Two Year CRP (1618) B-Lot Pt3 Jee Paper-2

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
CPT3 - 2 PAPER - 2
Time Allotted: 3 Hours Maximum Marks: 240
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
BATCHES – 1618
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each section is further divided into two sections: Part A & C.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

(i) PART-A (01 – 08) contains 8 Multiple Choice Questions which have One or More Than One Correct
answer. Each question carries +4 marks for correct answer and –2 mark for wrong answer.
PART-A (09 – 12) contains 2 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions
have to be answered. Each question has Only One Correct answer and carries +4 marks for the
correct answer and –2 mark for a wrong answer.
(ii) PART-C (01 – 08) contains 8 Numerical Based questions with Single Digit Integer as answer, ranging
from 0 to 9 and each question carries +4 marks for correct answer. There is no negative marking.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________
FIITJEE Ltd., Punjabi Bagh Centre, 31-32-33, Central Market, West Avenue Road, Punjabi Bagh (West), New Delhi - 110026, Ph: 011-45634000
PT-III-(Paper-2)-PCM-IITJEE/18
2
S
SEEC
CTTIIO
ONN –– 1
1:: P
PHHY
YSSIIC
CSS
PART – A
(Multi Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
1. In the figure shown the block of mass m is in equilibrium initially.

Now the block is pushed down by a slight distance and released.
(springs are identical and massless having spring constant k) Then
mg
(A) Initial elongation of the spring is .
2k cos θ θθ
mg
(B) Initial elongation of the spring is . m
2k cos2 θ
m
(C) Time period of oscillation of the block is 2π .
2k cos2 θ
m
(D) Time period of oscillation of the block is 2π .
2k cos θ
2. The temperature drop through a two layers furnace wall is

900ºC. Each layer is of equal area of cross-section. Which of the Inner Outer
following actions will result in lowering the temperature θ of the
layer layer
interface? 1000ºC 100ºC
(A) by increasing the thermal conductivity of outer layer
(B) by increasing the thermal conductivity of inner layer
(C) by increasing thickness of outer layer
(D) by increasing thickness of inner layer θ
3. Two concentric spherical shells masses m1 and m2 and radii r1 and r2 .

Then m2 m1 m3
(A) outer shell will have no contribution in gravitational field at point P
(B) force on P is directed towards O P
Gm1m2
r
(C) force on P is r1 O
r2
Gm1m3
(D) force on P is r2
r2
space for rough work
3
4. A particle of mass m is moving in a field where the potential energy is given by

U(x) = U0 (1 − cos ax) , where U0 and a are constants and x is the displacement from mean
position . Then (for small oscillations)
m
(A) the time period is T = 2π (B) the speed of particle is maximum at x = 0
aU0
π m
(C) the amplitude of oscillations must be (D) the time period is T = 2π 2
a a U0
5. The x coordinate of a particle moving on x axis is given by x = 3 sin100t + 8cos2 50t where x
is in cm and t is time in seconds. Which of the following is/are correct about this motion
(A) The motion of the particle is not SHM
(B) The amplitude of the SHM of the particle is 5cm
(C) The amplitude of the resultant SHM is 73 cm
(D) The maximum displacement of the particle from the origin is 9 cm
6. A block A of mass m connected with a spring of force constant k

is executing SHM on a frictionless surface. The position (x) and
time (t) equation of the block is x = x 0 + a sin ω t . An identical
block B moving towards negative x-axis with velocity v0 collides A v0 B
x
elastically with block A at time t = 0. Then
m
(A) displacement time equation of A after collision will be x = x 0 − v 0 sin ωt
k
m
(B) displacement time equation of A after collision will be x = x 0 + v 0 sin ωt
k
(C) velocity of B just after collision will be a ω towards positive x-direction.
(D) velocity of B just after collision will be v0 towards positive x-direction.
7. In the isothermal expansion of an ideal gas:

(A) there is no change in the temperature of the gas
(B) there is no change in the internal energy of the gas
(C) the work done by the gas is equal to the heat supplied to the gas
(D) the work done by the gas is equal to the change in its internal energy.
8. A mixture of two diatomic gases X and Y is enclosed in a container at constant temperature.

The molecular weight of X is 16 times that of Y and mass of the gas X is 2 times that of Y.
Then
(A) The average molecular kinetic energy of X equals that of Y
(B) The r.m.s. molecular speed of translation of X is 1/4th that of Y.
(C) The pressure exerted by X is 1/8th that by Y.
(D) The pressure exerted by X is 8 times that by Y.
4
Comprehension Type
This section contains 2 paragraph C9-10 and C11-12 Based upon each paragraph, multiple choice question have
to be answered. Each question has 4 choices (a), (b), (c) and (d), out of which ONLY ONE is correct
C9-10 : Comprehension for Question Nos. 9 to 10
Consider a planet of radius r having density λ. A tunnel λ kg/m3

is dug inside it at a distance r/2 from it’s centre as
shown in figure. An object of mass m is left in the tunnel r/2
r
at the surface at t = 0 , then
9. Time taken by the object to reach the centre of the tunnel? Will be
3π π
(A) (B)
16Gλ 16Gλ
π 3π
(C) (D)
4Gλ Gλ
10. Magnitude of velocity of object at the centre of the tunnel

1
(A) πGλ r (B) πGλ r
2
1
(C) 2 πGλ r (D) πGλ r
3
P
A (Vo, 4Po)
Consider a monoatomic ideal gas undergoing a process

AB as shown in figure.
(4Vo, Po)
B
V
11. Find the maximum temperature of the gas if temperature at A is To.
21 23
(A) To (B) To
16 16
25 27
(C) To (D) To
16 16
12. Volume at which rate of heat exchange is zero.

22 21
(A) Vo (B) Vo
8 8
23 25
(C) Vo (D) Vo
8 8
5
SECTION – C
(Integer Type)
This section contains 8 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.
1. A thin wire of area of cross-section A = 10 −2 m2 is used to make a ring of radius r = 10 −1m .

This ring is placed on a smooth horizontal floor & is given angular velocity ω = 2 rad / s about
its centre. Find out stress in the ring (mass per unit length of wire λ = 1 kg/m)
2. A string is stretched along the X axis. A disturbance given by the equation y(x,t) =
 πx 
4 sin   cos (10πt ) . Where X is in cm and t is in seconds. Distance between two adjacent
 3 
nodes is n cm, then n = ?
3. A system of two identical rods (L shaped) of mass m, length P

L. System rest on a peg p as shown in the figure. Period of
900
n 2L
oscillations T = 2π then n = ?
3g
P
B(2P,V) C(2P,2V)
4. An ideal monoatomic gas is taken round the cycle
ABCDA as shown in the P – V diagram (see figure).
pv
The work done during the cycle is then n = ?
n
D(P,2V)
A(P,V)
5. A satellite is moving in a circular orbit around earth at a height R above earth surface(R
being radius of earth) It’s velocity should be increased to k times its initial orbital speed
value, so as to make it escape from earth gravitational pull and reach infinity. Find k
6
6. Inner surface of a cylindrical shell of length l and of material of T1 T2

thermal conductivity k is kept at constant temperature T1 and outer
surface of the cylinder is kept at constant temperature T2 such that
( T1 > T2 ) as shown in figure. Heat flows from inner surface to outer
surface radially outward. Inner and outer radii of the shell are R and
R l
2R respectively. Due to lack of space this cylinder has to be replaced 2R
l R
by a smaller cylinder of length , inner and outer radii and R
2 4
respectively and thermal conductivity of material nk. If rate of radial
outward heat flow remains same for same temperatures of inner and
outer surface i.e. T1 and T2, then find the value of n.
7. A particle is subjected to two simple harmonic motions in the same direction having equal
amplitudes and equal frequency. The resulting amplitude is equal to the amplitude of
aπ
individual motions. If the phase difference between them is , then a=
6
8. A uniform rod is placed on two spinning wheels l/2 l/2
as shown in the figure. The axes of the wheels

are separated by l. The coefficient of friction
between the rod and the wheel is µ. If the
a l
period of small oscillations is π , a=
2µg
7
S
SEEC
CTTIIO
ONN –– 2
2 :: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. Which of the following compound(s) forms C2H6 when react(s) with C2H5MgBr?
(A) HC ≡ CH (B) CH3C ≡ CCH3
(C) H2O (D) CH3OH
OH
(i) CF3COOOH
2. ( X ) 
ii H O/H+
→ CH3 CH − CHCH3
() 2
OH
Which of the following compound(s) can be (X) in the above reaction?
(A) CH3CH2CH2CH3 (B) CH3CH = CHCH3
(C) CH3C ≡ CCH3 (D) CH3CH2CH = CH2
3. Which of the following is/are the functional isomer(s) of n-butanol(C4H9OH)?

CH3
(A) CH3CH2OCH2CH3 (B) CH3 - C - OH
CH3
O
(C) CH3OCH2CH2CH3 (D)
CH3CCH2CH3
CH3
4. Cl (1 eq )
( S ) ← 2
Light
 Cl2 /FeCl3
 → (P ) + ( Q ) + (R )
The product yield in the above reaction is:

P = 52%, Q = 43% and R = 5%
Choose correct statements
(A) (P), (Q) and (R) are positional isomer
(B) (P) and (S) are formed by different reaction mechanism
(C) The C – Cl bond in (S) is longer than that in (Q)
(D) (S) can undergo dehydrochlorination (loss of HCl) reaction when treated with alc. KOH
8
5. Which of the following compound(s) undergo(es) elimination reaction to form 1, 3-butadiene?

CH2 = CH – CH = CH2(1, 3-butadiene)
CH3CHCHCH3
(A) (B) ClCH2CH2CH2CH2Cl
Cl Cl
Cl
CH3CH2CHCH2Cl
(C) (D) CH3CH2C - CH3
Cl
Cl
6. Which of the following species exert stronger –I effect than ‘Cl’ in a particular compound?
(A) F (B) NO2
(C) CH3 (D) Br
7. H Cl Cl Cl
C C C C
Cl H H H
(X) (Y)
The correct order of the physical properties of (X) and (Y) is:
(A) Boiling point: X < Y (B) Melting point: X > Y
(C) Solubility in water: X < Y (D) Dipole moment: X > Y
8. Which of the following molecule(s) display(s) optical isomerism?

(A) CH3CH2CHCH2Cl (B) CH3
Cl
CH3
(C) CH3CHCH2CHCl (D) F
CH3 Br
CH2F
9
Comprehension Type

OH
Conc.H2SO4
CH3 − CH2 − C − CH3 
High Temperature
→ (P ) + ( Q ) + (R )
CH2CH2CH3
In the above reaction, the alcohol undergoes dehydration at high temperature forming alkenes (P),
(Q) and (R).
(P ) →
ozonolysis
Ketone (I) + other products
( Q ) 
ozonolysis
→ Ketone (II) + other products
(R ) 
ozonolysis
→ Ketone (III) + other products
Ketone(I) contains four carbon atoms
Ketone(II) contains five carbon atoms
Answer the following questions on the basis of above write up.
9. How many carbon atoms are present in ketone(III)?

(A) 3 (B) 6
(C) 8 (D) 7
10. The order of heat of hydrogenation of (P), (Q) and (R) is:
(A) Q > R > P (B) R > Q > P
(C) R > P > Q (D) Q > P > R
CH3 – CH = CH – CH = CH2
The diene given above reacts with HBr giving six monosubstituted unsaturated bromides. The
products are 1, 2 as well as 1, 4 addition products. Out of the products, two are 1, 4-addition
products and four are 1, 2-addition products.
Answer the following questions on the basis of above write up.
11. How many products contain bromine atom at allylic positions?

(A) 2 (B) 3
(C) 4 (D) 5
12. How many monobromo product(s) display(s) geometrical isomerism?

(A) 2 (B) 4
(C) 1 (D) 3
10
SECTION – C
(Integer Type)
1. The molecular formula of a monocarboxylic acid is C5H10O2. How many CH3 group(s) is/are
present in its least acidic isomer, if inductive effect is assumed to be the only deciding factor
for acidic strength?
2. How many stereoisomer(s) is/are possible for the following compound?

(Do not count this compound as an isomer)
OH
(d - cyclohexan -1, 3-diol)
OH
COONa
Kolbe ' s electrolysis

3.  → Products
COONa
How many aromatic product(s) is/are formed in the above reaction?
4.
CH3Cl( excess )
→ Product
Anhy.AlCl3 ( excess )
If the no. of carbon atom(s) present in the largest possible product of above reaction is X,
X
then is
2
5. CH3CHCH2CH = CHCH3
Cl
How many stereoisomer(s) is/are possible for the above compound?
2( ) 3 (
NaNH 2 eq ) CH Cl excess
6. HC ≡ CH  → ( X ) → (Y)
How many carbon atom(s) is/are present in the end product(Y) in above reaction?
HgSO 4
7. CH3 − C ≡ CH 
dil.H2 SO4
→ Product
How many π-bond(pi-bonds) is/are present in the organic product of above reaction?
8. Br2/H2O, Br2/CCl4, HBr, H3O+, KMnO4/OH–/Cold, KMnO4/H+/∆ and H2/Ni

How many of the above reagent(s) is/are used usually to check the unsaturation of acyclic
aliphatic hydrocarbons?
11
S
SEEC
CTTIIO
ONN –– 3
3:: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. If 1, ω, ω2 ,....., ωn−1 are the n, nth roots of unity, then ( 2 − ω) 2 − ω2 ....... 2 − ωn−1 equals:( ) ( )
n
(A) 2 − 1
(B) n C1 + nC2 + ..... + nCn
1/2
(C)  2n C0 + 2n+1C1 + 2n+1C2 + ...... + 2n+1Cn  −1
(D) 2n + 1
1/5 x y
2. If x, y, a, b are real numbers such that ( x + iy ) = a + ib, and p = − , then:
a b
(A) ( a − b ) is a factor of p (B) ( a + b ) is a factor of p
(C) a + ib is a factor of p (D) a − ib is a factor of p
3. In a class tournament when the participants were to play one game with another, two class
players fell ill, having played 3 games each. If the total number of games played is 84, the
number of participants at the beginning was:
(A) 15 (B) 30
6
(C) C2 (D) 48
4. Let n = 3100 , then for n:

(A) unit’s digit is 1 (B) ten’s digit is 0
(C) unit’s digit is 7 (D) ten’s digit is 2
5. The solution of the equation cos103 x − sin103 x = 1 is:

π
(A) − (B) 0
2
π
(C) (D) π
2
6. If sin2 x − 2 sin x − 1 = 0 has exactly four different solutions in x ∈ [0,nπ] , then value/values of
n are (n ∈ I) :
(A) 5 (B) 3
(C) 4 (D) 6
7. If α is a complex constant such that αz 2 + z + α = 0 has a real root, then:

(A) α + α = 1 (B) α + α = 0
(C) α + α = −1 (D) the absolute value of the real root is 1
12
8. Let z, ωz and z + ωz represent three vertices of ∆ABC where ω is cube root unity, then:
2 2
(A) centroid of ∆ABC is ( z + ωz ) (B) orthocenter of ∆ABC is ( z + ωz )
3 3
2 2
(C) circumcenter of ∆ABC is ( z + ωz ) (D) incenter of ∆ABC is ( z + ωz )
3 3
Comprehension Type
Let set S = {1,2,3,......n} be a set of first n natural numbers and A ⊆ S . Suppose n (A)
represents cardinal number and min (A) represents least number among the elements of set
A.
9. The greatest value of min (A), where A ⊆ S and n ( A ) = r, 1 ≤ r ≤ n ; is

(A) r (B) (n − r )
(C) n − r + 1 (D) r + 1
10. The number of subsets A of S for which n ( A ) = r and min ( A ) = k, is

n −k
(A) Cr −1 (B) n Cr −1
n −k +1 n −k
(C) Cr −1 (D) Cr −1
6m
=
6m
Consider the identity (1 + x ) 6m
Cr . xr . By putting different values of x on both sides,
r =0
we can get summation of several series involving binomial coefficients. For example, by
6m
1 6m
1 3
putting x = we get  6m Cr r =  
2 r =0 2 2
6m
11. The value of  r =0
6m
Cr 2r /2 is equal to
36m 3m
(A)
2
(
(B) 1 + 2 )
3m
(
(C) 3 + 2 2 ) (D) None of these
3m
 ( −1)
r 6m
12. The value of C2r is
r =0
(A) 23m (B) 0 if m is odd

(C) −23m if m is even (D) None of these
13
SECTION – C
(Integer Type)
n n n
n n n n
1.   i   j   k  ,  r  = n
Cr is less than 50000, if max value of n is equal to
i=0 j=0 k = 0      
2 2
2. The number of solutions of the equation 16sin x
+ 16cos x
= 10, 0 ≤ x < 2π, is
B C
3. If b + c = 3a, then the value of cot   cot   is ______
2 2
4. If cos−1 λ + cos−1 µ + cos−1 γ = 3π , then the value of λµ + µγ + γλ is ___________
2 2 2 3π2
5. (
If sin−1 x ) + ( sin y ) + ( sin z )
−1 −1
=
4
, then the maximum value of x + y + z is ________
6. If the number of zeroes at the end of 130! is 2n , then the value of n is ___________
20 20 20
20 C1 C2 C3
7. The value of C0 − + − + _________is p then 21p is
2 3 4
8. In any triangle ABC, the least value of

(r1 + r2 + r3 ) is ______
r
14
BATCHES –
PHASE – III
PAPER – II
ANSWER KEY
Physics
Part – A
1. AC 2. AD 3. ABD 4. BD
5. BD 6. AC 7. ABC 8. ABC
9. A 10. A 11. C 12. D
Part – C
1. 4 2. 3 3. 2 4. 1
5. 2 6. 4 7. 4 8. 4
Chemistry
Part – A
1. ACD 2. B 3. AC 4. ABC
5. AB 6. AB 7. ABC 8. AC
9. B 10. C 11. C 12. B
Part – C
1. 3 2. 2 3. 1 4. 6
5. 4 6. 4 7. 1 8. 4
Mathematics
Part – A
1. ABC 2. ABCD 3. AC 4. AB
5. AB 6. AC 7. ACD 8. A
9. C 10. A or D 11. C 12. B
Part – C
1. 5 2. 8 3. 2 4. 3
5. 3 6. 5 7. 1 8. 9

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

Time Allotted: 3 Hours Maximum Marks: 240

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

1. In the figure shown the block of mass m is in equilibrium initially.

2. The temperature drop through a two layers furnace wall is

3. Two concentric spherical shells masses m1 and m2 and radii r1 and r2 .

4. A particle of mass m is moving in a field where the potential energy is given by

6. A block A of mass m connected with a spring of force constant k

7. In the isothermal expansion of an ideal gas:

8. A mixture of two diatomic gases X and Y is enclosed in a container at constant temperature.

C9-10 : Comprehension for Question Nos. 9 to 10

Consider a planet of radius r having density λ. A tunnel λ kg/m3

10. Magnitude of velocity of object at the centre of the tunnel

C11-12 : Comprehension for Question Nos. 11 to 12

Consider a monoatomic ideal gas undergoing a process

12. Volume at which rate of heat exchange is zero.

1. A thin wire of area of cross-section A = 10 −2 m2 is used to make a ring of radius r = 10 −1m .

3. A system of two identical rods (L shaped) of mass m, length P

6. Inner surface of a cylindrical shell of length l and of material of T1 T2

8. A uniform rod is placed on two spinning wheels l/2 l/2

as shown in the figure. The axes of the wheels

3. Which of the following is/are the functional isomer(s) of n-butanol(C4H9OH)?

The product yield in the above reaction is:

5. Which of the following compound(s) undergo(es) elimination reaction to form 1, 3-butadiene?

8. Which of the following molecule(s) display(s) optical isomerism?

C9-10 : Comprehension for Question Nos. 9 to 10

Answer the following questions on the basis of above write up.

9. How many carbon atoms are present in ketone(III)?

C11-12 : Comprehension for Question Nos. 11 to 12

11. How many products contain bromine atom at allylic positions?

12. How many monobromo product(s) display(s) geometrical isomerism?

2. How many stereoisomer(s) is/are possible for the following compound?

(d - cyclohexan -1, 3-diol)

Kolbe ' s electrolysis

8. Br2/H2O, Br2/CCl4, HBr, H3O+, KMnO4/OH–/Cold, KMnO4/H+/∆ and H2/Ni

4. Let n = 3100 , then for n:

5. The solution of the equation cos103 x − sin103 x = 1 is:

7. If α is a complex constant such that αz 2 + z + α = 0 has a real root, then:

C9-10 : Comprehension for Question Nos. 9 to 10

9. The greatest value of min (A), where A ⊆ S and n ( A ) = r, 1 ≤ r ≤ n ; is

10. The number of subsets A of S for which n ( A ) = r and min ( A ) = k, is

C11-12 : Comprehension for Question Nos. 11 to 12

(A) 23m (B) 0 if m is odd

4. If cos−1 λ + cos−1 µ + cos−1 γ = 3π , then the value of λµ + µγ + γλ is ___________

8. In any triangle ABC, the least value of

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Batch :__ Date of Examination :_