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DOI: 10.1007/s12583-016-0910-2
ABSTRACT: Evaluation of shale gas hydrocarbon potential of Talhar Shale member of Lower Goru
Formation, by using well logs data only, has been a challenging task in Southern Lower Indus Basin
Pakistan. This paper is helpful to evaluate shale gas potential of source rock by using well log data. We
have introduced and applied Empirical and Graphical method to resolve this task and have derived
geochemical parameters from well logs data. The way mentioned is fastand the cheapest. Talhar Shale
has kerogen typeIII and type II which has potential to produce, mainly, oil and gas. Talhar Shale is of
Montmorillonite clay type. So, Talhar Shale has better sorption property. Empirical formulas are used
to derive parameters, using well logs of Porosity, Density and Uranium. Porosity and Volume of
Kerogen, calculated from density log, gives average values of 11.8% and 11.4%. Level of Maturity
Index (LMI), derived by log, average value is 0.54 which indicates that it is on early stage of maturity.
Vitrinite reflectance is between 0.5-0.55% as calculated by graphical method and empirical formula.
Talhar Shale with main products of oil and gasis onset of oil generation,;could be a good potential
source in the study area.
KEY WORDS:Talhar Shale,kerogen type,sorption property,thermal maturity,vitrinite reflectance (RO),
Southern Lower Indus Basin
0 INTRODUCTION
The exploration of hydrocarbons is significant and Manuscript received October 02, 2015.
essential for the economy and growth of a country. With the Manuscript accepted April 13, 2016.
start of 21st century, depletion of hydrocarbons has put onus on out its complete theoretical solution.Machel et al., (1995)
unconventional hydrocarbon resources. Shale gas exploration, developed a method to check the effect of formation
nowadays, is the hottest debate going among the geoscientists. temperature and vitrinite reflectance on oil and gas window.
The geochemical parameters which are used to evaluate For the evaluation of sorption property, Zhang et al., (2013)
unconventional hydrocarbons, are expensive in terms of introduced another technique. Godec et al., (2013) introduced a
bothinvestment and time. Therefore, geoscientists and scholars, formula to derive Porosity value from Density log. Log derived
worldwide, are trying to develop newer, faster and cheaper Maturity Index (LMI) values calculation is formulated
methods and techniques for the exploration and production of byLabani andRezaee, (2012) by using Porosity, Density and
hydrocarbons than methods and techniques are being used Uranium logs. For TOC value calculation, Schmoker, (1979)
before. introduced empirical formula and Passey et al., (1990)
In developing countries, geoscientists are facing problems introduced a ΔLogR method. Vitrinite reflectance and level of
due to lake of funding and are unable to study the geochemical organic maturity (LOM) calculations are introduced by
parameters liketotal organic carbon (TOC), hydrogen index
Alyousuf et al., (2011), Lecompte and Hursan, (2010) and Hill
(HI), oxygen index (OI), level of maturity index (LMI), Tmax,
S1, S2, vitrinite reflectance(Ro) and level of organic et al., (2007). In this current paper we have arranged and
maturity(LOM) from Rock-Eval pyrolysis and well adopted a possible theoretical way to check the hydrocarbon
coresamples because it is very expensive in terms of cost and potentials of source rock.
time. Many oil and gas exploration and developmentcompanies
Many researchers are working to find out solution to are trying to explore the shale gas potential of Southern Lower
thisproblem. In previous research papers no one was able to Indus Basin of Pakistan andtheir main targeisTalhar Shale
find
which is a member of Lower Goru Formation. The area is
terrain and shallow to deeper depth of the formation makes it
*Corresponding author. E-mail: zhouzhg@cugb.edu.cn
lucrative for the study. The reason lies in high rate of success
©China University of Geosciences and Springer-Verlag Berlin
and easy drilling of thewells.The study area lies in petroleum
Heidelberg 2016
concessions zone III , petroleum exploration in this zone has
Ehsan M., Gu H.M, Akhta M.M et al., 2016. The Identification of Hydrocarbon Potential of Talhar Shale: Member of Lower Goru
Formation by Using Well Logs Derived Parameters, Southern Lower Indus Basin, Pakistan.Journal of Earth Science, Printed in
China. doi:10.1007s12583-016-0910-2. http://en.earth-science.net
Muhsan Ehsan,
E HanminggGu, Malik Muhhammad Akhtaar, SaiqShakeel Abbasi1 and ZaaheenUllah
2DATA SET
Thedata set used forr calculations comprises upp of 3 METHODOLO
M OGY
formation tem
mperature, form mation depth, geothermal
g graddient, Kerogen typee is found by uusing oxygen index
i (OI) andd
surface tempeerature,level of organic maturrity(LOM) and total hydrrogen index (HI)( cross ploot. To check the effect off
organic carboon(TOC) of HakeemH Dahoo-01 well. Gaamma form
mation temperaatureand vitrinitte reflectance ono oil and gass
Ray,porosity, density, deep resistivity,
r sonic and uranium logs winddow applied acccording to Macchel et al., (19995) method.Thee
are used. Whhile parameters such as hyddrogen index (HI), sorp
ption property of Talhar Shale ischecked by y Zhang et al.,,
oxygen index (OI), Tmax, S1 and S2 are takeen from Oil andd Gas (201
13) technique. Porosity
P valuess are derived by
y using Densityy
Development Company Limited L (Pakisstan). Some input log values, the method
m introducced byGodec et al., (2013)..
parameters aree taken from strranded publisheed values. Keroogen volume iss determined by using Empiriical formula off
denssity log values. Porosity, Density and Uraniumm logs are usedd
The Identification of Hydrocaarbon Potentiall of Talhar Shalee
for the Log deerived Maturityy Index (LMI) by b using Labanni and calculated by the use oflevel oof organicmatuurity (LOM),ass
Rezaee, (20122) method. To calculate
c the LOM value, we used intro
oduced byAlyoousuf et al., (22011).Lecompte and Hursan,,
TOC value which
w is calcullated by usingg Schmoker, (11979) (20110)transformed the LOM vvalues into Ro values andd
empirical form mula and ΔLogR value whicch is calculateed by deveeloped antransfformed the LO
OM values into Ro values andd
using Passey ete al., (1990) method.Vitrinite
m reflectance vallue is
developed an empirical relattion from grapph which is useed to accoordance with CH4 sorptioon property. Everyminerall
calculate R0vaalues. Vitrinitee reflectance vaalues are founnd by hasmmineral has its own sorption pproperty. So, claay mineral typee
using formatioon temperatureaas introduced by Hill et al., (2007), is very
v helpful too understand the sorption of gas. Thesee
using graphicaal method. The method adopteed for all mentiioned clay
ymineralsmainlyyare, accordding tothe sedimentaryy
calculations iss by comparing the values withh stranded charrts. In rock mectite (montmorillonite), kaolinite, illite andd
k'sdefinition, sm
the current reesearch, cheapeer and faster way w to find ouut the chlo
orite. Montmorrillonite isa meember of smecctite group.Thee
hydrocarbon potentialbefore
p investing and drilling
d by the use
u of main n componentts ofof gas adsorption are organicc
Well Logs Derrived Parameterrs is introducedd. mattter,thermal matturity and clay mineral type. The effects off
these factors are exxtensively obserrved in gas adssorption (Zhangg
4 RESULTS et al.,
a 2012). Metthane sorptionn is controlled by two mainn
4.1 Kerogen Type factoors,which arethhermal maturitty and clay type. With thee
Kerogen type decides the potential of o oil and gas in a increasing of therm mal maturity, m methane sorption n also increasess
source rock. Kerogen
K is of foour types, whichh are: type I, typpe II, becaause of the inccreasing develooping of nano-pores and thee
type III and type IV. Typee I can only produce
p oil, typpe II decoomposition of organic matteer. Methane so orption is alsoo
produces bothh oil and gas, tyype III can onlyy produce gas, but
b it conttrolled by clayy type, the soorption capacity y of CH4is inn
also produce asminor
a amounnt of oil and typpe IV produces none follo
owing order montmorillonite>
m >>illite with smectite
s mixedd
of the hydroccarbons(Holditch, 2011).Crosss plot of kerrogen layeer > kaolinite > chlorite >illite (Zhang et al., 2013).
2
types in Loweer Goru Formatiion is shown inn Fig.2 as defineed by
Rock-Evalhyddrogen index (H HI) and oxygen index (OI) in which
w
gas-prone type-III kerogen and a kerogen III type are founnd in
Lower Goru Formation.
F
of sorption both external and internal surface area modify after (Passey et The porosity is calculated by using formula as given in
al., 2010). Equation 1, the matrix grain density for shale is taken
2.77g/cm3and density of formation water is taken
4.4DENSITY POROSITY 1.10g/cm3(Godec et al., 2013;Magara, 1978). The bulk density
is taken from the density log of Talhar Shalemain effectfactors 2990m; from 3000-3010m it has medium range values. It
Ρma- Ρb shows low values at interval 3010-3061m,which is shown in
=Ρ (1) Fig.5a. It is concluded that with increasing depth the values of
ma- Ρf
whereФisdensity drive porosity , ρmaismatrix grain density, porosity are showing decreasing trend due tocompaction and
ρfisdensity of formation water , ρbisbulk density takes from overburden of rocks.
density log.
The high values of porosity are shown at interval 2982-
Figure 5. (a) Density derived Porosity plot with depth in Talhar Shale; (b) Kerogen volume plot with depth in Talhar Shale
where Vkerogenisfractional volume of kerogen (organic matter), ρ 4.6.2 Labani and Rezaee Log Derived Maturity Index (LMI)
noisbulk density of non-organic matter , ρlogisdensity values Labani and Rezaee (2012) gave a relationship between
taken from well log. thermal maturities and well logs, which is called as log derived
The high kerogen volume values are shown at interval maturity index (LMI) and its values range from 0 to 1. The
2982-2990m; from 3000-3010m it has medium ranges values. LMI higher values indicate that this formation is thermally
It shows low values at interval 3010-3061m and it is illustrated mature and lower values indicate that it is immature. The input
inFig. 5b. It is concluded that thevolume of kerogen is logs were used for LMI porosity, density and uranium log.
decreasing with respect toincreasing depth. They developed the empirical formulas for the calculation of
LMI. They adopted following procedures; first they calculated
4.6 THERMAL MATURITY OF TALHAR SHALE the LMI from three logs, then they took average of these logs to
To calculatethe thermal maturity of Talhar Shale, we used overcome the effect of individual log results.
log derived maturity index (LMI) in accordance with log data.
In this section, different methods are used to calculate the (3)
thermal maturity details of each method. These details are as
follows. (4)
on average its values are medium ranged which are shown in To calculate the value of vitrinite reflectance (Ro), two
Fig.6.The porosity and uranium logs show the LMI values methods are used, empirical and graphical. In the present study,
greater than 0.6 while only density log shows low LMI values both methods are applied to calculate the vitrinite reflectance
(Ro) values of the Talhar Shale. It is measured in percentage (%)
4.7 Vitrinite Reflectance (RO) Calculation units normally. .
Figure 6. Plotting of Level of Maturity Index (LMI) with depth in Talhar Shale
where ΔLogR isseparation value of resistivity/ density 4.7.3 Formation temperature and Vitrinite reflectance (Ro)
crossover, ρ is baseline values of density. To calculate the formation temperature,we required mean
surface temperature and geothermal gradient of the target
4.0 ∗ (10) formation. The mean surface temperature of the study area is
taken from Energy Year Book 2012, published by Hydrocarbon
where ΔLogR is separation of resistivity and porosity,
Development Institute of Pakistan, and well header of Hakeem
Φ is baseline porosity value baseline interval
Daho-01 well. The geothermal gradient values are taken from
(11) published geothermal gradient contour map of thestudy area.
The procedure adopted for this calculation is described below;
where LOM is calculated by using the TOC values obtained Input parameters as T1 = 26.6°C(HDIP, 2012) and
from density log and ∆ Log R values. Which areobtained from Geothermal Gradient = 22 °C/km(Kadri, 1995) into the
crossover method and it has an average value of 0.1861, used Equation 14
inEquation 12.
(14)
Muhsan Ehsan, HanmingGu, Malik Muhammad Akhtar, SaiqShakeel Abbasi1 and ZaheenUllah
where FT isformation temperature, T1ismean surface formation temperature at hand. It is a graphical method in
temperature, D is depth of formation in Km. which formation temperature (F0) is plotted on x-axis and
According to this equation, the average temperature of Vitrinite reflectance (R0)in percentage (%) is plotted on y-axis.
formation in celsius scale is 93°C, and the average temperature The plot is shown in Fig7(b).Talhar Shale temperature is 200F0
of formation in fahrenheit scale is 200°F. Hill et al., so their Vitrinite reflectance (R0) value is 0.5 % from the
(2007)introduced the method to calculate Vitrinite reflectance Graph.
(R0) values in organic rocks with a condition to havethe
Figure 7. (a)Vitrinite reflectance and Level of Organic Maturity Model modify after (Alyousuf et al., 2011); (b)Vitrinite reflectance and Formation
Temperature Model modify after (Hill et al., 2007)
of vitrinite reflectance values between present research and good to excellent. This correlation validates the authenticity of
values calculated by geochemical data is 83% which verifies our study.
our work.
ACKNOWLEDGEMENTS
6 CONCLUSION I thank Directorate General Petroleum Concession
Talhar Shale is member of lower Goru Formation. It has (DGPC) Pakistan, Oil and Gas Development Company Limited
kerogen typeIII and type IIwhich has potential of producing oil (OGDCL) Pakistan and LMKR Pakistan for providing Data for
and gas. Talhar Shale has montmorillonite clay type which this research. I would also like to pay complements to Prof. Dr.
means that it has good sorption property. Thissorption property Zulfiqar Ahmad from Quaid-i-Azam University, Islamabad and
is present at both, internal and external surface. The results of Dr. Khalid Amin Khan (Chief-Geophysicist) from OGTI (Oil
the study show that the average value ofdensity derived and Gas Training Institute, Pakistan) for their kind guidance
porosity is at 11.8%, the volume of kerogen is calculated from and help to get data.I would also like to pay my regards to my
density log and its average value is 11.4%.level of maturity elder brother Mr. Mohsin Raza from University of East
index(LMI) is derived from three well logs density, porosity London, United Kingdom (U.K), my friends Mr. Tariq Zia from
and uranium. Its average value is 0.54 which indicates that Department of Earth Science, Quaid-i-Azam University,
Talhar Shale is on early stage of maturity. Vitrinite reflectance Islamabad, Pakistan and Mr. Ahsan Shafi from School of Public
is calculated by graphical as well as empirical formula and it Administration, China University of Geosciences, Wuhan for
ranges from 0.5 to 0.55%. So,Talhar Shale is onset of oil their moral support and their help to complete this work. The
generation and have ability ofoil and gasproduction.Current final publication is available at Springer via
research findings of well log data derived parameters and their http://dx.doi.org/10.1007/s/s12583-016-0912-2.
correlation with geochemical parameters is about 83% which is
AAPG bulletin, 91(4): 501-521
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Muhsan Ehsan, HanmingGu, Malik Muhammad Akhtar, SaiqShakeel Abbasi1 and ZaheenUllah