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Gases and Thermochemistry
This week, we will discuss gases and itscharacteristic,behavior, and the laws
associated to it. We will also discuss about thermochemistry – the branch of
chemistry which explains how energy changes during chemical reactions.
Gases
As discussed in the previous modules, gases like solids and liquids are also
considered a phase of matter.Gases are less complex than solids and liquids
in many forms – forces in between gas molecules are relatively weak, thus, its
molecules move in a random motion, freely and independently of each other.
When exposed to temperature and pressure changes, behavior of gases can
be easily predicted.
Some solids and liquids on ordinary conditions can also appear in a gaseous
state. These are identified as vapors. For example, water (H2O) can exist as
solid ice, liquid water, or water vapor.
Course Module
Table below shows some common compounds that are gases at room
temperature.
Pressure of Gas
Pressure is defined as the effect of a force applied to a surface. Measurement
can be done by means of using a barometer or manometer.
P = (Force) F
(Area) A
Atmospheric pressure
2 Types of Manometer:
1. Closed-tube – measures pressure below atmospheric pressure
2. Open-tube – measures pressure equal to or greater than the
atmospheric measure
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Gas Laws
1
V = constant x or PV = constant
p
V
V = constant x T or constant = T
*value of constant depends on the pressure and amount of gas
V
V = constant x n or constant = 𝑛
*n = number of moles
General Chemistry
5
Gases and Thermochemistry
The Ideal Gas Equation (or also called the Ideal Gas Law) is a combination of
laws of Boyle, Charle and Avogadro. These laws were expressed individually
as:
V∝ _nT_
P
Course Module
The proportionality constant is referred to as the gas constant. It is denoted
by the letter R. Thus, the equation becomes:
𝑛T
V=R ( )
P
Above equation can be rearranged and the Ideal Gas Law is expressed as:
PV=nRT
In order to use the Ideal Gas Law, the gas constant R needs to be known.
Image below shows the numerical values of the gas constant R, in various
units.
where, Pt is the total pressure of a gas mixture and P1, P2, P3, P4, P5 and so on,
are the partial pressures of each component gases.
Gases contained in one container will occupy the same volume and exposed
to same temperature, thus,
RT RT
Pt = (n1 + n2 + n3 + n4 + n5 + …)( V ) = nt( V )
Course Module
This theory provides a molecular explanation of both pressure and
temperature. The pressure of a gas is produced when molecules collide with
the container walls. The number of times and degree of hardness the
molecules collide with the walls determine the magnitude of the pressure.
The average kinetic energy of the gas molecules determines the absolute
temperature of a gas. If different gases are kept at the same temperature,
they have the same average kinetic energy.Once the temperature is doubled,
the average kinetic energy will also double.
Thermochemistry
Thermochemistry is the branch of chemistry that explains energy changes
that occur during chemical reactions. Thermodynamics on the other handis
the study of energy and how it changes. Further details on thermodynamics
will be discussed in the next modules.
Nature of Energy
Since energy comes in many forms, it can only be observed and measured by
its effect on matter.
1
𝐸𝑘 = 𝑚𝑣 2
2
There are times in which potential energy is transformed into kinetic energy.
See illustration below:
Units of Energy
Joule (J) is the SI unit of energy, and is defined as 1 J = 1 (kg-m2)/s2. Another
unit being used is calorie (cal), and is defined as the amount of energy
needed in order to raise the temperature of 1 g of water by 1°C. Calorie is
defined as 1 cal = 4.184 J.
In a laboratory, the system is the reactants and products being used, while
the surroundings is the container and all things beyond it.
Internal Energy
The total of all the kinetic and potential energies in a system is referred to as
the internal energy (E).
ΔE = Efinal– Einitial
The total of the heat (q) applied to or from the system and the work (w) done
on or by the system may be expressed as:
ΔE=q + w
The internal energy of a system increases when we put heat or work into it.
State Functions
Internal energy is a state function. It depends only on the present state, and
not on its history or the path by which the system arrived at that state. Thus,
ΔE is dependent only on Einitialand Efinal, and not how the change occurs.
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Enthalpy
Enthalpy (H) – described as the sum of the internal energy(E) and product of
pressure (P) and volume (V) in a system. It is expressed as:
H = E + PV
w =P Δ V
where; P = pressure
Δ V (change in volume in system) = Vfinal– Vinitial
Enthalpy Change
At constant pressure, change in enthalpy (ΔH) is expressed as:
Δ H = (E + PV)
=ΔE+PΔV (constant pressure)
ΔH = ΔE + P Δ V = (qp + w) – w = qp
Positive ΔH means that heat is absorbed by the system from its surroundings
(endothermic), while negative ΔH means that heat is lost from the system
into its surroundings (exothermic).
Enthalpies of Reaction
Enthalpy of reaction (heat of reaction) is defined as the enthalpy change in
a reaction; usually expressed as ΔHrxn.
Since, ΔH = Hfinal– Hinitial
Calorimetry
Calorimetry measures enthalpy change or heat flow in a chemical reaction.
A devices used to measure is referred to as calorimeter. Calorimeter
measures the magnitude of the change in temperature in a chemical process.
Molar heat capacity (Cm) is the amount of heat needed to raise the
temperature of 1 mole of a substance by 1K or 1°C.
The specific heat (Cs) is the amount of heat needed to raise the temperature
of 1gram of the substance by 1K or 1°C. Specific heat is expressed as:
𝑞
𝐶𝑠 = 𝑚 𝑋 ∆𝑇
Course Module
Figure 10.Bomb calorimeter;
http://hrsbstaff.ednet.ns.ca/benoitn/chem12/thermochemistry/calorimeter/bomb_calorimeter.htm;
April 26, 2017
Glossary
absolute temperature: expressed in Kelvin (K); 0 K is the lowest
temperature which can be reached
atmospheric pressure: pressure exerted by Earth’s atmosphere which
depends on temperature, location and weather conditions
calorie (cal): amount of energy needed in order to raise the temperature of
1 g of water by 1°C
compressible:able to mix in all proportions
directly proportional: as one amount increases, the other amount
increases, and vice versa
enthalpy: sum of the internal energy and product of pressure and volume in
a system
heat: energy used to cause the temperature of an object to increase
inversely proportional: as one amount increases, the other amount
decreases, and vice versa
internal energy (E): energy possessed by a system; sum of all the kinetic
and potential energy of a system
Joule (J): SI unit of energy
kinetic energy: energy of motion
moles: measurement of atoms and molecules used by chemists
negligible: unimportant; insignificant
General Chemistry
15
Gases and Thermochemistry
Understanding Entropy;
http://www.chem1.com/acad/webtut/thermo/entropy.html; April 27, 2017
Basic Thermochemistry;
http://physics.unm.edu/Courses/Duncan/physics452/048/EvansL2.pdf;
April 27, 2017
Thermochemistry;
http://www.oneonta.edu/faculty/viningwj/chem111/chapter_05_4_sy.pdf;
April 27, 2017
Thermochemistry;
https://ww2.odu.edu/~ppleban/pdf/chem115/Zumdahl6.pdf; April 27,
2017
Course Module
Online Instructional Videos
The Ideal Gas Law;
https://www.youtube.com/watch?v=BxUS1K7xu30&index=12&list=PL8dPu
uaLjXtPHzzYuWy6fYEaX9mQQ8oGr; April 26, 2017
Enthalpy;https://www.youtube.com/watch?v=SV7U4yAXL5I&list=PL8dPuu
aLjXtPHzzYuWy6fYEaX9mQQ8oGr&index=18; April 26, 2017
Calorimetry;https://www.youtube.com/watch?v=JuWtBR-
rDQk&index=19&list=PL8dPuuaLjXtPHzzYuWy6fYEaX9mQQ8oGr; April 26,
2017