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CA Cellulose acetate
CAB Cellulose acetate-butyrate
CAN Cellulose acetate-nitrate
CAP Cellulose acetate-propionate
CB Cellulose butyrate (also carbon black reinforcing pigment)
CBR Chlorinated butadiene rubber
CDB Conjugated diene butyl elastomer
CE Cellulose plastics in general
CEM Polychlorotrifluoroethylene (also CFM, CTFEP, PCTFE)
CF Cresol-formaldehyde resins (also reinforcing carbon fiber)
CFM Polychlorotrifluoroethylene (also CEM, CTFEP, PCTFE)
CHR Elastomeric copolymer from epichlorohydrin and ethylene
oxide
CIIR Post chlorinated elastomeric copolymer from isobutene and
isoprene
CM Chloro-polyethylene (also compression molding)
CMC Carboxymethyl cellulose (or critical micelle concentration)
CMHEC Carboxymethyl hydroxyethyl cellulose
CMPS Poly(chloromethyl styrene)
CN Cellulose nitrate (celluloid)
CNR Elastomeric terpolymer from tetrafluoroethylene, trifluoro-
nitrosomethane, and a small amount of an unsaturated mono-
mer, e.g., nitrosoperfluorobutyric acid and nitroso or carboxy
nitroso rubber
CO Polychloromethyl oxirane elastomer, epichlorohydrin rubber
COP Cycloolefin polymers or copolymers
CO-PAI Copolyamideimide
COPE Copolyester elastomer
CO-PI Copolyimide
COPO Poly(carbon monoxide-co- polyolefin), a linear, alternating
terpolymer: ethylene-co- propylene-co-carbon monoxide
COX Carboxylic rubber
CP Cellulose propionate, or chlorinated polyethylene, also CPE
CP2 Alternating copolymer from vinyl ether and maleic acid
CP4 Copolymer from acrylic acid and maleic acid
CPE Chlorinated polyethylene
CPET Crystallizable (or chlorinated) polyethyleneterephthalate
CPI cis-Polyisoprene, also IR
CPVC Chlorinated polyvinyl chloride
CR Chloroprene, or neoprene, rubber
CRM Chlorosulfonated polyethylene
CRP Carbon fiber reinforced plastics
CS Casein
2158 Appendix I: International Abbreviations for Polymers and Polymer Processing
PDMS Polydimethylsiloxane
PDPS Polydiphenylsiloxane
PE Polyethylene
PEA Polyetheramide
PEAc Polyethylacrylate
PEB Polyethylene-p-oxybenzoate
PEBA Thermoplastic elastomer, polyether block amide
PEC Polyestercarbonate or chlorinated polyethylene, usually CPE
PeCe Chlorinated PVC (also CPVC, PC, PVCC)
PECO Polyethylene carbonate
PEE Polyester ether fibers (containing diol and p-hydroxy benzoate
units, e.g., polyethylene-p-oxybenzoate
PEEI Polyesteretherimide
PEEK Polyetheretherketone
PEG Polyethyleneglycol
PEH High-density polyethylene, also HDPE
PEI Polyetherimide
PEIE Polyetherimide ester copolymer
PEIm Polyetherimine
PEK Polyetherketone
PEKEKK Poly(ether-ketone-ether-ketone-ketone)
PEL Low-density polyethylene, also LDPE
PEM Medium-density polyethylene, also MDPE
PENDC, PEN Poly(ethylene 2,6-naphthalene dicarboxylate) or
polyethylenenaphthalate
PENi Polyethernitrile
PEO Polyethylene glycol, usually PEG
PEOX Poly(2-ethyl-2-oxazoline)
PEP Thermoplastic copolymer from ethylene and propylene
PEPA Polyether-polyamide copolymer
PES Polyethersulfone [j-SO2-j-O–]n
PEsA Polyesteramide
PESK Polyarylenethioetherketone
PEST Thermoplastic polyesters, e.g., PBT, PET, also TPES
PET, PETP Polyethyleneterephthalate
PETG Polyethyleneterephthalate glycol, copolymer with 66 mol%
ethylene glycol and 34 mol% cyclohexylene dimethanol
PEtI Polyethyleneimine
PEUR Polyether urethane
PF Phenol-formaldehyde resin
PFA Polyfluoroalcoxyalkane, copolymer of tetrafluoroethylene and
perfluorinated
PFEP Copolymer from tetrafluoroethylene and hexa-fluoro propyl-
ene, also FEP
Appendix I: International Abbreviations for Polymers and Polymer Processing 2167
Polymer
No. A B Name Supplier Comments
1. PS PB(BR) Hostyren Hoechst The blends are formulated
or PE for extrusion, injection and
blow molding
Limera R Dainippon Ink and They show excellent
Chemicals processability, low moisture
Polysar Bayer Miles absorption and shrinkage,
Polystyrol BASF AG improved impact strength.
Composition-dependent
Styroblend BASF AG
modulus, toughness,
Styroplus BASF AG ductility, transparency, and
gloss
2. ABS or Elastomer Cadon* Monsanto Chem. Blends of ABS or ASA with
ASA or SMA* Centrex Monsanto Chem. either acrylic rubber (800) or
Luran S BASF AG PB (900 series) were
formulated for extrusion,
Magnum Dow Chem. Co.
thermoforming, injection,
Rovel Uniroyal and blow molding. They
Starflam ABS Ferro Plastics show excellent
Terluran BASF AG processability,
weatherability, impact
strength, HDT, scratch
resistance, paintability, and
plateability
(continued)
Polymer
No. A B Name Supplier Comments
3. TPU ABS Prevail Dow Chem. Co. The blends can be injection
Techniace TU Sumitomo Dow molded, extruded, blow
molded, or thermoformed.
Transfer or compression
molding, calendering, and
solid state may also be used.
They show hardness between
that of TPU and ABS, superb
toughness, chemical
resistance, appearance
4. LDPE PIB Lupolen O 250 BASF AG The 1:1 blends are flexible
Pax-Plus Paxon Polymer Co. and resistant to cracking
under stress and show good
water-vapor properties. The
blends are formulated for
extrusion, injection, and
blow molding. The weld-line
strength, resistance to
warpage, and shrinkage
depend on processing
conditions
5. NBR EPDM or Geolast JSR Monsanto JSR The blends are formulated
CPE or PVC NE * for extrusion, calendering,
Chemigum Goodyear Tire & injection, and blow molding.
TPE# Rubber Co. They have either
Krynac NV Polysar, Inc. co-continuous or (less
# frequently) dispersed
Nipol Nippon Zeon
#
morphology. They show
Paracril OZO Uniroyal Chemical good processability; ozone,
oil, and heat resistance; low
compression set;
low-temperature flexibility;
nearly total elastic recovery;
and excellent weather
resistance. Principal use
includes automotive weather
stripping, interior moldings,
tubings, hoses, seals, gaskets,
expansion joints, cable
sheathings, conveying belts,
roofing, pond liners,
geomembranes, floorings,
etc.
(continued)
Appendix II: Examples of Commercial Polymer Blends 2177
Polymer
No. A B Name Supplier Comments
6. PP TPO or EPR BK 891 Mitsui Chemical The blends are formulated
or EPDM Deflex A. Schulman mainly for injection molding,
Dynaflex JSR but they can also be extruded,
thermo- or vacuum-formed
Ferrolene Ferro Plastics
(e.g., Optum), compression
Ferro Flex Ferro Plastics or transfer molded,
HiFax Himont Adv. Mat. calendered, and blow
Hostalen PP Hoechst molded. Several have
IPCL JSA1986 IPCL dynamic properties, viz.,
hardness and heat resistance.
Kelburon, DSM Polymer
Some blends are vulcanized,
Keltan TP International
showing toughness, and are
Milastomer Mitsui Petrochem. composition dependent
Modylen Tiszagi Vergi Kom. (30 wt%) (e.g., Kelburon)
Moplen SP Himont and reactor made. Reinforced
Oleflex Showa Denko Co. and filled grades (containing
Optum Ferro Plastics glass fiber, talc, CaCO3, or
mineral filler) are available.
Polytrope A. Schulman, Inc. These blends show good
Propathene ICI processability,
PU-21713 Ferro Plastics low-temperature modulus
RPI 507 EP Research Polym. and impact strength,
RxLOY Ferro Plastics dimensional stability, low
shrinkage, good mechanical
Santoprene Monsanto
properties at temperatures
Sarlink Novacor from 40 to 150 C, ozone
Sumitomo Sumitomo Chem. resistance, dynamic fatigue
TPE and abrasion resistance, as
Thermolan Mitsubishi well as high good weather
2000 Petrochemicals ability (especially carbon-
TPO 900 Reichhold Chem. black filled grades) tear
strength and paintability.
Vestolen EM H€
uls A.-G.
Over 200 applications have
been found for these
materials, e.g., they are used
in appliances, hardware and
plumbing, automotive
industry (arm rests, pillar
trim, door panels, radiator
grilles, dashboards, children
seats, side protectors,
bumpers, spoilers), etc.
(continued)
2178 Appendix II: Examples of Commercial Polymer Blends
Polymer
No. A B Name Supplier Comments
7. PVC Acrylics Acrylivin General Tire & Suspension PVC modified by
Rubber 5–15 wt% acrylic elastomer.
Cladux R. Daleman The blends are are
Decoloy GE Plastics formulated for extrusion,
injection, and blow molding,
Fiberloc HTX The Geon Company
vacuum- or thermoforming,
Haibulen Nippon Zeon and calendering. They show
Kane-ace Kanegafuchi Chem. high impact strength,
Kydex Rohm and Haas rigidity, resilience,
Metabulen Mitsubishi Rayon dimensional stability, flame
retardancy, excellent outdoor
Polycast Royalite
performance, and good
Sunloid KD Tsutsunaka flame, abrasion, electrical,
Vinidur BASF AG chemical, and solvent
resistance. These blends are
used in industrial,
commercial, consumer (e.g.,
as wall coverings, corner
guards, column covers,
shelving, counter laminates,
ceiling tiles), medical, food
or beverage equipment,
aircraft or mass transit
interior components, and
applications requiring good
resistance to weathering
8. PVC NBR Carloy Cary Chem. Inc. These blends (containing
Geon/Hycar B. F. Goodrich 30–60 wt% PVC) are
Denka LCS Showa Denko Co. formulated mainly for
extrusion and calendering,
JSR NV Jap. Synth. Rub.
but injection, blow,
Krynac NV Miles-Polysar compression, and transfer
Nipol Nippon Zeon molding can also be used.
Oxyblend OxyChem They show good
Paracril OZO Uniroyal Chem. processability, fast
calendering and extrusion,
Vynite Alpha Chem. Plast.
impact and tear strength, and
oil, fuel, improved chemical,
abrasion, weathering, ozone,
antistatic, flame, and
moisture resistance. Their
applications include cables
and hoses, printing plates and
rollers, shoe soles, bottles for
cosmetics and edible oils,
profiles, etc.
(continued)
Appendix II: Examples of Commercial Polymer Blends 2179
Polymer
No. A B Name Supplier Comments
9. PVC ABS or Abson 042 Abtec Chem. Co. These blends are formulated
ASA* Cycovin K-29 The Geon Co. for injection molding,
Denka Taimel. Denki Kagaku extrusion, and thermo-or
* vacuum forming, but
Geloy GE Plastics
calendering can also be used.
XP2003
The blends show superior
Kaneka Enplex Kanegafuchi Corp. processability to component
Kralastic Uniroyal/Sumitomo polymers, impact strength,
Lustran ABS Monsanto Chem. flame retardance, and cost-to-
860 performance ratio. The blends
Nipeon AL Zeon Kasei Co. with ASA show superior
weatherability, while those
Polyman 500 A. Schulman,
containing SMA high
Inc. DSM
HDT. The main use is for
Ronfaloy V DSM business machines, electrical
Tufrex VB Mittsubishi and electronic equipment
Triax CBE Monsanto Chem. housings, automotive
(discontinued) applications, swimming pool
fittings, irrigation, etc.
10. PA-6 Grilon BT EMS-Chemie Miscible blends show
PA Wellamid MR Wellman, Inc. improved processability,
Zytel 3100 E. I. du Pont solvent resistance,
elongation, low-temperature
impact and tensile strength
11. PA PA Akuloy RM DSM Eng. Plast. The blends are formulated
Dexpro, Dexter Corp. mainly for injection molding
Dexlon and extrusion. Polyamides
Eref Solvay PA-6, PA-66, PA-mXD6, and
PARA. In most blends PA is
Flexloy Sumitomo Chem.
the matrix phase, but those
Gapex Ferro Plastics with PP as a matrix are also
LAX 23 Ube, Inc. available (e.g., from Solvay).
MCX-Q Mitsui Petrochem. The blends show good
NB Toyobo processability; reduced water
absorption; dimensional
Novamid AC Mitsubishi Chem.
stability; low density (i.e., low
Orgalloy R-6 Atochem cost per volume); low liquid
Poliblend NH Poliresins SA and vapor permeability;
Snialoy Nylon Corp. Amer. moderate impact strength;
Systemer S Showa Denko Co. good resistance to alcohols,
Thermocomp LNP glycols, and gasohol;
improved heat aging; primer-
Ube Alloy CA Ube Inc. less paintability; and
Ultramid KR BASF AG resistance to cracking when
UTX Unitika exposed to metal halides (e.g.,
CaCl2). Some grades are
reinforced. Principal blend
uses include appliances,
automotive, tools, building,
furniture, and industrial
(continued)
2180 Appendix II: Examples of Commercial Polymer Blends
Polymer
No. A B Name Supplier Comments
12. PA-6, P E, EPR, Albis Albis Plastics The blends are formulated
PA-66, acrylic Bexloy C E. I. du Pont for extrusion, co-extrusion,
PARA, elastomers, Brilion BT-40 Emser Ind. injection, compression,
or or ionomers transfer, and blow molding.
Capron AlliedSignal
PA-666 They can also be
Durethan Bayer A.-G thermoformed. Grades
Dynyl Rhône Poulenc containing up to 40 wt%
Fiberfil TN DSM Eng. Plast. mineral or glass fibers are
Grilon A EMS-Chem. A.-G. available. Some may contain
PTFE. The blends have good
Maranyl ICI
processability,
Minlon E. I. du Pont low-temperature impact
Nybex Ferro Plastics strength, rigidity, stiffness,
Nycoa Nylon Corp. Amer. high heat resistance, lower
Nydur Bayer A.-G service temperature. The
Nylafil Wilson-Fiberfil Int. molded articles can suppress
vibration, even when dry and
Nylon Celanese Eng. Res. at sub-zero temperatures.
Star X Ferro Plastics The blends find use in
Technyl A Rhône Poulenc a broad range of applications,
and B viz., automotive (stone and
Ultramid A, BASF AG splash guards, under-the-
B, C, and T hood moldings, seals, hoses,
Vydyne Monsanto Chem. tubes, clips, fasteners, fuel
doors, gears), appliances,
Wellamid 22 L Wellman Inc.
sport (e.g., ski bindings,
Zytel ST E. I. du Pont roller skates), business
Zytel 300, 400 E. I. du Pont equipment, consumer
products (office chair seats,
housings, casters, wheels,
rollers, pulleys, gears), etc.
13. PA-66, Brominated Akulon K228 DSM These fire-resistant,
or PA-6 PS Latamid 66 Lati unreinforced blends designed
Starflam PA6 Ferro Plastics for injection molding or
extrusion are used in
Ultramid A3X BASF AG
automotive and electrical
Zytel FR E. I. du Pont applications. They show
good flame retardance,
mechanical properties, and
dimensional stability
(continued)
Appendix II: Examples of Commercial Polymer Blends 2181
Polymer
No. A B Name Supplier Comments
14. PA-6 or ABS Alphaloy MPA Kanegafuchi Chem. The compatibilized blends
PA-66 Elemid GE Plastics (with either PA as matrix or
Diaaloy N Mitsubishi Rayon co-continuity of both phases)
are formulated for injection
Kane ace Kanegafuchi Chem.
molding, extrusion, and
MUH
thermoforming, but blow and
Malecca S Denki Kagaku K. compression molding also
Maxloy A JSR can be used. The blends show
Monkalloy N Monsanto Kasei good processability and flow;
N5 Thermofil Inc. high heat and chemical
resistance; high resistance to
Novaloy-A Daicel Chem. Ind.
oil, wear, and abrasion;
Stapron N DSM Polymer Int. dimensional stability;
SX Toray Ind., Inc. low-temperature impact
Techniace TA Sumitomo Dow strength; reduced moisture
Toyolac alloy Toray Ind., Inc. sensitivity; and economy.
Triax 1000 Monsanto Main application is in
automotive, chemical,
Ultramid BASF AG electrical, customer, and
sport industries. Some grades
are glass fiber reinforced.
The material has been also
used in anti-vibration
damping structures
15. PA Cyclic - PO Elmit ZF Mitsui Processability, impact
Petrochemicals strength, moisture
insensitivity
16. PA PC Dexcarb D & S Int. Processability,
Iupilon Mitsubishi Gas HDT > 200 C, impact
SC 720 Idemitsu strength, low mold
shrinkage, solvent, and
Petrochemicals
moisture sensitivity
17. PC TPU Texin 3000 Bayer/Miles PC blends with polyester
Texin 4000 urethane were designed for
extrusion or molding articles
used in automotive and
consumer goods’ industries
18. PC Elastomer Idemitsu Idemitsu The blends for extrusion or
SC-150 Petrochemicals injection molding
Makrolon T-78 Bayer/Miles contain < 6 wt% elastomer
Novarex AM Mitsubishi Chem. (e.g., butyl acrylate-co-
methacrylate) and thus are
opaque. They show low
temperature toughness, high
impact strength, good weld-
line strength, and HDT
(continued)
2182 Appendix II: Examples of Commercial Polymer Blends
Polymer
No. A B Name Supplier Comments
19. PC ABS (and Alphaloy Kanegafuchi Chem. The blends are formulated for
SAN in Bayblend T Bayer/Miles injection molding, extrusion,
some Cycoloy GE Plastics and thermo-or vacuum
blends) forming, but they can also be
Denka HS Denki Kagaku
compression or transfer
Dialoy C Mitsubishi Rayon molded. They show good
Exceloy JSR processability, excellent
Iupilon MB Mitsubishi Gas plating, HDT and impact
Lynex B Asahi Chem. strength, high stiffness and
strength, dimensional
Malecca P Denka
stability, toughness,
Multilon PX Teijin Chem. Ltd. delamination resistance,
Novaloy-S Daicel Chem. Ind. low-temperature impact
Proloy/Lexan GE Plastics strength, good weld-line
Pulse Dow Chem. Co. strength, and solvent and
Ronfalin DSM chemical resistance. These are
three-phase blends, with
Royalite R11 Uniroyal 30–65 wt% PC usually being
Ryulex Dainippon the matrix. Grades with glass
SC 250 Idemitsu fiber reinforcement are
Petrochem. available. The blends are used
Techniace TC Sumitomo Dow for housings of computers,
Toplex Multibase, Inc. business machines and
electrical appliances,
Terblend B BASF AG
electrical and electronic parts,
Triax 2000 Monsanto Chem. connectors, carriages,
ABS/PC 7901 Diamond Polymers switches, fans, power and
agricul-tural, garden and lawn
tools, cameras, optical
instruments, exterior
automotive components,
electronic or
telecommunication parts,
sporting goods, etc.
20. PC ASA, or Baitaloy* Hitachi Chem. High impact strength,
AAS* high- thermal stability, improved
Dialoy A Mitsubishi Rayon resistance to temperature
Geloy XP4001 GE Plastics aging and UV degradation,
excellent weatherability,
Terblend S BASF AG
rigidity, and dimensional
stability. The blends are
formulated mainly for
extrusion, injection molding,
and thermoforming
21. PC PS Novadol Mitsubishi Chem. Impact strength, thermal
SC 200 Idemitsu stability, and weatherability
Petrochemicals
(continued)
Appendix II: Examples of Commercial Polymer Blends 2183
Polymer
No. A B Name Supplier Comments
22. PC SMA Arloy 1000 ARCO Chem. Co. The blends are designed for
Ektar MB Eastman Kodak extrusion, thermoforming, or
R4 9900 Thermofil Inc. injection molding. They
show excellent
processability, toughness,
and heat resistance
23. PC PBT or PET Azloy Azdel, Inc. The blends are formulated
or PCTG BCT 4201 Toray for injection molding,
(and Defsan Russia extrusion, and blow molding,
10–20 wt% but they can be transfer or
Dialoy P Mitsubishi Rayon
impact compression molded, formed
modifier) Ektar MB, Eastman Chemical in solid state, or
Company thermoformed. In most
blends PC is the matrix
phase. The impact modifier
can be PE, ABS, or acrylic
copolymer, e.g., MBS. The
blends show good
processability; heat
resistance; ductility; HDT;
high modulus, impact,
tensile, and flexural strength
over a wide temperature
range; good adhesion;
solvent, chemical, and UV
resistance. They can be
painted, hot stamped,
metallized, and plated. Some
blends (containing
polybutadiene as impact
modifier) may have poor
weather-ability. The blends
are mainly used in
automotive industry
Eastalloy DA Eastman Chemical
(PCTG) Company
Idemitsu SC Idemitsu
600 Petrochem.
Makroblend Bayer A.-G.
MB4300 Mitsubishi Gas
Novadol Mitsubishi Chem.
Pocan Bayer
R2-9000 Thermofil Inc.
Sabre Dow
Stapron E DSM Polymer Int.
Ultrablend KR BASF
Valox GE Plastics
Xenoy 1000 GE Plastics
(continued)
2184 Appendix II: Examples of Commercial Polymer Blends
Polymer
No. A B Name Supplier Comments
24. PET Elastomer Arloy 2000* ARCO Chem. Co. The blends are formulated for
or SMA* Celanex Celanese Eng. Res.extrusion, injection,
Rynite E. I. du Pont compression, blow, and
transfer molding. The blends
SC-150 Idemitsu
contain up to 35 wt% glass
Petrochemicals
fiber. They show good
processability, rigidity, impact
and tensile strength, as well as
excellent weatherability
25. PET or PC (and *Ektar MB Eastman These blends can be injection
PCTG* 15–20 wt% Hyperlite Kanegafuchi Chem. molded or extruded. They are
impact Impact AlliedSignal partially miscible, with
modifier) co-continuous morphology
Makroblend Mobay
showing improved
UT
processability, solvent
MB 3500 Mitsubishi Gas resistance, elongation,
Petsar Polysar low-temperature impact and
Sabre 1600 Dow tensile strength (possible
SC Idemitsu reduction of crystallinity upon
Petrochemicals blending) Ektar resins are
based on poly(cyclohexane-
Xenoy 2000 GE Plastics
terephthalate-glycol) mixed
with PC and/or with
SMA. They are primarily used
in business machines,
appliances, consumer goods,
garden tools, lightning,
automotive, sports equipment,
fluid handling, etc.
26. PBT PET C, CN Teijin Good surface properties,
Celanex Hoechst Celanese HDT, impact strength,
EMC Toyobo dimensional stability, and
economy
Valox GE Plastics
27. PBT Acrylic BU Dai Nippon Ink Improved processability and
rubber BX Toray impact resistance
Novadol Mitsubishi Chem.
Vandar Hoechst
28. PBT Elastomer Bexloy J E. I. du Pont These impact-modified PBT
Celanex Hoechst Celanese blends are formulated for
Gafite GAF injection molding, but they
can also be extruded and
Macroblend Bayer Miles
thermoformed. They show
Pibiter HI Montedipe good processability,
Starflam PBT Ferro Plastics electrical properties, high
Techster T Rhône Poulenc stiffness and strength, HDT,
Ultradur KR BASF AG dimensional stability, impact
strength, and solvent and
chemical resistance
(continued)
Appendix II: Examples of Commercial Polymer Blends 2185
Polymer
No. A B Name Supplier Comments
29. PBT ABS or A, AN Teijin The blends contain
AAS* Alphaloy MPB Kanegafuchi Chem. 0–30 wt% glass fiber or
BA Dai Nippon Ink mineral fillers. They are
formulated for injection
Baitaloy VL* Hitachi Chem.
molding but can be extruded,
Cycolin GE Plastics thermoformed, or solid state
Diaaloy B Mitsubishi Rayon formed. They show excellent
Lumax Lucky Co., Ltd. processability, high gloss,
Malecca B Denka Kagaku K. stiffness at high temperature,
good electrical properties,
Maxloy B JSR
thermal stability, mechanical
Novaloy-B Daicel Chem. Ind. strength, HDT, low
Techniace TB Sumitomo Dow shrinkage, good dimensional
Triax 4000 Monsanto stability, impact strength, as
Ultrablend S BASF AG well as solvent (e.g., to
VX Toray gasoline and motor oils) and
chemical resistance. The
main consumption includes
electronics, automotive and
electrical industry, as well as
office, sports, and household
equipment
30. PAr PET or PC Ardel D-240 Amoco Corp. Processability, high HDT,
U-8000 Unitika tough, high impact strength
31. POM PBT Duraloy Celanese HDT, toughness, softness,
Lynex T Asahi Chem. high impact strength
32. POM TPU Celcon Celanese Eng. Res. The blends are formulated
Delrin E. I. du Pont for extrusion, injection,
Duraloy H.-Celanese compression, blow, and
transfer molding. They show
Formaldafil Wilson-Fiberfil
excellent processability;
Fulton KL LNP Corp. rigidity; high impact
Hostaform S Hoechst A.-G. strength; high fatigue,
RTP 800 RTP Corp. flexural, and tensile strength;
TC Polyplastics high toughness; low water
absorbency; gloss; and
Thermocomp LNP
resistance to chemicals. In
Ultraform BASF AG most blends POM is impact-
modified with 10–30 wt%
TPU. Some grades contain
PTFE. Co-continuous
morphology gives especially
good performance. These
blends find use in sports
equipment, plumbing,
electronic/mechanical parts,
automotive, appliances,
hinges, etc.
(continued)
2186 Appendix II: Examples of Commercial Polymer Blends
Polymer
No. A B Name Supplier Comments
33. PPE PS (HIPS, Gepax GE Plastics These blends, with
SBS, SEBS, Luranyl BASF AG 25–60 wt% PPE, were
ABS, Noryl GE Plastics designed for injection or blow
SB,. . .) molding, calendering,
Prevex GE Plastics
thermoforming, and
Verton H€
uls extrusion. Some grades are
Vestoran 1900 H€
uls-Nuodex rein-forced with < 30 wt%
and 2000 glass fibers. They show good
Xyron 200 Asahi Chem. Ind. processability, heat
resistance,
HDT ¼ 90–150 C,
toughness, good dimensional
stability, resistance to hot
water, flame retardance, low
density, cost/performance
ratio, and low moisture
absorption
34. PPE PA Artley Sumitomo Chem. The blends are designed for
Dimension AlliedSignal extrusion, thermoforming, or
Lynex A Asahi Chem. Ind. injection molding. They are
compatibilized, with
Noryl GTX GE Plastics
40–60 wt% PA, showing
Remaloy Mitsubishi moderate processability and
Petrochemicals impact strength; good tensile
Ultranyl BASF AG and flexural strength; high-
Vestoblend H€
uls A.-G. temperature creep, solvent,
Xyron A and G Asahi Chem. Ind. and chemical resistance; and
low moisture absorption.
They are dimensionally
stable, paintable, and
palatable
35. PPE PBT (+ PC Dialoy X Mitsubishi Rayon Excellent processability,
+ impact BE Dai Nippon Ink high solvent and temperature
modifier) Gemax GE Plastics resistance, and dimensional
stability
Iupiace Mitsubishi Gas
36. PPE PPS DIC PPS Dainippon Ink & The blends are designed for
Chemicals injection molding, but
Iupiace Mitsubishi Gas extrusion, compression
Noryl APS GE Plastics molding, or thermoforming
can also be used. The blends
have to be compatibilized
and contain up to 40 wt%
glass fibers. They show good
compatibilized and contain
up to 40 wt% glass fibers.
They show good
processability, reduced flash,
toughness, and high heat
resistance
(continued)
Appendix II: Examples of Commercial Polymer Blends 2187
Polymer
No. A B Name Supplier Comments
37. PVDF PMMA Polycast Royalite Used for electrets or as
outdoor films with good
clarity and chemical and UV
stability
38. PSF ABS Arylon Uniroyal The blends can be either
Mindel A Amoco Corp. extruded or injection molded.
They show good
processability, toughness,
dimensional stability, high
HDT, hot water resistance,
plateability, and paintability.
The applications include
plumbing, food service, and
fiber optics controlled system
39. PSF PET Mindel B Amoco Corp. The blends can be either
extruded or injection molded.
They show improved
processability and impact
strength, low shrinkage and
warpage, high HDT, good
stress crack chemical and
solvent resistance, and good
economy. The blends find
applications as molded
electrical parts, viz.,
connectors, relays, switches,
motor starters, control
housings, etc.
40. PSF PA Reo-alloy Riken Vinyl Processability, low viscosity,
and low water absorption
41. SMI SAN Malecca A Denka High heat and impact
resistanc
42. SMI ABS Malecca K Denka High heat and impact
resistance
43. SMI PA Malecca N Denka High heat, solvent, and
impact resistance
44. PEEK PES Sumiploy SK Sumitomo Chem. The blends are designed for
injection molding, but
extrusion, compression
molding, or thermoforming
can also be used. SK 1660
grade contains glass fibers.
The materials show good
processability, excellent high
temperature, and chemical
and hot water resistance
(continued)
2188 Appendix II: Examples of Commercial Polymer Blends
Polymer
No. A B Name Supplier Comments
45. PEEK LCP Sumiploy EK Sumitomo Chem. The blends are designed for
injection molding, but
extrusion, compression
molding, or thermoforming
can also be used. They show
good process- ability, high
strength, modulus, and HDT
46. PEI PC Ultem LTX GE Plastics Designed for injection
molding and extrusion.
Processability; HDT;
flexural, tensile, and impact
strength; flame retardancy;
long-term hydrolytic
stability; stain and chemical
resistance; and lower cost
than PEI
47. PI LCP Aurum Mitsui Toatsu Good processability, low
viscosity, HDT, and low
water absorption
48. HIPS Hydrophilic Toray Permanent antistatic
polymer properties
Appendix III: Dictionary of Terms Used in
Polymer Science and Technology
n ¼ 1 m1 m2
I þ M ! IM
IM þ M ! IMM
H H
H CH3
H H
H H
H CH3
gauche trans
Double strand polymer Rigid rod “ladder polymer,” consisting of two parallel
chains of polymer regularly joined by covalent
bonding, viz., pyrrones, polyquinoxalines, and
polyphenylsilsesquioxane.
Double-shot molding A method of producing two-color pieces in thermoplas-
tic materials by successive injection molding operations.
Draft A taper or slope in a mold that facilitates removal of
the molded piece. The opposite of this is called back
draft, q.v.
Drool Melt oozing from a nozzle that is not correctly temper-
ature controlled, or presence of drip on the face of
extruder die.
Drop impact test Impact resistance test in which a predetermined weight
is allowed to fall freely onto the specimen from varying
heights.
Dry as molded (DAM) Term used to describe a part immediately after it is
removed from a mold and allowed cooling down. All
physical, chemical, and electrical property tests are
performed on nonconditioned test bars and the results
recorded on the data sheets. Parts and test bars in this
DAM state are felt to be their weakest in some properties
as they have not had time to condition or relieve the
molded-in stresses.
Dry blend Molding compound containing all necessary ingredients
mixed in a way that produces a dry, free flowing, par-
ticulate material (commonly used for PVC
formulations).
Dry coloring A method commonly used to color plastic by tumble
blending uncolored particles of the plastic material with
selected dyes and pigments.
Dryers Auxiliary equipment used to dry resins before
processing to ensure that surface properties are within
manufacturer specifications. There are several styles of
dryers, including ovens, microwave, hot-air desiccant
bed, and refrigeration types.
Ductility The amount of plastic strain that a material can with-
stand without fracturing, the extent to which a solid
material can be drawn into a thinner cross section with-
out breaking. Also, the ability of material to deform
plastically before fracturing.
Duromer Old German name for thermosets, i.e., strongly cross-
linked, insoluble polymer.
Durometer hardness Measure of the indentation hardness of plastics, usually
understood as hardness measured by the Shore
Appendix III: Dictionary of Terms Used in Polymer Science and Technology 2215
Fan gate A shallow gate somewhat wider than the runner from
which it originates.
Fatigue Permanent structural changes that occur in a material
subjected to fluctuating stress and strain, which cause
decay of mechanical properties. See “S-N diagram.”
Fatigue ductility The ability of a material to plastically deform before
fracturing in constant strain amplitude and low-cycle
fatigue tests. See “S-N diagram.”
Fatigue failure The failure or rupture of a plastic under repeated cyclic
stress, at a point below the normal static breaking
strength. See “S-N diagram.”
Fatigue limit The stress below which a material can be stressed cycli-
cally for an infinite number of times without failure. See
“S-N diagram.”
Fatigue strength Magnitude of fluctuating stress required to cause failure
in a fatigue test specimen after specified number of
cyclic loading – determined from the S-N diagram.
Also the maximum cyclic stress a material can with-
stand for a given number of cycles before failure. The
residual strength after being subjected to fatigue. See
“S-N diagram.”
Feathered thread A thread that is thin at one end and does not end
abruptly. Usually found in screw machine parts.
Feed throat The section of the hopper mounted on the extruder to
feed resin into the feed section of the barrel and screw.
Feedback Information returned to a system or process to maintain
the output within specified limits. See also “Closed loop.”
Fiber Often the term is used synonymously with filament
having a finite length, L ¼ 100d, where the diameter is
typically d ¼ 100–130 mm. In most cases, it is prepared
by drawing from a molten bath, spinning, or depositing
on a substrate. Fibers can be continuous, long
(10–50 mm) or short (about 3 mm). In the plastics
industry almost synonymous with thin strands of glass
used to reinforce both thermoplastic and thermosetting
materials.
Fiber-reinforced plastic A general term for a plastic that is reinforced with cloth,
(FRP) mats, strands, or any other fiber form.
Fiberglass Filaments made by drawing molten glass. Continuous
filaments have indefinite length. Staple fiber mat is made
of glass fibers of the length generally 430 mm, the length
depending on the forming or spinning process used.
Fiberglass Major material used to reinforce plastic, available as
reinforcement mat, roving, fabric, and so forth. It is incorporated into
both thermosets and thermoplastics.
Appendix III: Dictionary of Terms Used in Polymer Science and Technology 2221
Median The middle value when all values are arrayed in order of
magnitude.
Melt fracture An elastic strain set up in a molten polymer as the
polymer flows through the die. It may show up as irreg-
ularities on the surface of the plastic. Several stages (and
different mechanisms responsible for these) are recog-
nized, viz., shark skin, pressure oscillation (or spurt),
and gross distortions.
Melt front The exposed surface of molten resin as it flows into
a mold. The melt front advances as the molten resin is
continuously pushed through its center section.
Melt index (MI), melt The amount in grams of a thermoplastic resin forced
flow index (MFI), or through a 2.10 mm (0.0825 in. orifice when subjected to
melt flow rate (MFR) the prescribed force, e.g., 2.16 kg force during 10 min at
the prescribed temperature ( C) using an extrusion
plastometer (ASTM D1238). It is customary to refer to
the flow rate of polyethylene as “melt index.” However,
for all other materials, the term “melt flow rate” should
be used.
Melt strength The strength of a plastic while in the molten state.
Melt temperature The temperature at which a resin melts or softens and
begins to flow. The temperature of resin melt taken with
a pyrometer melt probe.
Melting point The temperature at which a resin changes from a solid to
a liquid.
Metal plating The process of plating a plastic part by chemically
etching the surface to accept a base metal on which the
subsequent layers of metal are deposited. Usually
a multistep process. Not all plastics can be metallized.
Metallizing A general term used to cover all processes by which
plastics are coated with metal.
Metallocenes Metallo-organic sandwich compounds in which two
cyclopentadienlidene, Cp, rings form a sandwich around
a metallic ion of, e.g., Fe, Co, Ni, Cr, Ti, V, and Zr. They
have been used to catalyze the coordination polymeri-
zation of olefinic or vinylic monomers into highly reg-
ular macromolecules, viz., with narrow molecular
weight, high regularity of comonomer placement,
and/or high tactic purity. For example, ethylene was
catalyzed with R’s(Cp)2MeQ [Me is metal from group
4b, 5b, or 6b (preferably Zr); R’ is a C1–C4 alkylene
radical, a dialkyl germanium, or silicone; Q is an
alkylidene radical having from 1 to about 20 carbon
atoms, s ¼ 0–1, p ¼ 0–2, m ¼ 4–5], in combination
with alumoxanes.
2238 Appendix III: Dictionary of Terms Used in Polymer Science and Technology
Multicavity mold A mold having more than one cavity or impression for
forming finished items during one machine cycle.
Multichain polymer A polymer with more than two chains extending from
a center, e.g., comb or star polymer.
Multiple-screw An extruder machine that has two or more screws, as
extruder contrasted with conventional single-screw extruders.
Nanocomposite (NC) A matrix material (metallic, ceramic, or polymeric in
nature) having dispersed particles, with at least one
dimension that does not exceed 10 nm. Polymeric
nanocomposites (PNC) of commercial interest comprise
2–5 wt% of exfoliated clay.
Necking Localized reduction in cross section that may occur in
a material under tensile loading during a tensile test.
Necking is disregarded in calculation of the engineering
stress, but is taken into account in determining the true
stress.
Network polymer A cross-linked polymer forming infinite network,
obtained in a step-growth polymerization with
multifunctional monomers.
Newtonian fluid An ideal fluid characterized by a constant ration of the
shear stress to the rate of shearing in a simple shear defor-
mation and with zero normal stress difference (nonelastic).
Nondestructive evalua- An analysis to determine whether the material is accept-
tion (NDE) or nonde- able for its function.
structive inspection
(NDI)
Nondestructive inspec- A process or procedure, such as ultrasonic or radio-
tion (NDI) graphic inspection, for determining the quality or char-
acteristics of a material, part, or assembly, without
permanently altering the subject or its properties. Used
to find internal anomalies in a structure without
degrading its properties.
Nonpolar Incapable of having a significant dielectric loss. Poly-
styrene and polyethylene are nonpolar.
Nonreturn valve See “Ball or checking valve.”
Nonrigid plastic A plastic that has a modulus of elasticity (either in
flexure or in tension) of not over 69 MPa (10,000 psi)
at 25 C and 50 % relative humidity (ASTM D747).
Normal distribution See “Gaussian distribution.”
Notch sensitive A plastic material is said to be notch sensitive if it will
break when it has been scratched, notched, or cracked.
Glass is considered to be highly notch sensitive.
Notch sensitivity A measure of reduction in load-carrying ability caused
by stress concentration in a specimen. Brittle plastics are
more notch sensitive than ductile.
Appendix III: Dictionary of Terms Used in Polymer Science and Technology 2243
Packing pressure The pressure applied just before the part cavity fills,
which is about 50 % of the injection pressure required
to continue filling the mold without flashing it. Packing
pressure is maintained until the gate freezes.
Pad See “Cushion.”
Paint line The point where two colors meet.
Paint step Break in a smooth surface that allows a mask to rest.
Parallel to the draw The axis of the cored position or insert parallel to the
up-and-down movement of the mold as it opens and
closes.
Parallels (risers or The support spacers between the mold and press platen
support fillers) or clamping plate.
Pareto analysis An analytical and statistical technique used to determine
part defect type and quantity. Ranks each type of defect
as a percentage of the total number of defects found,
based on the quantity of each type of defect.
Parison Hollow plastic tube from which a part is blow molded.
Part separator A machine or system used to automatically separate
parts from the runner system after molding. Separated
parts go to their next station and the runner moves to
a granulator for reuse if permitted. The system may use
blades, rigid pins, or a degating station with parts placed
by a robot for separation.
Parting agent See “Mold release.”
Parting line The point in the mold where two or more metal surfaces
meet creating a shutoff. Mark on a molding or casting
where halves of a mold met in closing.
Partitioned mold See “Bubbler.”
cooling
Pastel A tint, a tone to which white has been added.
Paucimolecular Polymers that consist of only a few different molecular
weight components. Also called the paucidisperse
polymers.
Peak exothermic The maximum temperature reached by reacting thermo-
temperature setting plastic composition is called peak exothermic
temperature.
Permeability The passage or diffusion of a gas, vapor, liquid, or solid
through a barrier without affecting it. The rate of the
passage.
pH Negative logarithm of concentration of hydrogen ions,
log [H+], a measure of the acidity or alkalinity of
a substance. Acid solutions have pH < 7, at neutrality
pH ¼ 7, and in alkaline solutions pH > 7.
Phase A separate, but not necessarily separable, portion of
a system.
2246 Appendix III: Dictionary of Terms Used in Polymer Science and Technology
Product certification The certificate or letter stating that the material or prod-
uct meets or exceeds customer requirements. Values are
often listed for the tested or measured results. To be
signed by a key representative of the company to verify
accuracy.
Projected surface area The exposed resin area of a mold on the parting line that
transmits the injection pressure on the closed mold
halves. It includes part, runner, and sprue surfaces.
Propagation A series of reaction steps in a chain polymerization in
which the monomers are being added to the active
polymerization center.
Proportional limit The greatest stress that a material is capable of sustain-
ing without deviation from proportionality of stress and
strain (Hooke’s law).
Prototype mold A simplified mold construction often made from a light
metal casting alloy or from an epoxy resin to obtain
information for the final mold and/or part design.
Pseudo-IPN Simultaneous IPN in which one polymer is in network
form and the other linear.
Pultrusion A continuous process for manufacturing composites
that have a constant cross-sectional shape. The
process consists of pulling a fiber-reinforcing mate-
rial through a resin impregnation bath and then
through a shaping die, where the resin is subse-
quently cured.
Purging Cleaning one color or type of material from the
processing machine by forcing it out with the new
color or material to be used in subsequent production.
Special purging materials are also available.
Pyrometer An electrical thermometer for measuring high tempera-
tures. The units come with two probes to measure melt
and surface temperatures.
Quality assurance A separate department established to direct the quality
function of the business areas. Major efforts are directed
to assisting and auditing the activities of the quality
control department in their efforts to ensure that quality
products are manufactured.
Quality circles A quality analysis group consisting of employees with
specific departmental knowledge used to provide sug-
gestions and ways to solve a procedural or manufactur-
ing quality problem. If found acceptable, the group’s
findings and solutions are then passed on to upper man-
agement for implementation.
Quality control (QC) A department set up to be technically involved in the
control of product quality. Involved in the principal
Appendix III: Dictionary of Terms Used in Polymer Science and Technology 2255
Release or parting agent A material that is applied in a thin film to the surface of
a mold to keep the resin from bonding (also mold release
agent).
Relief angle The angle of the cutaway portion of the pinch-off blade
from a line parallel to the pinch-off land. In a mold, the
angle between the pitch-off land and the cutaway
portion adjacent to the pinch-off land.
Repeatability The variation obtained when one person measures the
same quantity several times using the same instrument.
Reprocessed plastic A thermoplastic material, prepared from melt-processed
scrap or reject parts, or from nonstandard or nonuniform
virgin material. The term scrap does not necessarily
connote feedstock that is less desirable or usable than
the virgin material from which it may have been gener-
ated. Reprocessed plastic may or may not be
reformulated by the addition of fillers, plasticizers, sta-
bilizers, or pigments.
Reproducibility The variation in measured averages obtained when sev-
eral persons measure the quantity using the same instru-
ment or when one person measures the quantity using
different instruments.
Residence time Time a resin spends in a given processing machine
(an extruder, injection molding unit, etc.) and is
subjected to heat and stress.
Residence time The distribution of residence time provides information
distribution how long different parts of the resin reside in the
processing equipment. The spread of the residence
times reflects, on the one hand, the uniformity of flow
inside the processing unit and, on the other, the quality
of the product, the degree of mixing, or the extent of
a chemical reaction.
Residual stress The stresses remaining in a plastic part as a result of
thermal or mechanical treatment.
Resin An organic material, usually of high molecular weight,
that tends to flow when subjected to stress. Any of
a large class of synthetic substances that have some of
the properties of natural resin (or rosin) but differ chem-
ically. “Resin” is often used as a general term for poly-
mers or plastics and denotes a class of material. It
usually has a softening or melting range and fractures
conchoidally. Most resins are polymers. Also any of
a class of solid or semisolid organic products of natural
or synthetic origin, generally of high molecular weight
with no definite melting point (also see “Polymer”).
2258 Appendix III: Dictionary of Terms Used in Polymer Science and Technology
Salt and pepper blends Resin blends of different concentrate additives, in pellet
form, mixed with virgin resin to make a different product.
Usually associated with color concentrate blends, that,
when melted and mixed by the injection molding
machine’s screw, yield a uniform colored melt for a part.
SAN An abbreviation for styrene-acrylonitrile copolymers.
Scanning electron Electron microscopy that uses the secondary emission of
microscopy (SEM) electrons from a surface when bombarded with an elec-
tron beam. The main advantage is the depth of field.
Technique in which the surface of a specimen is scanned,
point by point, with a finely focused electron beam.
Image formation is made by detecting the secondary
electrons emitted by the specimen’s surface. Even
though resolution in modern SEM can be as high as
4 nm, the main advantage of SEM over the other micros-
copy techniques is its very large depth of field.
Scanning probe a microscopy technique in which the surface of
microscopy (SPM) a specimen is scanned, point by point, using a very
sharp probe (d ¼ 10 nm). Accurate piezoelectric devices
are utilized to maintain the separation distance between
the lowest atom on the probe tip and the highest atom on
the specimen constant and in the range of 1–100 nm. In
this range of tip-to-sample spacing, phenomena like
tunneling current (scanning tunneling microscopy
(STM)) or interatomic repulsion/attraction (atomic
force microscopy (AFM)) can be used for determining
specimen topography with resolution ranging from
a few microns, down to atomic level.
Scanning transmission a microscopy technique in which an ultrathin specimen
electron microscopy is scanned, point by point, with a finely focused electron
(STEM) beam. Image formation is made by detecting the elec-
trons transmitted through the specimen.
Scrap A product or material that is out of specification to the
point of being unusable.
Screw plasticating See “Injection molding.”
injection molding
Screw The main component of the “reciprocating screw” injec-
tion molding machine. It may have various sizes,
lengths, and compression ratios. It is used to feed, com-
press, melt, and meter the resin for injecting into the
mold cavity. Basically divided into 3 major sections:
feed section, deep screw depths to convey the resin
into the next screw’s section; transition section, gradu-
ally decreasing screw depths when resin is compressed,
forced against the barrel’s surface, and melts; and
2260 Appendix III: Dictionary of Terms Used in Polymer Science and Technology
Shear rate The overall velocity over the cross section of a channel
with which molten polymer layers is gliding along each
other or along the wall in laminar flow. A change of
shear strain within one second.
Shear strain Deformation relative to the reference configuration of
length, area, or volume. Tangent of the angular change,
caused by a force between two lines originally perpen-
dicular to each other through a point in a body is called
angular strain.
Shear strength The maximum shear stress that a material is capable of
sustaining. The maximum load required to shear
a specimen in such a volume manner that the resulting
pieces are completely clear of each other. Shear strength
(engineering) is calculated from the maximum load dur-
ing a shear or torsion test and is based on the original
cross-sectional area of the specimen.
Shear stress Stress developed because of the action of the layers in
the material attempting to glide against or separate in
a parallel direction. In other words, the stress developed
in a polymer melt when the layers in a cross section are
gliding along each other or along the wall of the channel
(in laminar flow).
Shearing Breaking caused by the action of equal and opposed
forces, located in the same plane.
Shelf-life The time a material, such as a molding compound, can
be stored without loss of its original physical or func-
tional properties.
Shore hardness A method of determining the hardness of a plastic mate-
rial using a scleroscope or sclerometer. The device con-
sists of a small conical hammer fitted with a diamond
point and acting in a glass tube. The hammer is made to
strike the material under test and the degree of rebound
is noted on a graduated scale. Generally, the harder the
material, the greater the rebound (ASTM D2240).
Short or short shot A molded part produced when the mold has not been
filled completely.
Shot capacity The maximum volume of material that a machine can
produce from one forward motion of the plunger or
screw.
Shot peening Impacting the surface of the material with hard, small,
round beads of materials to disrupt the surface flatness.
Used to stress relieve welds and to improve the release
of plastic resins on smooth core surfaces.
Shot The yield from one complete molding cycle, including
cull, runner, and flash.
2262 Appendix III: Dictionary of Terms Used in Polymer Science and Technology
h i n o
y ¼ 1=sð2pÞ1=2 exp ½ðx xÞ=s2 =2
Variance s2 ¼ Sðx xÞ=ðN 1Þ
Size exclusion chroma- Recent name for what has been known as gel permeation
tography, SEC chromatography, GPC, q.v.
Skewness The degree to which a distribution is asymmetrical;
negative or positive skewness is observed when the
distribution peak is shifted to the upper or lower side.
Skins See “Flakes.”
Slides Sections of a mold cavity that form complex three-
dimensional parts that must move before the molding
can be ejected. Used to form openings and sections of
parts 90 to the part’s release from the mold cavity.
S-N diagram Plot of stress, S, vs. number of cycles, N, required to
cause failure of similar specimens in fatigue test. Data
for each curve on the S-N diagram are obtained by
determining fatigue life of a number of speci-
mens subjected to various amounts of fluctuating stress.
The stress axis may represent stress amplitude, maxi-
mum stress, or minimum stress. A log scale is usually
used, especially for the N-axis.
Snap fit An assembly of two mating parts, with one or both parts
deflecting under stress, mating the parts together.
Softening temperature Temperature at which amorphous polymer (or the amor-
phous part of crystalline polymer) passes from the hard
glass to the soft elastic or liquid state.
Sol solutions Solutions of macromolecules so diluted that they do not
hinder each other free rotation. The limiting concentra-
tion depends on the hydrodynamic volume of the
macromolecule, usually expressed by the intrinsic
viscosity, [Z].
Solid-state Polymerization of crystalline monomer, usually vinyl,
polymerization using high energy radiation. Topochemical, topotactic,
and canal polymers belong to this group.
Solvent Any substance, but usually a liquid, that dissolves other
substance.
Solvent welding, A method of bonding thermoplastic articles of like
cementing, or bonding materials to each other by using a solvent capable of
softening the surfaces to be bonded. Thermoplastic
materials that can be bonded by this method are ABS,
PA, PC, PS, acrylics, cellulosics, and vinyls.
Solvent casting A process that consists of mixing and dissolving the
ingredients in a suitable carrier that conveys the solution
of “dope” through a drier where the solvent is subse-
quently evaporated; the resulting film is removed from
the substrate surfaces and wound into rolls.
Specific gravity The ratio of the mass of a given volume of a substance to
the mass of an equal volume of a reference substance,
2264 Appendix III: Dictionary of Terms Used in Polymer Science and Technology
C 1 ð T T0 Þ
aT ¼
½C2 þ ðT T0 Þ
References
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H. Batzer, F. Lohse, Einf€uhrung in die makromoleculare (Chemie H€ utingt & Wepf Verlag, Basel,
1976)
J. Brandrup, E.H. Immergut, Polymer Handbook (Intersc Pub, New York, 1966)
P.J. Flory, Statistical Mechanics of Chain Molecules (Intersc Pub, New York, 1969)
J. Frado (ed.), Plastics Engineering Handbook, 4th edn. (Reinhold Pub Corp, New York, 1976)
C.A. Harper (ed.), Handbook of Plastics and Elastomers (McGraw-Hill, New York, 1975)
H.E. Pebly, Glossary of terms in composites, in Engineering Materials Handbook, vol. 1
(ASM International, Ohio, 1987)
2280 Appendix III: Dictionary of Terms Used in Polymer Science and Technology
T.A. Richardson, Industrial Plastics: Theory and Application (Cincinnati, South-Western, 1983)
Standard Abbreviation of Terms Relating to Plastics, D1600, Annual Book of ASTM Standards,
American Society for Testing and Materials
Standard Definitions and Descriptions of Terms Relating to Conditioning, E41, Annual book of
ASTM Standards, American Society for Testing and Materials
Standard Definitions and Descriptions of Terms Relating to Dynamic Mechanical Measurements
on plastics, D4092, Annual book of ASTM Standards, American Society for Testing and
Materials
Standard Definitions and Descriptions of Terms Relating to Methods of Mechanical Testing, E6,
Annual book of ASTM Standards, American Society for Testing and Materials
Standard Definitions and Descriptions of Terms Relating to Plastics, D883, Annual book of
ASTM Standards, American Society for Testing and Materials
Standard Definitions and Descriptions of Terms Relating to Reinforced Plastic Pultruded Prod-
ucts, D3918, Annual book of ASTM Standards, American Society for Testing and Materials
Standard Definitions and Descriptions of Terms Relating to Resinography, E375-75 (reproved in
1986), Annual book of ASTM Standards, American Society for Testing and Materials
Standard Guide for Identification of Plastic Materials, D4000, Annual book of ASTM Standards,
American Society for Testing and Materials
Standard Terminology Relating to Radiation Measurements and Dosimetry, E170, Annual book of
ASTM Standards, American Society for Testing and Materials
J. Thewlis, R.C. Glass, A.R. Meetham (eds.), Encyclopaedic Dictionary of Physics (Pergamon
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L.A. Utracki, Commercial Polymer Blends (Chapman & Hall, London, 1998)
L.A. Utracki, Encyclopaedic Dictionary of Commercial Polymer Blends (ChemTec Pub, Toronto,
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L.R. Whittington, Whittington’s Dictionary of Plastics, 2nd edn. (Technomic, Lancaster, 1978)
Appendix IV: Trade Names of Polymers
and Their Blends
A
A-C Low molecular weight polyethylene, PE Allied-Signal Inc.
A-FAX Amorphous polypropylene, PP Himont
A-fax Polypropylene, PP Himont
A-Tell Polyethylene-p-oxybenzoate for fibers ICI
Abbey #100 Poly(vinyl chloride) compound, PVC Abbey Plastic Corp.
Abbey #400 Polypropylene, PP Abbey Plastic Corp.
Absafil Acrylonitrile-butadiene-styrene terpolymer, ABS Fiberfil/Akzo/DSM
Abson ABS/PVC blends Abtec/BF Goodrich
Abstrene Acrylonitrile-butadiene-styrene terpolymer, ABS Distillers
Accpro Polypropylene blends Amoco Chemical
Acctuf High-impact ethylene-propylene copolymers Amoco Chemical
Acculloy Polymer alloys Aclo Compounders
Accutech Reinforced resins Aclo Compounders
Acetabel Cellulose acetate, CA Ponceblanc
Acetron GP Acetal POM reinforced or not (rods or sheets) Polymer Corp.
Acetron NS Acetal POM. lubricated (rods or sheets) Polymer Corp.
Achieve Metallocene-grade isotactic polypropylene, PP Exxon
Acihr Fluoropolymer film Allied-Signal Inc.
Aclar, Aclon Fluorocarbon PCTFE film Allied-Signal Inc.
Aclyn Low molecular weight EVAc ionomers Allied-Signal Inc.
Acme Epoxy resins and molding compounds Allied Products Corp.
Acpol Acrylic or thermoset polyesters; acrylic/urethane/ Freeman Chem Co.
styrene IPN
Acraldon Ethylene-vinyl acetate copolymer, EVAc Bayer AG
(continued)
Lubricomp A ABS/PTFE or PDMS with 0–30 % glass fiber ICI/LNP Eng. Plastics
Lubricomp Fulton/K POM + 0–25 PTFE, 0–2 % PDMS, filler ICI/LNP Eng. Plastics
Lubriloy Internally lubricated resins ICI/LNP Eng. Plastics
Lucalen Ethylene/acrylic acid/acrylate copolymers, EAA BASF Plastics
Lucalor Chlorinated poly(vinyl chloride), CPVC Elf Atochem
Lucel Polyoxymethylene (acetal), POM S.P.C.I.
Lucite Poly(methyl methacrylate) and copolymers, E. I. du Pont de
PMMA Nemours
Lucky ABS Acrylonitrile-butadiene-styrene terpolymer, ABS Standard Polymers
Lucobit Ethylene copolymer/bitumen blend BASF Plastics
Lucoflex Poly(vinyl chloride), PVC Péchiney, France
Lucolene/Lucorex Poly(vinyl chloride) compounds, PVC Elf Atochem
Lucovyl Poly(vinyl chloride) resin, PVC Elf Atochem Canada
Lucryl Poly(methyl methacrylate), PMMA BASF Plastics
Luparen Polypropylene, PP BASF Plastics
Luphen Phenol-formaldehyde resins, PF BASF Plastics
Lupolen Ethylene-vinyl acetate copolymer, EVAc BASF A.-G.
Lupolen O 250H LDPE blends with polyisobutylene BASF Plastics
Lupolen Polyethylenes: LDPE, LLDPE, MDPE, HDPE BASF Plastics
Lupox Thermoplastic polyesters; reinforced or not S.P.C.I.
Lupoy ABS alloys S.P.C.I.
Lupragen/Lupranat Polyurethanes, PU Elastogran France
Lupranol/Lupraphen Polyurethanes, PU Elastogran France
Luprenal Acrylic resin BASF Plastics
Luran Styrene-acrylonitrile copolymers and blends, BASF Plastics
SAN, ASA
Luran S SAN blended with grafted acrylic ester BASF Plastics
elastomer, ASA, and its blends
Luranyl PPE/styrene-butadiene copolymer blend, BASF Plastics
reinforced with up to 30 wt% glass fiber or not
Lustran ABS, SAN, alloys with PVC, etc. Monsanto Chem. Co.
Lustran ABS Acrylonitrile-butadiene-styrene terpolymer, Monsanto Chem. Co.
ABS, high gloss, general purpose
Lustran Elite ABS, low gloss, high flow grades Monsanto Chem. Co.
Lustran FRABS ABS, flame-retardant grades Monsanto Chem. Co.
Lustran SAN Styrene-acrylonitrile copolymer Monsanto Chem. Co.
Lustran Ultra ABS, for injection molding Monsanto Chem. Co.
Lustrex Polystyrene, PS Monsanto Chem. Co.
Lustropak Acrylonitrile-butadiene-styrene terpolymers, ABS Monsanto Chem. Co.
Lutonal Polyvinyl ethers BASF Plastics
Luvican Polyvinylcarbazole, PVK BASF Plastics
Luvitherm Poly(vinyl chloride) foil, PVC BASF Plastics
Luxis Polyamides, PA-66 Westover Color Chem.
Lycra Diisocyanates/polyether elastomeric fibers E. I. du Pont de
Nemours
Lynex PPE/polyamide blends Asahi Chemical
(continued)
2316 Appendix IV: Trade Names of Polymers and Their Blends
M
M-2014 Thermoset melamine, MF ICI/Fiberite
M-511, M-521 MBS modifiers for PC, PEST, PVC Kaneka
MA 5000 Polystyrene, PS Chevron Chem.
Mablex ABS/polycarbonate alloys Mazzucchelli Cell.
MABS Glass fiber-reinforced ABS Modified Plastics
MAC Glass fiber-reinforced polyoxymethylene, POM Modified Plastics
Macepreg Preimpregnated polyesters Mecelec Holding
Maflex Butadiene-styrene copolymer, SB Sic Plastics France
Magnacomp Polyamide-6 filled with barium ferrite LNP Engineering
Magnum Acrylonitrile-butadiene-styrene terpolymer, ABS Dow Chem. Co.
Makroblend DP Polycarbonate/PET/HDPE alloys; general purpose Bayer AG/Miles, Inc.
Makroblend EC 900 PVC/elastomer, high-impact blends Bayer AG/Miles, Inc.
Makroblend PBT/elastomer Bayer AG/Miles, Inc.
Makroblend PR Polycarbonate/PBT or PET alloys Bayer AG/Miles, Inc.
Makroblend UT Polycarbonate/PET/ABS alloys, filled or not Bayer AG/Miles, Inc.
Makrofol Polycarbonate films, PC or PC/PVF Bayer AG/Miles, Inc.
Makrolon Polycarbonate, PC, and impact-modified PC, Bayer AG/Miles, Inc.
containing <6 % butyl acrylate-methacrylate
elastomer; blends reinforced or not
Malecca SMI blends with ABS or PBT Denki Kagaku
Malon Thermoplastic polyesters MA Industries
Maragla Epoxy resins, EP Acme Div. of Allied
Maranyl Impact modified, PA-66 or PA-6/elastomer ICI Adv. Mater.
blends, mineral filled
Marlex Polyethylenes, PE Phillips 66 Co.
Marlex BMN Polyethylene, PE Phillips 66 Co.
Marlex CL Polyethylene, PE Phillips 66 Co.
Marlex CP Polypropylene, PP Phillips 66 Co.
Marlex EHM Polyethylene, PE Phillips 66 Co.
Marlex ER Mineral-filled polyethylene, PE Phillips 66 Co.
Marlex GP Polypropylene, PP Phillips 66 Co.
Marlex HGL Polypropylene, PP Phillips 66 Co.
Marlex PE Polyethylene, PE Phillips 66 Co.
Marnyte Poly(ethylene terephthalate); glass filled or not, PET Bamberger Polymers
Marvalloy Acrylic-modified polystyrene Marval Industries
Marvylan Poly(vinyl chloride) compounds, PVC L.V.M. France
Marvyloy ABS/poly(vinyl chloride) alloys DSM
MAT-20FG Glass fiber-filled polyoxymethylene, POM Modified Plastics
Mater-Bi Starch-based biodegradable thermoplastics Novamont
MB 1000 Unsaturated polyesters, UP Mar Bal Inc.
MC 2100 Polystyrene, PS Chevron Chem.
MDI Polyurethane, PU Dow
Megarad Polycarbonate, PC Dow Chem. Co.
Megol Elastomeric compounds Polymix
(continued)
Appendix IV: Trade Names of Polymers and Their Blends 2317
N
N05FG Polyamide-6 with 5 % glass fiber, PA-6 Thermofil, Inc.
N15-40NF Polyamide-610 with 40 % graphite fiber, PA-610 Thermofil, Inc.
N3-20FG Polyamide-66 with 20 % glass fiber, PA-66 Thermofil, Inc.
N40fm Polyamide-6 with 40 % glass fiber and mineral Thermofil, Inc.
N40MF Polyamide-6 with 40 % mineral, PA-6 Thermofil, Inc.
N5 PA/ABS alloys containing up to 30 wt% GF Thermofil, Inc.
N6-30MF Polyamide-612 with 30 % mineral, PA-612 Thermofil, Inc.
N66G-30 Polyamide-66 with 30 % glass fiber, PA-66 Polymer Composites
N8-30FG Polyamide-11 with 30 % glass fiber, PA-11 Thermofil, Inc.
N9-30FG Polyamide-12 with 30 % glass fiber, PA-12 Thermofil, Inc.
Nafion Perfluorinated membranes E. I. du Pont de
Nemours
Nalcite Ion-exchange resin National Aluminate
NAP Polyarylate, amorphous; 3,30 , 5,50 -tetramethyl- Kanegafuchi Chem.
dihydroxydiphenylmethane copolymer
Napryl Polypropylene, PP Péchiney, France
NAS 30 Poly(styrene-co-methyl methacrylate), Novacor Chemicals
transparent
NAS 50 Poly(methyl methacrylate-co-styrene), Novacor Chemicals
transparent
Natene Polyethylenes, PE Péchiney, France
Natsyn Polyisoprene Goodyear
Naxell Polycarbonate (recycled) MRC Polymers
Naxols/Naxoreses Polyester resins for paints and varnishes Convert
NCH “Nylon-Clay Hybrid”; polyamide-6 with Ube Industries, Ltd.
montmorillonite particles 0.1–0.2 nm diameter;
nanometer composite developed by Toyota
Research Corp.
Neo Cis Elastomers Enimont/Safic-Alcan
Neo-zex Polyethylenes, PE Mitsui Petrochem.
Neoflon FEP Fluorinated ethylene-propylene, FEP Daikin
Neoflon PCTFE Polychlorotrifluoroethylene, PCTFE Daikin
Neoflon PFE Perfluoroalkoxyether, PFE Daikin
Neoflon PVDF Poly(vinylidene fluoride), PVDF Daikin
Neopolen PE/polypropylene foam BASF Plastics
Neopolen Polystyrene/polyethylene, PS/PE, blend BASF Plastics
Neoprene Polychloroprene, CR E. I. du Pont de
Nemours
Neoprene Synthetic polychloroprene rubber E. I. du Pont de
Nemours
Neosepta F Ionic fluoropolymer membrane Tokoyama Soda
Neoxil Unsaturated polyester resin, UP DSM
Neste Oxo Plastisols, PVC Neste Chim.
Neste Polystyrene Polystyrene, PS Neste Chim.
Neste PP Polypropylene, PP Neste Chim.
(continued)
2320 Appendix IV: Trade Names of Polymers and Their Blends
Newcon Reactor made TPO/PP alloys for car bumpers Chiso Corp.
New TPI Polyimides; reinforced or not, PI S.P.C.I.
Niax Polyether from glycerin or hexane-1,2,6-triol Union Carbide Co.
Nike Cellulose nitrate, CN Punda Inc.
Nipoflex Ethylene-vinyl acetate copolymer Toyo Soda
Niopolon Polyethylene Toyo Soda
Nipeon AL ABS/poly(vinyl chloride) (50 %) alloy Zeon Kasei Co.
Nipol AR Polyacrylate elastomers Nippon Zeon Co., Ltd.
Nipol Carboxylated Nitrile rubbers lightly carboxylated, NBR Nippon Zeon Co., Ltd.
Nipol DP 5120P NBR modifiers for clear PVC Nippon Zeon Co., Ltd.
Nipol Nitrile elastomers, NBR, AN ¼ 21–51 % also Nippon Zeon Co.,
liquids, powders, or crumbs Ltd.
Nipol Polyblends NBR/PVC (30–50 %) elastomeric alloys Nippon Zeon Co.,
plasticized or not Ltd.
Nipol Terpolymer Acrylonitrile-butadiene-isoprene elastomers; Nippon Zeon Co.,
grade DN-224 contains 50 % DOP Ltd.
Nissan 1000–3000 Polyethylenes, PE Nissan Chem. Ind.
Nitriflex Acrylonitrile-butadiene-styrene copolymer, ABS A. Schulman, Inc.
Nitrilene Poly(vinyl chloride)/BR/ABS alloys Rhein Chemie
Nitron Cellulose nitrate, CN Monsanto Chem. Co.
Nitrovin Nitrile or polyurethane rubber/PVC, alloys Vi-Chem Corp.
Nivionplast Polyamides, PA-6, PA-66 ECP Enimont
Polymeri
Nivionplast Polyamide-6, PA-6 EniChem
Noblen Polypropylene, PP Mitsubishi Petrochem.
Noblen Polypropylene; filled or not, PP Sumitomo Chem. Co.
Nolimid 32 Polyimides; for junction coatings, PI Rhône-Poulenc
Nomex Poly(m-phenyleneisophthalamide) fibers, PPA E. I. du Pont de
Nemours
Norasol Polycarboxylate, water soluble Elf Atochem
Norchem Polyethylenes, PE Quantum Chem.
Norchem Polyethylenes, reinforced or not, PE Norchem, Inc.
Norchem Polyolefins: LDPE, HDPE, LLDPE, PP Enron Chem. Co.
Nordbak 7451 Epoxy or polyurethane Rexnord Chem.
Nordel EPDM, hydrocarbon rubbers E. I. du Pont de
Nemours
Norsodyne Polyester resins Norsolor/Please
Norsoflex Polyethylenes: LLDPE and VLLDPE S.F.PE
Norsolene C-9 hydrocarbon resins, PE Elf Atochem
Norsomix Polyester resin compounds Norsolor
Norsophen Phenol-formaldehyde resins, PF Norsolor
Norsorex Polynorbornene elastomers Cyanamid/Atochem/
Nippon Zeon Co.
Nortuff Polypropylene, PP Quantum Chem. Co.
Norvinyl Poly(vinyl chloride), PVC Norsk Hydro/Hydro
PLast
(continued)
Appendix IV: Trade Names of Polymers and Their Blends 2321
Oleflex TPO blend of PE, PP, and a-olefin random Showa Denko K. K.
copolymer.
Olehard Filled polypropylene Chiso America
Ontex ABX, APE PP/EPDM – elastomer/binder blends Dexter Corporation.
Oppanol B Polyisobutylene, PIB BASF Plastics.
Oppanol C Polyvinylisobutyl ether, PVI BASF Plastics.
Oppanol O Isobutylene-styrene copolymer (9:1) BASF Plastics
Oppanol Polyisobutylene, PIB BASF Plastics
Optema Ethylene-maleic anhydride, EMA copolymers Exxon Chem.
Optix Acrylic resins Plaskolite
Opto 90 Epoxy resins, EP ICI/Fiberite
Optum Polypropylene/TPO alloys, reinforced Ferro Corp.
Orevac Ethylene-vinyl acetate copolymers, EVAc Elf Atochem
Orgablend Polyamide/polypropylene recycled alloys, PA/PP Elf Atochem
Orgaflex Polyphosphazene Elf Atochem
Orgalan Polycarbonate, PC Elf Atochem
Orgalloy R 60ES Polypropylene/polyamide-6, CO2, H2O barrier Elf Atochem
Orgalloy R 6000 Polypropylene/polyamide-6 alloys, PP/PA-6 with Elf Atochem
up to 30 wt% GF
Orgalloy R 6600 Polypropylene/polyamide-66 alloys, PP/PA-66 Elf Atochem
Orgamide Polyamide-6, PA-6 Elf Atochem
Orgasol Ultrafine powder polyamides, PA Elf Atochem
Orgater PBT, PBT/EVA/PEBA alloys Elf Atochem
Orlon Polyacrylonitrile, PAN E. I. du Pont de
Nemours
Oroglas Polyacrylates and polymethacrylates Rohm and Haas
OS0100 Epoxy resins, EP Dexter Corp.
OS2000 Epoxy resins, EP Dexter Corp.
Owens-Corning E- Unsaturated polyesters, UP Owens/Corning
Oxy 3700 Poly(vinyl chloride), PVC Occidental Chem.
Corp.
Oxyblend Poly(vinyl chloride), PVC, elastomer blends Occidental Chem.
Corp.
Oxyclear Poly(vinyl chloride) rigid formulation, PVC Occidental Chem.
Corp.
Oxyclear 4190 PVC alloy with glutarimide acrylic copolymer Occidental Chem.
for hot-fill bottles Corp.
Oxyester Polyurethanes, PU H€
uls AG
Oxytuf Poly(vinyl chloride), PVC/EPDM blends Occidental Chem.
Corp.
P
P-2000 Unsaturated polyesters, UP Industrial Dielect.
P-9900- Polypropylene; filled or not, PP Thermofil, Inc.
P-xyBG Polypropylene with xy wt% glass beads, PP Thermofil, Inc.
P-xyCC Polypropylene with xy wt% CaCO3, PP Thermofil, Inc.
P-xyFG Polypropylene with xy wt% glass fibers, PP Thermofil, Inc.
(continued)
2324 Appendix IV: Trade Names of Polymers and Their Blends
Ultem Polyetherimide, PEI, and its blends, e.g., with PC, GE Plastics
TP
Ultem 2000 Polyetherimide with glass fiber, PEI GE Plastics
Ultem 5000 Polyetherimide copolymer, PEI GE Plastics
Ultem 6000 Polyetherimide copolymer, PEI GE Plastics
Ultem 8000 Polyetherimide/polycarbonate alloy, PEI/PC GE Plastics
Ultem LTX PEI/PC blends (unreinforced) GE Plastics
Ultem ATX PEI/PC blends (unreinforced) GE Plastics
Ultem HTX PEI/PPC blends (unreinforced) GE Plastics
Ultem PEI/PPO PEI blends with polyphenylene ether GE Plastics
Ultra-Wear Polyethylene, PE Polymer Corp.
Ultrablend ASA/PBT blend BASF Plastics
Ultrablend KR PET or PBT/PC/elastomer blends BASF Plastics
Ultrablend S PBT/SAN, ABS, or ASA blends, with up to BASF Plastics
30 wt% glass fiber
Ultradur B Poly(butylene terephthalate), PBT, and impact- BASF Plastics
modified PBT
Ultraform Polyoxymethylene, POM, acetal BASF
Ultraform Polyoxymethylene/thermoplastic polyurethane, BASF Plastics
POM/TPU, alloys, with 10–30 wt% TPU
Ultralastic Polyurethane sheet, PU Menasha Corporation
Ultramid A Polyamide-66, PA-66/elastomer, with glass fiber, BASF Plastics
mineral filler or not
Ultramid B Polyamide-6, PA-6/elastomer; with glass fiber, BASF Plastics
mineral filler or not
Ultramid C Copolyamide-6/66, PA-6,66/elastomer; 15 or BASF Plastics
30 wt% mineral filled
Ultramid Lurans Polyamide, PA-66/ASA alloys BASF Plastics
Ultramid PA-6, PA-66, PA-610; blends, reinforced BASF Plastics
Ultramid S Polyamide-610; with glass fiber or not BASF Plastics
Ultramid T Semi-aromatic polyamide-6/66, PA-66 T, or BASF Plastics
PARA with elastomer; 30 wt% glass fiber or
mineral filled
Ultramid Terluran Polyamide, PA-66/ABS alloys BASF Plastics
Ultranyl PA-66/PPE alloys, reinforced or not BASF Plastics
Ultrapas Melamine-based molding compound Dynamit Nobel
Ultrapek Polyaryletherketone, PAEK (PEKEKK, PEK) BASF Plastics
Ultrason E Polyether sulfone, PES BASF
Ultrason S Polysulfone, PSF (or PSO) BASF
Ultrason E Polyethersulfone, 30 wt% glass fiber, PES BASF Plastics
Ultrason Polyethersulfone, PES, alloys BASF Plastics
Ultrason S Polysulfone, 30 wt% glass fiber, PSU BASF Plastics
Ultrastyr OSA SAN-EPDM/ABS or PC alloys ECP Enimont
Polymeri
Ultrastyr Special styrene copolymers ECP Enimont
Polymeri
(continued)
Appendix IV: Trade Names of Polymers and Their Blends 2347
X
X-28057 Epoxy resins with mineral, EP ICI/Fiberite
Xantar Polycarbonate, PC DSM
XB-4000 Polyamide-6 with or without glass, PA-6 Allied Signal Corp.
Xenoy PC/PBT/MBA alloys, reinforced or not GE Plastics
Xenoy 1000, 5000 Polycarbonate, PC:PBT ¼ 1:1 alloys GE Plastics
Xenoy 2000 Polycarbonate, PC/PET/MBA alloys GE Plastics
Xenoy 3000 Polycarbonate, PC/TPE alloy GE Plastics
Xenoy 6125 PET/PC, impact mod.; 0–30 wt% glass fiber GE Plastics
Xenoy DX6302 Polycarbonate/polyester alloy with carbon fiber GE Plastics
XL-030 Polypropylene, PP Aristech Chem.
XP-50 Poly(p-methylstyrene-co-isobutylene)-based Exxon Chem. Co.
compatibilizing system
XT Acrylic-based multipolymer blends Cyro Industries
XT 3055 Polyamide alloys, PA EMS-American Grilon
XT Polymer Acrylic-based transparent, high-impact blend Cyro Industries
Xtcon Polyester/polyurethane hybrid resin Amoco Chem. Co.
XTPE Cross-linkable elastomers and olefins Quality Service
Technology
XTPL NFR-6000 Thermoplastic elastomer, TPE E. I. du Pont de
Nemours
XU TPU/acrylonitrile-butadiene-styrene, ABS alloys Dow Chem. Co.
XU61513 Polyethylene, PE Dow Chem. Co.
Xycon TPEs/TPU alloys Amoco Chem. Co.
Xydar Liquid crystal polymer, LCP Amoco Performance
Products
Xydar FC Liquid crystal polymer, LCP; glass/mineral Amoco Chem. Co.
Xydar FSR-315 Liquid crystal polymer, LCP; 50 % talc Amoco Chem. Co.
Xydar RC Liquid crystal polymer, LCP; glass/mineral Amoco Chem. Co.
Xylok Aralkyl thermoset resins O.F.A.C.I.
Xylon Polyamide-66 with a filler, PA-66 Akzo/DSM
Xyron 200 Poly(phenylene ether) PPE/HIPS alloys Asahi Chem. Ind.
Xyron A Polyamide/PPE/alloys, reinforced or not Asahi Chem. Ind.
Xyron G Polyamide/poly(phenylene ether) PPE alloys Asahi Chem. Ind.
Y
Y-xyFG Polystyrene with xy wt% glass fiber, PS Thermofil, Inc.
Y1-xyFG Polystyrene with xy wt% glass fiber, PS Thermofil, Inc.
Yukalon Polyethylenes, PE Mitsubishi
Petrochem.
Z
Zemid – E. I. du Pont de
Nemours
Zenite Polyamide-66, with glass fiber, PA-66 E. I. du Pont de
Nemours
Zenite Wholly aromatic polyester, LCP, HDT ¼ 295 C E. I. du Pont de
Nemours
(continued)
Appendix IV: Trade Names of Polymers and Their Blends 2353
The following list of commonly used notation and symbols is used in the Encyclo-
pedia. They are based on those listed in American National Standard Abbreviations
for Use on Drawings and in Text (ANSI Yl.l), American National Standard Letter
Symbols for Units in Science and Technology (ANSI Y10), and The Society of
Rheology [J. Rheol., 28, 181 (1984)].
Abbreviations
A Amorphous polymer
a-c Alternating current
abs Absolute
aq Aqueous
av Average
BC Block copolymer
bcc Body-centered cubic
bct Body-centered tetragonal
bp Boiling point
C Crystalline polymer
ca Circa (about as much)
cgs Old units: centimeter-gram-second
CH Centrifugal homogenizer
CMC Critical micelle concentration
conc Concentration
cp Chemically pure
CPC Cloud point curve
cryst Crystalline
CST Critical solution temperature
CTM Cavity transfer mixer
MWD Distribution of MW
mxt Mixture
na Not available
nat Natural
NDB Negatively deviating blends
neg Negative
NG Nucleation-and-growth
NI Notched Izod impact strength
NIRT Notched Izod impact strength at room temperature
nmr Nuclear magnetic resonance
no. Number
NRET Non-radiative energy transfer
NTP Normal temperature and pressure (25 C and 101.3 kPa or 1 atm)
o- Ortho
OD Outside diameter
OM Optical microscopy
p- Para
p-i-n Positive-intrinsic-negative
p., pp. Page, pages
PAB Polymer alloys and blends
PDB Positively deviating blends
Pe Peclet number
pH Negative logarithm of the effective hydrogen ion concentration
phr Concentration in parts per hundred of resin
PICS Pulse-induced critical scattering
pm Partially miscible
pmr Proton magnetic resonance
PNDB Positively and negatively deviating blends (sigmoidal)
pos Positive
ppb Parts per billion (109)
pph Parts per hundred
ppm Parts per million (106)
ppmv Parts per million by volume
ppmwt Parts per million by weight
PRC Particular rheological composition
pt Point; part
pwd Powder
qv Quod vide (which see)
r-f, rf Radio frequency; adj. and n., respectively
rad Radian
rds Rate-determining step
Re Real part of complex function
Ref. Reference
rh Relative humidity
Appendix VI: Notation and Symbols 2365
A Chemical affinity
a Drop curvature
2366 Appendix VI: Notation and Symbols
a, B alpha n, Ν nu
b, Β beta x, X xi
g, G gamma p, P pi
d, D delta r, Ρ rho
e, Ε epsilon s, S sigma
z, Ζ zeta t, Τ tau
Z, Η eta f, (o), F phi
y, (W), Y theta w, Χ chi
k, K kappa c, C psi
l, L lambda o, O omega
m, M mu
g Shear strain
g_ c , g_ y Critical value of g_ for onset of dilatancy or yield
gR Recoverable shear strain
g_ Shear rate
gr(t, s) Recoil strain
g‘(s) Ultimate recoil
D Increment
DEh Activation energy of flow
DGm, DGel Gibbs free energy of mixing and an elastic contribution
DHm Heat of mixing
Dl Thickness of the interphase
d Solubility parameter
« Dielectric parameter
« Tensile Hencky strain
«_ Strain rate ( 0)
«b Maximum Hencky strain at break
«max Maximum filament shrinkage
«r ðt; «_ Þ Tensile recoil function
«‘(sE) Ultimate tensile recoil
«B/«_ B Biaxial strain/strain rate ( 0)
z Correlation length; domain size
h Viscosity
ho Limiting viscosity at zero shear rate, i.e., at the upper Newtonian
plateau
h‘ Limiting viscosity at infinite shear rate, i.e., at the lower Newtonian
plateau
hs Viscosity of solvent or of continuous medium
hr Relative viscosity (/s)
hsp Specific viscosity (r–1)
[h] Intrinsic viscosity
[h]E, [h]E,d Emulsion and deformable droplet emulsion intrinsic viscosity,
respectively
hd, hm Viscosity of dispersed and matrix liquid; also 1, 2, respectively
hi, hsi, hei Interface viscosity and its shear and extensional components
happ Apparent viscosity
ho,M Maxwellian viscosity
h*(v) Complex viscosity
h0 (v) Dynamic viscosity
h00 (v) Out-of-phase component of complex viscosity
h+(t, g) _ Shear stress growth coefficient
h(t, g) _ Shear stress decay coefficient
h+E ðt; «_ Þ Tensile stress growth coefficient
hE– ðt; «_ Þ Tensile stress decay coefficient
Appendix VI: Notation and Symbols 2371
Subscripts
app, a Apparent
B Binodal
E Uniaxial extension
g Glass
i Counting subscript, inversion or dispersed phase
L Linear viscoelastic function
m Mixing, melt, matrix
R Reference variable
S Strain hardening
S Spinodal
s Suspension
y Yield
Superscripts
E Excess value
L Lattice gas model
+ Stress growth function
Decay function
(tilde) Reduced variable
* Complex or reducing variable
Mathematical Symbols
<> Average
P Multiplication
p 3.1415926536
S Summation
Index
A C
Acrylic blends, 1739, 1740, 1785–1789 Carbon nanotube (CNT), 1532–1539,
Acrylonitrile-butadiene-styrene (ABS), 1542–1547
1415–1425 Cavitation, 1214–1216, 1219–1221, 1225,
blends, 1739, 1769, 1774, 1811–1813, 1227, 1230, 1231, 1234, 1236–1241,
1824, 1827, 1852 1243, 1246, 1248, 1252–1257,
Acrylonitrile-styrene-acrylate (ASA) blends, 1845 1260–1263, 1265, 1266, 1271,
Aerospace, 1444–1445, 1454 1273–1275, 1277, 1282–1287
Aging Chain dynamics, 1320, 1326, 1329, 1345
determination of, 1359–1360 Charpy impact, 1054, 1057, 1129
miscible blends, 1371 Chlorinated polyethylene, 1402
two phase systems, 1386 Clay, 1487–1492, 1495–1497, 1500, 1502,
Amorphous, 295–309, 311–315, 318, 319, 1503, 1507, 1509–1513, 1516–1523,
325, 326, 331, 338, 340, 343, 345–347, 1540, 1542, 1546, 1547
349–356, 359, 360, 365–368, 371–411, CNT. See Carbon nanotube (CNT)
418, 420, 431, 434 Coalescence, 761, 768–769, 791, 794,
Applications, 1433–1454 797–799, 801, 802, 805–811, 816, 817,
ASA. See Acrylonitrile-styrene-acrylate (ASA) 821–823, 826–828, 841, 925, 933, 939,
blends 941, 944–945, 948, 954–956, 958, 989,
Automotive, 1435, 1437–1439, 1441, 1011, 1012
1448–1452, 1454 Co-continuous morphology, 879, 889,
Avrami, 325–327, 331, 333–335, 353, 365, 891, 899, 902, 915
380, 392, 426 Co-crystallization, 296, 308, 310, 311,
324, 365, 427, 434
B Co-crystallized polymer blends, 1918,
Barrier films, 1162–1163 2101–2105
Batch, 926, 951, 958, 960–961, 985, 986, Commercial polymer blends, 20, 123
990, 998, 1000, 1011 Commodity polymer resin blends, 71–73
Bent strip ESC test, 1170–1171 Compatibility, 701, 712, 715
Binary blends, 450, 463, 485, 486 Compatibilization, 447–509, 920, 933,
Binary polymer blend, 1330, 1333 942, 946, 997–1011, 1737–1744, 1746,
Biodegradable applications, 1436–1437 1752, 1761, 1773, 1774, 1776, 1778,
Biodegradable polymer blends, 124, 125, 1794, 1801, 1802, 1804, 1810–1812,
129, 527, 1868–1874 1814–1816, 1834, 1837–1839, 1849,
Biomedical, 686, 709, 711–714, 717 1850, 1874, 1902, 1904
Block copolymer, 455–459, 461, 463–465, strategies, 520, 521, 529, 566, 605, 640
470, 471, 481, 485, 488, 490, 492, 494, Compatibilized blends, 1050, 1073, 1091,
498, 502, 503, 505 1103, 1129, 1165–1168
Breakup, 927–934, 937, 944, 945, 955, 956, 978 Compatibilized polymer blend, 522, 529,
Broadband dielectric spectroscopy, 1299–1350 532, 533, 536, 583
Compatibilizer, 521, 523, 529, 530, 532, 533, mechanisms, 1205, 1207, 1212, 1216, 1221,
556, 559, 562, 569, 570, 573, 582, 586, 1225–1227, 1232, 1244, 1252–1288
587, 596, 597, 606–608, 638, 642 Degradation, 1888–1890, 1893, 1895, 1897,
Composition asymmetry, 1344 1899–1902, 1905
Compressive strength, 1039–1040 Determination of Gc, 1058–1061
Concentration fluctuations, 1335–1337, Developing opportunities, 1435–1441
1345, 1348 Dielectric
Concurrent crystallization, 296, 309, relaxation, 1301, 1307–1312, 1320–1348
311, 365, 434 strength, 1144, 1150, 1178, 1304, 1306,
Conduction, 1309, 1312–1313 1311, 1322, 1325–1326, 1346
Conductivity, 1035, 1043, 1105–1107, 1127, Differential scanning calorimetry, 306, 433
1140–1143, 1146–1148, 1179, 1180 Dispersion, 922, 939–942, 945, 946, 948, 950,
Confinement effects, 1301, 1343–1345 952, 954, 956, 961, 967, 977, 987, 989,
Continuous, 922, 926, 944, 956, 958–988, 993, 1006, 1012
990, 998, 1004, 1011 Distribution, 922, 932, 938, 947, 951, 954,
Cooperatively rearranging region, 1324, 1336 956, 960, 964, 968, 975–981,
Copolymer, 942, 943, 950, 962, 985, 989, 984, 997–1001, 1010
992–995, 1004, 1005, 1007–1009 Drop, 921, 926–935, 937–946, 949, 953–958,
addition, 463, 465, 467, 470, 471, 481, 961–963, 989, 1012
484, 487, 491, 498, 501, 506 breakup, 765–768, 799, 804, 806, 807,
characterization, 542, 551, 554, 560, 816, 817
580, 612, 615, 639 Dynamic asymmetry, 1343
formation, 519–521, 528, 531–639, 642 Dynamic glass transition, 1311, 1322–1326,
homopolymer blends, 457–460 1330–1343, 1346
Coupling reaction, 905–906, 911, 912 Dynamic heterogeneity, 1333–1334, 1343,
Cowie-Ferguson (C-F) model, 1365, 1376 1348
Crazing, 1205–1210, 1212, 1213, 1219, 1220,
1225–1227, 1230–1233, 1236, 1238, E
1241, 1245, 1252, 1253, 1263–1269, Elastomeric blends, 1740, 1759–1760,
1273, 1277, 1284–1287 1790–1800
Crosslinks/crosslinking, 680, 686–688, Electrical, 1434, 1438, 1439, 1442, 1446–1450
692, 693, 695–698, 700–702, 704–706, Electronics, 1435, 1439, 1440, 1442,
709, 713, 717 1445–1447, 1449, 1450
Crystalline, 295, 297–312, 314, 324, Elongational flows, 765, 766, 799, 811,
326, 334–336, 340, 341, 344, 355, 815, 816, 847–852
360, 366–374, 376, 378, 379, 382, Encapsulation, 817, 822, 831
383, 386, 390–394, 396, 398, Engineering polymer resin blends, 84
401, 402, 406, 407, 410, 411, 417, 420, Enthalpy, 1464, 1479
422–430 relaxation, 1360–1380, 1386
Crystallization, 291–439, 487, 493–496, 503 Entropy, 173, 174, 176–178, 180, 197,
Crystals, 296, 304, 309, 311–314, 316, 325, 200, 203, 207, 208, 210, 219, 227, 231,
326, 332, 336–340, 344, 345, 347, 348, 239, 267, 1467, 1479
350, 357, 359, 360, 377, 378, 391, 392, Equation of state, 174, 177, 179–187,
399, 411, 412, 415, 416, 422, 423, 426, 189, 204–207, 239, 240, 278
427, 429, 430, 433 Equilibrium melting temperature, 336–340
Curing, 349, 350, 354, 360–365, 434 Experimental determination of interaction
Curing reaction, 892, 895 parameters, 254, 256–262
Experimental techniques for interface, 483
D Extension, 923, 924, 929, 936, 939, 954,
Damping, 686, 705–708, 710, 711, 976, 988
714, 715, 717 Extrusion, 519–521, 525, 526, 530–532,
Deformation, 923–925, 927–929, 931–934, 535, 536, 542–544, 546, 549, 551–553,
936–939, 949, 955, 961, 1002, 1011 555, 558, 560–565, 567, 570–572,
Index 2375