A.

THE TITLE OF EXPERIMENT

Preparation of standard solution KMnO4 and determination the mixture Fe2+
and Fe3+
B. THE OBJECTIVE OF EXPERIMENT
1. Student learn about the preparation of standard solution KMnO4
2. Student learn about the standardization KMnO4 solution
3. Student learn about the determination of the mixture ferro and ferri
C. REVIEW OF LITERATURE
D. APPARATUS AND CHEMICALS
1. Apparatus
a. Analytical balance (1 piece)
b. Watch glass (1 piece)
c. Tripod and asbestos (@ 1 piece)
d. Beaker glass (1 piece)
e. Spiritus burner (1 piece)
f. Stirrer glass (1 piece)
g. Brown bottle (1 piece)
h. Volumetric pipette (1 piece)
i. Burette 50 mL (2 piece)
j. Stative and clamp (@2 piece)
k. Erlenmeyer flask 250 mL (6 piece)
l. Graduated cylinder 25 mL (1 piece)
m. Spray bottle (1 piece)
n. Rough and smooth rag (@1 piece)
o. Matches (1 piece)
2. Chemicals
a. Potassium permanganate (KMnO4)
b. Crystal oxalate acid (C2H2O4)
c. Sulfuric acid 1N (H2SO4)
d. Sulfuric acid concentrated (H2SO4)
e. Hydrochloric acid concentrated (HCl)
f. Tin (II) chloride 5% (SnCl2)
g. Mercury (II) chloride 5% (HgCl2)
h. Aquadest (H2O)
E. WORK PROCEDURES
1. Standardization of KMnO4 solution
a. Weight 0,65 gram of oxalic acid crystal and dissolved it into volumetric flask
100 mL
b. Took oxalic acid solution of 25 mL and then added 5 mL of H2SO4 and heated
until ± 700 C
c. Titrated solution in hot condition with KMnO4 standard solution until the purple
color of drop test permanganate missed
d. Repeat the process of titration up to three times and write the average volume of
titrant
2. Determine constant of Fe2+ and Fe 3+
a. Pipette 25 mL of sample solution and then update 25 mL of H2SO4 in solution
b. Titrated the solution with KMnO4 standard solution until a light purple and write
the average volume of titrant
c. Repeat the process of titration up to three times and write the average volume
of titrant
d. Took 25 mL sample of solution then added 10 mL of concentrated HCl and then
heated until ± 700 C
e. In hot condition added a few drop SnCl2 solution 5% until the solution become
green
f. Cooled the solution as soon possible and added 10 mL of HgCl2 solution 5%. If
from a white AgCl2 precipitate
g. Titrated the solution with KMnO4 standard solution until a light purple and write
the titrant volume
h. Repeat the process of titration up to three times and write the average volume of
titrant
i. Calculated ferrous and ferric contain solution
F. OBSERVATION RESULT
Experiment Activities Result
1. Standardization 0,65 gram oxalate acid+100 mL Purple colorless
of KMnO4 H2O take 25 mL + H2SO4 5mL V1 = 6,05 mL
solution +heated until 700C + titration V2 = 6,40 mL
until 3 minutes V3 = 6,00 mL
Averange = 6,15 mL

2. Determine a. 25 mL sample + 25 mL Browny purple

constant of H2SO4 + Titration until 3 V1 = 4,5 mL
Fe2+ and Fe minutes V2 = 4,3 mL
3+
V3 = 4,6 mL
Averange = 4,4 mL
b. 25 mL sample + 5 mL HCl Browny purple
heated until 700C + SnCl2 3% + V1 = 5,50 mL
HgCl2 5% 10 mL + titration V2 = 5,65 mL
until 3 minutes V1 = 5,70 mL
Averange = 5,62 mL

G. DATA ANALYSIS
1. Standardiization of KMnO4 solution
Known : w C2H3O4 = 0,65 gram
V1 : 6,05 mL
V2 : 6,40 mL
V3 : 6,00 mL