Energy Balance on Separator (V-102)

Stream 19

V-102
Stream17

Stream18
o
Reference state: C24 H51 Al (l), C24 H54 Al O3 (l) at 25 C, 1 atm

Substance Inlet stream 17, T: 300oC, P = 5 bar Outlet stream 18 & 19, T: 220oC, P = 1 bar

ṅin (kmol/hr) Ĥin (kJ/kmol) ṅout (kmol/hr) Ĥout (kJ/kmol)

C24 H51 Al (l) - - 12.8333 Ĥ3

C24 H51 Al (g) 12.9394 Ĥ1 0.1110 Ĥ4

C24 H54 Al O3 (g) 19.1206 Ĥ2 15.7391 Ĥ5

C24 H54 Al O3 (l) - - 3.3867 Ĥ6

Inlet Stream: Stream 17

H1
Path: C24 H51Al (l, 25 oC, 1 atm) C24 H51Al (g, 300oC, 4.93 atm)
H1a H1b

C24 H51Al (l, 126.4oC, 1 atm) C24 H51Al (g, 126.4oC, 1atm)
Hv

Calculation:
126.4
H1a=∫25 1.239 𝑑𝑡 = 125634.6 kJ/kmol

Hv = 0
 300
H1b=∫25 1.239𝑑𝑡 = 340725 kJ/kmol

Ĥ1= H1a + H1b = 466359.6 kJ/kmol

H2
Path: C24 H54 Al O3(l, 25 oC, 1 atm) C24 H54 Al O3 (g, 300oC, 4.93 atm)

H2a H2b

C24 H54 Al O3 (l, 194.7oC, 1 atm) C24 H54 Al O3 (g, 194.7oC, 1atm)
Hv

Calculation:
194.7
H2a=∫25 1.368 𝑑𝑡 = 232149.6 kJ/kmol

300
H2b=∫25 1.368 𝑑𝑡 = 376200 kJ/kmol

Ĥ2= H2a + H2b = 608349.6 kJ/kmol

Outlet Stream: Stream 18

H3
Path: C24 H51 Al (l, 25 oC, 1 atm) C24 H51 Al (l, 220oC, 1.013 atm)

Calculation:
220
H3=∫25 1.239 𝑑𝑡

= 241.605 kJ/mol

= 241605 kJ/kmol

H6
Path: C24 H54 Al O3(l, 25 oC, 1 atm) C24 H54 Al O3(l, 220oC, 1.013 atm)

Calculation:
220
H6=∫25 1.368 𝑑𝑡

= 266.76 kJ/mol

= 266760 kJ/kmol
Outlet Stream: Stream 19
H4
Path: C24 H51Al (l, 25 oC, 1 atm) C24 H51Al (g, 220oC, 1.013 atm)
H4a H4b

C24 H51Al (l, 126.4oC, 1 atm) C24 H51Al (g, 126.4oC, 1atm)
Hv

Calculation:
126.4
H4a=∫25 1.239 𝑑𝑡 = 125634.6 kJ/kmol

Hv = 0
220
H4b=∫25 1.239𝑑𝑡 = 241605 kJ/kmol

Ĥ4= H4a + H4b = 367239.6 kJ/kmol

Path: C24 H54 Al O3(l, 25 oC, 1 atm) H5 C24 H54 Al O3 (g, 220oC, 1.013 atm)
H5a H5b

C24 H54 Al O3(l, 194.7oC, 1 atm) C24 H54 Al O3 (g, 194.7oC, 1atm)
Hv

Calculation:
194.7
H5a=∫25 1.368 𝑑𝑡

= 232.1496 kJ/mol

= 232149.6 kJ/kmol
220
H5b=∫25 1.368 𝑑𝑡

= 266.76 kJ/mol

= 266760 kJ/kmol

Ĥ5= H5a + H5b = 498909.6 kJ/kmol

 Substance Inlet stream 17, T: 300oC, P = 5 bar Outlet stream 18 & 19, T: 220oC, P = 1 bar

ṅin (kmol/hr) Ĥin (kJ/kmol) ṅout (kmol/hr) Ĥout (kJ/kmol)

C24 H51 Al (l) - - 12.8333 241605.0

C24 H51 Al (g) 12.9394 466359.6 0.1110 367239.6

C24 H54 Al O3 (g) 19.1206 608349.6 15.7391 498909.6

C24 H54 Al O3 (l) - - 3.3867 266760.0

Hence,
H Total H Outlet H inlet

= 11897177.22 kJ/hr – 17666422.77 kJ/hr

= -5769245.55kJ/hr