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SPE&c4st410fWR4SU13EIWtH90fAIS4E

SPE 14477

Foam and Nitrified Fluid Treatments—Stimulation Techniques


and More
tiyGeorge E. King, Amoco Production Co,
SPE Member

Copyright
1985,
Society
ofPetroleum
Engineers

Thispaper
wasprepared
forpreaenlation
asa Oktinguished
Lecture
during
the1985-86
SPE Distinguished
Lecturer
Program.

ABSTRACT
FoLLowing the familiar coLLapse from superfLuid
The addition of compressed gas to a stimuLat ion status that is part of the introduction of every new
fluid may be one of the biggest advances in well fluid, the best uses of foam were researched and the
treating technology in the past two decades. When applications base expanded by improvements in sur-
carefully deeigned and applied, foams and treatment factants and hardware. By the mid to late 1970’s,
using gas can result in better stimuLatio,\s through foam wbs entrenched as a treatment for shallow, Low
improved proppant placement, more rapid cLeanup, and pressure gas reservoirs whete ite Low water volume
in some cases, Less damage from the treating fLuid. and rapid cLeanup made stimulations possible where
previously onLy esarginaL successe~ had been seen.
Alas, foam treatments”are neither magic nor can From thi~ base, advances in foaming agents such as
they be used as universaL stimulations. Obtaining the fluorocarbons have made oiL reservoir frac-
the maximum benefit from a foam or nitrified fLuid turing practicaL. Improvements in Liquid geLling/
requires thoughtful design and carefuL application. breaking proce:;~e, 6 the mechanical sand
This paper provides information on how to get it concentrators, and changes in bLender designg
done. have increased sardt~;;:ings and helped start foam
massive fracturing, and foam fracturing with
INTRODUCTION high rate proppant Loading.s’12

A LittLe History Foam is an unusual fLuid; very few testing


techniques applicable to Liquid systems13 were
The” first use of foam as a fracturing fLuid was usabLe in gathering data on foams. The recent
reported as 1968.1 The firat widespread use of foam advances in test procedures and stimulation foam
fracturing foLlowed papers by I!lauer, et al.,2’3’4 technology have been due to the persistence of
in the earLy 1970’s. From its introduction as a authors such as Harris 14-16 HoL,.omb,i7-le ~en-
superfluid, foam has rapidly come to be recognized dorf, 20 Ford,21 Lord, 24 and others. The technology
as an exceLLent fracturing fLuid for many reservoirs of foam is just over a decade old, this paper will
and a poor choice in a few others. The best attri- try to report the.advances, the new information, and
butes of foam as a stimulation fLuid were recognized the probLems.
earLy and have endured the process af reduction of
cure-aLl to reality. They are: DISCUSSION

(1) Reduction oi Liquid voLume Foam Basics


(2) Good proppant support
(3) Exceptional fLowback and cleantip. Foams are gas-in-Liquid dispersions with many
of the same traits as emuLsions. The Liquid may be
Other firstheld beliefs such as low fLuid Loss and water, acid, aLcohoL, or oiL, and the gas is usuaLly
very high viscosity vaLues have given way to weLL either nitrogen or carbon dioxide. A surfactant
researched fact. These are discussed Later. stabilizes the foam. The type of surfactant depends
on the liquid phase; a hydrocarbon surfactant foamer
is usuaLLy adequate for water or aqueous acid while
a fluorocarbon surfactant or e mixture of fluoro-
carbon and hydrocarbon sur;~ttfii!ts are ceeded for
References and illustrations at end of paper. oiLe and anhydrous alcohoLe.

—...-
FOAM AN,,N!rRIFIED TLUJIJT“9ATMENTS-STIMULATION TECHNIQUES’AND
2 MORE
w 14477 “
The voLume percent of gas in foam is known as Multiphase gas-in-liquid mixtures have some
the quality. Most fracturing foams are in the range fLuid Loss advantage over a single phase fluid. The
of 60 to 85 quality with only a few applicaticms for effectiveness of the fluid loss control is reported
Eoam above 85 quality. 23 The bubble and quality to be a function Jf the gas phase voium~ with fluid
relationships attributed to Einstein24 and Hat- Loss control increasing as gas concentrati~n rises
schek25?28 by Mitchell*’ and BLauer,3 state that from’5% to 20%.3’ Additional gas VOIUIW over 2JZ

foam enters a bubble interference region (too many showed no improvement in Flu;d loss. Pressure cnn-
bubbles to avoid contact) at qualities of over 54. trol with these gas-cut fluids must account for
rhis is the Lower limit of the regi~n where fLuid their lighter densities.
loss control is noticeably improved over the
gas-in-water dispersions (nitrified fLuids). The 54 Although many beneEits are touted for the
quality lowe~’Limit of the bubble interference nitrified fluids, the most important is rapid Load
region is accurate for monodispersed (sin le bubbLe Eluid recovery and debris removal by faster back-
9
>ize) foam wtly; for polydisperse foams, 1 s1S the flow.
bubble interference region is higher than S4
quality. Exact Limits for this region will vary Additional benefits of C02 are Less trapped gas sat-
with the variation in bubble size, The references uration37 and interracial tens~on and oil viscosity
to Einstein24 ai,dHat~chek2s~26 deal with emuLsions, Lowering effects.
~uspensions, and dispersions; all of which are very
similar to foam structure and the behavior of gas Fracturing Foams
dispersions in liquid.
Foam, as well as any other fluiti, can be used
The deformation region, where bubbles are so for hydrauLic fracturing. Fractures can be created
tightly packed that they must deform, starts at by gas-in-water dispersions, foams of any quality,
about 74 quality for Eoam with a single bubble size and even gas.38’39 ALthough compressible, the foam
mnd somewhere above 74 quality fo;,;~~ actual case can generate bottomhole treating precsure by hydro-
~f a foam with many bubble sizes. The final static Loading and wiLL transfer surface pressure to
Eoam bubble region, that of a mist, starts at about bottomhole. Foams are aLso used to store energy for
92 to 96 quality. In this region, the foam loses backflow of other fluids40’41 or in special cases of
texture and inverts from a gas-in-liquid emulsion to no-proppant fracturing. 42 Where a proppant needs ‘0
s liquid-in-gas emuLsion, and alL suspension and be carried, foams of at Least 65 quality are nor-
viscosity characteristics of the foam disappear mally used aLthough there are reports of success at
lower quality. 43 Foams bf 65 and greater quality
The stability of foam is related to its haLf- are more stable (have Longer measured half-lives)
Life. This is the time required, at static condi- than the Lower quality foams and probably exhibit
tions, to lose half of its volume. The loss of better proppant support. .4sfoam quality increases,
volume begins-with Liquid drainage between the bub- however, the water phase must cairy larger amounts
bles.2* AS the film around the bubbles thins, the of proppant. A 65 quality foam with 4 pounds of
bubbles may rupture and gas separation occurs. The proppant per gallon of foam requires the water
longer the half-Life, the more stable the foam. volume (35% of totaL) to transport 11.4 pounds of
rhese tests must be run under pressure to obtain proppant per gaLLon. To get 4 ppg of proppant in an
meaningful results. 80 quality foam wouLd make the water volume (20% of
total) carry 20 ppg. Obviously, trying this more
Nitrified Fluids and C02 Mixtures than once or twice in a conventional blender will
result in shoveL work to clean out a jammed blender
Nitrified fLuids and fluids containing carbon tub or a pump. When Lar~e proppant loadings are
dioxide are most often used where flowback is diEfi- needed in a foam, conventional equipment and techni-
cuLt because of Low bottomhole pressures or where ques must give way to devices such as the mechanical
long fluid recovery times must be avoided. Volumes sand concentrators or specially designed blending
of nitrogen gas Erom 300 scf per bbl in a 2000 ft equipment.
well with an effective bottomhole pressure of
500 psi to 900 ccf per bbl. in a 10,000 ft welL (at One important difference between foam and an
effective BHP 2000 psi) are common flow ratios for alL liquid fLuid is the surface pressure during a
water or acid.zg Ratioa of gas to liquid other than job: Since foam fracturing fLuids in the 65 to 85
those necessary for~~as lift are sometimes used for quality range exert only about 17% to 40% as much
formation cleaning, weLL circulating, 31’32 and hydrostatic pressure as a pure Liquid, the surface
reestablishing gas saturations in a water damaged pressure when using foam must be higher to achieve
gas reservoir. One common and successful treatment che necessary downhole fracturing pressure.
for removal of water blocks in low pressure gas res-
ervoirs is 20% methanol alcohol in 5% HC1 or water, Rheology
nitrified at 300 to 500 scf per barrel. Flow back
ratios for COZ fluids were not found during the lit- Foam ia a complex fluid which may display dif-
erature search for this paper although reports OE Eerent viscosit at different shear condi-
300 to 500 scf per barreL are common.33 Foam frac- tions.a$ll ,27,4~-WavierAt shear.rates close to what is
turing with COZ is also widely used although there encountered in a frac treatment foam behaves in a
are a few disadvantages such as increased corro- manner which Harris and Reidenbach describe as a
sion.34 Other usefuL informatioq~on C02 are yield pseudopLastic 14?47 (where the yield point ‘s a
reported by Black and Langsford. function of che quality).

,
G. E. KTNC 1
.

~.a.

The basic Lam~nar flow equation for pressure by 5% or more from surfac$gto bottomhole conditions,
Loss of foam at 75 F in a pipe was given as:47 published friction charts can be at least 10% off
a..doften more than 20% in error. To arrive at
better estimates of friction loss requires a calcu-
DAP/4L = T + K’ (8V/D)n’ Lation of foam quality and friction at every point
YP in the tubing during pumping. The information for
this type of calculation is available from several
yield point, T , is a iunction of quality, r, sources .so’s’
YP
Fluid Loss ControL
For r s 0.6, T s o.07r
YP Foam was originally thought to have excellent
fluid loss contro12 but a number of scr~enouts have
shown instances where foam must have leakoff control
For r > 0.6, ‘r = 0.00022r fielp.11~12 There are even a few caaes of leakoff
YP
that foam cannot handle without use of additionaL
fluid loss additives such as 100 mes~ sand.12’s2 As
(Clr+ 0.75r2) shown in several Laboratory papers53 55 and some
=K{~ field reports, 56,57 the fluid 10SS of foam increases
‘:
rapidly in formations with naturaL fractures or
where permeability is above about 5 md. Fluid Loss
1.8 data generated by severaL authora is contained in
where C Figure 2. The best data is probabLy that of
L = 4 ‘is
Harris,54’s5 Craighead,48
?r a5i98&;’#4°;o::~d
acid (in inert cores) by King.
n’ of the foam is assumed :0 be the same as n’ of Lates that Leakoff cuntrol from foams in formations
the base fluid at 75 quaLity and 75°F. with permeabilities below 5 md is heavily influenced
by the vir.coaity of the external phase.
A parent viscosity may then be calculated
from: 4? Spurt Loaa voLumes generated on 2“ diameter by
4-L/2’$long sandstone cores are shown in Figure 3.
The tests were run using snap opening balL valves
n’
4 below a liquid saturated core. The upper surface of
the core was exposed CO flowing foam at 1500 psi and
papp =47880 [we + K (8V/D)n’-11 the chamber beLow the vaLve was set at 500 psi back-
pressure.sa

where 47880 is the conversion factor to centi- In highLy naturaLLy fractured formations, the
poise. Leakoff from foam treatments may be so severe that
large concentrations of fluid loss control additive
Ottierrecent work in foam viscosity has pred- are required. 12 In the early days of foam ‘rac-
icted sLightLy Lower vaLues. 4S Viscosity curves turing, few screenout were seen since the initial
calcuLa~~d from the equations of4~idenbach, proppant concentration in the foam was very low and
et al., and Craighead, et al., are shown in the proppant support characteristics of even m
Figure 1. unstable foam are very good. Much of the fluid
voLume could be lost without over concentrating the
In their work at higher temperature, Harris and sand in the foam. With the development @i processes
Reidenbach14 presented equations for n’ and K’ and equipment that can doubLe or triple the initiaL
which were functions of foam temperature and [he sand concentrations of early treatments, more
room temperature base fluid parameters n~s and screenout~o;~2foam treatments are being
K#5. observed.

In small volume foam fracs, in low proppant


e(0.0028-0.0019r) (T-75)
concentration jobs of about the 2 lb/gaLLon, or
‘; = ‘;5
where a caii end screenout is beneficial, very
LittLe fLuid Loss concroL is needed with foam. In
‘ couLd not have a maximum vaLue of more than 1. Larger jobs and in higher permeability or naturalLy
‘t
fractured formations, additional fluid loss control
in the foam is required. The fluid loss controL
(C2r-0.018)(T-75) additive most compatible with foam is one of the
K: = K* cLean breaking poLymers.53’s7 In severe fluid Loss
75 e
a cross Linked poLymer foam may be neces-
::;;:? or use of a fLuid Loss concrol additive such
-(3.1 + 3n’ as 100 mesh sand.’2’52 With the polymers, fluid
where C = e 75)
Loss control can be improved over clean foam as
2 shown in Figure 4. With the addition of polymer;
however, comes a new consideration, the foam will be
more stabLe and may require a Longer break time
Viscosity and the resultant friction caLcuLa-
tions are heaviLy influenced by changes in the
quaLity of foam. Since foam quality changea, often

.–. .— —.. .
tw.w AND NIrRi”” EIJ LUIII “P $l”!lFN7S-STIMULATION
TEcHNIQUES AND

WE 144?7

prior to flowback. The break Ilme should h~~ be gelled to carry the proppant prior to creating
established by Laboratory tests prior to the tre~t.- foam. Rheology and fluid loss daLa on the alcohol
nent. This wilL heLp avoid trial and error backflow foams are available in the literature.4s’6s In gen-
rates and damage to the fracture proppant pack. eral, the aLcohoL foams are Less viscous and have
higher fLuid Loss than aqueous foams. Addition of
A method of fluid diversion using foams of dif- poLymer improves performance in both areas. Cra[g-
ferent qualities has been proposed.43 The main head, e& al., 48 aLso agree with Harris
“ 54 that the
basis of this argument is that the higher quality viscosity of the externaL foam phase directly
Eoams are more viscous and will divert the treat- affects leakoff. Use of polymers in the alcohol
nent. Although still advanced by some, the system foams generated some walL buiLding effects which
tas not worked for this author in field tests using further reduced fluid leakoff.
95 quality pads in a 65 quality treatment. Part of
the reason for the failure appears to be no signifi- Foamed oiLs have been availabLe for some time
cane difference in fluid loss between 65 and 80 but have not grown in popularity aLong with the
qualit foams, especially at permeabiLities beLow water foams. The oiL foams have been6g:g$ for sti-
5 ~d.5~*54 Some success has been reported, however, muLation in very sensitive formations and in
using 70 quality stages in 40 to 50 quality some cases of paraffin removaL. ‘8’69 The foamed
oiLs are probably a better choice than foamed waters
(unstabLe foam) treatments.sg
for fracturing of oiL reservoirs since there is less
Proppant Carrying Capacity chance of destabilized foam during tht treatme~ts or
creating emuLsions during fLowback.
Foams are evidentLY excellent proppant support
Eluids. There has not been an analytical study of Backflow
the proppant silpportof fracturing foams at high
pressure. The only known studies of proppant car- Even the best proppant-;ontaining fo~m frac can
rying capacity of fracturing foam were done at be ruined by a poor flowback procedure.’” 72
atmospheric pregsure.“6° There is, however, a good Because of Its proppant support capacity, ?oam can
study on slip velocities in drilling foam avail- easily pull the proppant out of the fracture and
~ble.sl The results of sLip of sphericaL particLes drop it in the pit where its use as landfill is
in this air foam indicate very low settling veLoci- quite expensive. On a few occaaions, I have
ties. ALso, numerous foam treatments have been observed 20% to 50% of the totaL amount of proppant
stopped for over an hourll’62 without accumulating used in the treatment returned to the pit after
sand in the casing and without difficulty on the fLowback of some earLy foam treatments. Uncont-
restart with a proppant laden fluid and no pad. The roLLed or poorly supervised flowbacks can “severeLy
onLy case of severe proppant dropout in the tubulars reduce the capacity of a propped fracture.
due to a shutdown that I have observed was a foam
which fLashed back through a broken surface connec- Uhen using a foam which carriea proppant, the
tion. The flowback Left a sand plug in the tubing formation must be alLowed to cLose on proppant
at about 1200 fc in a 2700 ft well. The pressure before the weLL is turned around. Too short a clo-
was reduced sufficiently to reach the mist region sure time wiLl aLlow the proppanc to be removed, too
during the uncontrolled fLow back, which dropped the long a shut-in time wiLL aLlow the recovery energy
sand from the foam. to dissipate.

As with any fLuid that has demonstrated good prop- A recovery procedure advanced by Holcomb73’74
pant carrying capacity, there are a few important is probably the most effective in recovering the
considerations for design and application. After fluids without proppant pack damage. He points out
the pad, the entire foam frac fluid volume shouLd that when brought back as a mist, foam Losses its
contain proppant. Any use of no-proppant pads in proppant support. A brief recapitulation of this
the body of the treatment would Likely result in procedures is as follows:
parts OE the fracture cLosing or severely reduc~ng
fracture width. A foam frac (with proppant) shoul,d L. Rig up aLL flow Lines and wellhead with an
never be overflushed. The proppant will be carried adjustable choke prior to treatment. -
away from the weLLbore and the well will appear to
be damaged. 2. Rig Fressure gauge to maintain a welLhead preb-
sure no higher than 200 psi under closure pres-
Nonaqueous Foams sure.

With the introduction of foamers for hydrocar- 3. Open choke to 12/64, allow enough time for
bons and aLcohoLs, foams can be even less damaging flush voLume to be recovered, check for prop-
to water sensitive formations. The use of an pant flow. If proppant is being produced,
aLcohoL in foam was first reported in 1978.e3’64 shut-in for 15 minutes and then resume the
Since the earLy jobs using mixtures of alcoh~~ and flowback on a 12/64 inch choke.
water, 100% methanol has been used in foams.
These nonaqueous systems, especially the 100% 4. If no significant proppant is detected, open
aLcohoL foams, are not as stable as the water base the choke to 24/64 inch for 1 hr.
fLuids. Leakoff is more rapid (Figure 5) and a
higher incidence of screenout may be expected. The 5. If no significant proppant is detected, open
aLcohoL in the foamed alcohol fracs normally has to the choke for 36/64 inch for L hr and finaLLy

. .

.—
.
C. E. KING 5
SPE
--- -— 1447.7

to 48/64 inch. If proppant is detected at any These formations had,a,hisr.ory .f damage or “death”
time, shut-in the wellhead and restart the after treating “with conventional liquid fluids. The
procedure with the choke on 12/64 inch. Sig- Eoamed fluids, including foamed alcohoL and hydro-
nificant proppant “in the backfLow ie considered carbons, have shown dramatic success.
to be 50 or more grains obtained in 1 pint of
the returning fLuid. Some proppant fLowback is At the present time, the only reaL constraints
associated with any type of fracturing treat- on foam are (1) surface pressure limitations and
ment, if kept to a minimum, it causes little well control on high pressure wells, and (2) the
harm. relative permeability problems associated with the
use of nitrogen foams and nitrified fluids in an oil
ROFP detailed fLowback procedures are available reservoir which is above the bubble point. The
73*74 (jther nitrogen gas, which is only slowly soluble in crude
in the referenced articles.
articles offer additional comments on flow- oil, will create a trapped gas saturation. This
backOt!5?70?72 relative permeability effect will be slowly removed
by soLubilization in produced oil. Carbon dioxide
The controlled flowback procedure also reduces foams also may protiucea trapped gas saturation, but
the chance of casing collapse due to rapidLy C02 is more soluble in oil and water.
reducing preseure in the pipe before the
pressured-up zone behind the pipe can be relieved. High permeability formations (above about
This point is important in foamed acid recoveries 20 md) are aLso more difficult to treat with foam
where fLowbacks can usuaLLy be much quicker. [t due to leakoff Leases. This can be controlled in
should be noted, however, that casing collapse after some cases by polymers or fluid loss additivee; how-
a foam job is virtuaLly unknown. BackfLow of prop- ever, the very limited folds of production increase
pant or high rate return of soLids can also severeLy at the higher permeabilities usuaLLy make any type
damage chokes. One source reports cutting out,~s of fracturing uneconomic.
many as 30 chokes on a high velocity backfLow.
P@&!!
Foam Acidizing
The design of a foam frac may be done by com-
Foam acidizin$ is one of che highLights of the puter simulation package or by hand caLcuLa-
foam fLuids.19*5s~ 6-80 Nitrogen has been used in tions.sO’51’a3-8s The application of a foam frac
acid for a number of years to speed flow back requires knowledgeable corrections to deal with
response and remove undissolved soLids from the changirigpressure cf~$~~~~ns which may radically
fractures and vugs. Foaming the acid goes one step aLter foam quality. The corrections are
further by changing the acid reaction rate to some simple, if properly done. Modifying the design in “
carbonates. The basic acid reaction control the field, even changing sand Loading, requires
reported by Fordzl is “mass transfer or diffusion” changes in nitrogen or,~~ Mid injeccion rate to
maintain foam quality. ‘i?
(the same as for liquid HCL) for Limestones. Foam
acid reactions, however, with dolomites at low tem-
peratures were said to be controlled by surface Application
rea@ion kinetics. In limes~t~ngS,.andin dolomites
at higher temperatures, the speed of the mass The mechanical equipment used in foam fra~-
transfer of acid to and from the waLL of fracture turing has been described in nurnerons papersa’ ‘1
wiLl dictate the speed of the acid reaction. The and need not be mentioned beyond a brief synopsis.
acid reaction rate of foamed acid wiLL be Less since In nitrogen jobs, a nitrogen pumper pumps liquid
foam viscosity will SLOW the mixing of acid in the nitrogen (-325°F) through a diesel fired heat
fracture. An::.her interesting observation about exchanger which converts the Liquid co a gas and
was the creation of stabLe delivers it at pressure to the “T” junction in the
such as shown in the photographs and
~~~~n~~~;!!~gbehavior treating string. The gas mixes at this point with
metal cast of Figure 6. the surfs tant containing sand-Liquid mixture or
acid from ~he bLender and pump truck. The foam is
The greatest benefits in Eoam acidizing, how- formed and stabilized by the turbulent mixing of the
ever, may be from the rapid recovery of spent acid, gas and liquid at the “T” and down the length of the
Liberated fines, and partially dissolved scales. In tubing. In carbon dioxide treatments, the C02 is
several casuaL studies of foam fracs I have seen, as pumped as a liquid, mixing with the sand-water mix
much as 70% more solids have been recovered with a or acid between the blender and the pump truck. In
foamed acid job as compared to an aLL Liquid job. the initial stage, the C!2Z “Foam” is COZ Liquid
mixed with the stable liquid. After heating in the
Reservoirs tubing or in the formation, or when pressure is
reduced, the C02 enters a dense phase and finally a
Foams have been successfu\~y used on gas form. More compLete discussions on C02 are
z3*81 Lightsandstones~ and carbo- available in Che literature.
33-35?37)62}90
~fi~;~;6’7g From the early operations base of Low
pressure gas sands, the jump to shaLe and other sen- One of the original drawbacks to foam was the
sitive formations was rapid. Among the most inter- inability to get more than about 2 pounds of sand
esting applications has been the use of foam per gaLlon of foam. Since the sand was necessarily
fracturing of the Devonian Shale73’al’82 the compLex mixed in the water before foaming, only about 8 ppg
Niobrara Formation,64’67 and coal degas weLLs.42 of sand was carried to mix at 1 part water to 3

.-
FOAM AND NTTRI,PIRD FIJIJO“’REATMENIS-S1lM
ULATION TECHNIQUES AND
6 MONK .
S?E 14477

parts gas. The sand Concentrate.nn dropped ff 2 ppg t = foam yield point, lbf/ft2
in the foam. The problem was ti’Rstaltacked by YP
using a crosslinked gelled wfitpr to carry more sand DAP/4L = water shear stress, lbf/ft2
to the “T”.6 Since the crossllnked fiuids tended to
over stabilize the foam, snap acting breakers were 8VID = Shear rate, sec -1
included ’to drop the water viscosity about the time
it was foamed. Like most chemical breakers, it is a Bibliography
bit touchy to get everything =ight. Recent improve-
ments to carry more sand have been the sand concen- 1. Crundmen, S. R., and D. L. Lord: “Foam Stimu-
trators”a which by centrifugal action or vacuum lation” SPE 9754, presented at the Prod. Opera-
remove a portion of the water immediately before the tions Symposium” OkLa. City, March 1-3, 1981
gas is added. Charges in blender tub and pump
designg have also been incorporated in the evolution 2. Blauer, R. E., and C. A. Kohlhaas: “Formation
of equipment to achieve higher sand concentrations. Fracturing with Foam”, SPE 5003, presented at
Success with these devices have been very good and the 49th Annual Tech. Conf., Houston Oct. 6-9,
proppant concentrations in the foam of 4 to 8 ppg 1974.
have been achieved.
3. Blauer, R. E., and B. J. MitchelL: “Determina-
Effect of Temperature tion of Laminar, Turbulent, and Transitional
Foam FLOW Losses in Pipes”, SPE 4885, presented
The effect of temperature on foam appears to be at the Calif. Regional Mtg, San Francisco, .
minor in the few high temperature experimefits to be April 4-5, 1974.
run thus far. The viscosity is reduced,14 ae shown
in Figure 7, but the other properties~~uch as fluid 4. Blauer, R. E., and D. L. Holcomb: “Foam
loss control,54’5s foam acid etching, and proppant Fracturing-Application and History,” South-
sup ort are LittLe affected tittemperatures to western Petroleum Short Course, Lubbock, April
~
300 F. 1975.

Foams have been applied in the field in wells 5. Clark, H. B., M. T. Pike, and G. L. RengeL:
with bottomhole temperatures from 80°F7a to 185°F12 “The Use of Fluorochemical Surfactants in Non
on a regular basis. Deeper wells with temperatures Aqueous Stimulation Fluide”, J. Pet. Tach.
to 280°F have also been fractured with foam.11 (Oct. 1980), pp. 1695-1697. .

Surface Monitoring of Foam Fracs 6. Lewis, A. D., and C. F. Ferguson: “An Improved
Foam Fracturing Process”, Southwestern Petro-
140nitoring surface pressure to check on Leum Short Course, Lubbock, April.1976.
diverter performance or to use the Nolte-Smithg2’g3
technology is more difficult with foams because of 7. Anderson, H. A., and J. B. Palmer: “The Sand
their compressibility and resultant pressure sensi- Intensifier--Its Development and Application to
tive nature. The best approach to the gathering and Fracturingt’,J. Can. Pet. Tech. (April-June
use of pressure data is to use downhole monitors 1981), pp. 45-50.
with surface readouts.
8. “Proppant Concentrator Boosts Foam Frac Effec-
Nomenclature (after Harris and Reidenbach)14’47 tiveness”, Drilling (Nov. 1981), pp. 124, 126,
131.
C1,2 = Foam consistency, index exponent
9* Ely, J. A.: *’RecentMechanical and ChemicaL
K’ = consistency index Improvements in Foam Fracturing,” Southwestern
Petroleum Short Course, Lubbock, April 1985.
= consistency index of foam
‘;
10. Bleakley, W. B.: “Mitchell Energy Foam Fracs
K; = consistency index of liquid phase Tight Gas Zones”, Petrol. Eng. Int.
(Dec. 1980), pp. 24, 26, 28.
K+5 = consistency index of liquid phase at 75°F
11. Wendorf, C. L., and B. R. AinLey: “Massive
K; = consistency index of liquid phase at high Hydraulic Fracturing of High Temperature Wells
temperature with Stable Foam Fracs”, SPE 10257, presented
at the 56th Annual Tech. Conf., San Antonio,
n’ = flow behavior index Oct. 5-7, 1981.

n+s = flow behavior index 12. Coelitz, R., and G. E. Evertz: “Foam Frac-
turing in the Unita Basin - A Field Study of
n’ = flow behavior index of liquid phase ac the Dakota and Uasatch Formations”, SPE 10883,
high temperature presented at the Rocky Mtn Regional Mtg., Bill-
inge, Hay 19-21, 1982.
r = fractional.foam quality
13. Howard, C. C., and C. R. Fast: “Hydraulic
T = temperature, F Fracturing,” SPE Monograph, VOL. 2 (1970),
p. 31.

14. Harris, P. C., and V. G. Reid?nbach: “High Between Foam 8ubbles,” I. and E.Q
Temperature Theological Study of Foam Frac- Fundamentals, Vol. 6, N~y 1967),
turing Fluids”, SPE 13177, presented at tha p. 225-231.
59th Annual Tech. Conf., Houston, Sept. 16-19,
1984. 29. Nowsco Services’: “Nitrogen Calculator,”
approximations. (Effective BHP is 80% of
1s. Gaydes, J. S., and P. C. Harris: “Foam Frac- static 8HP for gas wells and 50% of static BHP
turing Theories, Procedures, and Results”, for oil wells).
Southwestern Petroleum Short Course, Lubbock,
April 1982. 30. Boren, R. J.: “Stimulation and BackfLow of
Injection Wells Using Nitrogen Techniques”,
16. Harris, P. C., and D. E. Bailey: “Stimulation Southwestern Petroleum Short Course, Lubbock,
Results in the Low Permeability Wasatch Forma- April 1973.
tion - An Evolution to Foam Fracturing”, &
Pet. Tech., (Sept. 1SS4), pp. 1545-1551. 31. Milhone, R. S., C. A. Haskin, and A. H. @eyer:
“Flow Behavior of Foam, as a Well Circulating
17. Holcomb, D. L., R. E. Callaway, and L.L. Curry: Fluid”, SPE 4001, presented at the 47th Annual
“Chemistry, PhysicaL Nature, and Rheology of Tech. Conf., San Antonio, Oct. 8-11, 1972.
Aqueous Stimulation Foams”, Sot. Petrol. Eng.
~ (Aug. 1981), pp. 410-414. 32. Beyer, A. H., R. S. Millhone, and R. W. Foote:
“Flow Behavior of Foam as a UeLL Circulating
18. Holcomb, D. L., B. C. Ewing, and M. A. Scott: Fluid”, SPE 3986, presented at the 47th Annual
“The Structure of FLowing Aqueous Stimulation Tech. Conf., San Antonio, Oct. 8-11, 1972. “
Foams at High Pressures,” presented at AIChE
Summer Meeting, Denver, Aug. 28-31, 1983. 33. Chapman, R.: “Acidizing Low Pressure Gradient
Wells Lking Carbon Dioxide”, SPE 9694, pre-
19. Holcomb, D. L.: “Foamed Acid aa a Means for sented at the Deep Drilling and Production Sym-
Providing Extended Retardation”, SPE 6376, pre- posium, Amarillo, April 5-7, 198L.
sented at the Permian Basin Oil and Gas
R.scovery Conf., HidLand, Harch 10-11, 1977. 34. Harris, P. C., R. J. Haynes, and J. P. Egger:
!~Theuse of C02 Based Fracturing Fluids in Rad
20. Wendorf, C.L., and R.B. Earl, “Foam Fracturing Fork @ormation~” J. Pet. Tech. (June 1984),
Laboratory”, SPE 12025, presented at the 58th pp. 1003-1008.
Annual Tech. Conf., San Francisco, Oct. 5-8,
1983. 35. Black, H. N., findR. W. Langsfoid: “Energized
Fracturing with 50% COZ for Improved Hydro-
21. Ford, W. G. F., and L. D. Roberts: “The Effect carbon Recovery”, J. Pet. Tech. (Jan. 1982),
of Foam on Surface Kinetics in Fracture Aci- pp. 135-1400
dizing”, J. Petrol. Tech. (Jan. 1985),
pp. 89-97. 36. Foshee, W. C., and R. E. Hurst: “Improvement
of Well Stimulation Fluids by Including a Gas
22. Lord, D. L.: “Analysis of tiynamicand Static Phase,” J. Pet. Tech., (JuLY 1963), p. 768-772.
Foam Behavior”, J. Pet. Tech. (Jan. 1981),
pp. 39-45. 37 ● Poettman, F. H.: “Vaporization Characteristics
of Carbon Dioxide in a NaturaL Gas-Crude Oil
23. Scrang, D. L., and J. L. Norton: “Foamed Sand System, Trans. A.I.K.E. (195L), 192, 141-144.
Provides Improved Stimulation Results from
Devonian Shale’’,”SPE 2312, presented at the 38. Freeman, E. R., J. C. Abel, and C. M. Kim: “A
Eastern Regional Meeting, Champion, PA., Stimulation Technique Using onLy Nitrogen”, SPE
NOV. 9-11, 1983. 10129, presented at the 56th Annual Tech.
Conf., San Antonio, Oct. 5-7, 1981.
24. Einstein, ALbert: “Eine Neve Bestimmung Der
Mole Kuldimensiowen,” AnnaLen Der Physik 39. Abel, J. C.: “Application of Nitrogen Frac-
(1906), V. 19, SFl?4, p. 289. turing in the Ohio Shale,” SPE 10378, pre-
sented at the Eastern RegionaL Meeting,”
!lDieViskositat Der Disper-
25. Hatschek, Emil: Columbus, Nov. 4-6, L981.
soide, I. Suspensoide,” Kolloid Z (1910), v. 7,
p. 301-304. 40. Ainley, 8. R. and J. C. Charles: “Fracturing
Using Stabilized Foam Pad;’,SPE/DOE L0825, pre-
~!DieViskositat Des Disper-
26. Hatschek, Emil: sented at the Symposium on Unconventional Gas
soide II. Die Emulsionen Und Emulsoide.”
,_ Kol- Recovery, Pittsburgh, May 16-18, 1982.
LoidZ (1910), v. 8, p. 34-39.
41. Rullen. R. S.: “Combination Foam/Fluid Frac-
21. Mitchell, B. J.: “Viscosity of Foam,” Ph.D. turing;” J. Can. Pet. Tech., (JuLy-Sept.~
Dissertation, University of Oklahoma, 1969. 1980), p. 51-56.

28. Haas, P. A., and H. F. Johnsm: “A Model and 42. Mahoney, J. V., P. B. Stubbs, F. C. Schnerer,
Experimental Results for Drainage of Solution and F. X. Dobscha: “Effect of a No-Proppant

I
n
. .. ....
MORE

s~E 14477

Foam Stimulation Treatmenl ~n a Coal Seam 57. Watkins, E. K., C, L. Wendorf, and B. R.
De~asification WelL”, SPE/DOK 8931, presented Ainley: “A New Crosslinked Foam Fracturing
at the Symposium on Unron ‘en~ional Gas Fluid”, SPE 12027, 58th Annual Tech. ConF., San
Recovery, Pittsburgh, May 18-21, 1980. Francisco, Oct. 5-8, 1983.

43, HoLcomb, D. L., and S. C. WiLson: “Foamed Aci- 58. Kings G. E.: “Laboratory Investigation of
dizing and SeLective Diverting Using Stable Foamed Acid as a Fracturing Fluid in Carbonate
Foam for Improved Acid Stimulation”, South- Formations”, independent study project, Univer-
western Petroleum Short Course, Lubbock, April sity of Tulsa, June, 1!381.
1978.
59. Conversation with Dave ‘!oLcomb, Smith Energy.
44. Mitchell, 8. J.: “T~st Data Fill Theoretical
Gap on Using Foam as a Drilling Fluid”, Oil and 60. Elswi, T. D., and G. W. Anderson: “Foam Gravel
Gas J. (Sept. 6, 1971), pp. 96-100. Packing,” SPE 11013, presented at 57th Annual
Tech. Conf., New Orleans, Sept. 26-29, 1982.
45. Vocadlo, J. J., and K. E. Charles: “Character-
llAeAnalysis of Slip velocities
ization and Laminar Flow of Fluid-T.ikeVisco- 61. Abbott, W. A.: ...
plastic Substances”, Can. J. of Chern.Eng., of Spherical ParticLes in Foam Drilling Fluid,”
(Feb. 1973), pp. 116-121. Master of Science Thesis, Colorado School of
Mines, 1974.
46. Hoffer, M. S., and E. Rubin: “FLow Regimes of
Stable Foams”, I. & E.G. Fundamentals, 62. Warnock, W. E., P. C. Harris, and D. S. King:
Aug. 1969. pp. 483-490. “Successful FieLd Applications of C02 Foam
Fracturing Fluid in the Ark-La-Tex Region”, ~
47* Reidenback, V. G., P. C. Harris, Y. N. Lee, and Pet. Tech. (Jan. 1985), pp. 80-88.
D. L. Lord: “Theological Study of Foam Frac-
turing FLuids Using Nitrogen and Carbon 63. King, G. E., and T. M. Brown: “Performance of
Dioxide”, SPE 12026, presented at the 58th Amoco A-SOL aa a Mutual Solvent”, Southwestern
Annual Tech. Conf., San Francisco. Oct. 5-8, Petroleum Short Course, Lubbock, April 1978.
1983.
64. Rohret, M. T., and T. C. Jones: “Stimulation
48. Craighead, M. S.p M. Hossaini, and R. W. of the Niobrara Formation Using Foamed Methanol.
Watson: “Foamed A,nhydrous Methanol StimuLa- Water’”, SPE 7174, pr>sented at the Rocky Mtn
tion”, SPE 12315, presented at the Easterri Regional Meeting, Cody, May 17-19, 1978.
Regional Meeting, Champion, PAF, Nov. 9-11,
1983. 65. 8J Hughes: “Nitrogen/Foam Technical Oata.”

49. Krug, J. A.: “Foam Pressure Loss in Vertical 66. Holcomb, D. L., R. E Callaway, and L. L. Curry:
Tubing”, Oil and Gas J. (Oct. 6, 1975), “Foamed Hydrocarbon Stimulation of Water Sensi-
Pp. 74-76. tive Formations”, SPE 9033, presented at Rocky
Mtn. Regional Meeting, Casper, May 14-16, 1980.
50. Nowsco Services “Nitrogen Technical Manual”.
67. Driscoll, P. L., J. C. Bowen, and M.A. Roberts:
51. Smith Energy “Foam Manual”. “Oil Base Foam Fracturing AppLied to the Nio-
brara ShaLe Formation”, SPE 9335, presented at
52. Ford, W. G. F.: “Foamed Acid Stimulation of the 55th Annual FalL Ileeting, DaLlas,
OLd Wells,” Pet. Eng. Int. (Dec. 1980), p. 96, Sept. 21-24, 1980.
98, 100.
68. Smith, H. A., and D. L. Holcomb: “Foamed
53. King, C. E.: “Factors Affecting Dynamic FLuid Hydrocarbons: Compatible Stimulation and
Leakoff with Foam Fracturing Fluids”, SPE 6817, CLeanout Agents,” Pet. Eng. Int. (Sept. 1969),
presented.at the 52th Annual Tech. Conf., p. 76, 78, 82, 84, 86.
Denver, Clct.9-12, 1977.
69, Smith, M. A.t and D. L. Holcomb: “Foamed
54. Harris, P. C.: “Dynamic Fluid LOSS Character- Hydrocarbons: An Effective and Economical
ist’icsof Foam Fracturing Fluids”, SPE 11065, Alternative to Conventional Stimulation
presented at the 57th AnnuaL Tech. Conf., New Methods”, Southwestern Petroleum Short Course,
Orleans, Sept. 26-29, 1982. Lubbock, April 1979.

55. Harris, P. C.: “Dynamic Fluid-Loss Character- 70. Fielder, E., and C. L. Boney: “The Use of Foam
istics of C02 Foam Fracturing Fluids”, Fracturing Fluids in the Fort Worth Basin”,
SPE 13180, presented at the 59th Annual Tech. Southwestern Petroleum Short Course, Lubbock,
Conf. , Houston, , Sept. 16-19, 1984. ApriL 21-22, 1982.

56. Norton, M. C., and S. J. Hoffman: “The Use of 71. King, G. E.: “Foam ~timulation Fluids: What
Foam in Stimulating Fractured California Reser- They Are, Where They Work”, PetroL. Eng. [nt.,
voirs”, SPE 10769, Calif. Regional Mtg, San iiOL. 8, N.54 (July 1982), pp. 22, 56, 58, 60.
Francisco, March 24-26, 1982.
72. Hack, D., M. Mooney, and C. Terry: “Correct 87. Bullen, R. S., and T. F, Bratr~d: “Fracturing
Procedures Improve Foam Fracture Treatments,” with Foam”, Pet, Soc . of CIM preprint, pre-
PetroLeum Eng. Inst., (Nov. 1983)) p. 64? 66, sented at the 26th ~nnual Tech, Mtg. Banff,
68, 70-?2, 74. June 10-13, 1975.

73. Holcomb, D. L.: “Correct Flowback Procedure - 88. Abbott, 8.: “Design, Logistics, and Implemen-
A Key to Successful Foam Stimulation”, South- tation of a Foams Frac Job”’t presented at the
western Petroleum Short Course, ApriL 1983. Symposium on Stimulation of Low Permeability
Reservoirs, Colorado School of Hines,
74. Holcomb, D. L.: “Plinimizing Problems D~ring Feb. 16-17, 1976.
FLowback After Foam Stimulation”, presented at
the The Denver Petroleum Exhibition and Confer- 89. Holditch, S. A. and R. A. plumer: #*TheDesign
ence, Denver, October 2-3, 1984. of Stable Foam Fracturing Treatments”, South-
western Petroleum Short Course, ApriL 1976.
75. Tiner, R. L., and C. E. Folmnsbee: “Foam
Stimulation-State of the Art,” Proc. of 90. Leinan, A. C., and P. C. Harris: “Carbon
Drilling and Prod. Inst. Ur.iv. of Kansas, Dioxide Aqueous Mixtures and Fracturing Fluids
Feb. 4-5, 1981. in Western Canada,)’ paper 83-.34-36, presented
at 34th Annual Tech. !ftg.of CIM, 8anff,
76. Wilson, S. C.: “Foamed Acid Stimulation of the May 10-13, 1983.
San Andres: An Area Study”, Petrol. Eng. Inter-
national (M.v 1978), pp. 90-98. 91. BalLard, J. L.: “Successful Application of
Foam Frac to Shallow Cas Sands”, SPE 6377, pre-
77, SherubeL, C. A. and C. W. Crowe: “Foamed Acid, sented at the Permian Basin OiL and Gas
A New Concept in Fracture Acidizing”, SPE 7568, Recovery Conf., MidLand, March 10-11, 1977.
presented at the 53rd Annual Tech. Conf., Hou-
ston, Oct. 1-3, 1978. 92. Nolte, K. C., and M. B. Smith: “Interpretation
of Fracturing Pressures,” SPE 8297, presented
78. Ford, W. G. F., L. F. Burrkleca, and K. A. at the 54th Annual Tech. Conf. Las Vegas,
Squire: “Foamed Acid Stimulation: Succe?=~ in Sept. 23-26, 1979.
the IILinois and Michigan Basins’*,SPE 9356, -
presented at the 55th Annual Tech. Conf., 93. Nolte, K. C.: “Determination of Fracturing
Dallas, Sept. 21-24, 1980. Parameters from Fracturing Pressure Decline,”
SPE 8341, pre:?nted at the 54th Annual Tech.
79. Petryk, R. P., and B. W. Coruk: “Fracture Aci- “ Conf., Las Vegas, Sept. 23-26, 1979.
dizing with Foamed Acid: Success in the Cross-
field D-1 Carbonate,” Paper 69-30-37, presented
at Pet. Sot. of CIM, Banff, Hay 8-11, 1979.

80. Ford, W. C. F.: “Foamed Acid, An Effective


Stimulation Fluid”, J. Petrol. TechnoL. (July
1981), pp. 1203-1210.

81. Komar, C. A., A. B. Yost, and A. R. Sinclair:


“Practical Aspects of Fracturing the Devonian
Shale”, SPE 8345, presented at the 54th Annual
Tech. Conf., Las Vegas (Sept. 23-36), 1979.

82. Komar, C. A., A. B. Yost, and A. R. Sinclair:


“Foam Fracturing the Devonian ShaLe,” World OiL
(July 1980), p. 119, 120, 122, 124} 126, 128,
132, 134.

83. Holcomb, D. L.: “Foam for Fracturing and Acid


Stimulation, Pt. 1“, DrilLing (Jan. 1982),
pp. 46-48, 52, 168.

84. Holcomb, D. L.: “Foam f-r Fracturing and Acid


Stimulation, Pt. 2“, DriL1.ing (Feb. 1982),
pp. 128, 131, 132, 134, 136.

85. Holcomb, D. L.: “Foam for Fracturing and Acid


Stimulation, Pt. 3“, DrilLing (May 1982),
pp. 199, 200, 203, 20A, 206, 210.

86. Shotton, B.: “EFF .< of Sand Concentration in


Foam Fracturing’’,”Southwestern Petroleum Short ,
Course, Lubbock, April 1982.
NITROGEN FOAM FLUID LOSS COEFFICIENTS
VISCOSITY VS QUALITY FOR AQUEOUS NITROGEN FOAMS
75 QUALITY FOAM, NO POLYMERS OR STABILIZERS
AT 170 SE~AND 75 F
flGURE 2
FIGURE 1
300

250

200

150

100

50

o.000;~; , , ,, mm I , I I 1

’60 65 70 75 80 85 90 10 110
FOAM QUALITY CORE PERMEABILITY. MD

NITROGEN F@W! SFUHT LOSS. 75 QUALITY FOAM, NO POLYMERS NITROGEN FOAM FLUID LOSS COEFFICIENTS
75 QUALITY FOAM, WITH POLYMER
OR STABILIZERS, 2“ DIAM X 4.5” LONG CORE – FROM KING w
FIGURE 3 “ FIGURE.4 .

o
“ ‘“”r~

I I I I 1-
11
I I I
g
0.01 .
t
Ii
ii
E
% 0.001
0
-1
n
q .—
L
0.0001
0.01 0.1 1 10 100
CORE PERMEABILITY, MD

.
*

* SPE 14477

ax

d; ‘J:S il~L LV A.ISK&A LN3&VdaV

l\
1
.—

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