MANUFACTURED BY: BMW® AG, Munich D-80788 München DATE MSDS PRINTED & REVIEWED: 05/19/11 LAST FORMULA REVISION DATE: 05/19/11
SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS
SARA 313 LISTED CARCINOGEN BY: # COMPONENT CAS# % by WT. LISTED NTP IARC OSHA 1 XYLENE 1330-20-7 25-31 Y N N N 2 N-BUTYL ACETATE 123-86-4 15-21 N N N N 3 *ETHYLBENZENE 100-41-4 5-8 Y N Y N 4 ETHYL ESTER 763-69-9 3-5 N N N N 5 ALUMINUM FLAKE 7429-90-5 3-5 N N N N *See Section 15 and Section 11
SECTION 3: HAZARDS IDENTIFICATION
Emergency Overview: WARNING! Flammable Liquid. APPEARANCE/ODOR: Liquid Paint / Solvent Odor POTENTIAL HEALTH EFFECTS: See Section 11 for more information. LIKELY ROUTES OF EXPOSURE: Eye contact, skin contact, ingestion, and inhalation EYE: Contact may cause redness, irritation, tearing, and blurred vision SKIN: Contact may dry skin causing cracks and irritation INGESTION: May be harmful if swallowed INHALATION: Exposure to high concentrations of vapors may cause drowsiness, breathing difficulty, respiratory irritation, or headaches. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Product Description: MATERIAL SAFETY DATA SHEET BMW® TOUCH-UP PAINT BMW® COLORSYSTEM®
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Asthma and other respiratory
ailments. TARGET ORGANS: Kidney Liver Lung Brain Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
SECTION 4: FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with water for at least 15 minutes. If irritation develops get medical attention. SKIN CONTACT: Remove contaminated clothing and wash before reuse. Wash skin with soap and water. Get medical attention if irritation develops. INHALATION: Move to fresh air. INGESTION: Do NOT induce vomiting. Get medical attention immediately.
SECTION 5: FIRE FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA: CO2 (Carbon Dioxide), dry chemical, or water fog. UNSUITABLE EXTINGUISHING MEDIA: Water spray may be unsuitable. However, if water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up. PRODUCTS OF COMBUSTION: These products are carbon oxides (CO,CO2). PROTECTION OF FIREFIGHTERS: Full protective equipment including self-contained breathing apparatus should be used.
SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Use
personal protection recommended in Section 8. ENVIRONMENTAL PRECAUTIONS: None known. Product Description: MATERIAL SAFETY DATA SHEET BMW® TOUCH-UP PAINT BMW® COLORSYSTEM®
METHODS OF CONTAINMENT: Absorb spilled liquid in suitable material. METHODS OF CLEAN-
UP: Use spark-proof tools to sweep or scrape up and containerize. OTHER INFORMATION: Ventilate the area.
SECTION 7: HANDLING AND STORAGE
HANDLING: Prevent buildup of vapors; use with adequate ventilation. Keep from sparks, heat, flame or other heat sources. Keep container tightly closed while not in use. STORAGE: Store in dry, well-ventilated area and in accordance with federal, state, and local regulations. Do not expose to heat or store at temperatures above 48 C (120 F). If storing in cold temperatures, allow product to warm to room temperature before use.
2 N-BUTYL ACETATE 200 ppm 150 ppm 150 ppm 3 *ETHYLBENZENE 125 ppm 100 ppm 100 ppm 4 ETHYL ESTER 100 ppm 50 ppm N/E 5 ALUMINUM FLAKE N/E 10 mg/m3 15 mg/m3 *See Section 15 and Section 11 ENGINEERING CONTROLS: Not generally required if product is applied in small quanti- ties. If product is applied in larger quantities, provide ventilation to keep air contamination below OSHA permissible exposure limits and ACGIH TLV exposure limits. EYE/FACE PROTECTION: Wear safety glasses with side shields. Have eye wash facilities immediately available.
SKIN PROTECTION: Chemical resistant gloves if contact is likely.
RESPIRATORY PROTECTION: Use NIOSH-approved air-purifying respirator with organic cartridge or canister if exposure cannot be controlled within applicable limits with ventilation.
GENERAL HYGIENE CONSIDERATIONS: Wash thoroughly after handling.
Product Description: MATERIAL SAFETY DATA SHEET BMW® TOUCH-UP PAINT BMW® COLORSYSTEM®
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Color: see product description Odor: Solvent Odor Physical State: Liquid Freezing Point: Not established (mixture) Boiling Range: 138 - 177 C (280 - 350 F) Flash Point: 27 C (81 F) Evaporation Rate: Slower than ether Upper Flammability Limit: Not established (mixture) Lower Flammability Limit: Not established (mixture) Vapor Pressure: Approximately 9 mm Hg @ 20 C (68 F) Specific Gravity: 0.960 @15 C (60 F) Solubility (water): Negligible Percent Volatile, wt. %: 59.550 VOC Percent (CA): 59.550 Coating Category (CA): NOT APPLICABLE
SECTION 10: STABILITY AND REACTIVITY
STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Keep away from heat, sparks, and flames. INCOMPATIBLE MATERIALS: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: by fire - Carbon Dioxide and Carbon Monoxide POSSIBILITY OF HAZARDOUS REACTIONS: Will not occur. Product Description: MATERIAL SAFETY DATA SHEET BMW® TOUCH-UP PAINT BMW® COLORSYSTEM®
SECTION 11: TOXICOLOGICAL INFORMATION
# COMPONENT LD50 Oral LD50 Dermal
1 XYLENE 4300 mg/kg 2000 mg/kg
2 N-BUTYL ACETATE 10768 mg/kg 17601 mg/kg 3 *ETHYLBENZENE 3500 mg/kg 5000 mg/kg 4 ETHYL ESTER 5000 mg/kg 10000 mg/kg 5 ALUMINUM FLAKE N/E N/E *See Section 15 See section 3 for other acute effect information. CHRONIC EFFECTS: Prolonged over-exposure to solvent ingredients in Section 2 may cause adverse effects to the liver, urinary, cardiovascular and reproductive systems. Reports have associated the repeated and prolonged occupational OVER- EXPOSURE to solvents with brain and nervous system damage. The deliberate misuse by concentrating and inhaling the vapors may be harmful or fatal. CARCINOGENICITY: See Section 2 for additional information.
SECTION 12: ECOLOGICAL INFORMATION
No data available.
SECTION 13: DISPOSAL CONSIDERATIONS
Do not puncture, incinerate or place container in trash compactor. Dispose of product in accordance with Federal, State, and Local regulations. Product Description: MATERIAL SAFETY DATA SHEET BMW® TOUCH-UP PAINT BMW® COLORSYSTEM®
SECTION 14: TRANSPORTATION INFORMATION
US DOT (Ground) Proper Shipping Name: Consumer Commodity Hazard Class: ORM-D US DOT (Air) Proper Shipping Name: Consumer Commodity Hazard Class: ORM-D-AIR IATA/ICAO (International Air) Proper Shipping Name: Paint ID no.: UN1263 Hazard Class: 3 Hazard Label: Flammable Liquid Packing Group: II Packing Instruction: Y305 (NOTE, maximum net qty/pkg cannot exceed 1L per Y305!) Authorization: LTD QTY No component of this product is a listed Marine Pollutant (49 CFR 172,101,Appendix B).
SECTION 15: REGULATORY INFORMATION
International Chemical Inventory TSCA: United States The components of this product are listed on the TSCA inventory. DSL/NDSL: Canada The components of this product are listed on the DSL inventory. AICS: Australia The components of this product are listed on the AICS inventory. Section 313 Toxic Chemicals See section 2. Chemicals marked with a "Y" are subject to the SARA reporting requirements under 40 cfr 372.45(c)(5).
SECTION 16: OTHER INFORMATION
HMIS(National Paint & Coatings Association's Hazardous Material Identification System):
This MSDS is based on information believed to be reliable and accurate. Because of
changing reporting requirements and other variables it is impossible to guarantee the accuracy of the information contained in this document. It is the responsi- bility of the user to determine proper personal protection based on the actual condition of use and to comply with all Federal, State and Local laws and regulations.
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