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2.0 Coagulation......................................................................................................................... 4
References ............................................................................................................................... 16
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1.0 Introduction
Water and waste management covers the design, building and operation of plants for water
treatment and supply, sewerage, wastewater treatment and disposal, and solid waste treatment
and disposal. It aims to understand and control pollution of air, water and land, and to improve
amenity (Scott and Smith, 2005).
Wastewaters are normally treated by a combination of physicochemical and biological
operations. However, it is possible to treat wastewaters solely with physicochemical methods
(Droste, 1997). According to Pawłowski (1980), physicochemical treatment of wastewater
focuses primarily on the separation of colloidal particles. This is achieved through the addition
of chemicals (called coagulants and flocculants). These change the physical state of the colloids
allowing them to remain in an indefinitely stable form and therefore form into particles or flocs
with settling properties.
A brief description of two physicochemical processes used for water and wastewater
treatment, viz. coagulation and flocculation, are given in this document, along with an
explanation of where the processes may occur in the treatment stream.
The Dictionary of Water and Waste Management (Scott and Smith, 2005) defines
flocculation as the grouping of solids in water, resulting in flocs, often wrongly thought to be
the same as coagulation; it can be promoted by gentle stirring (mechanical flocculation) or by
adding chemicals (flocculants). Likewise, coagulation is defined as the addition of a chemical
to water or wastewater to form a precipitate (usually a metal hydroxide) that entraps or adsorbs
unwanted material such as suspended particles, colloids, colour, etc.
According to Reynolds and Richards (1996), in water treatment the principal use of
coagulation and flocculation is to agglomerate solids prior to sedimentation and rapid sand
filtration. In municipal wastewater treatment, coagulation and flocculation are used to
agglomerate solids in the physicochemical treatment of raw wastewaters and primary or
secondary effluents. In industrial waste treatment, coagulation is employed to coalesce solids
in wastewaters that have an appreciable suspended solids content. In water treatment, the
principal coagulants used are aluminium and iron salts, although polyelectrolytes are employed
to some extent in wastewater treatment, aluminium and iron salts, lime, and polyelectrolytes
are used. Chemical precipitation, which is closely related to chemical coagulation, consists of
the precipitation of unwanted ions from a water or wastewater. In the coagulation of municipal
wastewaters, not only does coagulation of solids occur, but also the chemical precipitation of
much of the phosphate ion takes place.
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Figure 1: Waste water treatment process.
Taken from:
https://www.researchgate.net/post/What_is_the_difference_between_coagulation_flocculatio
n_and_sedimentation on March 15, 2018 at 03:55 hrs.
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2.0 Coagulation
Derived from the Latin coagulare meaning driving together, coagulation refers to
destabilization or neutralization of the negative charges contained in the wastewater by the
addition of a coagulant applied during rapid mixing (which can vary from 250 - 1500 s-1) and
a very short contact time (times ranging between 5 - 60 s) (Libhaber and Jaramillo, 2012).
Figure 2: Coagulation
Taken from: http://www.bionicsro.com/water-treatment-chemicals/alum-salt.html on
March 15, 2018 at 03:40 hrs.
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layer or film to collect and surround the hydrophilic colloid. Frequently, this water layer or
film is termed the water of hydration or bound water. Usually, organic colloids, such as proteins
and their degradation products, are hydrophilic.
Hydrophobic colloids have little, if any, affinity for water; as a result they do not have any
significant water film or water of hydration. Usually inorganic colloids, such as clays, are
hydrophobic. Colloidal particles have electrostatic forces that are important in maintaining a
dispersion of the colloid.
The surface of a colloidal particle tends to acquire an electrostatic charge due to the
ionization of surface groups and the adsorption of ions from the surrounding solution. Also,
colloidal minerals such as clays, have an electrostatic charge due to the ionic deficit within the
mineral lattice. Hydrophilic colloids such as proteinaceous materials and microbes have
charges due to the ionization of such groups as the amino (—NH2) and the carboxyl (—COOH),
which are located on the colloidal surface. When the pH is at the isoelectric point, the net or
overall charge is zero since the amino group is ionized (—NH3-) and also the carboxyl group
is ionized (—COO-). At a pH below the isoelectric point, the carboxyl group is not ionized
(—COOH), and the colloid is positively charged as a result of the ionized amino group
(—NH3-). At a pH above the isoelectric point, the amino group loses a hydrogen, producing a
neutral group (—NH2), and the colloid is negatively charged because of the ionized carboxyl
group (—COO-) (Reynolds and Richards, 1996).
In general, most naturally occurring hydrophilic colloids such as proteinaceous matter and
microbes have a negative charge if the pH is at or above the neutral range. Some colloidal
materials such as oil droplets and some other chemically inert substances will preferentially
adsorb negative ions, particularly the hydroxyl ion, from their surrounding solution and become
negatively charged. Usually most naturally occurring hydrophobic colloids, such as clays, are
inorganic materials and have a negative charge. The sign and magnitude of the charge of a
colloid will depend on the type of colloidal matter and on the characteristics of the surrounding
solution.
In most colloidal systems, the colloids are maintained in suspension (in other words,
stabilized) as a result of the electrostatic forces of the colloids themselves. Since most naturally
occurring colloids are negatively charged and like charges are repulsive, the colloids remain in
suspension because of the action of the repulsive forces.
A negative colloidal particle will attract to its surface ions of the opposite charge —
counterions — from the surrounding water. The compact layer of counterions is frequently
termed the fixed layer; outside the fixed layer is the diffused layer.
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Hydrophilic colloids have a shear surface at the outer boundary of the bound water layer.
Conversely, hydrophobic colloids have a shear surface near the outer boundary of the fixed
layer.
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In conclusion, proper coagulation and flocculation of a water are very important in the
settling of the coagulated water, because the settling velocity is proportional to the square of
the particle diameter. Thus the production of the large floc particles results in rapid settling.
2.3 Coagulants
The most widely used coagulants in water treatment are aluminium sulphate and iron salts.
Aluminium sulphate (filter alum) is employed, more frequently than iron salts because it is
usually cheaper. Iron salts have an advantage over filter alum because they are effective over
a wider pH range. In the lime-soda softening process, the lime serves as a coagulant since it
produces a heavy floc or precipitate consisting of calcium carbonate and magnesium hydroxide.
This precipitate has coagulating and flocculating properties. The most widely used coagulants
in wastewater treatment are filter alum and lime (Reynolds and Richards, 1996).
Sometimes coagulant aids such as recycled sludge or polyelectrolytes, are required to
produce a rapid-settling floc. The principal factors affecting the coagulation and flocculation
of water or wastewater are turbidity, suspended solids, temperature, pH, cationic and anionic
composition and concentration, duration and degree of agitation during coagulation and
flocculation, dosage and nature of the coagulant, and, if required, the coagulant aid.
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Turbidity addition, such as recycling some chemically precipitated sludge ahead of the
mixing or flocculation basins, is occasionally required to furnish sufficient particulate
concentrations for rapid coagulation. Adequate particulate concentrations provide sufficient
interparticulate collisions to yield optimum coagulation. Clays are sometimes used for turbidity
addition instead of recycled sludge.
Adjustment of pH is required if the pH of the coagulated water does not fall within the pH
range for minimum solubility of the metallic hydroxide. Increasing the pH is usually done by
addition of lime; pH reduction is usually accomplished by the addition of a mineral acid, such
as sulfuric acid.
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3.0 Rapid Mixing
The rapid mixing stage is possibly the most important component of coagulation-
flocculation processes, since it is here that destabilization reactions occur and where primary
floc particles are formed, whose characteristics markedly influence subsequent flocculation
kinetics (Mara, 2005).
In the rapid-mix basins, intense mixing or agitation is required to disperse the chemicals
uniformly throughout the basin and to allow adequate contact between the coagulant and the
suspended particles. By the time the water leaves the rapid-mix basins, the coagulation process
has progressed sufficiently to form micro flocs.
In the flocculation basins, the fine micro flocs begin to agglomerate into larger floc
particles. This aggregation process (flocculation) is dependent on the duration and amount of
gentle agitation applied to the water. By the time the water leaves the flocculation basins, the
floc has agglomerated into large, dense, rapid-settling floc particles. The types of devices
usually used to furnish the agitation required in both rapid mixing and flocculation may be
generally classified as (1) mechanical agitators, such as paddles, (2) pneumatic agitators, and
(3) baffle basins. The mechanical type is the most common (Reynolds and Richards, 1996).
Although power for rapid mixing may be imparted to the water by mechanical agitation,
pneumatic agitation, and baffle basins, the power required for each method must be the same
if the mixing is to be at the same intensity.
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Mechanical mixing basins are not affected to any extent by variation in the flowrate and
have low head losses. Detention times from 20 to 60sec are generally used, although some
mixing basins have had detention times as small as l0 sec or as long as 2~5 min.
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Figure 4: Typical pneumatic rapid mixer.
Taken from: Unit Operations and Processes in Environmental Engineering (Reynolds
and Richards, 1996) on March 16, 2018 at 19:36hrs.
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4.0 Flocculation
Flocculation is stimulation by mechanical means to agglomerate destabilised particles into
compact, fast settleable particles (or flocs). Flocculation or gentle agitation results from
velocity differences or gradients in the coagulated water, which causes the fine moving,
destabilized particles to come into contact and become large, readily settleable flocs. It is a
common practice to provide an initial rapid (or) flash mix for the dispersal of the coagulant or
other chemicals into the water. Slow mixing is then done, during which the growth of the floc
takes place. Significantly, it must be noted that flocculation is a physical process that does not
involves the addition of chemicals (Warren, 2004).
Design contact times for flocculation range from 15 or 20 minutes to an hour or more, and
flocculation requires careful attention to the mixing velocity and amount of mix energy. To
prevent floc from tearing apart or shearing, the mixing velocity and energy are usually tapered
off as the size of floc increases. Once flocs are torn apart, it is difficult to get them to reform to
their optimum size and strength. The amount of operator control available in flocculation is
highly dependent upon the type and design of the equipment.
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Figure 6: Stokes Law and Settling Particles
Taken from: Unit Operations and Processes in Environmental Engineering (Reynolds
and Richards, 1996) on March 20, 2018 at 04:59 hrs.
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4.3 Mechanism of Flocculation
According to Scott and Smith (2005), mechanism involved with flocculation are as follows:
Gravitational flocculation: Baffle type mixing basins are examples of gravitational
flocculation. Water flows by gravity and baffles are provided in the basins which induce the
required velocity gradients for achieving floc formation.
Mechanical flocculation: Mechanical flocculators consists of revolving paddles with
horizontal or vertical shafts or paddles suspended from horizontal oscillating beams, moving
up and down.
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5.0 Conclusion
Physicochemical treatment may constitute a single stage in the wastewater treatment
process or be added as an additional treatment process during pre-treatment (to improve the
biodegradation of wastewater in the biological process and secondary treatment (such as
polishing). The two most widely utilised physiochemical processes are coagulation and
flocculation.
Coagulation and flocculation are two processes commonly used in water treatment in order
to get rid of unwanted suspended material in water. However, they can be commonly adopted
for de-stabilizing any suspension system. Coagulation involves the use of a coagulant which
has the potential to de-stabilize the previously stabilized charged particles in the suspension. In
contrast, in flocculation, the de-stabilization is brought about by physical techniques such as
mixing of the solution, and also sometimes aided by the addition of polymers.
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References
Droste, Ronald L. Theory and Practice of Water and Wastewater Treatment. New York: Wiley,
1997.
Libhaber, M., and A. O. Jaramillo. Sustainable Treatment and Reuse of Municipal Wastewater.
London: IWA Publishing, 2012.
Reynolds, Tom D., and Paul A. Richards. Unit Operations and Processes in Environmental
Engineering. Boston: PWS Pub., 1996.
Thakkar, Shreya, Viral Shah, Manju Misra, and Kiran Kalia. "Nanocrystal Based Drug
Delivery System: Conventional and Current Scenario." Recent Patents on
Nanotechnology11, no. 2 (2017). doi:10.2174/1872210510666161014122439.
Viessman, Warren. Water Supply and Pollution Control. 7th ed. Upper Saddle River, NJ:
Pearson Education, 2005.
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