THE COMMITTEE OF THE 6TH INTERNATIONAL CONFERENCE OF

THE INDONESIAN CHEMICAL SOCIETY (ICICS 2017)

Adsorption of Cobalt (II) on Layered Double Hydroxides (Mg/Al and Ca/Al)

In Aqueous Medium : Kinetic and Thermodynamic Aspect
Neza Rahayu Palapa , Muhammad Said, Risfidian Mohadi, Aldes Lesbani
Nezarahayu@gmail.com

Abstract. The synthesis of layered double hydroxides has been conducted using M2+/M3+ INTRODUCTION
metal cation in aqueous medium on high bacisity, where M2+: Mg2+, Ca2+ and M3+: Al3+. Structure of Layered
The materials Mg/Al and Ca/Al layered double hydroxides were characterized using High Toxicity Double Hydroxides
Layered Double Hydroxides
FTIR and X-Ray powder analyses. Layered double hydroxides (Mg/Al and Ca/Al) And Harmfull
materials then were applied as adsorbent of cobalt (II) in aqueous medium. Kinetics To Enviroment
and thermodynamic adsorption of cobalt (II) were studied. The results of FTIR
spectrum of layered double hydroxide Mg/Al and Ca/Al were showed by unique
vibration of layered material at wavenumber 500-1600 cm-1. The result of X-Ray
powder analysis was showed high crystallinity. Kinetically, Mg/Al layered double
hydroxides are more reactive than Ca/Al to adsorb cobalt (II) in aqueous medium.
Thermodynamically, adsorption of cobalt (II) on Mg/Al layered double hydroxides is
Adsorp
larger than Ca/Al layered double hydroxide.
Use
METHODS
Cobalt (II) Nitrate

add

Removal methods
LOW ADSORBENT
Adsorption
COST
Kind Coagulation
Kinetics and
Thermodynamic Mg/Al Ca/Al Ozonation

Study Filtration

Precipitation

Variated of concentration
RESULT and temperature Layered double
Layered Double
hydroxides Mg/Al
Hydroxides
Ca/Al Variated of time

Layered Double Hydroxides Ca/Al

Layered Double
Hydroxides Mg/Al

Layered Double Hydroxides Mg/Al

XRD Powder Pattern FTIR Spectra

Layered double

Kinetics Study PSO kinetic models

hydroxides Ca/Al

T (K) Adsorbent K2
R2
(mg/g L min)

Layered double hydroxides

Ca/Al
0.165 0.956 CONCLUSION
303
Layered double hydroxides
0.018 0.962
Mg/Al Adsorption process of cobalt (II) on layered
double hydroxides Mg/Al and Ca/Al showed
Thermodynamics Study
b E Concentrati ΔH ΔS
the adsorption rate 0.018 and 0.165,
respectively. Layered double hydroxides
Adsorbent T (K) Adsorbent
(mg/g) (kJ/mol) on (kJ/mol) (kJ/mol K) Mg/Al more reactive than layered double
303 6.6401 x 10-3 7.1877 10 -13.40 45.00
layered 308 6.9013 x 10-3 7.4890 layered hydroxides Ca/Al. Thermodynamics
15 -75.40 24.88
double
313 7.0872 x 10-3 7.7661 double
20 -58.44 18.99
adsorption layered double hydroxides Mg/Al
hydroxides hydroxides
Mg/Al 318 6.7981 x 10-3 8.1184 25 -83.55 26.02 has higher adsorption capacity than layered
Ca/Al
323 6.9444 x 10-3 8.3008 30 -79.86 22.66 double hydroxides Ca/Al. Other
303 3.6232 x 10-3 7.8748 25 -36.81 140.42 thermodynamic parameters such as entalphy
layered 308 3.0769 x 10-3 6.6784 layered 30 -21.59 85.05 is decreases with increasing concentration
double double
313 3.2895 x 10-3 6.9292 35 -19.52 75.16 and entrophy decreases with increasing of
hydroxides hydroxides
Ca/Al 318 3.4483 x 10-3 7.0161 Mg/Al 40 -91.70 38.83 cobalt (II) concentration.
323 3.6470 x 10-3 7.2493 45 -87.04 36.92