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1007/s11015-015-0080-y
Metallurgist, Vol. 59, Nos. 1–2, May, 2015 (Russian Original Nos. 1–2, January–February, 2015)
Results are given for autoclave leaching of concentrates and mattes from polymetal semiproduct melts
containing arsenic alongside copper. The possibility is demonstrated of selective copper and arsenic
leaching into solution. It is confirmed that with autoclave leaching arsenides are broken down better than
for natural arsenic-containing minerals.
Keywords: leaching, matte, concentrate, copper, arsenic.
The main arsenic-containing minerals in copper ores [1] and concentrates are arsenopyrite (FeAsS) and enargite
(3Cu2S·As2S5 or Cu3AsS4). The proportions of enargite and arsenopyrite in copper concentrates differ in relation to the
deposit [2]. With increased contents (>2.0%) of arsenic within copper concentrates, their pyrometallurgical processing is
connected with contamination of the environment by arsenic compounds and worsening of final copper cathode quality.
Non-traditional pyrometallurgical methods should be used for processing arsenic-containing concentrates, for example,
autoclave leaching.
Tests were performed in a titanium autoclave with a capacity of 1 dm3. An ore copper-arsenic concentrate of the fol-
lowing composition was used, wt.%: 16.8 Cu, 32.2 Fe, 31.4 S, 0.9 Sn, 9.7 As. Its main phases were: chalcopyrite, arsenopy-
rite, enargite, pyrite; approximately 12% copper was represented by secondary sulfides (covellite, bornite). Concentrate size:
83% of fraction 44 μm.
In the first stage, concentrate was treated with acidified copper sulfate solution (180°C; original concentration
10 g/dm3 H2SO4; 16% solid fraction of concentrate in pulp; duration 1.5 h). With an increase in copper sulfate consumption
from 20 to 43 g/dm3 (molar ratio Cu:As = 1.2–2.7), the transfer of iron into the solution increased from 22 to 40%, arsenic
from 4.4 to 26.3%; and with Cu:As > 2.0, the role of copper sulfate consumption appeared to be insignificant. With an
increase in temperature from 140 to 160°C (Cu:As = 1.2; 10 g/dm3 H2SO4; duration 1,5 h), the transfer of arsenic into the
solution increased from 20.6 to 31.5% and iron from 27 to 26%; at 180–200°C, the transfer of iron into solution, and espe-
cially arsenic, decreased to 22.0 and 5–7%, respectively; the copper content in the final solution was markedly reduced. Phase
analysis data for cakes showed that there was a marked increase in the content of chalcosine and iron arsenate. Apparently
with an increase in temperature chalcopyrite becomes an active precipitating agent for copper and strengthens hydrolysis of
arsenic-containing anions and iron (III) sulfate with the formation of insoluble iron arsenate. Favorable results were not given
by an increase in original solution acidity from 5.0.to 53 g/dm3 H2SO4 (180°C, Cu:As = 2.5, duration 1.5 h), the transfer of
iron and arsenic into the solution increased by 7–10%, and the degree of copper deposition decreased by 30%.
In balanced tests (160–180°C, Cu:As = 2.7), not more than 40–42% As and 52–56% Fe passed into the solution, and
up to 62–70% Cu was precipitated; cake composition, %: 37–40 Cu, 16–18 Fe, 27–29 S, 0.6–0.7 Sn. Thus, during hydrothermal
treatment of original concentrate with acidified copper sulfate solution it was impossible to achieve good arsenic extraction
Ural Federal University, Ekaterinburg, Russia; e-mail: neustroev1948@mail.ru, kirill_karimov07@mail.ru. Translated from Metallurg, No. 2,
pp. 72–74, February, 2015. Original article submitted October 8, 2013.
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2. Autoclave leaching of arsenic-containing matte made it possible to separate arsenic and copper with extraction of
copper (by 94.2%) into solution, containing a small impurity concentration and suitable for subsequent processing by tradi-
tional methods (electro-extraction, evaporation). Lead was concentrated within cake that may be processed by lead producers.
3. With treatment of matte with copper sulfate solution, it was possible extract selectively up to 93% of arsenic into
solution.
4. It was confirmed that with autoclave leaching of arsenic-containing materials arsenides appear to be more readily
broken down compared with natural arsenic-containing minerals.
REFERENCES
1. I. E. Makhov, S. V. Mikhailov, L. D. Shishkina, et al., Behavior of Arsenic and Antimony During Pyrometallurgical
Copper Production, TsNIIEItsvetmet, Moscow (1991).
2. R. Padilla, G. Rodriguez, and M. C. Ruiz, “Copper and arsenic dissolution from chalcopyrite-enargite concentrate
by sulfidation and pressure leaching in H2SO4–O2,” Hydrometallurgy, 100, 152–156 (2010).
3. G. V. Skopov and A. V. Matveev, “Combined processing of polymetal semiproducts of metallurgical production,”
Metallurg, No. 8, 73–76 (2011).
4. K. D. Gerlakh and F. E. Pavlek, “Autoclave leaching of speiss,” in: Gidrometallurgiya [Russian translation], Moscow
(1971), pp. 99–114.
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