] ? b. [NO ─] ?
3 c. [H3O+] ?
2. 7.30 grams of HCl is dissolved in water to make 250 mL of solution. Find the
a. moles of HCl dissolved in the solution, per liter.
0.20 M H+ from the acid, with doubt in the hundredth’s place, compares to
0.0000001 M H+ initially in the water, with doubt in a much higher place.
This is one indication that any initial H+ contribution from the water’s ions is too small to
be significant. The acid ionization is the dominant reaction. For this reason, the rule is:
2. Strong monoprotic acids ionize ~100% to form H+. For [ions], write the REC steps.
3. Quick rule: [HCl or HNO3]mixed = [H+]in soln.
ANSWERS
Practice A
1a,b. For problems involving HCl or HNO3 and [ions], write the REC steps for 100% ionization.
Rxn. and Extent: 1 HNO3 Æ Æ 1 H+ + 1 NO3─ (goes ~ 100%)
^ ^ ^
Conc.: 0.50 M 0 M 0.50 M 0.50 M
1c. [H3O+] = [H+] = 0.50 M
2a. WANT: ? mol HCl = [HCl]as mixed (it helps to label units with the symbols
L soln used in rules and equations)
DATA: 7.30 g HCl = 250 mL soln (equivalent: two measures; same soln.)
36.5 g HCl = 1 mol HCl (grams prompt)
You want moles over liters. The data includes grams, moles and mL. Use conversions. WANT a
ratio? Start with a ratio.
SOLVE: ? mol HCl = 7.30 g HCl ● 1 mol HCl ● 1 mL = 0.80 M HCl = [HCl]mixed
L soln 250 mL soln 36.5 g HCl 10─3 L
When solving in parts, label answers with symbols from rules that may be needed in later parts.
2b,c. For problems involving HCl or HNO3 and [ions], solve by the REC steps.
Rxn. and Extent: 1 HCl Æ Æ 1 H+ + 1 Cl─ ( goes ~ 100%)
^ ^ ^
Conc.: 0.80 M 0 M 0.80 M 0.80 M
[HCl]mixed = 0.80 M from part a = [H+]in soln = [Cl─]in soln d. [H3O+] = [H+] = 0.80 M
Practice B
Quick rule: In HCl or HNO3 , for [H+], use [HCl or HNO3]mixed = [H+]in soln.
* * * * *
decreasing the [OH─] . The value of the [OH─] after the shift can be calculated by the
equilibrium constant for water’s ionization:
When solving for [H+] and [OH─] in an acid solution, the rule is
In an acid solution, first use acid ionization rules to find [H+], then Kw to find [OH─].
c. WANT [OH─].
In an acid solution, first use acid rules to find [H+], then Kw to find [OH─].
2. Strong monoprotic acids ionize ~100% to form H+. For [ions], write the REC steps.
3. Quick rule: [HCl or HNO3]mixed = [H+]in soln.
5. In acid solutions, use acid ionization rules to find [H+], then Kw to find [OH─].
Practice
1. From memory, write the numbered acid-base rules learned so far in this module.
2. In a solution labeled 10─3 M HNO3, what will be the
ANSWERS
2 a,b. For problems involving HCl or HNO3 and [ions], solve by the REC steps.
2d. To find [OH─ ] in an acid solution, use acid rules to find [H+], then Kw to find [OH─ ].
1 mol/L HCl used up = 1 mol/L H+ formed, which can be written: [HCl]used up = [H+]formed
[OH─] ? In an acid solution, use acid rules to find [H+ ] (done above), then use Kw to find [OH─ ].
Kw check: [H+] x [OH─] (circled above) must estimate to 10.0 x 10─15 or 1.0 x 10─14
* * * * *
● NaOH and KOH ionize ~100% to form OH─. For [ions], write the REC steps.
● If only [OH─] is needed, use the quick rule: [NaOH or KOH]mxd = [OH─]in soln.
● In a base solution, use base rules to find [OH─], then Kw to find [H+].
We will add these to our rules that, when committed to long-term memory, simplify acid-
base problem solving.
Acid-Base Fundamentals
1. See [H+] and [OH─] ? Write: Kw = [H+][OH─] = 1.0 x 10─14
2. Strong monoprotic acids ionize ~100% to form H+. Alkali metal hydroxides
ionize 100% to form OH─. For [ions], write the REC steps.
3. Quick rules: [HCl or HNO3]mixed = [H+]in soln.
5. In acid solutions, use acid ionization rules to find [H+], then Kw to find [OH─].
6. In base solutions, use base rules to find [OH─], then Kw to find [H+].
a. NaOH ionizes to form Na+ and OH─ ions. Water ionizes to form H+ and OH─ .
The three ions are Na+, OH─, and H+.
b. For NaOH or KOH and [ions], write the REC steps for ~100% ionization.
To find the [H+] in a base solution, first use the base rules to find [OH─] (done),
then use Kw to find [H+].
(Kw check: [H+] x [OH─] = 3 x 3.3 ≈ 10; 10─3 x 10─12 = 10─15, combined ≈ 10 x 10─15)
Practice: Learn the Acid-Base Fundamental rules above, then try these.
ANSWERS
1a. 1 NaOH Æ 1 Na+ + 1 OH─
1b. Strong bases ionize 100%, this ionization favors the products.
iii,iv. [H+] ? To find [H+] in a base solution, first find [OH─] (above), then [H+] using
c. [H+] = ? [OH─] is known. The relationship between those two is: [H+][OH─] = 1.0 x 10─14
Note that each of the basic solutions above contain both OH─ and H+, but in solutions of bases, [OH─] is
always higher than [H+].
3a. WANTED = ? = [OH─] = mol OH─ First find [NaOH], then use [NaOH] = [OH─]
L soln.
DATA: 5.00 mmol NaOH = 0.250 L soln. (two measures of same solution)
SOLVE: ? mol NaOH = 5.00 mmol NaOH · 10─3 mol = 2.00 x 10─2 mol = [NaOH] = [OH─]
L soln. 0.250 L soln. 1 mmol L
[H+] = 1.0 x 10─14 = 1.0 x 10─14 = 0.50 x 10─12 = 5.0 x 10─13 M H+ = [H+] = [H3O+]
[OH─] 2.00 x 10─2
* * * * *
pH Prompt. If you see pH, write: pH ≡ ─ log [H+] and [H+] ≡ 10─pH
Solve using a calculator, round your answer to tenths, and then check it below.
* * * * *
This is a brief review of log calculations. For detail, see Lesson 27D, sections I to V.
• On a standard TI–type calculator, try: 5.0 EE 4 +/- log +/-
• An RPN calculator might use: 5.0 E +/- 4 enter log +/-
• On one type of graphing calculator: (-) log 5.0 EE (-) 4 ) enter
For your calculator, either read your calculator manual (the best approach) or experiment
until you get the following answer. Write down the key sequence that works.
For this problem, pH = 3.30 rounds up to 4. The [H+] exponential term in scientific
notation should therefore be 10─4, and it is: 5.0 x 10─4.
When complex operations are done on a calculator, estimate the answer – or do the
calculation two ways on the calculator – as a check on your calculator operation.
Rounding pH Calculations
Mathematically, the statistical basis for using significant figures to convey uncertainty does
not directly apply to logarithmic functions. In these lessons, we will use these rules.
• When the [H+] is written as simply a power of 10 (with no significand in front), the
pH is written as a whole number;
Example: [H+] = 10─4 M, pH = 4 ;
• When [H+] is written as a significand times 10 to a power , round the pH so that the
number of digits in the significand equals the number of digits after the decimal in the
pH.
Examples: [H+] = 5 x 10─4 M, pH = 3.3 ; [H+] = 5.1 x 10─12 M, pH = 11.29
• Due to the inherent uncertainty of the Kw values on which pH is based, calculated pH
values will be rounded to have at most two digits past the decimal.
Does this answer make sense? [H+] = 10─9.70 M is close to [H+] = 10─10 M. Since pH =
9.70 is a bit more acidic than pH = 10, the [H+] should be a bit higher than 10─10 M, and it
is: 2.0 x 10─10 M.
To check your answer, use this estimate: Round the pH up to the next highest whole
number. This should match the number after the minus sign of the exponent for [H+] in
scientific notation.
For this problem, pH = 9.70 rounds up to 10, so the [H+] exponent should be 10─10.
The answer is 2.0 x 10─10. Check!
b. [H+] =
c. [OH─] =
Work Problems 3-7 in your problem notebook.
3. In an HCl solution of pH = 3.60, find
a. [H+] b. [OH─] c. [Cl─] d. [HCl]
The pOH is often calculated by first finding the pH and then applying the pH + pOH
relationship.
The 14.00 represents the value of at Kw at 25ºC. At other temperatures, the relationship is
e. pOH = f. pH =
6. The pOH in a KOH solution is 1.5 . What is the [KOH]?
ANSWERS
Pretest: 1. ─ 4 2. ─ 11.7 3. 6.3 x 10─10 4. 5.0 x 10─13
Practice A: Whole Number pH
2. If [H+] = 10─4 M, a. [OH─] = 10─10 M b. pH = 4 c. Acidic
(pH will be lower than zero when [H+] > 1.0 M) c. Highly acidic
pH = ─ log (2.1 x 10─3) = 2.68 (Estimate was 2.? in answer 1a. Check.)
pH is WANTED, use ? = pH ≡ ─ log [H+] = ─ log (8.2 x 10─11) = 10.09 (checks above)
WANT pH, need [H+] to find pH, but are given [OH─].
See H+ and OH─ ? Write: Kw = [H+][OH─] = 1.0 x 10─14 Use Kw to find [H+]:
Then ? = pH ≡ ─ log [H+] pH = ─ log (5.0 x 10─11) = 10.30 (pH rounds up to 11; check.)
WANT pH. Need [H+] first. For quick [H+]in soln.: [HCl]mixed = 0.040 M = [H+]in soln.
For pH: pH ≡ ─ log [H+] = ─ log (0.040) = ─ log (4.0 x 10─2) = 1.40 (rounded up = 2. check.)
Need [H+] to find pH, but given is [KOH]. Quick: [KOH]mixed = 0.0030 M = [OH─] To find [H+],
pH = ─ log (3.3 x 10─12) = 11.48 (Base solution, basic pH; 11.48 rounded up = 12. Check.)
b. The equation that finds [H+] from pH is: [H+] = 10─pH ; [H+] = 10─5.5 = 3 x 10─6 M
WANT [H+] from pH, use [H+] = 10─pH ; [H+] = 10─8.20 = 6.3 x 10─9 M H+ Checks vs. pH .
WANT [OH─] . Know [H+] and pH. Kw relates [H+] and [OH─ ]: [H+][OH─] = 1.0 x 10─14 ;
? = [OH─] = 1.0 x 10─14 = 1.0 x 10─14 = 0.16 x 10─5 = 1.6 x 10─6 M OH─
[H+] 6.3 x 10─9
? = [OH─] = 1.0 x 10─14 = 1.0 x 10─14 = 0.40 x 10─10 = 4.0 x 10─11 M OH─
[H+] 2.5 x 10─4
c, d. [HCl]mixed = [H+]soln = [Cl─]soln From Part a, [H+] = 2.5 x 10─4 M = [Cl─] = [HCl]
8. Problem 7 has the both the lowest pH and the highest [H+]. By either measure it is the most acidic.
b. [OH─] = ? [NaOH] mxd. = 0.0667 M (part a) = [OH─]in soln = [Na+]in soln = Part c answer
See pOH? Write: pOH ≡ ─ log[OH─] and [OH─] ≡ 10─pOH and pH + pOH = 14.00
* * * * *
Acid-Base Fundamentals
1. See [H+] and [OH─] ? Write: Kw = [H+][OH─] = 1.0 x 10─14
2. Strong monoprotic acids ionize ~100% to form H+. Alkali metal hydroxides
ionize 100% to form OH─. For [ions], write the REC steps or use the quick rules.
5. In acid solutions, use acid ionization rules to find [H+], then Kw to find [OH─].
6. In base solutions, use base rules to find [OH─], then Kw to find [H+].
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