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INTRODUCTION TO MASS
TRANSFER AND DIFFUSION
Chapter 1 outline
• Similarity of Mass, Heat and Momentum
Transfer Processes
• Examples of Mass-Transfer Processes
• Fick’s Law for Molecular Diffusion
• Convective Mass-Transfer Coefficients
Prepared by:
Ummi Kalthum Binti Ibrahim
Fakulti Kejuruteraan Kimia
OBJECTIVES
Definition:
d x
= momentum transferred
s.m²
dz = kinematic viscosity (m²/s)
z = distance (m)
x = momentum/m³ , momentum (kg m/s)
d c pT
q
q = heat flux (w/m²)
A
A dz = thermal diffusivity(m²/s)
c pT = J/m³
Heat transfer is the transfer of energy from high temperature to low temperature
(temperature gradient). Example: evaporation, distillation and drying.
MASS, HEAT AND MOMENTUM TRANSFER PROCESSES
3. Mass transfer (Fick’s Law) :
Mass transfer is the net movement of mass from one location, usually meaning a stream,
phase, fraction or component, to another. Example: distillation, absorption, drying, liquid-liquid
extraction, adsorption, crystallization, etc.
WHAT IS THE SIMILARITY BETWEEN MASS, HEAT AND MOMENTUM??
Momentum transfer
= momentum transferred
d x s.m²
= kinematic viscosity (m²/s)
dz z = distance (m)
x = momentum/m³
Heat transfer q
d c pT
= heat flux (w/m²)
q A
= thermal diffusivity(m²/s)
A dz z = distance (m)
c pT = J/m³
The similarity:
1) All the fluxes on the left hand-side have units transfer of quantity
per unit time per unit area.
2) The transport properties (constant) have units of m2/s.
3) All the concentrations are represented as transfer quantity/m3 .
EXAMPLES OF MASS TRANSFER
• Liquid in an open pail of water evaporates into air because of
the difference in concentration of water vapor and surrounding
air.
• A piece of sugar added to a cup of coffee dissolves by itself and
diffuses to the surrounding solution.
• Difference between diffusion and convection mass transfer:
• If C is constant : C A Cx A
Cdx A d (Cx A ) dC A
J A = molar flux of component A (kg mol A/s.m²)
dC A
J A DAB z = distance due to molecular diffusion (m)
dz
DAB = molecular diffusivity of A in B (m²/s)
JA⌠
⌡ dz = - D AB⌠
⌡dCA PA1 = 0.6 atm
z1 CA1 5
= 0.6 x 1.01325 x 10 Pa
JA(z2 – z1) = - DAB (CA2 – CA1) = 6.08 x 104 Pa
*The negative value for JB means the flux goes from point 2 to point 1.
DIFFUSION OF GASES A AND B PLUS CONVECTION
• The rate at which moles of A passed a fixed point to the right,
which will be taken as a possible flux, JA kg mol A/s.m²
• This flux can be converted to a velocity of diffusion of A to the
right by
JA(kg mol A/s.m²) = C
Ad A
m kg mol A Ad = diffusion velocity of
s m³ , A in m/s
A Ad m
A
Ad m
• Multiply by CA
CA A CA Ad CAm
❖ N A J A C A m
Let N be the total convective flux of the whole stream relative to the stationary point:
N C m N A N B
N A NB
m
C
❖ NA JA
CA
N A N B
C
• Similarly:
N A CD AB
dxA C A
N A N B
dz C
N B CD BA
dxB C B
N A N B
dz C
• For equimolar counterdiffusion:
N A NB
• Example (Figure a): the evaporation of a pure liquid benzene (A) at the bottom
of tube, where nondiffusing air (B) is pass over the top.
• The benzene vapor (A) diffuses through the air (B) in the tube.
• The boundary at the liquid surface at point 1 is impermeable to air, since air is
insoluble in benzene.
• Hence, air(B) cannot diffuse into or away from the surface.
• At point 2, the partial pressure PA₂= 0 since a large volume of air is passing by.
• To derive the case for A diffusing in stagnant, nondiffusing B, NB = 0
0
N A CD AB
dxA
CA
N A N B
dz C
• The convective flux of A:
C A X AC
CA
N A 0 CA P
XA A
C C P
P C A PA
• At P = constant, C , PA x AP,
RT C P
dC A C A
N A DAB NA
dz C
DAB dPA PA
NA NA
RT dz P
• Rearranging and integrating
PA
N A 1 DAB dPA
P RT dz
z2 PA 2
DAB dPA
N A dz
RT PA
P
z1 1
A1
P
N A z 2 z1 D
PA 2
P ✓P = PA1 + PB1
AB
RT P P PA dPA = PA2 + PB2
PB1 = P – PA1
PB2 = P – PA2
A1
DAB P
InP PA PP
A2
Solution:
• DAB = 0.250 x 10-4 m2/s
• From appendix A.2.2, vapor pressure of water
at 20°C :
PA1 = 17.54 mmHg
= 2.338 kPa
= 2.338 x 10³ Pa z₂ - z₁
PA2 = 0 (pure air)
N A CDAB
dx A C A
N A NB
dz C
0
N A CDAB
dx A C A
N A NB
dz C
At P = constant:
DAB dPA PA
NA NA
RT dz P
Integrate:
PBM = PB2 – PB1 = 1.01325 x 10⁵ Pa - 9.899 x 10⁴ Pa
In(PB2/PB1 ) 1.01325 10 5
In 4
Pa
9.899 10
= 1.001 x 10⁵ Pa
NA
DAB P
PA1 PA2
RT z2 z1 PBM
0.25 10 m 2 / s 1.01325 10 5 Pa 2.338 10 3 Pa
4